Metalworking Fluids. Copyright Croda Europe Ltd All Rights Reserved
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1 Metalworking Fluids
2 Metalworking Fluids Boundary Lubricants/ Lubricity Additives Neat / Straight oils Semi-synthetic oils Synthetics EP/AW Additives Surfactants Fatty Acids and Corrosion inhibitors Self-Emulsifying Esters
3 Boundary Lubricants / Lubricity Additives
4 Neat / Straight Oils Low Viscosity Esters Unit/s Prifer 6813 Priolube 1400 Priolube 1406 Estol 1540 Hydrolytically stable, high volatility petrochemical mono-ester Hydrolytically stable oleochemical mono-ester Hydrolytically stable oleochemical mono-ester High volatility oleochemical mono-ester Viscosity at 40 C mm 2 /s Viscosity at 100 C mm 2 /s Viscosity Index 221 Acid Value (mg KOH/g) Pour Point ºC Flash Point ºC Iodine value g/100g Saponification value (mg KOH/g) Biodegradability OECD 301B % Biodegradable
5 Neat / Straight Oils Low - Medium Viscosity Esters Unit/s Priolube 1415 Estol 1527 Priolube 1935 Priolube 1429 Hydrolytically stable oleochemical mono-ester Oxidatively stable oleochemical polyol ester Oxidatively and hydrolytically stable petrochemical di-ester Polyol oleochemical ester Viscosity at 40 C mm 2 /s Viscosity at 100 C mm 2 /s Viscosity Index Acid Value (mg KOH/g) Pour Point ºC Flash Point ºC Iodine value g/100g Saponification value (mg KOH/g) Biodegradability OECD 301B % Biodegradable
6 Neat / Straight Oils Medium Viscosity Esters Priolube 1808 Priolube 1435 Priolube 1427 Unit/s Oxidatively stable oleochemical polyol ester Oleochemical polyol ester Hydrolytically stable oleochemical polyol ester Viscosity at 40 C mm 2 /s Viscosity at 100 C mm 2 /s Viscosity Index Acid Value (mg KOH/g) Pour Point ºC Flash Point ºC Iodine value g/100g Saponification value (mg KOH/g) Biodegradability OECD 301B % > Biodegradable
7 Neat / Straight Oils High Viscosity Esters Unit/s Priolube 1847 Priolube 1929 Priolube 3986 Oxidatively stable oleochemical complex ester High viscosity, hydrolytically stable oleochemical complex ester High viscosity, hydrolytically stable oleochemical complex ester Viscosity at 40 C mm 2 /s Viscosity at 100 C mm 2 /s Viscosity Index Acid Value (mg KOH/g) Pour Point ºC Flash Point ºC Iodine value g/100g Saponification value (mg KOH/g) Biodegradability OECD 301B % Biodegradable
8 Semi-synthetic oils Low Medium Viscosity Esters Unit/s Priolube 1406 Hydrolytically stable oleochemical mono-ester Priolube 3959 Oxidatively and hydrolytically stable petrochemical di-ester Priolube 1415 Hydrolytically stable oleochemical mono-ester Priolube 1935 Oxidatively and hydrolytically stable petrochemical di-ester Priolube 1936 Oxidatively and hydrolytically stable petrochemical di-ester Viscosity at 40 C mm 2 /s Viscosity at 100 C mm 2 /s Viscosity Index Acid Value (mg KOH/g) Pour Point ºC Flash Point ºC Iodine value g/100g Saponification value (mg KOH/g) Biodegradability OECD 301B % Biodegradable 74
9 Semi-synthetic oils Medium High Viscosity Esters Unit/s Priolube 1808 Oxidatively and hydrolytically stable polyol ester Priolube 1427 Hydrolytically stable polyol ester Priolube 1939 Oxidatively and hydrolyticall y stable trimellitate ester Priolube 1929 High viscosity, hydrolytically stable complex ester Priolube 3986 High viscosity, hydrolyticall y stable complex ester Viscosity at 40 C mm 2 /s Viscosity at 100 C mm 2 /s Viscosity Index Acid Value (mg KOH/g) Pour Point ºC Flash Point ºC Iodine value g/100g Saponification value (mg KOH/g) Biodegradability OECD 301B % > Biodegradable
