IPPC BAT REFERENCE DOCUMENT LARGE VOLUME SOLID INORGANIC CHEMICALS FAMILY PROCESS BREF FOR SODA ASH
|
|
- Carol Webster
- 8 years ago
- Views:
Transcription
1 EUROPEAN CHEMICAL INDUSTRY COUNCIL IPPC BAT REFERENCE DOCUMENT LARGE VOLUME SOLID INORGANIC CHEMICALS FAMILY PROCESS BREF FOR SODA ASH ESAPA European Soda Ash Producers Association Issue N : 3 Date of issue: March 2004 Document approved by ESAPA
2 Soda Ash Process BREF - Issue N 3 March
3 PROCESS BREF FOR SODA ASH TABLE OF CONTENTS PREFACE... 8 DEFINITIONS GENERAL INFORMATION HISTORY OF THE PRODUCTION OVERVIEW ABOUT TYPE OF PRODUCTION Solvay process Trona and nahcolite based process Trona Nahcolite Nepheline syenite process Carbonation of caustic soda USES IN INDUSTRIAL SECTORS Glass industry Detergent industry Steel industry Non-ferrous metallurgy industry Chemical industry Sodium bicarbonate Sodium sesquicarbonate Chemically pure sodium carbonate Sodium bichromate Sodium percarbonate Sodium phosphates Sodium silicates Sodium sulfites Other applications PRODUCTION CAPACITY IN THE WORLD AND IN EUROPE Worldwide European Union SOCIO-ECONOMICAL ASPECTS Main characteristics of the industry Social integration - employment General economic standing Environmental taxes and levies Manufacturing and operating cost APPLIED PROCESS AND TECHNIQUES PROCESS Main chemical reactions Process steps Brine purification Soda Ash Process BREF - Issue N 3 March
4 Lime kilns and milk of lime production Absorption of ammonia Precipitation of sodium bicarbonate Separation of sodium bicarbonate from mother liquid Sodium bicarbonate calcination Ammonia recovery Product storage and handling RAW MATERIALS Brine Typical composition Storage Limestone Carbon for the lime kiln Typical composition Storage Ammonia Characteristics Storage Miscellaneous additives MAIN OUTPUT STREAMS POSSIBILITIES FOR PROCESS OPTIMIZATION AND IMPROVEMENTS Purity of raw materials Raw material consumptions Energy PRESENT INPUT/OUTPUT LEVELS RAW MATERIALS UTILITIES Steam Process water Cooling waters Electricity GASEOUS EFFLUENTS Particulate dust Carbon dioxide and monoxide Nitrogen oxides Sulfur oxides Ammonia Hydrogen sulfide LIQUID EFFLUENTS Wastewater from distillation Wastewater from brine purification SOLID EFFLUENTS Fines of limestone Non recycled stone grits at slaker CO-PRODUCTS Calcium chloride Refined sodium bicarbonate Background information Soda Ash Process BREF - Issue N 3 March
5 Process description Major environmental impact CANDIDATE BEST AVAILABLE TECHNIQUES ENVIRONMENTAL ASPECTS ENERGY MANAGEMENT Energy conversion of primary fuels Energy saving in the process Heat recovery Energy minimisation GASEOUS EFFLUENTS MANAGEMENT Calcination of limestone Precipitation of crude sodium bicarbonate Filtration of the bicarbonate Production of dense soda ash Conveying and storage of light and dense soda ash LIQUID EFFLUENT MANAGEMENT Liquid effluent treatments Marine outfalls Lake and river discharge Settling ponds Purpose and principles Operation of settling basins Monitoring during operation Hydraulic confinement Coverage and final closure Underground disposal Liquid effluent discharge management Concept of equalisation in modulation basins Performance Available techniques Management of equalization basins Adjustment of ph By-products recovery and reuse Dissolved CaCl 2 in distillation wastewater Suspended solids in distillation wastewater Product from brine purification SOLID MATERIALS MANAGEMENT Limestone fines Grits from slaker BEST AVAILABLE TECHNIQUES FOR THE MANUFACTURING OF SODA ASH INTRODUCTION CONSIDERATION TO BE TAKEN INTO ACCOUNT WHEN DETERMINING BAT FOR THE MANUFACTURING OF SODA ASH EMISSION TO WATER Ammonia Suspended solids Soda Ash Process BREF - Issue N 3 March
6 5.4. EMISSION TO AIR Lime kilns gas Quantity of lime kiln gas produced Composition of lime kiln gas Gas effluent of the manufacturing sector Dust ENERGY Heat recovery Energy minimisation REFERENCES Soda Ash Process BREF - Issue N 3 March
7 PROCESS BREF FOR SODA ASH LIST OF TABLES Table 1 Worldwide capacity of soda ash manufacture (reference year : 2000) Table 2 European soda ash capacity and producers (reference year : 2002) Table 3 Soda ash manufacturing costs Table 4 Plant area/operations Table 5 Raw and purified brines (typical composition ranges) Table 6 Coke for lime kilns (typical composition ranges) Table 7 Main output streams from the soda ash process Table 8 Soda ash process major Input/Output levels Table 9 Wastewater from distillation Table 10 Effluent from brine purification (typical composition) Table 11 Solid effluents from soda ash process Table 12 Worldwide Refined Sodium Bicarbonate Annual Capacities (reference year : 2002) Table 13 Consumption of Refined Sodium Bicarbonate in EU (reference year : 2002) Table 14 European Refined Sodium Bicarbonate capacity and producers (reference year : 2002) Table 15 Vent gas from bicarbonation columns blown with lime kiln gas Table 16 Vent gas from lime kilns after cleaning Table 17 Vent gas from column section after washing Table 18 Filter gas after washing Table 19 Typical gas composition resulting of limestone calcination Table 20 Vent gas from column section after washing Table 21 Ranges of energy consumption LIST OF FIGURES Figure 1 Geographic distribution of soda ash plants (Solvay process) within the European Union (2002) Figure 2 Process block diagram for the manufacture of soda ash by the Solvay process Figure 3 Process block diagram for the manufacture of refined sodium bicarbonate.. 49 Soda Ash Process BREF - Issue N 3 March
8 PREFACE The European Soda Ash Producers Association (ESAPA), through CEFIC, has produced this Best Practice Reference Document (BREF) in response to the EU Directive on Integrated Pollution Prevention and Control (IPPC Directive). The document was prepared by technical experts from the ESAPA member companies and covers primarily the production of soda ash (sodium carbonate) by the Solvay Ammonia-Soda process. This BREF reflects industry perceptions of what techniques are generally considered to be feasible and presently available and achievable emission levels associated with the manufacturing of soda ash. It does not aim to create an exhaustive list of Best Available Techniques (BAT) but highlights the most widely used and accepted practices. The document uses the same definition of BAT as that given in the IPPC Directive 96/61 EC of BAT covers both the technology used and the management practices necessary to operate a plant efficiently and safely. The principles of Responsible Care to which the companies voluntarily adhere provide a good framework for the implementation of management techniques. The BREF is focused primarily on the technological processes, since good management is considered to be independent of the process route. It should be noted that different practices have developed over time, dependant upon national and local regulatory requirements, differences in plant location and issues of local environmental sensitivity. This has resulted in differences in best practices between EU Member States. Moreover certain practices may be mutually exclusive and it must no be assumed that all achievable minima can be met by all operations at the same time. Neither CEFIC, ESAPA nor any individual company can accept liability for accident or loss attributable to the use of the information provided in this document Soda Ash Process BREF - Issue N 3 March
