Production of Biogas by Using Food Waste

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Vol. 3, Issue 4, Jul-Agu 213, pp. 39-394 Production of Biogas by Using Food Waste S.Mohan*, K.Jagadeesan* *Department of Civil Engineering, Mahendra Engineering College, Tamilnadu-63 53 ABSTRACT The current work focuses on the generating bio-gas from food waste produced by Mahendra Engineering College Canteen using anaerobic digestion process. Attempts have been made to optimize various parameters in order to determine the most favorable recipe for maximum biogas production from the digested food waste. The biogas yields have been determined using batch anaerobic thermophilic digestion tests for a period of 9 days. Characteristic oscillation was observed in the rate of methane production, which may be due to the presence of methylotroph population in the activated sludge, which uses methane as a carbon source for their growth. The total biogas generated in the system over the experimental period was the sum of methane and carbon dioxide. Biogas produced from the decomposition of food waste was a mixture of 6% methane and 24% carbon dioxide. Keywords- Anaerobic Digestion, BOD, Biogas, Food Waste, I. INTRODUCTION Biogas refers to a gas made from anaerobic digestion of kitchen waste. Methane is a clean energy one of the constituent of biogas which has a great potential to be an alternative fuel. Abundant biomass from various institutions could be a source for Methane production where combination of waste treatment and energy production would be an advantage. In state of Tamil Nadu around of 2944 educational institutions are there, from those institutions a large amount of waste is produced but those waste are not utilized. Objective of this study is to utilize the kitchen waste in a bio digester to produce biogas which will be the alternative fuel for their kitchen energy need. This work was carried out to produce biogas in a Compact Water Plastic Tank with a fixed type, using different kitchen waste from the kitchen, hostel, and canteen in Mahendra Engineering College. 1.1 PURPOSE OF WASTE WATER TREATMENT Manufacturing of food items, chemicals ingredients and fat produces numerous by-products, solid wastes, high amounts of wastewater containing different loads of pollutants and emissions into the air. The uncontrolled release of effluents to natural water bodies increases health risks for human beings and environmental pollution. Effluents from raw hide processing food items, which produce rotten smell, crust or finished items, contain compounds of trivalent chemical compounds in most cases. Organic and other ingredients are responsible for high BOD (Biological Oxygen Demand) and COD (Chemical Oxygen Demand) values and represent an immense pollution load, causing technical problems, sophisticated technologies and high costs in concern with effluent treatment. 1.2. OBJECTIVES OF THE PRESENT STUDY Anaerobic treatment is clearly suitable for India s tropical climate. The reduced cost brought about by lower power consumption are generally enough among all the waste treatment methods even if any returns of gas utilization are neglected. 1.3. SCOPE OF PRESENT STUDY Solid and liquid waste of food is collected from kitchen and their characteristic has been studied. Before discharging waste water to water bodies it has to be treated to reduce the Chemical Oxygen Demand, Sulphate content. As a result of this treatment Biogas liberated can be used for domestic purpose. The amount of land fill has also been considerable reduced. 1.4. UPFLOW ANAEROBIC SLUDGE BLANKET (UASB) REACTORS. The UASB is a high rate suspended growth in which a pre-treated raw influent is introduced into the reactor from the bottom and distributed evenly. Flocs of anaerobic bacteria will tend to settle against moderate flow velocities. The effluent passes upward through, and helps to suspend, a blanket of anaerobic sludge. A particular matter is trapped as it passes upward through the sludge blanket, where it is retained and digested. Digestion of the particular matter retained in the sludge blanket and breakdown of soluble organic materials generate gas and relatively small amounts of new sludge. The rising gas bubbles help to mix the substrate with the anaerobic biomass. The biogas, the liquid fraction and the sludge are separated in the gas/solid/liquids phase separator, consisting of the gas collector dome and a separate quiescent settling zone. The settling zone is relatively free of mixing effect of the gas, allowing the solid particles to fall back into the reactor; the 39 P a g e

