Reworkability of DBA Adhesives. March 2013

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1 Reworkability of DBA Adhesives March 2013

2 Topics DuPont s Philosophy for Rework How to disassemble bonded module - Manual - Automation How to clean residual adhesive - Chemical method - Mechanical method Conclusions 2

3 DuPont s Philosophy for Rework

4 DuPont s Philosophy for Rework DuPont s rework philosophy is to minimize chemicals and adopt Mechanical methods to ensure no chemical damage to the expensive components To ensure mechanical method can be effectively executed with high yield, we have developed adhesive formulation that have a good balance between adhesive properties. In 2009 DuPont commercialized DBA2000 to overcome reworkability issues and compete effectively with OCA. DBA2000 has excellent rework properties, is easy to separate and clean 4

5 DuPont s Rework Process 5

6 DuPont s Rework Process As adoption of LOCA has increased the requirements on the materials and processes have become more stringent Delamination and bonding mura are key concerns and adhesive have been developed to meet these challenges however rework becomes more challenging. DuPont has developed new adhesive to meet these need without scarifying the Mechanical rework philosophy 6

7 Disassemble Bonded Module

8 How to Disassemble Bonded Module - Manual For de bond process a wire is used to separate bonded components, like glass, sensor and LCM. TP Adhesive LCM Wire 8

9 How to Disassemble Bonded Module - Automation De bond process could be designed as an automatic process. The concept is same as manual process. TP Adhesive LCM Wire 9

10 Clean Residual Adhesive

11 Typical Methods to Clean Residual Adhesives Method Component Removal Chemical Soaking Mechanical Roll Up Temperature-Assisted Peel-off Residual adhesive is removed by replacing new POL Put substrate into chemical solvent, then peel-off Peel-off adhesive directly Description Heating or cooling can be adapted to help residual adhesive removal Chemical Soaking Remove POL 12

12 How to Clean Residual Adhesive - Chemical Method Use solvent to soak adhesive for 5~10mins. Adhesives become softer, then use plastic blade to remove residual adhesive. Solvent Clean Cloth Adhesive LCM Plastic Blade Soften Adhesive 13

13 How to Clean Residual Adhesive - Mechanical Solution I For small size panel, residual adhesive can be removed by itself. Use wand to stick adhesive from corner. It is easy to clean due to good cohesion and elongation. 14

14 How to Clean Residual Adhesive - Mechanical Solution II The residual adhesive becomes a more complete structure by recoating with an adhesive with good cohesion, it thus becomes easier to be removed by mechanical force. De-bond Cured adhesive (non-uniform) Recoating Coating uncured adhesive Curing Cured adhesive (uniform surface) 15

15 How to Clean Residual Adhesive - Mechanical Solution III Additional PET film is placed on top of recoating adhesive, so it can assist the mechanical separation by peel off PET film. De-bond Recoating with film Cured adhesive (non-uniform) PET Film Coating uncured adhesive Curing Cured adhesive (uniform surface) 16

16 Rework Tact Time and Yield Below is the rework tact time of a 7 TP-to-LCM boning panel from DuPont internal bonding operation experience as well as working together with adhesive customers. Method Tact time for 7" LCM (min.) 25 o C 65 o C Notes Chemical Solvent might damage human body It takes longer time to react with adhesive The surface will remain microscale adhesive and need alcohol to clean. Mechanical I 10 <10 Good for small size panel Mechanical II Fixture needed. Mechanical III Need to find out proper PET film for different LCM Fixture needed. The typical rework LCM yield rate from our customers is in the range of 85%~95% depending on the design. 17

17 Conclusions

18 Conclusions DuPont had adopted a philosophy of avoiding chemicals and adopting Mechanical method s for rework DuPont has formulated Vertak adhesive to meet high bonding yield and good reworkability requirements by having better mechanical properties while maintaining good adhesion property DuPont Vertak adhesive has proven to work well with customers real commercial rework process whether adopting chemical or mechanical methods. Tact time can be half of traditional solvent soaking and rework yields can be as high as 95%. 19

19

20 Appendix- How to accelerate rework process

21 How to Accelerate Rework Process- Temperature To increase temperature will soften adhesive and it could accelerate rework process when using mechanical force. Therefore, putting debonded LCM on hot plate could get higher temperature. Temperature 25C 65C Tact time of 7 LCM 30mins 25mins 22

22 How to Accelerate Rework Process- Tooling Tooling is a key factor to get more efficient rework process. Design proper tooling, - Fixture for automation machine - Holder for constrain substrates - Tool for increasing efficiency of mechanical force Fixture Holder Proper Glove 23

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