9 DEFINITIONS The following definitions are taken from Council directive 96/61/EC of 1996 on Integrated Pollution Prevention and Control: Best Available Techniques shall mean the most effective and advanced stage in the development of activities and their methods of operation which indicate the practical suitability of particular techniques for providing, in principle, the basis for emission limit values designed to prevent or, where that is not practicable, generally to reduce emissions and the impact on the environment as a whole: "Techniques" include both the technology used and the way in which the installation is designed, built, maintained, operated and decommissioned. Available techniques shall mean those developed on a scale which allows implementation in the relevant industrial sector, under economically and technically viable conditions, taking into consideration the costs and advantages, whether or not the techniques are used or produced inside the Member State in question, as long as they are reasonably accessible to the operator. Best shall mean most effective in achieving a high general level of protection for the environment as a whole. Soda Ash Process BREF - Issue N 3 March
10 1. GENERAL INFORMATION 1.1. HISTORY OF THE PRODUCTION Before the advent of industrial processes, sodium carbonate, often-called soda ash, came from natural sources, either vegetable or mineral. Soda made from ashes of certain plants or seaweed has been known since antiquity. At the end of the 18 th century, available production was far below the growing demand due to the soap and glass market. The French Academy of Science offered an award for the invention of a practical process to manufacture soda ash. Nicolas Leblanc proposed a process starting from common salt and obtained a patent in The so-called Leblanc or black ash process was developed in the period 1825 till The major drawback of this process was its environmental impact with the emission of large quantities of HCl gas and the production of calcium sulfide solid waste which not only lost valuable sulfur but also produced poisonous gases. In 1861, Ernest Solvay rediscovered and perfected the process based on common salt, limestone and ammonia. Competition between both processes lasted many years, but relative simplicity, reduced operating costs and, above all, reduced environmental impact of the Solvay process ensured its success. From 1885 on, Leblanc production took a downward curve as did soda ash price and by the First World War, Leblanc soda ash production practically disappeared. Since then, the only production process used in Western Europe as well as in main part of the world is the Solvay process. In the meantime and mainly since the twenties, several deposits of minerals containing sodium carbonate or bicarbonate have been discovered. Nevertheless the ore purity and the location of these deposits, as well as the mining conditions of these minerals, has limited the effective number of plants put into operation. Soda Ash Process BREF - Issue N 3 March
11 1.2. OVERVIEW ABOUT TYPE OF PRODUCTION Solvay process The Solvay process, also called ammonia soda process, uses salt (NaCl) and limestone (CaCO 3 ) as raw materials. Ammonia, which is also used in the process, is almost totally regenerated and recycled. The main advantage of this process is the availability of the raw materials, which can be found almost everywhere in the world and therefore allows operating production units relatively close to the market. The Solvay process produces light soda ash, with a specific weight or pouring density of about 500 kg/m3. It is used in that form mainly for the detergent market and certain chemical intermediates. Light soda ash is transformed by recrystallization firstly to sodium carbonate monohydrate, and finally to dense soda ash after drying (dehydration). Dense soda ash has a pouring density of about 1000 kg/m3. It is used mainly in the glass industry. Dense soda ash can also be produced by compaction. Some producers have made several modifications to the original process. The main ones are: - the dual process, which allows production units to co-produce in nearly equal quantities ammonium chloride, which is used as a fertilizer in rice cultivation. There are several plants in the world which are working with that process. Most are situated in China - the Akzo or dry lime process, which uses dry lime instead of lime milk for ammonia recovery Trona and nahcolite based process All processes are based on ore treatment from which impurities (i.e. organics and insolubles) have to be stored underground or in tailing ponds Trona Trona minerals can be found underground (Green River trona deposit in Wyoming - USA, Inner Mongolia - China, Henan - China) or in dry lakes (Searles Lake trona brine deposit in California USA, Magadi Lake trona brine deposit in Kenya, Sua Pan trona brine deposit in Botswana). Soda Ash Process BREF - Issue N 3 March
12 Underground "dry" trona processing consists in several steps: - mechanical mining by the room and pillar or long wall method - as trona is an impure sodium sesquicarbonate mineral (Na 2 CO 3 NaHCO 3 2H 2 O), it has firstly to be calcined to produce a soda ash still containing all the impurities from the ore - next, calcined trona is dissolved, the solution is settled and filtered to remove impurities (insolubles and organics) - the purified liquor is sent to evaporators where sodium monohydrate crystals precipitate - the monohydrate slurry is concentrated in centrifuges before drying and transformation into dense soda ash Deposits from trona lakes and solution mined trona are processed as follows : - dissolving trona in wells - carbonation of the solution in order to precipitate sodium bicarbonate - filtration of the slurry - calcination of the bicarbonate to get light soda ash, recycling of the carbon dioxide to the carbonation - light soda ash transformation into dense by the monohydrate method - carbon dioxide make-up produced by burner off-gas enrichment Nahcolite A Nahcolite deposit has been found in Piceance Creek in Colorado - USA and an industrial soda ash plant has been put into operation at the end of the year Little practical experience of this process is therefore available. Nahcolite is processed as follows: - by solution mining (wells, with injection of hot mother liquor returned from the surface facilities) - as nahcolite is an impure sodium bicarbonate mineral (NaHCO 3 ), it must be treated - the hot solution is decarbonated by heating - the solution is sent to settling and filtration. - next, the purified liquor is sent to evaporators where sodium monohydrate precipitates - the slurry is concentrated by centrifugation and the monohydrate crystals transformed to soda ash by drying - the mother liquor is sent back to the solution mining Soda Ash Process BREF - Issue N 3 March
13 Nepheline syenite process There is still a process operated in Russia, mainly in a plant situated in Siberia, which uses mixed minerals and allows the coproduction of alumina, cement and soda ash. The soda ash produced is of poor quality Carbonation of caustic soda Small quantities of soda ash are made by the carbonation of caustic soda. This produces a soda liquor solution which is treated in similar ways to those described above. Alternatively where this caustic soda is from diaphragm cells it contains high levels of residual sodium chloride which can be used either in conjunction with a conventional Solvay ammonia soda process or in the brine purification process USES IN INDUSTRIAL SECTORS Soda ash is a commodity chemical used in several branches of industry. The main ones are quoted in the following paragraphs Glass industry Soda ash is used in the manufacturing of flat and container glass. Acting as a network modifier or fluxing agent, it allows lowering the melting temperature of sand and therefore reduces the energy consumption Detergent industry Soda ash is used in a large number of prepared domestic products: soaps, scouring powders, soaking and washing powders containing varying proportions of sodium carbonate, where the soda ash acts primarily as a builder or water softener Steel industry Soda ash is used as a flux, a desulfurizer, dephosphorizer and denitrider. Soda Ash Process BREF - Issue N 3 March
