NH Department of Environmental Services Drinking Water Program Analytical Requirements for Community Public Water Systems 2016



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Many of the parameters listed in the table below must be analyzed and reported to DES. Please pay close attention to the footnotes on page 6 which further explain the sampling requirements. The water system is responsible for sample collection, reporting, and ensuring that the correct analytical methods are used. Please visit http://des.nh.gov/organization/commissioner/pip/publications/co/documents/r-co-01-5.pdf to review the sample collection and preservation guidance document. Please contact DES Drinking Water and Groundwater Bureau at (603) 271-2513 with questions regarding drinking water compliance. Click on: http://www4.egov.nh.gov/des/nhelap/ to verify which labs are accredited by DES to perform analysis on drinking water samples. The laboratory must: 1. Use EPA approved drinking water methods specified in 40 CFR 141, 142, and 143 2. Have current drinking water accreditation for analyses 3. Comply with Env-Dw 719.02, Reporting Data from Laboratories (which includes electronic reporting) Parameter Env-Dw Group SDWIS E. coli p 702.03 Bio 3014 Absent Presence Human & animal fecal waste May cause gastro-intestinal illness Total Coliform p 702.03 Bio 3100 n.e. q Presence Naturally present in the environment None, indicates possible presence of other bacteria Aluminum l 706.01 (b,c) IOC 1002 0.05 l 0.2 0.05 Antimony 704.02 IOC 1074 0.006 0.003 Geological; flame retardants, ceramics, pesticides Arsenic 704.02 IOC 1005 0.010 0.005 Erosion of natural geological deposits; pesticide residue, industrial waste Asbestos j (fiber>10 micrometers) 704.02 IOC 1094 7 million fibers 3.5 MFL Decay of asbestos cement in water mains; per liter (MFL) j erosion of natural deposits Barium 704.02 IOC 1010 2 1 Geological; oil/gas drilling, painting, industrial waste Beryllium 704.02 IOC 1075 0.004 0.002 Geological; used in high thermal conductivity materials Cadmium 704.02 IOC 1015 0.005 0.0025 Geological; mining, smelting, metal finishing; runoff from waste batteries and paints Chloride d IOC 1017 250 d 250 Wastewater, road salt, water softeners, corrosion Chromium 704.02 IOC 1020 0.1 0.05 Discharge from steel and pulp mills; erosion of natural deposits Color l NH Department of Environmental Services Drinking Water Program Analytical Requirements for Community Public Water Systems 2016 IOC 15 color units l Copper c 704.03 IOC 5000 exceeded 1.3 Corrosion of household plumbing; at 90% c erosion of natural deposits Copper d IOC 1022 1.0 d 1.3 Increase in blood cholesterol; decrease in blood sugar Skin damage, circulatory system, carcinogen Increased risk of developing benign intestinal polyps Muscular weakness, increase in blood pressure Intestinal lesions Kidney damage Aesthetic Allergic dermatitis Gastrointestinal distress; liver or kidney damage 1

Corrosivity l IOC Non-corrosive l Cyanide (as free C) i 704.02 IOC 1024 0.2 i 0.1 Used in electroplating, steel proc, plastics, synthetic fibers Fluoride a 704.02 IOC 1025 4.0 a 2.0 Geological; additive to drinking water, toothpaste Neurological, thyroid Skeletal damage/mottled teeth in children Fluoride d IOC 1025 2.0 d 2.0 Foaming Agents l IOC 0.5 l Iron d IOC 1028 0.3 d 0.3 Geological Aesthetic Lead c 704.03 IOC 5000 exceeded 0.015 Corrosion of household plumbing; at 90% c erosion of natural deposits Manganese d IOC 1032 0.05 d 0.05 Geological Aesthetic Mercury 704.02 IOC 1035 0.002 0.001 Geological; used in mfg. of paint, paper, fungicides Nickel n IOC 1036 n.e. n Geological; electroplating, battery production, ceramics 2 Delays in physical or mental development in infants and children Nervous system disorders, kidney damage Heart, liver, skin, weight loss Nitrate (as N) 704.02 IOC 1040 10 5 Geological; fertilizer, sewage, feedlots Methemoglobinemia, Blue Baby Syndrome Nitrite (as N) 704.02 IOC 1041 1 0.5 Geological; fertilizer, sewage, feedlots Methemoglobinemia, Blue Baby Syndrome Total Nitrate and Nitrite 704.02 IOC 1038 10 5 Geological; fertilizer, sewage, feedlots Methemoglobinemia, Blue Baby Syndrome Odor l IOC 3 threshold odor number l ph b,d IOC 1925 6.5-8.5 b,d 8.5 Precipitation and geology Aesthetic Selenium 704.02 IOC 1045 0.05 0.025 Geological; by-product of copper mining/smelting Silver l Sodium r 713.08 IOC 1050 0.1 l 0.1 IOC 1052 100-250 250 Road salt, septic systems (salt from water softeners) Sulfate d IOC 1055 250 d 250 Naturally occurring Sulfide l IOC 0008 0.05 l 0.05 Thallium 704.02 IOC 1085 0.002 0.001 Geological; electronics industry, alloys and glass mfg Numbness in fingers or toes; circulatory, hair or nail loss Aesthetic Kidney, liver, or intestinal ; blood chemistry; hair loss

