SUNJIN Part 4: Skin Care SINCE 1978

Transcription

1 SUNJIN Part 4: Skin Care SINCE 1978 THE 10 TH Edition 2 SUNJIN Members in Company overview 5 Skin Care with Micro Beads inside 6 Micro Beads are commonly used in Skin Cares, Why? April 2012 (1) Instant Whitening Agent 8 Skin Whitening: Instant Whitening 10 SUNSIL T in NaturalWhite(CO) TiO 2 containing Silica Bead 12 Instant Whitening Cream (2) Soft Focus Agent 14 What is Soft Focus? 18 SH219 High Refractive Index Silica Bead Refractive Index: Primer (3) Skin Brightener 21 Use of Pearlescent for Skin Care 22 JH-Series PMMA coated Pearl Satin Pearl for Skin Care 23 Moisturizing Essence (4) Cushion feel and Elastic Bead 27 Elastic Skin: Instant Anti-Wrinkle 28 SUNPU 170 Urethane Elastomer Bead 29 Anti-wrinkle Cream (5) Controlled Release Carrier 31 Porous PMMA Beads: Advantages of micro porous bead system 33 Porous PMMA As Controlled Release Carrier 35 FP Powders Porous PMMA with actives loaded inside 36 Sun Protect Gel (6) Silica Beads 40 Silica Bead Surface Treated Silica Bead 42 Silica Bead for Skin Care : Thickener compatible Sebum Control Essence 43 Velvet Feel Body Lotion (7) PMMA Beads 45 PMMA Beads for Skin Care

2 SUNJIN MEMBERS in 2012 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 2

3 INTRODUCTION COMPANY OVERVIEW Founded in 1978 Headquartered in Korea Product Category: Cosmetic Raw Materials, Surfactants, Paint & Coating Raw Materials, Plastic, Optical Materials ISO 9001 certified TECHNOLOGY OVERVIEW Micro bead synthesis Nano powder synthesis Encapsulation & Composition Surface treatment Dispersion Organic synthesis hollow porous nano & micro encapsulation solid nano & micro Triple composition SUNJIN brings new concepts & new technologies From other industries TO COSMETICS Paint & coating Flat Panel Display: LCD, PDP Plastic Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 3

4 Micro Bead for Skin Care

5 Skin Care with Micro Beads inside An Anti Wrinkle Cream Refining Cream and fluid Skin is relaxed, smoothed, visibly re-plumped, transformed! Ultra-comfort textures, oil free light fluid 3um PMMA Bead 12% An Whitening Cream Power Whitening Essence Now, shatter the look of dark spots with pinpoint accuracy this silky opalescent serum helps prevent future discoloration 3um Silica 5% An Anti Wrinkle Cream Correcting serum for Lines/Wrinkles/Age Spot Instantly see up to a 29% reduction in fine, dry lines. Skin is luminous. 13um Urethane Bead 20% An Eye Care Cream Visibly Rejuvenating Eye Care Bags and dark circles are less visible. wrinkles are diminished and the eye area looks visibly younger. 4um Silica 2.86% A Night Cream Anti-Age Retexturing Night Cream Ultra-nourishing renewal night cream 8um Urethane Bead 4% A Moisturizer For Oily Skin Active Anti-Shine Moisturizer A unique formula that absorbs and regulates excess shine 8um Silica 3.58% A Radiance Cream Maximum Radiance Cream skin care gets skin glowing, revealing its original radiance, maximize luminosity. 5um Silica 2.53% A Sun Screen Cream UV essential SPF45, PA+++ Daily protection fluid for face. This high protection skincare products has a wonderfully soft texture. It offers a velvety, powdery, sheer finish. 4um PMMA 2% A Hydration Cream Moisturizing Body Lotion instantly enhances the skin. spherical powders for a unique powdery cotton tactile effect. 15um Silica 3.92% Fill lines and wrinkles; microspheres help fill creases for a smoother look Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 5

6 Micro Beads are commonly used in Skin Cares, Why? If you don t use micro beads, Then Cosmetic texture may be too tacky & oily 1) Sensorial Modification Reduce too much tackiness Modification of Texture Elegant feeling Micro Beads can alter tactile qualities of a cosmetic: initial contact, application, after feel 2) Optical Effects Soft Focus effect, optical blurring Matte look 3) Absorption, Release & Delivery Sebum, oil absorption Slow release Loading active ingredients Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 6