14 Non-ferrous metallurgy industry - treatment of uranium ores - oxidizing calcination of chrome ore - lead recycling from discarded batteries - recycling of zinc, aluminium Chemical industry Soda ash is used in a large number of chemical reactions to produce organic or inorganic compounds used in very different applications Sodium bicarbonate - animal feeds to balance their diets to compensate for seasonal variations and meet specific biological and rearing needs - paper industry for paper sizing - plastic foaming - water treatment - leather treatment - flue gas treatment, especially in incinerators - detergent and cleaning products such as washing powders and liquids, dishwashing products, etc - drilling mud to improve fluidity - fire extinguisher powder - human food products and domestic uses : baking soda, effervescent drinks, toothpaste, fruit cleaning, personal hygiene, etc - pharmaceutical applications : effervescent tablets, haemodialysis Sodium sesquicarbonate - bath salts, water softener Chemically pure sodium carbonate - pharmaceuticals industry, cosmetics, food industry and fine chemicals Soda Ash Process BREF - Issue N 3 March
15 Sodium bichromate Sodium percarbonate - bleaching agent for various fabrics and constituent of domestic detergent powders - cosmetology Sodium phosphates Sodium silicates Sodium sulfites Other applications - production of various chemical fertilizers - production of artificial sodium bentonites or activated bentonites - manufacture of synthetic detergents - organic and inorganic coloring industry - enamelling industry - petroleum industry - fats, glue and gelatine industry, etc PRODUCTION CAPACITY IN THE WORLD AND IN EUROPE Worldwide The current worldwide soda ash nameplate capacity is estimated to be around 42 million t/year. The split between processes and geographical zones is given in Table 1. Soda Ash Process BREF - Issue N 3 March
16 Table 1 Worldwide capacity of soda ash manufacture (reference year : 2000) Production capacity EU25 Rest of Europe North. America Latin America Asia Africa Oceania Total million t/year Solvay process Na minerals process Others Total European Union There are only four producers in the European Union (EU15) applying the Solvay process: Solvay, Brunner Mond, Novacarb, Sodawerk Stassfurt, with a total capacity of 6625 kt/year. BASF has two plants which co-produce sodium carbonate with a combined capacity of 65 kt/year. Solvay has 7 plants situated in 6 countries: France, Germany, Italy, Spain, Portugal and Austria with a total capacity of 4200 kt/year. Brunner Mond has 3 plants in 2 countries: United Kingdom and Netherlands with a total capacity of 1375 kt/year. Novacarb has one plant, in France, with a capacity of 600 kt/year. Sodawerk Stassfurt has one plant, in Germany, with a capacity of 450 kt/year. The enlarged European Union (EU25) will take in two additional plants in Poland operated by Ciech with a combined capacity of (1100 kt/year) already member of ESAPA. ESAPA also represents the Turkish operation of Şişecam (800 kt/year) and the Bulgarian factory (1200 kt/year) operated as a production joint venture between Solvay (75%) and Şişecam (25%) and the two Romanian factories operated by Bega with a combined capacity of (710 kt/year). These give a combined additional production capacity of 3810 kt/year. Soda Ash Process BREF - Issue N 3 March
17 Table 2 European soda ash capacity and producers (reference year : 2002) Producers Country - location Capacity (kt/year) Plant start-up (*) Solvay France Dombasle Germany Rheinberg Germany Bernburg Spain Torrelavega Italy Rosignano Portugal Povoa Austria Ebensee Solvay - Şişecam Bulgaria Devnya Brunner Mond United Kingdom Northwich (Winnington/Lostock) The Netherlands Delfzijl Novacarb France - La Madeleine Sodawerk Stassfurt Germany Stassfurt Ciech Janikosoda Poland Janikowo Ciech Soda Matwy Poland Inowroclaw Soda Sanayii Turkey Mersin Bega Govora Romania Govora Bega Upsom Romania Ocna Mures Sodaso Bosnia Herzegovina BASF (*) Obviously, all these plants have been revamped several times in order to implement technology upgrade and plant capacity has been increased progressively to follow market demand. Production sites in the European Union are shown on a map in Figure 1. Soda Ash Process BREF - Issue N 3 March
18 Northwich (2) Delfzijl Inowroclaw Stassfurt Rheinberg Janikowo Bernburg Torrelavega Dombasle La Madeleine Ebensee Rosignano Lukavac Ocna Mures Govora Devnya Povoa Mersin Figure 1 Geographic distribution of soda ash plants (Solvay process) within the European Union (2002) Soda Ash Process BREF - Issue N 3 March
19 1.5. SOCIO-ECONOMICAL ASPECTS Main characteristics of the industry Soda ash is a chemical product of the inorganic commodity family. As one of the major raw materials of the chemical and glass industry, it is also of strategic importance for the industrial framework in the world and especially in Europe. The estimated invested capital necessary to build a new soda ash plant in the EU is very high : about 600 /t of annual capacity (excluding the cost of steam and power plant). The current economic situation could not justify the construction of new plants and for many years producers have been progressively revitalizing and modernizing existing plants Social integration - employment The total number of people employed directly by the European producers (EU25) is estimated at 8500 persons (or about 900 t per person employed per year). These numbers will of course depend upon the boundary of operation and will therefore vary from site to site. Furthermore, there are a certain number of subcontractors working in the plants on activities such as bagging, loading, transport, engineering, construction, maintenance, which can be estimated to persons. In Western Europe it is estimated that about are employed, directly and indirectly, in the production of soda ash and direct derivatives General economic standing Since the end of the eighties, the progressive opening of the borders, the reduction of trade barriers and the reduction of transportation costs have created very competitive conditions in the soda ash business to the point where today this market can be considered as worldwide and predominantly commodity. The European Union soda ash industry has suffered severely from these changes. In the last ten years, five plants shut down: three in Germany, one in France and one in Belgium. Constant efforts have been made by the European soda ash industry to improve its competitiveness in order to resist cheap Eastern Europe and US imports. The soda ash industry in these other regions is favoured by lower energy costs both for natural gas and electricity. Soda Ash Process BREF - Issue N 3 March
20 Total manpower costs in the EU are, in general, significantly higher than in the US and than in Eastern Europe. At the beginning of the twenty-first century, the European soda ash industry is still being challenged by US and Eastern Europe imports Environmental taxes and levies There is no consistent picture throughout Europe on Environmental Taxes or Levies. In the UK the majority of the costs are associated with maintenance of existing authorisations where as in other member states the emphasis is on taxes for specific discharges to water, or emissions to atmosphere. As for other industries, a number of taxes and levies are imposed on producers, such as social or environmental fees. The soda ash sector is especially sensitive to those when they are based on occupied surface, water consumption or energy inputs/outputs and emission. In some countries, the total amount of taxes and levies, including local taxes, energy, mining, housing, training, properties are as high as 6.4 /t soda ash Manufacturing and operating cost Exact Figures for production costs are obviously confidential. A rough existing indication provided by consultants is given in Table 3. These data have to be considered carefully since operating costs will vary depending on the production location. Table 3 Soda ash manufacturing costs Item Cost [ /t soda ash] Raw materials 25 Energy 40 Labour 35 Maintenance 20 Total (cash costs) 120 Soda Ash Process BREF - Issue N 3 March
