Date issue:2006-03-23 The information contained within is provided as a service to our customers and for their information only. The information and recommendations set forth herein are made in good faith and are believed to be accurate at the date compiled. ANSMANN makes no warranty expressed or implied. 1. IDENTIFICATION 1.1 Product type: rechargeable Lithium Ion battery electrochemical system: LiCoO 2 model: prismatic cells Electrodes: Positive: LiCoO 2 Negative: carbon Electrolyte: EC, EMC, DEC, 1mol LiPF6 Nominal voltage: 3.7 7,4Volts 1.2 Supplier Name: ANSMANN GMBH ACCU-TECHNIK Address: Industriestraße 10, 97959 Assamstadt Tel/Fax: + 49 62 94 42 04 0 / + 49 62 94 42 04 44 Emergency contact: ANSMANN local dealer 2. COMPOSITION Information on Ingredients (LP103450SR) Composition Wt % CAS number Lithium Cobalt Oxide 20 50 12190-79-3 PVDF (Polyvinylidene Fluoride) < 5 24937-79-9 Carbon (Graphite) 10 30 7782-42-5 PTFE 0,5 0,8 9002-84-0 Electrolyte (EC / EMC / DEC / 1mol LiPF6) 10 20 PP + PE 3 3,5 Copper 2 11 7440-50-8 Aluminium 2 10 7429-90-5 Nickel 0,1 0,3 7440-02-0 Steel 25 35 7439-89-6 3. HAZARD IDENTIFICATION Material Emergency Overview Toxicity (Appearance) (Potential Health Effects) Lithium Cobalt Oxide Blue-Black Powder (odourless) Cobalt and Cobalt compounds are considered to be possible human carcinogen(s). By IARC: May irritate eyes, skin, nose, throat and respiratory system. May cause allergic skin sensitization (rash). Carbon Black Powder (odourless) No cases of carbon being harmful to humans have been reported. WHO and ILO have never verified that carbon irritates the skin and mucous membrane, etc. in some individuals. Li-Ion Safety Data Sheet ANSMANN GMBH ACCU-TECHNIK page 1 of 5
Bond White Powder (odourless) Inhalation and skin contact are expected to be the primary routes of occupational exposure to this material. As a finished product it is a synthetic, high molecular weight polymer. Due to its chemical and physical properties, this material does not Caution! require special handling other than the good Melt processing industrial hygiene and safety practical releases vapours employed with any industrial material of which may cause this type. Under normal processing eye, skin and conditions this material release fume or respiratory tract irritation vapour components. These release may vary with processing time and temperatures. It may lead to eye, skin and/or respiratory tract irritation. Repeated or prolonged exposures may cause nausea, drowsiness, headache and weakness, although unlikely under normal handling conditions. If this material is heated in excess of 600F (315 C) hazardous, decomposition products will be produced. Hazardous decomposition products include hydrogen fluoride and oxides of carbon. The concentrations vary with temperature and heating Electrolyte Colourless Liquid May cause moderate to severe irritation, burning and dryness of the skin. May cause Warning! eye irritation or burning. Breathing of the mists, Reacts with water vapours or fumes may irritate the nose, throat to form hydrofluoric acid. and lungs. Exposure of material with areas May cause burn to skin which contain water may generate hydrofluoric and eyes. acid which can cause immediate burns on skin, Effects may be delayed. severe eye burns, burns to the mouth and May cause blindness. gastrointestinal tract if ingested and laryngeal Probable reproductive oedema, if inhaled. Direct exposure to areas of hazard. the body need to be treated immediately to prevent injury. 4. FIRST AID MEASURES Eyes: Skin: Inhalation: Flush with water for at least 15minutes. If irritation occurs and persists, contact a medical doctor. Remove contaminated clothing and thoroughly wash with soap and plenty of water. If irritation persists, contact a medical doctor. Remove to fresh air. If breathing difficulty or discomfort occurs and persists, see a medical doctor. If breathing has stopped, give artificial respiration and see a medical doctor immediately. Li-Ion Safety Data Sheet ANSMANN GMBH ACCU-TECHNIK page 2 of 5