Total Dissolved Solids l IOC 1930 500 l 500 3 Zinc d IOC 1095 5 d 5 Galvanized pipes Possible presence of other health related heavy metals Analytical Gross Alpha e Rad 4002 n.e. e Erosion of natural deposits and radioactive materials Compliance Gross Alpha 703.01 (a) Rad 4000 15 pci/l If Detected Erosion of natural deposits and radioactive materials Radium 226 e 703.01 (a,c) Rad 4020 n.e. e Erosion of natural deposits Radium 228 e 703.01 (a,c) Rad 4030 n.e. e Erosion of natural deposits Radium 226 & 228 (Combined) 703.01 (a,c) Rad 4010 5 pci/l If Detected Erosion of natural deposits Uranium (Mass) 703.01 (a) Rad 4006 30 ug/l If Detected Erosion of natural deposits ; kidney Radon k 703.02 (a) Rad 4004 n.e. k Erosion of natural deposits and radioactive materials Beta Particles i 703.01 (a) Rad 4100 4 mrem/year i If Detected Decay of natural and man-made deposits Alachlor (Lasso) 705.02 (b) SOC 2051 0.002 If Detected Herbicide used on corn, soybeans Eyes, liver, kidney,or spleen ; anemia; increased Aldicarb (Temik) o 705.02 (b) SOC 2047 0.003 o If Detected Insecticide used on cotton, potatoes Sweating, leg weakness, nausea, nervous system Aldicarb sulfoxide o 705.02 (b) SOC 2043 0.004 o If Detected Degraded from Aldicarb by Plants Nervous system Aldicarb sulfone (aldoxycarb) o 705.02 (b) SOC 2044 0.002 o If Detected Degraded from Aldicarb by Plants Nervous system Atrazine (Atranex, Crisazine) 705.02 (b) SOC 2050 0.003 If Detected Herbicide, weed control Cardiovascular system or reproductive Carbofuran (Furadon, 4F) 705.02 (b) SOC 2046 0.04 If Detected Soil fumigation. Insecticide on corn, cotton Nervous system, reproductive difficulties, headache, sweating, nausea Chlordane 705.02 (b) SOC 2959 0.002 If Detected Banned Insecticide for termite control Liver or nervous system ; increased Dalapon h 705.02 (b,c) SOC 2031 0.2 h If Detected Herbicide Kidney Dibromochloropropane (DBCP) h 705.02 (b,c) SOC 2931 0.0002 h If Detected Soil fumigation on soybeans, corn; prohibited in 1977 Liver or kidney ; increased Di(2-ethylhexyl)adipate 705.02 (b) SOC 2035 0.4 If Detected Plastics General toxic effects or reproductive difficulties; increased Di(2-ethylhexyl)phthalate 705.02 (b) SOC 2039 0.006 If Detected Plastics Liver and reproductive ; increased Dinoseb 705.02 (b) SOC 2041 0.007 If Detected Herbicide Reproductive difficulties Diquat h 705.02 (b,c) SOC 2032 0.02 h If Detected Herbicide Cataracts Endothall h 705.02 (b,c) SOC 2033 0.1 h If Detected Herbicide Stomach and intestinal