21 The actual cost will vary according to a number of factors including location and ownership of raw materials, energy sources etc. 2. APPLIED PROCESS AND TECHNIQUES 2.1. PROCESS Main chemical reactions The SOLVAY process relative to the production of soda ash could be summarized by the theoretical global equation involving the two main components: sodium chloride and calcium carbonate. 2 NaCl + CaCO 3 Na 2 CO 3 + CaCl 2 In practice this direct way is not possible and it needs the participation of other substances and many different process steps to get the final product: soda ash. First reactions occur in salt solution (brine). First of all, ammonia is absorbed (1) and then, the ammoniated brine is reacted with carbon dioxide to form successive intermediate compounds: ammonium carbonate (2) then ammonium bicarbonate (3). By continuing carbon dioxide injection and cooling the solution, precipitation of sodium bicarbonate is achieved and ammonium chloride is formed (4). Chemical reactions relative to different steps of the process are written below: NaCl + H 2 O + NH 3 NaCl + NH 4 OH (1) 2 NH 4 OH + CO 2 (NH 4 ) 2 CO 3 + H 2 O (2) (NH 4 ) 2 CO 3 + CO 2 + H 2 O 2 NH 4 HCO 3 (3) 2 NH 4 HCO NaCl 2 NaHCO NH 4 Cl (4) Sodium bicarbonate crystals are separated from the mother liquor by filtration, then sodium bicarbonate is decomposed thermally into sodium carbonate, water and carbon dioxide (5). 2 NaHCO 3 Na 2 CO 3 + H 2 O + CO 2 (5) CO 2 is recovered in the carbonation step (see equations 2 and 3 above). CO 2 recovery cycle is shown in Figure 2. Soda Ash Process BREF - Issue N 3 March
22 Mother liquor is treated to recover ammonia. The ammonium chloride filtrate (4) is reacted with alkali, generally milk of lime (6), followed by steam stripping to recover free gaseous ammonia: 2 NH 4 Cl + Ca(OH) 2 CaCl NH H 2 O (6) NH 3 is recycled to the absorption step (see equation 1 above). Ammonia recovery cycle is shown in Figure 2. Carbon dioxide and calcium hydroxide originate from limestone calcination (7) followed by calcium oxide hydration (8). CaCO 3 CaO + CO 2 (7) CaO + H 2 O Ca(OH) 2 (8) Brine (NaCl) has to be treated before the input in the process to remove impurities : calcium and magnesium. If not removed they would react with alkali and carbon dioxide to produce insoluble salts contributing to scale formation inside equipment. Brine purification reactions are described in the following equations: Ca 2+ + CO 3 2- CaCO 3 (9) Mg OH - Mg(OH) 2 (10) Sodium carbonate formed (equation 5) is called "light soda ash" because its bulk density is approximately 0.5 t/m3. A subsequent operation called densification enables this value to be doubled by crystallisation into sodium monohydrate, by adding water (equation 11) then followed by drying (equation 12). Final product is "dense soda". Na 2 CO 3 + H 2 O > Na 2 CO 3.H 2 O (11) Na 2 CO 3.H 2 O > Na 2 CO 3 + H 2 O (12) Process steps The SOLVAY process has been described in details in several recognized references (see chapter 6). Chemical reactions described in are realized industrially in different areas illustrated in the block diagram of Figure 2. Soda Ash Process BREF - Issue N 3 March
23 GO1 vent or recovery for bicarbonate production LIMESTONE screening of the limestone fines GO4 SO1 water vapor water fines containing inert material lime SO2 washing of the gas calcination lime kilns slaking of the lime lime milk CARBON (COKE, ) NH3 CO2 unburnt limestone water NH3 make up ammonia recovery cycle LO3 bis washing and cooling RAW BRINE brine purification NH3 absorption carbonation of ammoniated brine air reagents LO3 LO1 wastewater with salt impurities (CaCO3, Mg(OH)2 ) GI2 gas washing with purified brine water cooling LO4 CO2 gas GO2 energy gas compression steam recovery of ammonia filtration CO 2 recovery cycle wastewater LI2 GI3 LO2 treatment of the wastewater calcination of crude bicarbonate gas cooling and washing with purified brine GO6 GO3 GO5 water vapor gas washing with purified brine vacuum pumps washer condenser energy GI5 monohydratation of the light soda ash drying of the monohydrate water dedusting storage of light soda ash dedusting GO7 storage of dense soda ash LIGHT SODA ASH DENSE SODA ASH energy LEGEND process optional operation solid liquid liquids gaseous streams XXX GI, GO LI, LO SI, SO = Gaseous, Liquid, Solid streams Inlets/Outlets raw materials, end products Figure 2 Process block diagram for the manufacture of soda ash by the Solvay process Soda Ash Process BREF - Issue N 3 March
AMMONIA AND UREA PRODUCTION
AMMONIA AND UREA PRODUCTION Urea (NH 2 CONH 2 ) is of great importance to the agriculture industry as a nitrogen-rich fertiliser. In Kapuni, Petrochem manufacture ammonia and then convert the majority
More informationMulti-pollutant control solutions for coal based power plants
Multi-pollutant control solutions for coal based power plants By Luca Mancuso and Hans Janssen Content SOx control Wet Scrubbers Open towers Dual Flow Tray Technology Semi-Dry SDA CFB Scrubbers Dust control
More informationBasics of Kraft Pulping & Recovery Process. Art J. Ragauskas Institute of Paper Science and Technology Georgia Institute of Technology
Basics of Kraft Pulping & Recovery Process Art J. Ragauskas Institute of Paper Science and Technology Georgia Institute of Technology Outline History Goals Process Overview Kraft Pulping Process Kraft
More informationCHAPTER 7 THE DEHYDRATION AND SWEETENING OF NATURAL GAS
CHAPTER 7 THE DEHYDRATION AND SWEETENING OF NATURAL GAS Natural gases either from natural production or storage reservoirs contain water, which condense and form solid gas hydrates to block pipeline flow
More informationBalancing chemical reaction equations (stoichiometry)
Balancing chemical reaction equations (stoichiometry) This worksheet and all related files are licensed under the Creative Commons Attribution License, version 1.0. To view a copy of this license, visit
More informationWater Softening for Hardness Removal. Hardness in Water. Methods of Removing Hardness 5/1/15. WTRG18 Water Softening and Hardness
Water Softening for Removal 1 in Water High concentration of calcium (Ca2+) and magnesium (Mg2+) ions in water cause hardness Generally, water containing more than 100 mg/l of hardness expressed as calcium
More informationION EXCHANGE FOR DUMMIES. An introduction
ION EXCHANGE FOR DUMMIES An introduction Water Water is a liquid. Water is made of water molecules (formula H 2 O). All natural waters contain some foreign substances, usually in small amounts. The water
More informationThe Single Absorption Scrubbing Sulfuric Acid Process
The Single Absorption Scrubbing Sulfuric Acid Process Leonard J. Friedman, Samantha J. Friedman Acid Engineering & Consulting, Inc. 17770 Deauville Lane, 33496, USA LJ.Friedman@Acideng.com Keywords: Sulfuric
More informationHow To Make Calcium Carbide
11.4 Calcium Carbide Manufacturing 11.4.1 General Calcium carbide (CaC 2 ) is manufactured by heating a lime and carbon mixture to 2000 to 2100 C (3632 to 3812 F) in an electric arc furnace. At those temperatures,
More informationEXAMPLE EXERCISE 4.1 Change of Physical State
EXAMPLE EXERCISE 4.1 Change of Physical State State the term that applies to each of the following changes of physical state: (a) Snow changes from a solid to a liquid. (b) Gasoline changes from a liquid
More informationACIDS, BASES AND SALTS
Acids are those chemical substances which have a sour taste. Bases are those chemical substances which have a bitter taste. A salt is an ionic compound which dissociates to yield a positive ion other than
More informationWhat is Cement? History Overview of the Cement Manufacturing Process Brief Overview of Kiln Operations Why Burn Wastes?