7 SUNSIL TinNatural White Instant Whitening Agent

8 Skin Whitening Instant Whitening provides immediate and visible whitening effect Skin Whitening has been very big in Asia traditionally. Skin Whitening is getting bigger for men. For men and women, White skin often symbolizes social status. Naturally market competition has been very fierce. How to differentiate your products? Also Whitening takes time 4 weeks? 2 months? 3 months? So users must use a whitening care consistently, sincerely and happily over time. Otherwise, users rarely see real whitening effect Instant Whitening Agent can diminishes the look of darkness and wrinkles and provides brighter and smoother skin tone How to convince your users to continue to apply regularly to finally see the real whitening effect? To See is To Believe. INSTANT WHITENING! Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 8

9 Titanium Dioxide TiO2 is a natural Instant Whitening agent but needs to be improved TiO2, Natural earth mineral that protects skin from both UVA and UVB radiation without irritating skin, also as Instant Whitening Agent provides good coverage of skin imperfections, e.g., pores and uneven skin tone, while retaining a natural skin appearance. provides a more immediate improvement in the appearance of fine lines, wrinkles, pores and other forms of undesirable skin surface texture. provides a white appearance to the emulsion as an opacifying agent However, TiO2 may result in unacceptable skin whitening or other unnatural appearance, or unpleasant harsh and draggy feel when used in amounts which are esthetically acceptable to consumers. Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 9

10 Titanium Dioxide in Silica Bead SUNSIL Tin NaturalWhite 5um Silica Bead With 200nm TiO 2 by 35% 200nm TiO 2 TiO 2 TiO 2 Marketing claims of NaturalWhite Even skin tone Provide good coverage of skin imperfections while retaining a natural skin appearance Natural way to milky, translucent skin Can be an opacifying agent to provide a white appearance to the emulsion NaturalWhite does not suffer from unacceptable skin whitening. TiO 2 Grade Descriptions Surface Treatment SUNSIL-T in NaturalWhite(CO) 200nm TiO2 35% & Silica 65% TiO 2 Hydrogen Dimethicone Avg. Particle size(μm) 5 While TiO2 causes Too much whitening Too harshness TiO2 settles down(i.e TiO2 is very difficult to disperse so often cause separation of formula) SUNSIL-T in UVAB 200nm TiO2 35% & Silica 65% none 5 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 10

11 Natural White Bead for Natural Whiteness for Skin Care & Natural Coverage for Color Silica Bead TiO 2 SUNSIL Tin NaturalWhite(CO) TiO2 core for natural instant whitening effect Silica shell for Good spread Silky feel And better dispersibility in cosmetic media Good spread Silky feel + = Covering power of pigmentary TiO 2 (200nm) 5um Silica Bead With 200nm TiO 2 by 35% Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 11

12 Instant Whitening Effect for Whitening Cream SJF-0804-Whitening Cream-ver 1.1 Phase No. Trade Name % 1 D.I-WATER B.G 1.00 A 3 Glycerin Allantoin TEA Rheodol AO Rheodol TW-S Rheodol MS TEGOSOFT DEC 4.00 B 10 KALCOHL EMERSOL TCG-M TSF C 14 1% CARBOPOL SUNSIL Tin NaturalWhite provides good coverage of skin imperfections while retaining a generally natural appearance, e.g., without unacceptable skin whitening as TiO2 is predispersed inside silica bead for immediate visual improvement in skin appearance. desirable coverage of skin imperfections such as pores and uneven skin tone, while maintaining a natural skin appearance (e.g., without unacceptable skin whitening). regulating skin appearance and/or condition, especially regulating textural or tonal discontinuities in skin (e.g., pores, fine lines, wrinkles, uneven skin color). D 15 SEPIGEL E 16 NA-HYALUNOLATE (1%) 2.00 F G 17 D.I-WATER ARBUTIN FRAGRANCE ` Phenoxyethanol 0.5 H 22 SUNSIL-TinUVAB 3.00 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 12

13 High R.I. Silica Bead: SH219 Soft Focusing Agent

14 What is Soft Focus? Soft focus powder possesses the ability to blur skin troubles such as wrinkles. Wrinkles on the skin are perceptible though the contrast of light and dark that accentuates even very subtle creases. In photography, soft focus is a lens flaw, in which the lens forms images that are blurred due to spherical aberration. A soft focus lens deliberately introduces spherical aberration in order to give the appearance of blurring the image while retaining sharp edges The soft focus effect is used as an effect for glamour photography, because the effect eliminates blemishes, and in general produces a dream-like image. Hard Focus Soft Focus Instead of covering the trouble area by highly opaque materials such as TiO 2, soft focus powder diffuses optical light within the structures. Soft focus powder does not produce whiteness, but rather natural translucent finish Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 14