10 Hydrolytic Stability Acid Value (mgkoh/g) MWF Solution Time (weeks) P1929 / P3986 P1427 P1429 P1435 / vegetable oils P1406 P1415
11 Reichert steel ring steel cylinder 1500 gms weight applied measure wear scar
12 Reichert (Steel Steel) Esters as Boundary Lubricants wear scar (mm2) Reichert Wear (steel) Neat Ester Viscosity of Ester at 40C Mineral Oil Esters
13 Reichert (Steel Steel) Esters as Lubricity Additives Reichert Wear - Steel, Esters as Additives 5% ester in Paraffinic Oil, ISO 32 formulations Oleate Esters TMP Esters High Viscosity Complex Ester Wear (mm2) Viscosity at 40 C of Ester (cst)
14 Synthetics Water Soluble PAGs Unit/s Emkarox VG 130W Emkarox VG 330W Emkarox VG 681W Emkarox HV 20 Emkarox HV 45 Viscosity at 40 C mm 2 /s Viscosity at 100 C mm 2 /s Viscosity Index Pour Point ºC Flash Point ºC
15 EP/AW Additives
16 EP/AW additives Phosphate Esters Monalube 205 Monalube 215 EP Enhancers Priolube 1847, 1929, 3986 high viscosity complex ester which have synergistic EP/AW effect with conventional Sulphur and Phosphorus containing EP additives
17 Phosphate Esters Monalube 205 Monalube 215 Unit/s Phosphate ester Phosphate ester Appearance Clear amber liquid Clear amber liquid Colour Gardner 6 6 Viscosity at 40 C mm 2 /s Acid Value (mg KOH/g) Flash Point ºC > Phosphorous content % ph (10% aqueous) Density at 20ºC g/cm
18 EP Enhamcers High Viscosity Esters Unit/s Priolube 1847 Priolube 1929 Priolube 3986 Oxidatively stable oleochemical complex ester High viscosity, hydrolytically stable oleochemical complex ester High viscosity, hydrolytically stable oleochemical complex ester Viscosity at 40 C mm 2 /s Viscosity at 100 C mm 2 /s Viscosity Index Acid Value (mg KOH/g) Pour Point ºC Flash Point ºC Iodine value g/100g Saponification value (mg KOH/g) Biodegradability OECD 301B % Biodegradable
19 EP Enhancers Neat Oil, Synergy with P Welding Load (N) ball results of Monalube 205 in Vitrea 10 Effect of P Content % P Content in formulation No Ester 5% Ester
20 EP Enhancers Neat Oil, Synergy with Sulphur Welding Load (N) ball results of S containing additives in Vitrea 10 Effect of S Content % S Content in formulation +5% P1427 No Ester +5% P3986 P1929 demonstrates similar performance to P3986
21 Surfactants
22 Non-Ionic Emulsifiers and Other Surfactants (1) Product Description Emulsifiers (HLB) Wetting Agent Detergent Dispersant Foam Control Atlas G1086 POE sorbitol hexaoleate 10 Atlas G1096 POE sorbitol hexaoleate 11 Brij 72 POE-(2)-stearyl alcohol 5 Brij 721 POE-(21)-stearyl alcohol 16 Brij 92V POE-(2)-oleyl alcohol 5 Brij 96V POE-(10)-oleyl alcohol 11 Brij 98V POE-(20)-oleyl alcohol 15 Span 80 Sorbitan monooleate 4 Synperonic 91/6 Synperonic 91/8 Synperonic A2 POE-(6)-synthetic primary C9/C11 alcohol POE-(8)-synthetic primary C9/C11 alcohol POE-(2)-synthetic primary C13/C15 alcohol 6
23 Non-Ionic Emulsifiers and Other Surfactants (2) Product Synperonic A20 Synperonic A7 Description POE-(20)-synthetic primary C13/C15 alcohol POE-(7)-synthetic primary C13/C15 alcohol Emulsifiers (HLB) 16 Wetting Agent Detergent 12 Dispersant Synperonic LF/RA30 Alkoxylated primary alcohol Synperonic NCA850 POE/POP block copolymers Synperonic PE/25R2 POE/POP block copolymers Synperonic PE/L101 POE/POP block copolymers Synperonic PE/L62 POE/POP block copolymers Synperonic PE/L64 POE/POP block copolymers Tween 80 POE-(20)-sorbitan monooleate Tween 85 POE-(20)-sorbitan trioleate Foam Control
