SODIUM SACCHARIN E-954

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1 MATERIAL SAFETY DATA SHEET According to European Regulation 1907/2006 (REACH), European Regulation 1272/2008 (CLP) and European Regulation 453/2010 SODIUM SACCHARIN E-954 Issued: February 2003 Version: 09 (03/12/12) \\server\docs\public\calidad\compartida\i S O\MSDS Compart\Edulcorantes\Sac Na v09 ing.doc Página 1 de 5 1. Identification of the substance/mixture and of the company/undertaking Product identifier: Sodium Saccharin HQ 15% hydrated. Sodium Saccharin HQ 10% hydrated. Sodium Saccharin HQ 6% hydrated and sodium saccharin 6% hydrated powder. Sodium saccharin FG 15% hydrated, and sodium saccharin FG 6% hydrated Relevant identified uses of the substance or mixture and uses advised against: Food Additive Sweetener (E-954), used in food and as an excipient in pharmaceuticals. 1.3.Details of the supplier of the safety data sheet: Productos Aditivos, S.A. Planta: Av. Ferreria, 40. Pol. Ind. La Ferreria E Montcada i Reixac (España) 1.4. Emergency telephone number: Tel.: Fax: Web: National Toxicological Information Service of Spain: Catalonia Emergency Service: Productos Aditivos SA: Hazards identification Classification of the substance or mixture. Not classified as hazardous according to Regulation 1272/ Label elements. No Hazard label required Other hazards. Not classified as PBT (persistent, bioacumulative or toxic), or vpvb (very persistent and very bioacumulative). 3. Composition / Information on components. Name: 1,2-benzoisothiazol-3-(2H)-one 1,1-dioxide, sodium salt. Synonymous: Saccharin, sodium salt of saccharin. Formula: C 7 H 4 NNaO 3 S 2H 2 O (di hydrated form), C 7 H 4 NNaO 3 S 2/3 H 2 O (6% hydrated form). Relative molecular mass: 241 (di hydrated form), 217 (6% hydrated form). Nº CAS: (anhydrous form), EINECS (di hydrated form), (6% hydrated form)

2 \\server\docs\public\calidad\compartida\i S O\MSDS Compart\Edulcorantes\Sac Na v09 ing.doc Página 2 de 5 4. First aid measures Description of first aid measures. Inhalation exposure: An excessive exposure by inhalation is very difficult. In this case, get the person to fresh air. Skin contact: No hazard by skin contact. Wash with water. Eyes contact: Flush with water. Apply topic eyewash if they get irritated. Get medical advise if required. Ingestion: Due to its taste, an excessive exposure is very difficult. If it occurs, give a plenty of water, and induce vomiting. Get medical advice if required Most important symptoms and effects, both acute and delayed. None reported. 4.3 Indication of any immediate medical attention and special treatment needed. As described above. 5. Fire fighting measures Extinguishing media: Water. Foam. Powder. CO Special hazards arising from the substance or mixture: When burning, the product gives off sulphurous and nitrous gases, CO and CO Advice for fire-fighters: Self-containing breathing apparels and fireproof clothes are required. 6. Accidental release measures Personal precautions, protective equipment and emergency y procedures: Wear glasses, gloves and mask for dust Environmental precautions: Collect and send to plant for reprocessing, or incineration according to Point Methods and material for containment and cleaning up: Sweep or vacuum, avoiding dust formation, and wash with water. Send solid wastes to treatment.

3 \\server\docs\public\calidad\compartida\i S O\MSDS Compart\Edulcorantes\Sac Na v09 ing.doc Página 3 de 5 7. Handling and storage Precautions for safe handling: Wear glasses, gloves and masks to avoid dust inhalation Conditions for safe storage, including any incompatibilities: Store at room temperature and dry conditions in a well-closed packaging. Avoid dust formation Specific end use(s): Due its food use, in storage it must be protected from humidity and possible external vectors or pests. Packages must be kept separate from walls and floor. 8. Exposure controls/personal protection Control parameters: Food additive, not applicable Exposure controls: No risk of excessive exposure to a normal product handling. 9. Physical and Chemicals properties. Appearance: White crystals or microcrystalline powder Relative density: 0,6 to 0,8 kg/l Odour: Odourles Flavour: Intensely sweet Solubility: Solubility in water: 1000 g/l al 20ºC, 2540 g/lat 75ºC. Solubility in other products: sparingly soluble in ethanol. ph (10% w/v, 20ºC): 6 to 7,5 Melting point: 226ºC to 230ºC Flammability: no flamable Oxidising properties: No oxiding properties.

4 \\server\docs\public\calidad\compartida\i S O\MSDS Compart\Edulcorantes\Sac Na v09 ing.doc Página 4 de Stability and reactivity Reactivity: The product is not particularly reactive Chemical stability: The product is chemically stable Possibility of hazardous reactions: None reported Conditions to avoid: Avoid suspension of dust in the air Incompatible materials. Avoid contact with strong oxidizing agents, strong acids and nitrites Hazardous decomposition products: See section 5.2 of this document. 11. Toxicological information: 11.1 Information on toxicological effects: No allergic reactions are known. ADI (Acceptable Daily Intake): 5 mg/kg body weight/day as acid saccharin, 6,6 mg/kg body weight/day as sodium saccharin dihydrated, and 5,9 mg/kg body weight/day as sodium saccharin 6% hydrated. 12. Ecological Information Toxicity: No data are available Persistence and degradability: Persistence and degradability: Can be processed in a standard sewage treatment plant, producing CO 2, sulphate and nitrogen derived substances. Other information: COD: 1.8 g O 2 /g sodium saccharin. BOD: 4.33 mg O 2 /g sodium saccharin Bio-accumulative potential: Not bio-accumulative Mobility in soil: Results of PBT and vpvb assessment: 12.6 Other adverse effects.

5 \\server\docs\public\calidad\compartida\i S O\MSDS Compart\Edulcorantes\Sac Na v09 ing.doc Página 5 de Disposal considerations Waste treatment methods: Disposal of the substance: Any applicable regulation must be respected. Can be incinerated in an incineration plant, using a post burning and a collector of sulphurous and nitrous gases. Disposal of the packaging: Any applicable regulation must be respected. Cardboard and plastic packages can be incinerated. Metallic parts of drums must be removed before incinerating. 14. Transport information. The product is not considered hazardous for transport UN number: NA UN proper shipping name: NA Transport hazard class(es): NA Packing group: NA Environmental hazards: No special hazards to the environment Especial precautions for user: No special precautions required by the user. 15. Regulatory information Safety, health and environmental regulations/legislation specific for thr substance or mixture: The substance is a food additive (E-954), approved in the European Union by Regulation 1129/2011/CE and amendments, and included in the European Pharmacopoeia 7 th edition, USP 34 th edition and FCC 7 th edition Chemical safety assessment: 16. Other information. No Applicable: food additive (sweetener E-954). Changes in this version: Adaptation of the safety data sheet to the requirements of Regulation 453/2010 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of this publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release, and is not to be considered as warranty or Quality Specification. The information relates only to the specific material designated and is not valid for such material used in combination with any other materials or in any process.

MATERIAL SAFETY DATA SHEET According to European Regulation 1907/2006 (REACH), European Regulation 1272/2008 (CLP) and European Regulation 453/2010

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