15 Marketing Claims of Soft Focus in Skin Care Marketing Claims of SOFT FOCUS Micro beads are widely used in skin care for soft focus effect Less visible. Visibly younger. Light diffusers help hind imperfections to help brighten eyes When applied, immediately and visibly smoothed Instantly fine lines reduced The look of lines and wrinkles is significantly reduced Diminishes the look of darkness and wrinkles for highly defined luminosity around the eyes Notice immediately brighter, smoother eyes. Darkness and shadows diminish and eyes appear more luminous Delivers intensive anti-wrinkle action to help reduce the depths of lines and crow's feet Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 15

16 Skin Care with Micro Beads inside An Anti Wrinkle Cream Refining Cream and fluid Skin is relaxed, smoothed, visibly re-plumped, transformed! Ultra-comfort textures, oil free light fluid 3um PMMA Bead 12% An Whitening Cream Power Whitening Essence Now, shatter the look of dark spots with pinpoint accuracy this silky opalescent serum helps prevent future discoloration 3um Silica 5% An Anti Wrinkle Cream Correcting serum for Lines/Wrinkles/Age Spot Instantly see up to a 29% reduction in fine, dry lines. Skin is luminous. 13um Urethane Bead 20% An Eye Care Cream Visibly Rejuvenating Eye Care Bags and dark circles are less visible. wrinkles are diminished and the eye area looks visibly younger. 4um Silica 2.86% A Night Cream Anti-Age Retexturing Night Cream Ultra-nourishing renewal night cream 8um Urethane Bead 4% A Moisturizer For Oily Skin Active Anti-Shine Moisturizer A unique formula that absorbs and regulates excess shine 8um Silica 3.58% A Radiance Cream Maximum Radiance Cream skin care gets skin glowing, revealing its original radiance, maximize luminosity. 5um Silica 2.53% A Sun Screen Cream UV essential SPF45, PA+++ Daily protection fluid for face. This high protection skincare products has a wonderfully soft texture. It offers a velvety, powdery, sheer finish. 4um PMMA 2% A Hydration Cream Moisturizing Body Lotion instantly enhances the skin. spherical powders for a unique powdery cotton tactile effect. 15um Silica 3.92% Fill lines and wrinkles; microspheres help fill creases for a smoother look Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 16

17 How to Soft Focus effectively? Fresnel Loss When light rays cross the boundary from one medium t another, there is a loss due to reflection at the boundary, this is called Fresnel loss and is calculated with the following expression Fresnel Loss = 100*(Rm-Rp) 2 /(Rm+Rp) 2 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 17

18 High Refractive Index Bead with the refractive index of 1.8 5um Silica With 12nm TiO 2 Grade Composition (Silica/TiO2) Refractive Index Surface treatment Silica Bead size / TiO2 crystal size 12nm TiO 2 SH219 Silica 75% TiO2 25% 1.8 none 2~7μm / 12nm SH219-AS Silica 75% TiO2 25% 1.8 Alkyl silane 2~7μm / 12nm Refractive Index Of cosmetic powders RI=1.8 2% SH219 5% Urethane Bead PU170 RI= : Silicone 1.47: Silica 1.49: PMMA 1.51: Glass, CaCO : Urethane 1.53: Alumina: 1.56: Talc, Mica 1.63: BaSO 4 4% 6% 8% 10% 15% 20% Looks like 4% of SH : SH : ZnO RI=1.47 5% 10% Silica Bead: 130L 5% 10% PMMA Bead PMMA-S RI= : TiO2 anatase 2.7: TiO2 rutile 15% 15% 20% 20% Looks like 3% of SH219 Looks like 5% of SH219 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 18

19 SH219: Applications Best recommend for (1) O/W skin care Anti Wrinkle Cream Eye Care SJF-0801-Primer-ver.1.0 Phase No. Trade Name INCI Name % 1 Water Water A 2 Glycerin Glycerin KF6100 Polyglyceryl-3Disiloxane Dimethicone 1.00 B 4 Phenoxy Ethanol Phenoxy Ethanol TSF405 Cyclopentasiloxane KSG16 Dimethicone/Dimethicone Crosspolymer C 7 Sepigel305 Polyacrylamide/C13-C14 Isoparaffin/Laureth D 8 SH219 Silica/ Titanium dioxide 7.50 (2) Primer Primer Transparent foundation Primer What is Primer? Foundation primer is a relatively new product offered on the market. It creates a barrier between your skin & the foundation and helps the foundation go on smoothly. it actually works much like a moisturizer under your foundation does: they ease the application of foundation and are meant to create a barrier between foundation and skin. Makeup artists swear primers go one step further than moisturizers: They'll even out skin tone, help your makeup stay on longer Marketing Claims of Primers Going make-up free Skin look smoother and more even-toned on my make-up free days Primer primarily meant to mattify Oil free moisturizer Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 19