What is Cement? History Overview of the Cement Manufacturing Process Brief Overview of Kiln Operations Why Burn Wastes? A hydraulic cement made by finely pulverizing the clinker produced by calcining to
More informationEXTRACTION OF METALS
1 EXTRACTION OF METALS Occurrence ores of some metals are very common (iron, aluminium) others occur only in limited quantities in selected areas ores need to be purified before being reduced to the metal
More informationPhosphate Recovery from Municipal Wastewater through Crystallization of Calcium Phosphate
Phosphate Recovery from Municipal Wastewater through Crystallization of Calcium Phosphate A. Alamdari, Ph.D. * and S. Rohani, M.Sc. * Department of Chemical Engineering, School of Engineering, Shiraz University,
More informationSeparation by Solvent Extraction
Experiment 3 Separation by Solvent Extraction Objectives To separate a mixture consisting of a carboxylic acid and a neutral compound by using solvent extraction techniques. Introduction Frequently, organic
More informationGROUP II ELEMENTS. Beryllium to Barium
1 GROUP II ELEMENTS Beryllium to Barium Introduction Elements in Group I (alkali metals) and Group II (alkaline earths) are known as s-block elements because their valence (bonding) electrons are in s
More informationBASIC WATER TREATMENT OF STEAM BOILERS
BASIC WATER TREATMENT OF STEAM BOILERS Steve Kenny and Dave Pope Chemco Water Technology Vancouver, WA This is a brief discussion on low-pressure steam boiler chemistry. It provides dry kiln boiler operators
More informationThe National Board of Boiler and Pressure Vessel Inspectors 1055 Crupper Avenue Columbus, Ohio 43229 614.888.8320
TheNationalBoardofBoilerandPressureVesselInspectors 1055CrupperAvenue Columbus,Ohio43229 614.888.8320 NB-410, Revision 3 Sept, 2015 1 1.0 GENERAL The purpose of this document is to provide basic guidelines
More informationTRIAL CHEMICAL CLEANING OF FOULED APH BASKETS
TRIAL CHEMICAL CLEANING OF FOULED APH BASKETS Dr. Abhay Kumar Sahay, AGM(CC OS) Bijay Manjul, AGM( Operation) Kahalgaon Boiler has three inputs Steam generator 1. WATER 2. COAL 3. AIR Burner Air preheater
More informationSULFUR RECOVERY UNIT. Thermal Oxidizer
SULFUR RECOVERY UNIT Thermal Oxidizer BURNERS FLARES INCINERATORS PARTS & SERVICE SULFUR RECOVERY UNIT Thermal Oxidizer Tail Gas Thermal Oxidizer designed and built to GOST-R requirements. Zeeco can meet
More informationSanta Monica College Chemistry 11
Types of Reactions Objectives The objectives of this laboratory are as follows: To perform and observe the results of a variety of chemical reactions. To become familiar with the observable signs of chemical
More informationContinuous flow direct water heating for potable hot water
Continuous flow direct water heating for potable hot water An independently produced White Paper for Rinnai UK 2013 www.rinnaiuk.com In the 35 years since direct hot water systems entered the UK commercial
More informationIron and Steel Manufacturing
Pollution Prevention and Abatement Handbook WORLD BANK GROUP Effective July 1998 Iron and Steel Manufacturing Industry Description and Practices Steel is manufactured by the chemical reduction of iron
More informationTiO 2. : Manufacture of Titanium Dioxide. www.rsc.org/learn-chemistry Registered charity number 207890
TiO 2 : Manufacture of Titanium Dioxide www.rsc.org/learn-chemistry Registered charity number 207890 5: Manufacture of titanium dioxide Titanium dioxide has many uses. It is now the common white pigment
More informationGUIDELINES FOR LEACHATE CONTROL
GUIDELINES FOR LEACHATE CONTROL The term leachate refers to liquids that migrate from the waste carrying dissolved or suspended contaminants. Leachate results from precipitation entering the landfill and
More informationIB Chemistry. DP Chemistry Review
DP Chemistry Review Topic 1: Quantitative chemistry 1.1 The mole concept and Avogadro s constant Assessment statement Apply the mole concept to substances. Determine the number of particles and the amount
More informationHardness - Multivalent metal ions which will form precipitates with soaps. e.g. Ca 2+ + (soap) Ca(soap) 2 (s)
Water Softening (Precipitation Softening) (3 rd DC 178; 4 th DC 235) 1. Introduction Hardness - Multivalent metal ions which will form precipitates with soaps. e.g. Ca 2+ + (soap) Ca(soap) 2 (s) Complexation
More informationNitrogenous Fertilizer Plants
Pollution Prevention and Abatement Handbook WORLD BANK GROUP Effective July 1998 Nitrogenous Fertilizer Plants Industry Description and Practices This document addresses the production of ammonia, urea,
More informationExperiment 3: Extraction: Separation of an Acidic, a Basic and a Neutral Substance
1 Experiment 3: Extraction: Separation of an Acidic, a Basic and a Neutral Substance Read pp 142-155, 161-162, Chapter 10 and pp 163-173, Chapter 11, in LTOC. View the videos: 4.2 Extraction (Macroscale);
More informationSpecimen Paper. Chemistry 1F. Time allowed! 60 minutes
Centre Number Surname Candidate Number Specimen Paper For Examiner s Use Other Names Candidate Signature Examiner s Initials General Certificate of Secondary Education Foundation Tier Question 1 Mark Science
More informationChapter 1: Moles and equations. Learning outcomes. you should be able to:
Chapter 1: Moles and equations 1 Learning outcomes you should be able to: define and use the terms: relative atomic mass, isotopic mass and formula mass based on the 12 C scale perform calculations, including
More informationCHAPTER 3: MATTER. Active Learning Questions: 1-6, 9, 13-14; End-of-Chapter Questions: 1-18, 20, 24-32, 38-42, 44, 49-52, 55-56, 61-64
CHAPTER 3: MATTER Active Learning Questions: 1-6, 9, 13-14; End-of-Chapter Questions: 1-18, 20, 24-32, 38-42, 44, 49-52, 55-56, 61-64 3.1 MATTER Matter: Anything that has mass and occupies volume We study
More informationHow To Make A High Co 2 Gas Blend
ECONOMICAL OPTION FOR CO 2 / METHANE SEPARATION IN PRODUCED GAS CONTAINING A HIGH CO 2 FRACTION F. Patrick Ross, P.E. TPR Consulting 9907 Sagecourt Drive Houston, Texas 77089 (713) 870-9208 pat.ross@att.net
More informationNitrogenous Fertilizer Plants
Multilateral Investment Guarantee Agency Environmental Guidelines for Nitrogenous Fertilizer Plants Industry Description and Practices This document addresses the production of ammonia, urea, ammonium
More informationBest Practice in Boiler Water Treatment
Best Practice in Boiler Water Treatment Boiler Water Treatment Part 2 Internal Treatment Objectives of Internal Water Treatment 1 To control the level of total dissolved solids (TDS) within the boiler