Vol. 3, Issue 4, Jul-Agu 213, pp. 39-394 clarified effluent is collected in gutters at the top of the reactor and removed. The biogas has methane content typically around 5% and may be collected and used as a fuel or flared. II. MATERIALS AND METHODS 2.1. SOURCES AND GENERATION OF FOOD WASTE Food waste which is collected from Mahendra Engineering College canteen situated in Namakkal includes vegetables, fruits and other items. The treatment process of food waste products gives hazardous waste. The usage of chemicals are one of the main reason for this.the manufacturing of food items is a process that must be accomplished by adhering to strict controls of both the local and Federal food regulatory agencies. The items of food that are manufactured are as varied as the people they serve. Common staples, exotic delicacies, snack foods and ethnic specialties are all food items that go through a controlled and precise manufacturing process with safety always at the forefront. compact water plastic material. The effective volume of the reactors was maintained at 5ml.the reactor was provide with suitable arrangements for feeding, gas collection, draining residues. Experiments were carried out in the ambient temperature. Each reactor was added with 1ml sludge and diluted to 5ml of working volume. The characters of samples are show in Table -1 2.3. EXPERIMENTAL METHODS ph was measure using digital ph meter,alkalinity, acidity were estimated according to the procedure recommended, standard methods of examination water and (APHA-AWWA1992) appropriate. III. RESULT AND DISCUSSION Fig-1 Shows setup of anaerobic reactor (UASB reactor) 2.2. SAMPLE COLLECTION. Samples for treatment of food waste, both solid and liquid were collected from Mahendra Engineering College canteen. About 15 kg of waste items collected are categorized as vegetables, fruits, rice, other food items and waste water which mixing together, forms semi solid state. Fig-2 Diagram of UASB Reactor Fig-1 Food Waste Produced From College Canteen 2.3. MATERIALS The semi solid waste used in this study is collected from college canteen. The fresh Cow Dung Slurry was added to the above food waste to supplement the reaction process. It is used as a seeding material for the reaction process in the UASB (Up flow Anaerobic Sludge Blanket Reactor). Effective micro organism collected from private company was used to accelerate the reaction process. Also yeast is added for fermentation process to take place. 2.4 EXPERIMENTAL PROCEDURE Experimental studies were carried out in batch reactors of 1ml capacity and made up Fig-3 UASB Reactor before Production of Biogas 391 P a g e

ph S.Mohan, K.Jagadeesan / International Journal of Engineering Research and Applications Vol. 3, Issue 4, Jul-Agu 213, pp. 39-394 Table-2 chemical characteristics of food waste water sample after 9days S.No Parameters Results Fig-4 UASB Reactor after Production of Biogas S.No Parameters Results 1 P H 8.2 2 T. Alkalinity mg/l 51. 3 T. Acidity mg/l 628. 4 COD mg/l 24. 5 BOD 5 mg/l 812. 6 Chloride mg/l 849. Sulphate mg/l 329. ph Total alkali nity Table-1 chemical characteristics of sample Tota l acidi ty CO D BO D Chlo ride Sulp hate -1 8.2 51 628 24 812 849 329 1-2 8.2 56 62 239 99 848 3119 2-3.9 489 6 226 11 89 313 5 3-4.9 46 583 26 62 11 2994 1 4-5.8 368 51 128 6126 683 289 9 5-6.5 343 452 14 5424 633 2538 6-.5 321 395 15 492 59 2219 9-8.3 29 359 113 4225 56 191 1 P H.1 2 T. Alkalinity mg/l 235. 3 T. Acidity mg/l 315. 4 COD mg/l 421. 5 BOD 5 mg/l 341. 6 Chloride mg/l 425. Sulphate mg/l 164. Table-3 Indicates efficiency of the USAB Reactor for the digestion of food waste Table-3 Operational parameter and treatment efficiency of USAB Reactors. However Fig-5 demonstrates the ph of the waste is gradually reduced with increasing days. The similar trends as shown Fig-6- for the alkalinity and acidity. The COD, BOD, Chloride and Sulphate are decreased with Fig 8-11 increasing time 8.4 8.2 8.8.6.4.2 6.8 6.6 6.4 Change in ph -1 1.2 2-3 3-4 4-5 5-6 6- -8 8-9 Fig- 5 ph of effluent changes with time Change in ph 8-9.1 235 315 421 341 425 164 392 P a g e