20 JH Series Skin Brightener

21 Luminous Skin Pearlescent acts like a micro mirror on skin Reflecting lights so skin looks brighter Radiance Cream Pearlescent In Skin Care UV moisturizer MARKETING CLAIMS of use of pearlescent Your skin glowing and looking natural bright and radiant instantly brightening the skin Whitening Gel Essence Eye Lifting Serum The pearl tone provides your skin with a luminous quality Runway gleam you will look resplendent in 60 seconds Tired skin look awake and alive Visual effect of Interference Pearl based on light wavelength Blue spectrum(450~495nm) whitens skin Green spectrum(495~570nm) cleans skin Gold spectrum(570~590nm) for luxury skin Red spectrum(620~720nm) for healthy skin tone Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 21

22 JH RED, Lower specula reflection & Less color change on viewing angle Subtle pearlescent sheen to your skin Radiance without shine Satin Effect with lower specula reflection & less saturated colored reflection Grade Composition Avg. Particle size (μm) JH-Red JH-Gold JH-Blue NEW PMMA 40%, Mica/TiO2 60% PMMA 40%, Mica/TiO2 60% PMMA 40%, Mica/TiO2 60% 20~30 20~30 20~30 Radiant but not flashy Polymethyl Methacrylate (And) Mica (And) Titanium Dioxide Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 22

23 PMMA coated SATIN Pearl makes Skin Imperfections Less Noticeable JH series are specially developed for skin care for skin brightening effect without too much sparkling luster Pearl: Strong specula reflection JH series: Reduced specula reflection NOT Flashy Flashy interference Pearl Luster Pearl Light reflection Amplify skin imperfection light is reflected at certain angles and the edges of the wrinkles are emphasized Good for Point make-up Satin Pearl Low Luster Pearl Radiance Natural skin tone Light transmitting & scattering Reduce contrast, less visible skin imperfection Reduced color travel with viewing angle Good for skin care & base make-up Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 23

24 JH Series: Applications Best recommend for (1) Skin Care natural radiance skin brightening to skin care (2) Sun Care Skin Brightening effect Counter balance any whitening / dull appearance that can be created by the mineral UV filters. Instant natural glow effect provided by: Gives a more natural looking brightening effect compared to traditional pearls (less shiny) (3) Liquid Foundation satin pearl effect. Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 24

25 JH RED & BLUE for Skin Brightener JH-BLUE minimizing yellow skin tone Whitening Cream SJF-1125-Moisturizing Essence With JH-Series-ver.1.0 No. Trade Name % % 1 WATER JH-RED Maximizing vivid pink lively skin tone Radiance Cream A B C D 2 CARBOPOL GLYCERIN ALLANTOIN SODIUM HYALURONATE (1%) WATER TEA SEPIPLUS PHENOXYETHANOL FRAGRANCE JH-RED JH-BLUE Visual effect of Interference Pearl based on light wavelength Blue spectrum(450~495nm) whitens skin Green spectrum(495~570nm) cleans skin Gold spectrum(570~590nm) for luxury skin Red spectrum(620~720nm) for healthy skin tone Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 25

26 Urethane Elastomer Bead: SUNPU 170 Cushion Feel Elastic Touch

27 Elastic Urethane Elastomer Bead Marketing Claims of anti wrinkle cream The density, elasticity and firmness of your skin are preserved Fine lines are smoothed out Skin is left feeling velvety smooth As we age, our skin cell turnover rate slows down. new skin cells may take as long as days to appear Elastin and collagen fibers, which provide skin s Elasticity, break down. Skin loses its ability to retain protective moisture The dermis, or inner skin starts to thin. Skin may become dry and scaly skin gradually loses its elasticity, resulting in wrinkles and sagging. Collagen and elastin are two skin proteins that greatly determine elasticity levels, which makes them the primary focus of all efforts to help skin regain elasticity. As you begin to age, the natural stores of these important proteins in your body diminish, making skin appear more thin and saggy than in years past. To help skin gain elasticity, what is needed is a means to stimulate your skin cells' natural production of these essential proteins But regaining of skin elasticity takes time 4 weeks? 2 months? 3 months? So users must use a whitening care consistently, sincerely and happily over time. Otherwise, users rarely see real effect. How to convince your users to continue to apply regularly to finally see the real effect? To Touch is To Believe. Urethane Elastomer Bead for Elastic Feel & Touch Copyright 2011 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 27

28 Elastic Urethane Bead 37.5% Grade Descriptions Avg. Particle size(μm) Hardness SUNPU-170 Urethane bead 14~20 soft Recovery Rate 0% 6.0% 10.24% 8.71% 0% 925 Chemical Name: Hexamethylene Diisocyanate/Trimethylol Hexyllactone Crosspolymer & Silica INCI Name: HDI/Trimethylol Hexyllactone Crosspolymer & Silica Best recommend for premium skin care K value (A) is an unstressed polymer; (B) is the same polymer under stress. When the stress is removed, it will return to the A configuration. (The dots represent cross-links) Copyright 2011 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 28