More informationSyllabus OC18 Use litmus or a universal indicator to test a variety of solutions, and classify these as acidic, basic or neutral
Chemistry: 9. Acids and Bases Please remember to photocopy 4 pages onto one sheet by going A3 A4 and using back to back on the photocopier Syllabus OC18 Use litmus or a universal indicator to test a variety
More informationExtracting Valuable Lignin for Biorefinary Production and Replacement of Fossil Fuels
Extracting Valuable Lignin for Biorefinary Production and Replacement of Fossil Fuels Extrayendo valiosa lignina para Producción en Biorefinería y sustitución de Combustibles Fósiles Anders Larsson Martin
More informationCHEMICAL DETERMINATION OF EVERYDAY HOUSEHOLD CHEMICALS
CHEMICAL DETERMINATION OF EVERYDAY HOUSEHOLD CHEMICALS Purpose: It is important for chemists to be able to determine the composition of unknown chemicals. This can often be done by way of chemical tests.
More informationFact Sheet Technology. Bergius-Pier Process (1)
tec Energy Technology Projects Subject: Bergius 1: 1924 1945 Rev: April 2006 Fact Sheet Technology The information included in this document is property of. Use and reproduction of this document, without
More informationChapter 3 Mass Relationships in Chemical Reactions
Chapter 3 Mass Relationships in Chemical Reactions Student: 1. An atom of bromine has a mass about four times greater than that of an atom of neon. Which choice makes the correct comparison of the relative
More information1.3 Properties of Coal
1.3 Properties of Classification is classified into three major types namely anthracite, bituminous, and lignite. However there is no clear demarcation between them and coal is also further classified
More informationTREATMENT OF PHOSPHATE FERTILIZER PLANT WASTE WATER IN FLORIDA FOR DISCHARGE AND RE USE PURPOSES
TREATMENT OF PHOSPHATE FERTILIZER PLANT WASTE WATER IN FLORIDA FOR DISCHARGE AND RE USE PURPOSES JOHN F. BOSSLER, SIEMENS Water Technologies Corp., Hoffman Estates, IL RONALD TRAVIS, SIEMENS Water Technologies
More informationFURNACEPHOSPHORUS AND PHOSPHORICACID PROCESS ECONOMICS PROGRAM. Report No. 52. July 1969. A private report by. the
Report No. 52 FURNACEPHOSPHORUS AND PHOSPHORICACID by GEORGE E. HADDELAND July 1969 A private report by. the PROCESS ECONOMICS PROGRAM STANFORD RESEARCH INSTITUTE MENLO PARK, CALIFORNIA CONTENTS 1 INTRODUCTION........................
More informationEstimated emissions and CO2 savings deriving from adoption of in-place recycling techniques for road pavements
Estimated emissions and CO2 savings deriving from adoption of in-place recycling techniques for road pavements Introduction Objective: to estimate the CO2 emissions produced by road surface construction
More informationHardness ions also interfere with many chemical processes such as chemical compounding and aqueous cleaners.
Water Softeners Industrial Water Purification (800) CAL-WATER By Dave Peairs, Cal Water, Technical Director Rev: 06/08/2004 Before any discussion of water softeners, we must first define what hard water
More informationEnvironment Impact Assessment of Thermal Power Plant for Sustainable Development
International Journal of Environmental Engineering and Management. ISSN 2231-1319, Volume 4, Number 6 (2013), pp. 567-572 Research India Publications http://www.ripublication.com/ ijeem.htm Environment
More informationDEIONIZATION IN A "NUT SHELL"
Deionized Water (DI) DEIONIZATION IN A "NUT SHELL" City water is passed through dark amber colored, caviar sized plastic beads called cation ion exchange resin. The cation resin is in the hydrogen form
More informationLecture 35: Atmosphere in Furnaces
Lecture 35: Atmosphere in Furnaces Contents: Selection of atmosphere: Gases and their behavior: Prepared atmospheres Protective atmospheres applications Atmosphere volume requirements Atmosphere sensors
More informationLecture 28. Potash Fertilizers - Potassium Sulphate
Lecture 28 Potash Fertilizers - Potassium Sulphate Potassium Sulfate Potassium sulfate is the second largest tonnage potassium compound and it is also used primarily as a fertilizer. The sulfate or other
More informationBalancing Chemical Equations Worksheet
Balancing Chemical Equations Worksheet Student Instructions 1. Identify the reactants and products and write a word equation. 2. Write the correct chemical formula for each of the reactants and the products.
More informationCHAPTER 8 UPGRADING EXISTING TREATMENT FACILITIES
CHAPTER 8 UPGRADING EXISTING TREATMENT FACILITIES 8-1. General. Upgrading of wastewater treatment plants may be required to handle increased hydraulic and organic loadings to meet existing effluent quality
More informationM2M-TECHNOLOGY: THE NEW STANDARD TO MINIMIZE BAUXITE RESIDUE
Proceedings of the International Conference on Aluminium, INCAL 2007; 21-23 November 2007; Hyderabad Vol.1 (2007) 257-263; Eds. S. Subramanian and D. H. Sastry The Aluminium Association of India M2M-TECHNOLOGY:
More informationRemoving Thallium from Industrial FGD Scrubber Water with Sorbster Adsorbent Media
Case History MAR Systems Inc. Removing Thallium from Industrial FGD Scrubber Water with Sorbster Adsorbent Media Trace thallium levels in process and wastewater streams pose a human toxicity threat. Tidwell
More informationIntroduction to Waste Treatment Technologies. Contents. Household waste
Contents Introduction to waste treatment technologies 3 Section 1: The treatment of recyclable waste 4 Bulking facilities 5 Materials Reclamation Facility (MRF) 6 Reuse and recycling centres 8 Composting
More informationRemoving Heavy Metals from Wastewater
Removing Heavy Metals from Wastewater Engineering Research Center Report David M. Ayres Allen P. Davis Paul M. Gietka August 1994 1 2 Removing Heavy Metals From Wastewater Introduction This manual provides
More informationUsing Magnesium Hydroxide
Industrial Wastewater Neutralization Using Magnesium Hydroxide May 15, 2012 Steve Leykauf, Presenter Discussion Topics What is Magnesium Hydroxide? Technical Benefits of Magnesium Hydroxide Economic Benefits
More informationCGA Standard Practices Series. Article 600 Standard for Pozzolan Enhanced Grouts Used in Annular Seals & Well Destruction
California Groundwater Association An NGWA Affiliate State PO Box 14369 Santa Rosa CA 95402 707-578-4408 fax: 707-546-4906 email: cga@groundh2o.org website: www.groundh2o.org CGA Standard Practices Series
More informationWaste to Energy in Düsseldorf. for a clean city.
