MATERIAL SAFETY DATA SHEET according to 1907/2006/EC, article 31

Transcription

1 1. Identification of the substance / preparation and of the company 1.1 Identification of the substance / preparation MARTIN Solder paste lead free Finepitch 3 / Super Finepitch 6 rosin based. VD Class III lead free, Sn95,5 Ag4 Cu0,5 VD Class VI (5ml) lead free, Sn96,5 Ag3 Cu0,5 VD Class VI (3ml) lead free, Sn96,5 Ag3 Cu0,5 1.2 Application of the substance / preparation High and low melting point solder pastes for universal application. 1.3 Company/undertaking identification MARTIN GmbH Argelsrieder Feld 1b D Wessling Phone: +49-(0) Fax: +49-(0) Emergency telephone Please contact the nearest poison emergency center. 2. Hazards identification 2.1 Classification of the substance or mixture: Classification according to Regulation (EC) No. 1272/2008 (CLP- Regulation): GHS07 Skin Sens. 1 H317 May cause an allergic skin reaction. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. 2.3 Hazards pictograms GHS Signal word Warning 2.5 Hazard-determining components of labelling Rosin Maleic acid Page 1 of 8

2 2.6 Hazard statements H317 May cause an allergic skin reaction. 2.7 Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P321 Specific treatment (see on this label) P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P302+P352 IF ON SKIN: Wash with plenty of water. P501 Dispose of contents/container in accordance with local /regional /national / international regulations. 2.8 Additional information: 1.5 % of the mixture consists of component(s) of unknown toxicity. 2.9 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. 3.1 Chemical characterization: Mixtures 3. Composition/Information on ingredients 3.2 Description: Mixture of substances listed below with nonhazardous additions. 3.3 Dangerous components: CAS: Rosin EINECS: CAS: EINECS: CAS: EINECS: ~ Skin Sens. 1, H % silver substance with a Community workplace exposure limit % Rosin 3.4 Additional information: For the wording of the listed risk phrases refer to section 16. ~ Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335 2,5% 4. First aid measures 4.1 After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. 4.2 After Skin Contact: Immediately wash with water and soap and rinse thoroughly. 4.3 After eye contact: Rinse opened eye for several minutes under running water. 4.4 After swallowing: If symptoms persist consult doctor. 4.5 Information for doctor Most important symptoms and effects, both acute and delayed Page 2 of 8

3 4.5.2 Indication of any immediate medical attention and special treatment needed 5. Firefighting measures 5.1 Suitable extinguishing agents Use fire extinguishing methods suitable to surrounding conditions. 5.2 Special hazards arising from the substance or mixture: 5.3 Protective equipment: No special measures required 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Not required. 6.2 Environmental precautions Do not allow to enter sewers/ surface or ground water. 6.3 Methods and material for containment and cleaning up Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). 6.4 Additional information See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7.1 Handling 7. Handling and storage Information for safe handling: No special precautions are necessary if used correctly Information about fire - and explosion protection: No special measures required. 7.2 Conditions for safe storage, including any incompatibilities Requirements to be met by storerooms and receptacles: No special requirements Information about storage in one common storage facility Not required Further information on storage conditions: None Specific end use(s) 8. Exposure controls / personal protection 8.1 Additional information about design of technical facilities: No further data; see item 7. Page 3 of 8

4 8.2 Control parameters Ingredients with limit values that require monitoring at the workplace: Rosin WEL Short-term value: 0.15 mg/m³ Long-term value: 0.05 mg/m³ Sen silver WEL Long-term value: 0.1 mg/m³ Additional information: The lists valid during the making were used as basis. 8.3 Personal protective equipment: General protective and hygienic measures: Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work Respiratory protection: Not required Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed Eye Protection: Goggles recommended during refilling 9. Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Pasty Colour: Grey Odour: Characteristic Odour threshold: Not determined. ph-value: Not determined. Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: 100 C Flash point: >100 C Page 4 of 8

5 Flammability (solid, gaseous): Not applicable. Ignition temperature: Decomposition temperature: Not determined. Self-igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Upper: Not determined Not determined Vapour pressure: Not determined Density at 20 C: g/cm³ Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Kinematic: Not determined. Not determined. Solvent content: Organic solvents: 0.0 % Solid content: 93.8 % Other information 10.1 Reactivity 10. Stability and Reactivity 10.2 Chemical stability No decomposition if used according to specifications Possibility of hazardous reactions No dangerous reactions known Conditions to avoid 10.5 Incompatible materials 10.6 Hazardous decomposition products: No dangerous decomposition products known. Page 5 of 8

6 11. Toxicological information 11.1 Acute toxicity: Primary irritant effect: Skin corrosion/irritation No irritant effect Serious eye damage/irritation No irritant effect Respiratory or skin sensitization May cause an allergic skin reaction 11.3 CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) 12.1 Toxicity Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard 12. Ecological information Aquatic toxicity: Persistence and degradability 12.2 Behaviour in environmental systems: Bioaccumulative potential No further relevant information available Mobility in soil No further relevant information available 12.3 General Notes Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system Results of PBT and vpvb assessment PBT: Not applicable vpvb: Not applicable Page 6 of 8

7 12.5 Other adverse effects No further relevant information available 13. Disposal considerations 13.1 Waste treatment methods Must not be disposed together with household garbage. Do not allow product to reach sewage system Uncleaned packaging: Disposal must be made according to official regulations. 14. Transport information UN-Number ADR, IMDG, IATA Void UN proper shipping name ADR, AND, IMDG, IATA Void Transport hazard class(es) ADR, AND, IMDG, IATA dcgclass Void Packing group ADR, IMDG, IATA Void Environmental hazards: No Special precautions for user Not applicable. Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. Transport/Additional information: Not dangerous according to the above specifications UN "Model Regulation": Void 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation Hazard pictograms GHS Signal word Warning Hazard-determining components of labelling Rosin maleic acid Page 7 of 8

8 Hazard statements H317 May cause an allergic skin reaction Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P321 Specific treatment (see on this label) P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P302+P352 IF ON SKIN: Wash with plenty of water. P501 Dispose of contents/container in accordance with local /regional /national / international regulations Directive 2012/18/EU Named dangerous substances - ANNEX I None of the ingredients is listed National regulations Class Share in % III Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16. Other Information The information in this data sheet is based on our present state of knowledge and is provided without warranty of product features and shall not establish a legally valid contractual relationship Relevant phrases H302 Harmful if swallowed. H315 Causes skin irritation. H317 May Causes an allergic skin reaction H319 Causes serious eye irritation H335 May cause respiratory irritation Abbreviations and Acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) ICAO: International Civil Aviation Organization ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) PBT: Persistent, Bioaccumulative and Toxic vpvb: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 Skin Sens 1: Sensitisation Skin, Hazard Category 1 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 Page 8 of 8