29 Application of Elastic Urethane Bead: Skin Care SJF-0811-Anti Wrinkle Cream-ver.1.0 Urethane Bead is an excellent choice for skin care application due to its unique optical blurring effect and elegant texture Phase No. Trade Name INCI Name % A B 1 D.I. Water Water Adenosine Adenosine Glycerin Glycerin 4 4 KF6100 Polyglyceryl-3Disiloxane Dimethicone Phenoxy Ethanol Phenoxy Ethanol TSF405 Cyclopentasiloxane KSG16 Dimethicone/Vinyl Dimethicone Crosspolymer 26 C 8 Sepigel305 Polyacrylamide/C13-C14 Isoparaffin/Laureth D 9 Tocopheryl Acetate E 10 SUNPU-170 Tocopheryl Acetate 0.2 HDI/Trimethylol Hexyllactone Crosspolymer /Silica 20 Elegant & Elastic Luxurious Texture Copyright 2011 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 29

30 Controlled Release Carrier Porous PMMA Bead

31 Controlled Release of Drugs Controlled release of actives Extend the efficacy Lessen the irritation Porous PMMA Micro Porous PMMA Bead system For controlled release of active ingredient Is composed of porous PMMA beads with large porous surface, of particle size 8um in diameter Loaded with active pharmaceutical ingredient can entrap a wide variety of substances and can be incorporated into a formulation for a sustained rate of release of the active ingredients to skin over time Micro porous PMMA bead increases the stability, reduces side effects and modifies the drug release are highly cross-linked so are insoluble, inert, and of sufficient strength to stand up to the high shear commonly used in manufacturing of creams, lotions, and powders can entrap a wide variety of substances such as emollients, fragrances, essential oils, sunscreens, antiinfective, anti-fugal, and anti inflammatory agents adsorb or load a high degree of active materials into the particle Are too large to be adsorbed into the skin surface Prevent the excess accumulation of ingredients within epidermis and the dermis Can significantly reduce the irritation of effective drugs without reducing their efficacy The spherical nature of the Micro Porous PMMA Bead, combined with its rigidity, enhances the skin feel and elegance of creams and lotions resulting in uncompromising performance. Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 31

32 POROUS PMMA BEADS Grade INCI Avg. Particle size(μm) SUNPMMA-COCO130 SUNPMMA-COCO170 SUNPMMA-P SUNPMMA-PH Methyl Methacrylate Cross Polymer Methyl Methacrylate Cross Polymer Methyl Methacrylate Cross Polymer Methyl Methacrylate Cross Polymer Advantage of Micro Porous PMMA Bead system Oil Absorption (cc/g) 8 1.2~ ~ ~ ~2.4 Improves stability thermal(up to 200 ), chemical(ph stable 1~11), physical Temperature stable Payload up to 45% with SUNPMMA-PH Extended release continuous action up to 12 hours Why Porous PMMA is better than Porous Silica as an active carrier? Porous Silica is inorganic so has metal ions inside Porous PMMA is a kind of plastic so has no metals or ions inside Thus porous PMMA is an inert carrier for actives or fragrances which are susceptible for chemical degradation catalyzed by metallic ions Improved product aesthetics gives product an elegant feel Allows incorporation of immiscible Improves material processing liquid can be converted to powders Cost effective in comparison to other delivery system Absorbs skin secretion and reduces the oiliness Extensive safety studies have demonstrated that the polymers are non-irritating, nonmutagenic, non-allergenic, non-toxic and non-biodegradable Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 32

33 Active Ingredients often cause skin irritancy Benzyl Peroxide(BPO) BPO, an antibacterial agent, has been used for acne therapy for more than 30 years with skin Microencapsulation The rate of release can not be controlled as once the capsule wall is ruptured, the contents are released Liposome Relatively expensive Lower payload Difficult formulation Limited chemical stability Have a low capacity to hold the active ingredients irritation as a common side effects Hydroquinone(HQ) HQ is considered the most effective skin brightening product for treatment for hyper pigmentation Retinol, Peptides, pro-vitamin Skin Rejuvenation Sustained release feature reduces potential for irritation and provides continuous action to help reverse signs of aging 5-fluorouracil(5-FU) The treatment of choice for extensive, widespread actinic keratoses(ak) Micro porous PMMA system for controlled release Slow release Time-release delivery Lessens irritation and redness Porous round spheres containing Active ingredients are suspended in the formula When applied to the face, the micro porous PMMA beads naturally settle into the wrinkles slowly delivering active ingredients over many hours exactly where it is needed most. Some products flood the skin with a heavy amount of active ingredients but the concentration may be irritating and the skin cannot absorb it effectively Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 33

