MATERIAL SAFETY DATA SHEET Date : 14/03/2013 Page 1/5
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1 Page 1/5 1 - IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Identification of the substance or preparation: Name: LUBRICANT Product code: NL Company/undertaking identification: Registered company name: VAR. Address: 19 AVENUE GUSTAVE EIFFEL GELLAINVILLE - FRANCE Telephone: +33 (0) Fax: +33 (0) contact@vartools.com Emergency telephone: +33 (0) Association/Organisation: INRS/ORFILA HAZARDS IDENTIFICATION Properties / Symbols: F+ Extremely flammable Xi Irritant N Dangerous for the environment R Phrases: 3 - COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components within the meaning of EEC directive 67/548 and corresponding classification: 60% - 70% hexane, mixture of isomers (containing < 5 % n-hexane ( )) N.67/548/CEE: F,Xn,Xi,N; R % - 20% propane N.67/548/CEE: CAS: EC: % - 7% butane [1] N.67/548/CEE: CAS: EC: % - 5% and isobutane [2] N.67/548/CEE: CAS: EC: FIRST AID MEASURES Contact with skin: Immediately take off all contaminated clothing. Areas of the body that have - or are only even suspected of having - come into contact with the product must be rinsed immediately with plenty of running water and possibly with soap. Contact with eyes: Wash immediately with water for at least 10 minutes.
2 Page 2/5 Swallowing: Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY. A suspension of activated charcoal in water, or liquid paraffin may be administered. Inhalation: Ventilate the premises. The patient is to be removed immediately from the contaminated premises and made to rest in a well ventilated area. Should the patient feel unwell, OBTAIN MEDICAL ATTENTION. 5 - FIRE-FIGHTING MEASURES Recommended extinguishers: In case of fire, use dust fire extinguisher, CO 2 or foam. Extinguishers not to be used: None in particular. Risks arising from combustion: Avoid inhaling the fumes. Protective equipment: Use protection for the respiratory tract. Cool the containers exposed to the fire with water. 6 - ACCIDENTAL RELEASE MEASURES Measures for personal safety: Use a mask, gloves and protective clothing. Environmental measures: Limit leakages with earth or sand. Eliminate all unguarded flames and possible sources of ignition. Do not smoke. If the product has escaped into a water course, into the drainage system, or has contaminated the ground or vegetation, notify the competent authorities. Cleaning methods: Rapidly recover the product. To do so, wear a mask and protective clothing. If the product is in a liquid form, stop it from entering the drainage system. Recover the product for re-use if possible, or for elimination. The product might, where appropriate, be absorbed by inert material. After the product has been recovered, rinse the area and materials involved with water. 7 - HANDLING AND STORAGE Handling precautions: Avoid contact and inhalation of the vapours. See, too, paragraph 8 below. Do not eat or drink while working. Do not smoke while working. Incompatible materials: None in particular. Storage conditions: Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to sunlight. Keep away from flame and sparks. Avoid accumulating electrostatic charge. Instructions as regards storage premises: Cool and adequately ventilated. Safety electric system EXPOSURE CONTROLS / PERSONAL PROTECTION Precautionary measures: Give adequate ventilation to the premises where the product is stored and/or handled. Respiratory protection: Protection for hands: Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
3 Page 3/5 Eye protection: Protection for skin: Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton. Exposure limit(s) (ACGIH): propane VLE short: 1000 ppm TLV TWA: 1000 ppm - 0 mg/m3 butane [1] TLV TWA: 1000 ppm and isobutane [2] VLE short: 1000 ppm TLV TWA: 1000 ppm - 0 mg/m3 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance and colour: Odour: ph: Melting point: Boiling point: Flash point: Solid/gas flammability: Explosive properties: Oxidizing properties: Vapour pressure: Relative density: Solubility in water: Lipid solubility: Partition c. (n-octanol/h2o): Vapour density: Liquid limpid colourless Odourless N.a. <0 C 0,73 gr/ml c.ca Insoluble Total 10 - STABILITY AND REACTIVITY Conditions to avoid: Avoid accumulating electrostatic charge. Substances to avoid: Avoid contact with combustible materials. The product could catch fire. Hazardous decomposition products: It may catch fire on contact with oxidising mineral acids TOXICOLOGICAL INFORMATION The concentration of each substance should be borne in mind in assessing the toxicological effects deriving from the preparation. Set out below is the toxicological information relating to the main substances in the preparation. The product does not contain toxicologically relevant substances 12 - ECOLOGICAL INFORMATION Adopt good working practices, so that the product is not released into the environment. List of substances dangerous for the environment and corresponding classification: 60% - 70% hexane, mixture of isomers (containing < 5 % n-hexane ( )) N.67/548/CEE: DISPOSAL CONSIDERATIONS Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and national regulations currently in force.
4 14. TRANSPORT INFORMATION ADR-Numero ONU: 1950 ADR-Classe: 2 F ADR-Shipping Name: Aerosol with capacity of 1000 cm3 or less ADR-Label: UN 1950 Aerosols ADR-Packing group: III IMDG-Numero ONU: 1950 IMDG-Classe: 2 F IMDG-Shipping Name: Aerosol with capacity of 1000 cm3 or less IMDG-Label: UN 1950 Aerosols IMDG-Packing group: III IMDG-EMS: 2-13 IMDG-MFAG: Subsec IATA-Numero ONU: 1950 IATA-Classe : 2.1 F Page 4/ REGULATORY INFORMATION Council Directive 67/548/EEC (Classification, packaging and labelling of dangerous substances) and subsequent amendments. Council Directive 1999/45/EC (Classification, packaging and labelling of dangerous preparations) and subsequent amendments. Commission Directive 98/24/EC (Protection of the health and safety of workers from the risk related to chemical agent). Commission Directive 2000/39/EC (Occupational exposure limit values). Regulation (EC) No 1907/2006 (REACH). Symbols: Xi Irritant F+ Extremely flammable N Dangerous for the environment R Phrases: S Phrases: S16 Keep away from sources of ignition - No smoking. S29 Do not empty into drains. S33 Take precautionary measures against static discharges. S37 Wear suitable gloves. S43 In case of fire, use dust fire extinguisher, CO 2 or foam. S56 Dispose of this material and its container to hazardous or special waste collection point. S57 Use appropriate container to avoid environmental contamination. S60 This material and its container must be disposed of as hazardous waste. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Special Provisions: Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of reach of children. Where applicable, refer to the following regulatory provisions : Directive 2003/105/CE ('Activities linked to risks of serious accidents') and subsequent amendments. Regulation (EC) nr 648/2004 (detergents). Preparation classification: Irritant Dangerous for the environment Extremely flammable
5 16 - OTHER INFORMATION Page 5/5 Text of R phrases referred to under heading 3: R11 Highly flammable. R65 Harmful: may cause lung damage if swallowed. Main bibliographic sources: ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold ACGIH - Threshold Limit Values edition The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality. It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended. This MSDS cancels and replaces any preceding release.
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