5. FIRE FIGHTING MEASURES Hazardous combustion products: When burned, hazardous products of combustion including fumes of carbon monoxide, carbon dioxide and fluorine can occur Extinguishing media: Basic fire fighting procedures: Water, carbon dioxide, dry chemical or foam Wear NIOSH/MSHA approved positive pressure, self contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Unusual fire and explosions hazards: This material does not represent an unusual fire or explosion hazard. Auto-Ignition temperature: Flammable limits in air, lower: Flammable limits in air, upper: no data 1,4% by volume 11% by volume 6. ACCIDENTIAL RELEASE MEASURES Procedure for release and spill: Sweep up and place in a suitable container. Dispose or waste according to all local, state and federal laws and regulations Before cleaning up measures begin, review the entire MSDS with particular attention regarding potential health effects. Take care of the recommended personal protective equipment. 7. HANDLING AND STORAGE Handling: Material Lithium Cobalt Oxide Carbon Bond Electrolyte Avoid contact with eyes, skin or clothing. Use with adequate ventilation. Wear safety glasses and rubber gloves. Wash thoroughly after handling. Storage Keep away from strong acids. Keep container closed. Store this material in a sealed enclosure to avoid dispersion of carbon fiber dust. Keep container closed. Store in tightly closed containers in a cool, dry place. This material is not hazardous under normal storage condition. However, material should be stored in closed container, in a secure area to prevent container damage and subsequent spillage Store in tightly closed containers in a cool, dry, isolated, well-ventilated area away from heat, sources of ignition and in compatibles. Store in original container. Keep from freezing. Avoid exposure to high temperatures. Li-Ion Safety Data Sheet ANSMANN GMBH ACCU-TECHNIK page 3 of 5
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Controls / Person Protection Engineering controls: Eye / Face protection: Skin protection: Respiratory protection: Special clothing: Other: Investigate engineering techniques to reduce exposures. Use with adequate ventilation and recommended personal protective equipment. Use good industrial practice to avoid eye contact. Processing of this product releases vapours or fumes which may cause eye irritation. Where eye contact may be likely wear chemical goggles and have eye flushing equipment available. Minimize skin contamination by following good industrial hygiene practices. Wearing protective gloves is recommended. Wash hands and contaminated skin thoroughly after handling. Avoid breathing dust and processing vapours. When adequate ventilation is not available wear NIOSH / MSHA respirator, approved for protection against inorganic dust. Rubber gloves Quick-drench eye wash and safety shower 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Material Appearance Odour Molecular Weight Vapour Pressure LiCoO 2 solid, Blue-Black odourless 97,88 - Powder Carbon Black Powder odourless 12,01 - PTFE Latex odourless - - PVDF Powder odourless - - Copper Metal odourless 63,55 - Nickel Metal odourless 85,69 - Aluminium Metal Odourless 26,98 - Electrolyte colourless liquid, volatile with a mild organic odour - - (EC/DEC/EMC/1mol LiPF6) Material Sublimating Point Freezing Point Solubility in water Density Melting Point (Specific gravity) LiCoO 2 - > 1000 C insoluble - (1280 deg.f) Carbon 3000 C or more - insoluble - PTFE - - soluble - PVDF - 165 172 C negligible 1,76 1,80 g/ml Copper - 1083 C insoluble 8,96 g/ml Li-Ion Safety Data Sheet ANSMANN GMBH ACCU-TECHNIK page 4 of 5
10. STABILITY AND REACTIVITY Material Stability Incompatibility Hazardous Hazardous Polymerization Decomposition Products LiCoO 2 stable acids does not polymerize none Carbon stable strong oxidants - - Bond stable strong base, ester does not occur HF, possible Ketones, Silica, oxides of Carbon Titanium Electrolyte volatile strong reducers, will not occur volatile Pentafluoride bases, strong acids, compounds, Hydrogen oxidizing agents, fluoride, Carbon moist air or water monoxide, Carbon dioxide and other decomposition product etc. 11. ECOLOGICAL INFORMATION Eco Toxicological Information: Chemical Fate Information: Environmental Effects: no information available no data are available no data are available 12. DISPOSAL INFORMATIONS Ensure disposal of material in compliance with all local, State and Federal laws and regulations 13. TRANSPORT INFORMATION Product is shipped as: Ground Air Water Non hazardous UN3090 UN3090 Lithium batteries Lithium batteries Li-Ion Safety Data Sheet ANSMANN GMBH ACCU-TECHNIK page 5 of 5