Waste to Energy in Düsseldorf for a clean city. Waste Management in Düsseldorf. Düsseldorf s public utilities company known as Stadtwerke Düsseldorf operates a waste to energy plant (WtE) that has been
More informationLong-Term Demonstration of CO2 Recovery from the Flue Gas of a Coal-Fired Power Station
Long-Term Demonstration of CO2 Recovery from the Flue Gas of a Coal-Fired Power Station MASAKI IIJIMA* 1 SHOJIRO IWASAKI* 1 SHINYA KISHIMOTO* 1 TORU TAKASHINA* 2 SUSUMU OKINO* 2 There is now a growing
More informationExperiment 5. Chemical Reactions A + X AX AX A + X A + BX AX + B AZ + BX AX + BZ
Experiment 5 Chemical Reactions OBJECTIVES 1. To observe the various criteria that are used to indicate that a chemical reaction has occurred. 2. To convert word equations into balanced inorganic chemical
More informationChemistry at Work. How Chemistry is used in the Water Service
Chemistry at Work How Chemistry is used in the Water Service WATER TREATMENT Everyday, more than 100 water treatment works in Northern Ireland put approximately 680 million litres of water into the supply
More informationThe European Chlor-Alkali industry: an electricity intensive sector exposed to carbon leakage
Brussels, December 2010 The European Chlor-Alkali industry: an electricity intensive sector exposed to carbon leakage The revised EU ETS (Emission Trading Scheme) Directive 2009/29/EC will have financial
More informationINCINERATION IN JAPAN
INCINERATION IN JAPAN DR. CHIAKI IZUMIKAWA Regulations in the environmental field are becoming severe and severe. At the same time, NIMBY syndrome is becoming stronger day by day. The cost of incineration
More informationWASTEWATER TREATMENT OBJECTIVES
WASTEWATER TREATMENT OBJECTIVES The student will do the following: 1. Define wastewater and list components of wastewater. 2. Describe the function of a wastewater treatment plant. 3. Create a wastewater
More informationAssignment 8: Comparison of gasification, pyrolysis and combustion
AALTO UNIVERSITY SCHOOL OF CHEMICAL TECHNOLOGY KE-40.4120 Introduction to biorefineries and biofuels Assignment 8: Comparison of gasification, pyrolysis and combustion Aino Siirala 309141 Assignment submitted
More information12 November 2008 *** I:\CIRC\MEPC\01\642.DOC INTERNATIONAL MARITIME ORGANIZATION 4 ALBERT EMBANKMENT LONDON SE1 7SR
INTERNATIONAL MARITIME ORGANIZATION 4 ALBERT EMBANKMENT LONDON SE1 7SR Telephone: 020 7735 7611 Fax: 020 7587 3210 IMO E Ref. T5/1.01 MEPC.1/Circ.642 12 November 2008 2008 REVISED GUIDELINES FOR SYSTEMS
More informationdryon Processing Technology Drying / cooling in outstanding quality we process the future
dryon Drying / cooling in outstanding quality we process the future Processing Technology task The basic process of drying is a necessary step in all sectors of industry. Drying has to be performed for
More informationPutting a chill on global warming
Carbon capture and storage Putting a chill on global warming SABINE SULZER SULZER PUMPS MARKUS DUSS SULZER CHEMTECH Whenever fuel is burned, carbon dioxide (CO ) is emitted into the atmosphere. The subsequent
More informationPhysical and Chemical Properties and Changes
Physical and Chemical Properties and Changes An understanding of material things requires an understanding of the physical and chemical characteristics of matter. A few planned experiments can help you
More informationPHYSICAL SEPARATION TECHNIQUES. Introduction
PHYSICAL SEPARATION TECHNIQUES Lab #2 Introduction When two or more substances, that do not react chemically, are blended together, the result is a mixture in which each component retains its individual
More informationCoal ash utilisation over the world and in Europe
Workshop on Environmental and Health Aspects of Coal Ash Utilization International workshop 23 rd 24 th November 2005 Tel-Aviv, Israel Coal ash utilisation over the world and in Europe Hans-Joachim Feuerborn
More informationATOMS. Multiple Choice Questions
Chapter 3 ATOMS AND MOLECULES Multiple Choice Questions 1. Which of the following correctly represents 360 g of water? (i) 2 moles of H 2 0 (ii) 20 moles of water (iii) 6.022 10 23 molecules of water (iv)
More informationExperiment 16-Acids, Bases and ph
Definitions acid-an ionic compound that releases or reacts with water to form hydrogen ion (H + ) in aqueous solution. They taste sour and turn litmus red. Acids react with certain metals such as zinc,
More information2050 LOW CARBON ECONOMY Executive Summary THE EUROPEAN CEMENT ASSOCIATION
The role of CEMENT in the 2050 LOW CARBON ECONOMY Executive Summary THE EUROPEAN CEMENT ASSOCIATION Concrete is the third most used substance in the world after air and water, a staple of modern life and
More informationMechanical Systems Competency 1.20
Competency 1.20 Mechanical systems personnel shall demonstrate a working level knowledge of the safety and health fundamentals of mechanical systems and/or components. 1. Supporting Knowledge and Skills
More informationIMPACT OF CHEMICALS ADDITION IN WATER/WASTEWATER TREATMENT ON TDS CONCENTRATION AND SLUDGE GENERATION Jurek Patoczka, PhD, PE Hatch Mott MacDonald 27 Bleeker Str., Millburn, NJ 07041 (973) 912 2541 jurek.patoczka@hatchmott.com
More information7. 1.00 atm = 760 torr = 760 mm Hg = 101.325 kpa = 14.70 psi. = 0.446 atm. = 0.993 atm. = 107 kpa 760 torr 1 atm 760 mm Hg = 790.