Chemical Oxygen Demand Sulphate Total acidity Chloride Alkainity Biological Oxygen Demand S.Mohan, K.Jagadeesan / International Journal of Engineering Research and Applications Vol. 3, Issue 4, Jul-Agu 213, pp. 39-394 Change in Alkainity Total alkalinity Change in Biological Oxygen Demand 6 5 4 3 2 1-1 1.2 2-3 3-4 4-5 5-6 6- -8 8-9 Fig-6 Total alkainity of effluent changes with time 6 5 4 3 2 1 Change in Total acidity -1 2-Oct 2-3 3-4 4-5 5-6 6- -8 8-9 Total acidity Fig- Acidity of effluent changes with time 3 25 2 15 1 5-1 1.2 2-3 3-4 4-5 5-6 6- -8 8-9 Fig- 9 Biological Oxygen Demand of effluent changes with time 9 8 6 5 4 3 2 1 Change in Chloride Chloride -1 1.2 2-3 3-4 4-5 5-6 6- -8 8-9 3 Change in Chemical Oxygen Demand COD Fig- 1 Chloride of effluent changes with time Change in Sulphate 35 25 3 2 25 15 2 1 15 1 5 5-1 1.2 2-3 3-4 4-5 5-6 6- -8 8-9 Fig-8 Chemical Oxygen Demand of effluent changes with time -1 1.2 2-3 3-4 4-5 5-6 6- -8 8-9 Sulphate Fig- 11 Sulphate of effluent changes with time 393 P a g e

Vol. 3, Issue 4, Jul-Agu 213, pp. 39-394 IV. CONCLUSION After the thorough study on the performance of UASB reactor and evolution of acidogenic reactor, the following collusion have been reached, As a result of the treatment of food effluent using UASB reactor, the useful bi product, bio-gas has been produced with a considerable rate of decrease in the values of COD, BOD, ph, acidity and alkalinity. Through the successful anaerobic processing inside the UASB reactor in 9days food waste treatment, methanogen gradually converts the organic acids into the methane gas and carbon dioxide, which indicates that the waste has better anaerobic biodegradability. Thus achieves a waste of resource utilization. The results show that UASB reactor can treat food waste with high contaminated load. suspended solids by a novel multi-staged UASB reactor. Environ. Techno!. 26, 1335-1362 (25). [1] Valentini A, Grant G. and Rozzi A. Anaerobic degradation kinetics of particulate organic matter: a new approach. Water Sci. Techno!. 36,239-246 (199). REFERENCES [1] BryerslD. and Mason e.a. Biopolymer particulate turnover in biological waste treatment systems: a review. Bioprocess Eng. 2, 95-19 (198). [2] Cavalcanti P.F.F., Medeiros EJ.S., Silva lk.m. and Van Handel A Excess sludge discharge frequency for UASB reactors. Water Sci. [3] G. Durai and M.Rajasimman. (211). Kinetic studies on biodegradation of wastewater in a sequential batch bioreactor: (3):19-26: 211, [4] Halalsheh M., Sawajneh Z., Zubi M., Zeeman G., Lier l, Fayyad M. and Lettinga G. (25).Treatment of strong domestic sewage in a 96 m3 UASB reactor operated at ambient temperatures: two-stage versus single-stage reactor. Biores. Techno!. 96, 5-585 (25). [5] Lihui Huang, BaoyuGao, PengGuo, Bo Zhang., (29) Application of anaerobic granular sludge to treatment of fishmeal industry wastewaters under highly saline conditions, 433-43:29 [6] Lu WANG and Yong-feng Li., (21) Biohydrogen production and wastewater treatment by anaerobic fermentation with UASBProcess, 1-4: 21. [] Nayana Kumar Behera., (29) Treatment of Industrial Effluents in am Bioreactor, 2-3 : 29 [8] Rameshraja. D. and Suresh. S., (21) Treatment ofsago Wastewater by Various Oxidation and Combined Processes 5(2):349-36, Spring 211 [9] Uemura S., Harada H., Ohashi A and Torimura S. (25). Treatment of wastewater containing large amount of 394 P a g e