34 Release Mechanism Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 34

35 FP POWDERS are Porous PMMA with Actives loaded inside Grade INCI Name & composition Avg. Particle size(μm) EFFECT & APPLICATION FP-MENTHOL Methyl methacrylate crosspolymer 80% L-menthol 20% FP-OMC Methyl methacrylate crosspolymer 60% Ethyl hexyl methoxycinnamate 40% 8 Cooling agent 8 UV protecting High SPF sun care products Based on customers requests, Tailor-made loading possible Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 35

36 SUN PROTECT GEL, by using FP-OMC Sun Protect Gel Super light, Very translucent Aristoflex AVC used to thicken water phase No shine, No white casts, No oiliness, No stickiness, nothing! SJF-0905-SUN PROTECT GEL-ver1.0 A B C Trade Name INCI Name % PARSOL EHS Ethylhexyl Salicylate 3.0 PARSOL MCX Ethylhexyl Methoxy cinnamate 3.6 FP-OMC (SUNJIN) HYBRID ABOC (SUNJIN) Methylmethacrylate Crosspolymer & Ethylhexyl Methoxy cinnamate In vivo SPF 21.8, PA 5.0 (++) Polymethyl Methacrylate / Avo Benzone / Octocrylene 3.0 1,3-B.G. 1,3-Butylene Glycol 10.0 D.I. WATER Water ARISTIFLEX AVC Ammonium Acryloyldimethyltaurate / VP Copolymer % Hybrid ABOC provides PA++ No emulsifier No emulsion Process used So translucent Applicable to Skin care formula D FRAGRANCE Fragrance 0.15 Liquid Chemical Filter= 3.0% +3.6% +2.4%(6.0%*40%) =9.0% Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 36

37 Pressed Powder with POROUS PMMA WATER D5 LP Porous PMMA Porous Silica 3min Porous PMMA does not absorb water WATER D5 LP 3min Absorbing water & oil very fast Making skin feel dry SJF-0809-Powdery Pressed Powder-ver.1.1 Phase No. Trade Name % 1 SUNTALC-LL HOLLOW PMMA SUNPMMA-H 2 SUNMICA-LL 9.90 A B C 3 SH 219 AS SUNPMMA-P SUNSERI-LL SUNTITAN-LL Magnesium Myristate SUNIOR-AS SUNIOY-AS SUNIOB-AS Phenoxy Ethanol DC-200 F-100CS DC Fragrance 0.10 Porous PMMA, especially good for pressed powder for excellent feel and spread without skin dryness Best recommend for (1)Pressed powder Porous PMMA selectively absorbs oils So it is very good for transparent powdery make up which has sebumabsorbing-long -lasting effect without making skin too dry D5:Cyclomethicone LP: Liquid Paraffin Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 37

38 Porous PMMA Beads are of good Media Dispersibility Water/EtOH dispersible porous PMMA Best recommend for (1)Spray products Powder 10%, EtOH 10%, Water 80% 3 Month Later, upside down test Urethane Bead A No Good 2. Urethane Bead B No Good 3. COCO 130(porous) Good 4. Nylon 12 Powder No Good 5. SUSNIL 130NP O.K. 6. SUNPU170 No Good 7. SUNPMMA-S No Good 8. SUNPMMA-PH (porous) Good 9. PE Bead No Good 10. SUNSIL 130H No Good 11. SUNPMMA-P(porous) Good 12. SUNSIL 130 No Good (2)Shaking products Porous PMMA Beads have shown excellent re-dispersibility Skin toner Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 38

39 Silica Beads Non Oily Body Lotion

40 Silica Beads, SUNSIL 130 series SUNSIL 130 series approved by ECOCERT, Natural Origin Silica Beads Untreated Porous SILICA BEADS Grade Descriptions Avg. Particle size(μm) Oil Absorption(c c/g) SUNSIL 20 Porous Silica 2 0.9~1.3 SUNSIL 130L Porous Silica 7 0.6~0.9 SUNSIL 130 Porous Silica 7 0.9~1.3 SUNSIL 130H Porous Silica 7 1.3~1.7 SUNSIL 130SH Porous Silica 7 2.1~2.6 SUNSIL 150H Porous Silica ~2.1 Marketing claims of silica beads: Natural Finish Matting Less Oily Not Greasy Powdery Non-Transfer Extra Wear Smooth Full Extension Curving for Mascara Non Porous SILICA BEAD Grade Descriptions size(μm) (cc/g) SUNSIL 130NP Non Porous Silica 7 0.3~0.6 Very price affordable, only a few $ more expensive than the untreated silica beads Methicone Coated SILICA BEADS Grade Descriptions size(μm) (cc/g) SUNSIL 130L-SC Hydrophobic Silica 6~9 0.6~0.9 SUNSIL 130SC Hydrophobic Silica 6~9 0.9~1.3 SUNSIL 130H-SC Hydrophobic Silica 6~9 1.1~1.7 SUNSIL 150H-SC Hydrophobic Silica 10~15 1.2~2.0 Hydrophobical coating improves Better Skin adhesion, Better skin spread Better tactile properties More compatiable with oily binder Ease of press Reduce breakage by drop Long lasting Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 40