CHATER 3. The atmosphere is a homogeneous mixture (a solution) of gases.. Solids and liquids have essentially fixed volumes and are not able to be compressed easily. have volumes that depend on their conditions,
More informationUNIVERSITA DEGLI STUDI DI ROMA LA SAPIENZA DIPARTIMENTO INGEGNERIA CHIMICA MATERIALI AMBIENTE
UNIVERSITA DEGLI STUDI DI ROMA LA SAPIENZA DIPARTIMENTO INGEGNERIA CHIMICA MATERIALI AMBIENTE REPORT ON A TEST EXECUTED ON A KDV DEPOLYMERIZATION PLANT ON JAN 19TH 2012 IN THE ORION ECOSOLUTIONS DEMONSTRATION
More informationIT3 01 Conference, Philadelphia, PA, May 14-18, 2001
IT3 01 Conference, Philadelphia, PA, May 14-18, 2001 BAGHOUSE OPTIMIZATION AT A MEDICAL WASTE INCINERATOR R. D. Montgomery Phoenix Services, Inc. John Kumm EA Engineering, Science, and Technology C. P.
More informationPhysical flow accounts: principles and general concepts
Physical flow accounts: principles and general concepts Julian Chow United Nations Statistics Division 1 st Sub-Regional Course on SEEA 23-27 September 2013 Malaysia SEEA Conceptual Framework Outside territory
More informationWater Efficiency. Water Management Options. Boilers. for Commercial, Industrial and Institutional Facilities. Boiler Water Impurities
Water Efficiency Water Management Options Boilers for Commercial, Industrial and Institutional Facilities Boiler Water Impurities All boiler make-up water contains impurities. As clean steam is released
More informationSelf Assessment Exercise
Self Assessment Exercise Read the following extract of supporting documentation for Permit Application for Galvos plc galvanising facility and the accompanying tables. Decide if the proposed control techniques
More informationIon Selective Electrodes
Ion Selective Electrodes OAKTON has a large selection of Ion Selective Electrodes () to suit a wide variety of applications. Each electrode has a typical response time of 20 to 30 seconds but will vary
More informationFactors Affecting Precipitation of Calcium Carbonate
Factors Affecting Precipitation of Calcium Carbonate John A. Wojtowicz Chemcon Laboratory tests with clear solutions showed that precipitation of calcium carbonate does not occur in the ph range 7.5 to
More informationReuse of Alternative Water Sources for Cooling Tower Systems Two Case Studies Using Non-Traditional Water Sources
Reuse of Alternative Water Sources for Cooling Tower Systems Two Case Studies Using Non-Traditional Water Sources Matthew L. Haikalis Veolia Water Solutions & Technologies April 24, 2013 Operational Priorities
More informationENE 806, Project Report 3 CHEMICAL PRECIPITATION: WATER SOFTENING. Grégoire Seyrig Wenqian Shan
ENE 806, Project Report 3 CHEMICAL PRECIPITATION: WATER SOFTENING Grégoire Seyrig Wenqian Shan College of Engineering, Michigan State University Spring 2007 ABSTRACT The groundwater with high level initial
More informationChapter 6. Solution, Acids and Bases
Chapter 6 Solution, Acids and Bases Mixtures Two or more substances Heterogeneous- different from place to place Types of heterogeneous mixtures Suspensions- Large particles that eventually settle out
More informationSubject: Technical Letter 22 April 1977 Removal of Water Supply Contaminants -- Copper and Zinc
STATE OF ILLINOIS Department of Registration and Education JOAN G. ANDERSON DIRECTOR. SPRINGFIELD BOARD OF NATURAL RESOURCES AND CONSERVATION JOAN G. ANDERSON CHAIRMAN BIOLOGY THOMAS PARK CHEMISTRY H.
More informationEcological Aspects of Oil Shale Processing
Abstract Ecological Aspects of Oil Shale Processing Y. Zhirjakov, Institute of Oil Shale Research Tallinn Technical University Tallinn, Estonia 26 th Oil Shale Symposium Oil shale belongs to lean and environmentally
More informationContinuous process of sodium bicarbonate production by Solvay method
Continuous process of sodium bicarbonate production by Solvay method Manual to experiment nr 10 Instructor: Dr Tomasz S. Pawłowski 1 Goal of the experiment The goal of the experiment is introduction of
More informationPROPERTIES OF TYPICAL COMMERCIAL LIME PRODUCTS. Quicklimes High Calcium Dolomitic
National Lime Association L I M E The Versatile Chemical Fact Sheet PROPERTIES OF TYPICAL COMMERCIAL LIME PRODUCTS Quicklimes High Calcium Dolomitic Primary Constituents CaO CaO MgO Specific Gravity 3.2-3.4
More informationRULE 1102. DRY CLEANERS USING SOLVENT OTHER THAN PERCHLOROETHYLENE
(Adopted January 6, 1978)(Amended August 3, 1979)(Amended July 11, 1980) (Amended August 3, 1990)(Amended December 7, 1990) (Amended November 17, 2000) RULE 1102. DRY CLEANERS USING SOLVENT OTHER THAN
More informationChemistry Unit Test Review
SNC 2DI Chemistry Unit Test Review Note: this review sheet only covers the second half of our chemistry unit. You should use our mid-unit test review sheet to recall concepts from the first half of the
More informationSCH 4C1 Unit 2 Problem Set Questions taken from Frank Mustoe et all, "Chemistry 11", McGraw-Hill Ryerson, 2001
SCH 4C1 Unit 2 Problem Set Questions taken from Frank Mustoe et all, "Chemistry 11", McGraw-Hill Ryerson, 2001 1. A small pin contains 0.0178 mol of iron. How many atoms of iron are in the pin? 2. A sample
More informationRECOVERING RESOURCES FOR ALL. Integra South East Energy Recovery Facility
RECOVERING RESOURCES FOR ALL Integra South East Energy Recovery Facility Integra South East Energy Recovery Facility (ERF) is the third of its kind to be built in Hampshire and is a leading example of
More informationOXIDATION-REDUCTION TITRATIONS-Permanganometry
Experiment No. Date OXIDATION-REDUCTION TITRATIONS-Permanganometry INTRODUCTION Potassium permanganate, KMnO 4, is probably the most widely used of all volumetric oxidizing agents. It is a powerful oxidant
More informationCOAL, OIL SHALE, NATURAL BITUMEN, HEAVY OIL AND PEAT Vol. II -Extraction of Oil Shale: Surface and In Situ Retorting - Victor Yefimov and Shuyuan Li
EXTRACTION OF OIL SHALE: SURFACE AND IN SITU RETORTING Victor Yefimov Oil Shale Research Institute, KohtlaJärve, Estonia Shuyuan Li University of Petroleum, Beijing, China Keywords: Extraction, oil shale,
More informationDIN 2403 Identification of pipelines according to the fluid conveyed. Marking of pipes according to fluid transported
DIN 2403 Identification of pipelines according to the fluid conveyed. Marking of pipes according to fluid transported 1 Field of application This standard specifies the colours for the identification of
More informationThe chemical components of detergents and their roles in the washing process
The chemical components of detergents and their roles in the washing process Laundry detergents are formulated from six groups of substances :. surfactants. builders. bleachingagents. enzymes. fillers.
More informationIon Exchange Design Hand calculation. Brian Windsor (Purolite International Ltd)
Ion Exchange Design Hand calculation Brian Windsor (Purolite International Ltd) Introduction Before design programmes were introduced, every engineer had to calculate the design by hand using resin manufacturers
More information