24 Fatty Acids (1) Prifac 7901 Prifac 7920 Prifac 7986 Priolene 6900 Priolene 6907 Priolene 6910 Unit/s Distilled fatty acid Distilled fatty acid Distilled fatty acid Oleine Oleine Oleine Appearance Pale yellow paste Yellow solid Yellow paste Pale yellow liquid Pale yellow liquid Pale yellow liquid Acid Value mg/koh/g Titre ºC Iodine value g/100g Saponification value mg/koh/g Boiling Point ºC >200 >200 > Acid composition % C8 6 C10 5 C C C C C18: C18: C Renewability content %
25 Fatty Acids (2) PRIFRAC 2901 PRIFRAC 2906 PRIFRAC 2920 PRIFRAC 2942 PRIFRAC 2960 PRIFRAC 2980 PRIFRAC 2989 PRIFRAC 2990 Unit/s Fractionated Fractionated Fractionated Fractionated Fractionated Fractionated Fractionated Fractionated Appearance Colourless liquid White solid White solid White solid White solid White solid White solid White solid Acid Value mg/koh/g Titre ºC Iodine value g/100g Saponification value mg/koh/g Acid composition % C C C C C C C C22 87 C22:1 91 C22:2 1 C24 2 Renewability content %
26 Corrosion Inhibitors Pripol 1017 Monacor 39 Monacor BE Monacor TEH Polymerised fatty acid Oil soluble corrosion inhibitor with unique multifunctional properties Water soluble corrosion inhibitor Oil soluble corrosion inhibitor with unique multifunctional properties Appearance Unit/s Pale yellow liquid Liquid Clear to slightly hazy viscous liquid Acid Value (mg KOH/g) Alkali No. 36 Iodine value g/100g 118 Saponification value (mg KOH/g) 198 Activity % 100 Ash content mg/kg 0 Monomer % 2 Intermediate % 5 Dimer % 77 Trimer % 20 Renewability content % 100 Liquid
27 Self-Emulsifying Esters
28 Self Emulsifying Esters SEE s are multi-functional and can be used as base fluids and / or emulsifiers Hard Water Stability ( ) x Nonionic Emulsifier Anionic Emulsifier Lubricity Bio-stable Renewable resource Ester Lubricity Anionic Emulsification Waste Treatability
29 Self Emulsifying Esters Physical Properties Priolube 3952 Priolube 3953 Priolube 3955 Acid Value * mg/koh/g Apparent HLB value Saponification value mg/koh/g Iodine value g/100g * For maximum effectiveness, pre-neutralize mixtures containing SEEs prior to combining with water phase Performance Benefits: Bio-stable Exceptional emulsion stability Excellent lubricity properties Readily waste treatable Hard water stable Low foam profile
30 Disclaimer The information in this publication is believed to be accurate and is given in good faith but no representation or warranty as to its completeness or accuracy is made. Suggestions for uses or applications are only opinions. Users are responsible for determining the suitability of these products for their own particular purpose. No representation or warranty, express or implied, is made with respect to information or products including without limitation warranties of merchantability or fitness for a particular purpose or non-infringement of any third party patent or other intellectual property rights including without limit copyright, trademark and designs. Any trademarks identified herein are trademarks of the Croda group of companies.
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