41 Silica Bead, Natural Micro Bead Customer Needs (1) silica beads seems to disturb viscosity build up of thickeners. Do you have silica beads for o/w skin cares? (2) Polymer micro beads are synthetic. Do you have any natural & ECOCERT grade micro bead? Customers becoming label savvy! Silica, Natural Micro Bead While PMMA bead Nylon bead Urethane bead Silicone bead PE bead Are synthetic, can not be natural micro bead Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 41

42 Silica Beads for Skin Care Solution from SUNJIN SUNJIN provides Thickener SJF-0805-Sebum compatible Natural Control Silica Essence-ver.1.0 Beads for skin care SJF-0805-Sebum Control Essence_ver1.0 Phase No. Trade Name % 1 DI-Water ,3-B.G A 3 ALLANTOIN 0.10 Viscosity 1) CARBOPOL 940 9,000 10,500 Viscosity 2) Sepigel ,000 45,000 Viscosity 3) ARISTOFLEX AVC 16,000 17,300 4 TEA ARLATONE RHEODOL MS RHEODOL TW S B 8 LANETTE O EMERSOL % in water neutralized by TEA 1% in water 0.4% in water 10 TSF TEGOSOFT DEC 2.00 C 12 CARBOPOL 940 (1%) % 5% SUNSIL 130 0% 5% 130 added 0% 5% 130 added SUNSIL series are highly purified to remove ionic components and not to disturb polymeric thickeners SUNSIL series are natural, i.e. of ECOCERT approval. Polymeric Micro Beads such as nylon bead, urethane bead, PMMA bead, etc are of synthetic polymeric origin so can not be natural D 13 Sepigel E 14 ARBUTIN D.I.WATER F 16 Sodium Hyaluronate (1%) 1.00 G 17 SUNSIL H 18 Phenoxyethanol 0.5 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 42

43 Silica Beads for Body Lotion SJF-1124-Velvet Feel Body Lotion-ver.1.0 Part Camical Name % D.I-Water 59.2 A Carbopol 940 1% sol Glycerin 10.0 Peaster Myristic Acid 2.0 Arlacel DC 200F/10cs 0.5 B Finsolv TN 0.8 Marketing claims of Silica Bead in Body Lotion Velvet Feel Provide good maintaining the body's connective tissue strength protect against dry skin, brittle nails Provide excellent Light & Moisturizing feel Good Spread-ability Arlacel Lanette O 0.5 Vitamin E Acetate 0.1 C D.I-Water 1.0 TEA 0.2 Fragrance 0.2 D Opitiphen 0.5 SUNSIL Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 43

44 PMMA Beads

45 SUNPMMA-S No residual monomer(i.e. no odor), pharmaceutical grade by FDA regulation Grade Descriptions Avg. Particle size(μm) Oil Absorption (cc/g) SUNPMMA-S PMMA bead 7 0.4~0.6 Remark SUNPMMA-PLUS PMMA bead ~0.6 Improved Spread & Silky Feel 1) SUNPMMA-PLUS spreads very well on skin 8um PMMA PMMA-PLUS < 7um PMMA > Bigger particle size = less particles applied on skin SUNPMMA-PLUS has bigger particle size than 7um size PMMA, so its spread is improved and it looks more transparent. < SUNPMMA-PLUS > Chemical Name :Polymethyl Methacrylate INCI Name :Polymethyl Methacrylate CAS No. : ) PMMA-S is PRICE competitive SUNPMMA-S and SUNPMMA-PLUS are spherical PMMA micro-bead with a smooth surface, designed for use in skincare products and decorative cosmetics. The beads give a sensation of velvety smoothness during and after application, as well as filling up lines and wrinkles. Custom Tariff No. : Copyright 2011 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 45

