The Evolution of UV LEDs and UV Systems An Update

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SOLIDUV the LED cure The Evolution of UV LEDs and UV Systems An Update Robert F. Karlicek, Jr., Ph.D.* Professor, Electrical, Computer and Systems Engineering Director, Smart Lighting Engineering Research Center Rensselaer Polytechnic Institute Troy, NY * President, Founder, SolidUV, Inc.

Outline LED Technology A quick review UVA LEDs Status Update UV Systems two approaches (based on Etendue) UV LED customer challenges Is LED Lighting predicting the UV LED future?

Semiconductor Physics controls Wavelength Empty band Ec - conduction band edge E c E v Forbidden E g An electron in the conduction band will relax to the valence band to give off light Full valance band this process is called electron-hole recombination Ev - valence band edge Semiconductor Energy Gap determines LED Wavelength Energy Gap is Material Dependent Efficiency is crystal quality dependent For (AlGaIn)N semiconductors Any wavelength from 250 nm to 650 nm is possible, but

Group III Nitrides for LEDs Wavelength (from UVC to IR possible) Same family of materials as used for LED lighting Emission wavelength changed by selecting proper alloy composition Research continuing to improve efficiency, reduce cost Complex crystal growth fabrication process determines wavelength and operating efficiency UV LEDs riding coattails of Visible LEDs for lighting

LED supply chain (still)changing rapidly Materials Processes Devices Materials & Subsystems Materials & Subsystems Integration Full Systems Integration Semiconductor Crystal Growth LED Device Packaging Integration Increasing number of players for both UVA and UVC LEDs Power designs operate at high current Chip Scale packaging developing for lighting can now be used for UVA curing New design capabilities driving greater modularity More companies entering UVA due to lighting competition UVC companies increasing, focused on germicidal apps Increasing UVC makes true Hg lamp replacement possible 2013 versus 2015 Slowing down Greater interest in curing More true than ever, but

UVA Chip Design Summary Not useful for curing Best Thermal Operation* Easiest to use for some designs** Chip Irradiance Maps * When properly designed ** Close working distance easy to make custom designs Taiwan, May 2015

UVA Power versus Wavelength Most UVA die suppliers don t offer 365 nm devices (because they are harder to make) Irradiance goes down with decreasing wavelength Note range in source irradiance due to LED binning (variation in manufacturing yield) Several companies offering very good 365 nm devices (but they are pricey) Representative state-of-art UVA LED data 4 LED 365 nm package from Seoul Viosys with circuit layout

Source Irradiance Etendue or étendue (/eɪtändu/) is a property of light in an optical system, which characterizes how "spread out" the light is in area and angle Low Etendue High irradiance at source Can use optics to focus High Etendue Lower irradiance at source Much harder to focus Subject to the Inverse Square Law 1W/cm 2 0.25W/cm 2 0.11W/cm 2

Low Source Irradiance High Entendue source: Lots of space between die Close working distance needed for high irradiance Development of flipped chip UVA LEDs (like LumiLEDs UV die) simplifies design/construction LumiLEDs Chip Scale UVA LED No Wire Bonds: Significantly increases design freedom Many design houses can make custom cure systems Easier for end users to own their designs

High LED packing density in arc direction High Source Irradiance Large power chip 2 (50 mm) focal length Low Entendue source: Close packed large LED die Simple reflective optics Larger working distances possible Better for mixed wavelength systems (UVA + UVC) SolidUV Large die design (UVA) and system Large Chip: Large die = fewer points of failure Can use simple refocusing optics Lower assembly system level packaging costs Modular design (flexible focal length, web width)

UV LED Curing Challenges Formulation optimization versus LED Wavelength (Power, wavelength, chemistry all play a role in curing) Highly segmented UV curing market (web width, line speed, chemistry, power levels) Absence (to date) of adequate UVC LEDs (but they are currently in development) UV LED system price (sticker shock for the uninitiated)

For the future of UV LED curing, look at LED Lighting LEDs replace High Power HID lamps LED Power going up, LED prices coming down LED module customization getting easier Superbowl 2015 100% LED Lighting!! Government Incentives(?) How long will the Mercury exemption be available?

Summary UVA LEDs getting better, easier to use UVA LED curing systems still riding the coat tails of LED Lighting systems Pricing for UVA LED curing hardware will continue to come down as new business models evolve UVC LEDs getting better, will see them in curing applications soon (but look out for sticker shock) THANKS!