46 SUNPMMA-S is the most Economic sensory modifier for Mass Brands Best recommend for (1) W/O emulsion (2)O/W emulsion, especially for dry skin As for O/W formula, great formula stability due to lack of Liquid foundation, skin cover interaction with polymeric thickeners(i.e. PMMA bead is polymer so contains no metal Slightly hydrophobic surface, especially suitable for W/Si ions inside) Description SUNPMMA S Silica Bead EPU40 SUNPU 170 Soft Hard / Dry Creamy Smooth/ Wet or W/O formula such as liquid foundation or sun block lotions PMMA-S is not porous so can t absorb moisture on skin. Good for skin cares for dry skin (3) Mass sun care products Good price for mass sun care products Good for O/W sun care, great formula stability due to lack of interaction with polymeric thickeners(i.e. PMMA bead is polymer so contains no metal ions inside) Good for W/O sun care due to slightly hydrophobic surface so easily compatible with W/Si or W/O formula Copyright 2011 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 46

47 MEMO The information given in this publication is based on our current knowledge and experience, and may be used at your discretion and risk. We do not assume any liability in connection with your product or its use Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 47

48 Global Distributors List ASIA & Pacific China TIANJIN XIANGUANG CHEMICAL Jinyu Road, Xiditou Beichen District, Tianjin Tel : psf7337@xianguang-chem.com Mobile: Contact : Sheng-Fan Piao Japan/ LINDEN CO.,LTD. A202, 3-6-3Watado, Fujimi-Shi, Saitama TEL : (+81) kaz.miyadera@linden.jp Contact : Kazuyuki Miyadera Australia / New Zealand RPL Trading Allingham Street, Golden Square, VIC 3555, Australia Tel : rpltrading2@bigpond.com Contact : Russell McNab Thailand/ GOWELL CO. LTD 8/9 Moo 7, Bangna - Trad Road KM.9, Bangkaew, Bangplee, Samutprakarn 10540, Thailand TEL : nuttamol@purity.co.th Contact : Nutthamol Rattanachaiyaphong Taiwan/ WWRC 5F-A, No. 30, Chung Cheng 2nd Road, Kaohsiung 802, Taiwan, R.O.C. Tel : tommy@wwrc.com.tw Contact : Tommy Hu Malaysia/ DCM Personal Care Address : No. 5, Jalan U1/21 Seksyen U1, Hicom-Glenmarie Industrial park, Shah Alam, SelangorDarul Ehsan. Malaysia. Tel : Kokleong@drexchem.com.my Contact : Kok Leong, KHOO Indonesia/ PT. MEGASETIA AGUNG KIMIA JI. Paradise Timur Raya F21/58, Sunter Agung Podomoro, Jakarta Tel : abigail@megasetia.com Contact : Abagail EUROPE France / IMPAG France SAS 6, Boulevard du 21eme Regiment d'aviation NANCY France Tel : +33 (0) dominique.cormary@impag.fr Contact : Dominique Cormary Germany/ IMPAG GmbH Fritz-Remy-str.25,63071 offenbach Tel: Fax: karin.flach-zierer@impag.de Contact : Karin Flach-Zierer Switzerland/ IMPAG AG Feldeggstrasse 26, Postfach, CH-8008 Zürich TEL: peter.alder@impag.ch Contact: Peter Alder Italy/ Caldic Italia Srl Via Saronnino, Origgio (VARESE) Italy Tel : +39 (02) marcello.baggi@caldic.it Contact : Marcello Baggi UK/ ASTON CHEMICALS 1 Aylesbury Industrial Center Bicester Road, Aylesbury, HP19 8AL Tel: +44 (0) louism@aston-chemicals.com Contact: Louis Moulin Poland/ ASTON CHEMICALS Oddział w Polsce, ul. Mińska Warszawa Tel MariuszS@astonchemicals.pl Contact: Mariusz Siwiński Spain & Portugal / C.E.S.T.I.S.A. Bailen 43 pral, Barcelona Tel : laura@cestisa.com Contact : Laura Mas Turkey/ HD ULUSLARARASI TIC. VE AMBALAJ SAN. LTD.STI. Dilovasi Organize Sanayi Bolgesi 5.Kisim D-5007 Sokak No:2 Ofis No: 11 (Jokey Plastik Fabrikasi ici) TR Dilovasi- Kocaeli Turkey Tel : oozturk@hd.biz.tr Contact : Oktay OZTURK AMERICA USA & Canada KOBO PRODUCTS, INC. 690 Montrose Ave. - South Plainfield, NJ Tel : (Ext.6152) bscott@koboproductsinc.com Contact : Barbara Scott SUNJIN AMERICA INC Center Ave. (Suite 502) Fort Lee, NJ Tel : Mobile : plee@sunjinamerica.com Contact : Phil Lee MIDDLE EAST Jordan & Syria RIMA AL.SHURAFA & PARTENERS 149 Amman Jordan 8th Circle, Al.Bayader, Randa Complex Building, 2nd Floor, Office, 206 Tel: Mobile: Firas@Jadarahchemicals.com Contact : Firas Shurafa