4 Endrin i 705.02 (b) SOC 2005 0.002 i If Detected Banned Pesticide Liver /nervous system effects Ethylene dibromide (EDB) h 705.02 (b,c) SOC 2946 0.00005 h If Detected Gas additive; soil fumigant, solvent, prohibited in 1984 Reproductive, liver, or kidney, increased Glyphosate 705.02 (b) SOC 2034 0.7 If Detected Herbicide Kidney ; reproductive difficulties Heptachlor 705.02 (b) SOC 2065 0.0004 If Detected Banned insecticide Liver damage; increased Heptachlor epoxide 705.02 (b) SOC 2067 0.0002 If Detected Breakdown product of heptachlor Liver damage; increased Hexachlorobenzene 705.02 (b) SOC 2274 0.001 If Detected Fungicide, wood preservatives Liver or kidney ; reproductive difficulties; increased Hexachlorocyclopentadiene 705.02 (b) SOC 2042 0.05 If Detected Waste By-Product in mfg of Chlorinated Pesticides Lindane 705.02 (b) SOC 2010 0.0002 If Detected Insecticide used on seed, lumber, livestock, restricted 1983 Methoxychlor (DMDT, Martate) 705.02 (b) SOC 2015 0.04 If Detected Insecticide used on fruit trees, vegetables, livestock Oxamyl (Vydate) 705.02 (b) SOC 2036 0.2 If Detected Insecticide used on apples, potatoes, & tomatoes. Kidney or stomach Liver or kidney Reproductive difficulties Slight nervous system effects PAH (Benzo(a)pyrene) 705.02 (b) SOC 2306 0.0002 If Detected Fossil fuel, wood, coal, or tar burning Reproductive difficulties; increased Pentachlorophenol 705.02 (b) SOC 2326 0.001 If Detected Wood preservative and herbicide Liver or kidney ; increased Picloram 705.02 (b) SOC 2040 0.5 If Detected Herbicide Liver Polychlorinated biphenyls (PCB) h 705.02 (b,c) SOC 2383 0.0005 h If Detected Waste chemical runoff; old transformer Skin changes; immune deficiencies; reproductive or nervous system deficiencies; increased Simazine 705.02 (b) SOC 2037 0.004 If Detected Herbicide Blood Toxaphene 705.02 (b) SOC 2020 0.003 If Detected Insecticide used on cotton and cattle; prohibited in 1982 Liver, thyroid, or kidney ; increased 2,3,7,8 TCDD (Dioxin) h 705.02 (b,c) SOC 2063 0.00000003 h If Detected Combustion emissions Reproductive difficulties; increased 2,4,5 TP (Silvex) 705.02 (b) SOC 2110 0.05 If Detected Herbicide (prohibited in 1984) Liver 2,4-D 705.02 (b) SOC 2105 0.07 If Detected Herbicide to control broad leaf weeds Kidney, liver, or adrenal gland Benzene 705.01 (b) VOC 2990 0.005 If Detected Gas additive; Industrial solvent Anemia; increased Carbon tetrachloride 705.01 (b) VOC 2982 0.005 If Detected Industrial solvent/degreaser Liver ; increased risk of cancer 1,2 Dichlorobenzene (o-) 705.01 (b) VOC 2968 0.6 If Detected Industrial chemicals Liver, kidney, or circulatory system 1,4 Dichlorobenzene (para-) 705.01 (b) VOC 2969 0.075 If Detected Used in insecticides, moth balls, air deodorizers Anemia; liver, kidney, or spleen

1,2 Dichloroethane 705.01 (b) VOC 2980 0.005 If Detected Industrial extraction solvent 1,1-Dichloroethylene 705.01 (b) VOC 2977 0.007 If Detected Industrial extraction solvent Liver 1,2-Dichloroethylene (cis-) 705.01 (b) VOC 2380 0.07 If Detected Industrial extraction solvent Liver 1,2-Dichloroethylene (trans-) 705.01 (b) VOC 2979 0.1 If Detected Industrial extraction solvent Liver Dichloromethane (methylene chloride) 705.01 (b) VOC 2964 0.005 If Detected Solvent ; liver 1,2-Dichloropropane 705.01 (b) VOC 2983 0.005 If Detected Industrial solvent Ethylbenzene 705.01 (b) VOC 2992 0.7 If Detected Gas additive Kidney or liver Methyl tertiary-butyl ether 705.01 (b) VOC 2251 0.013 g (MtBE) g Methyl tertiary-butyl ether VOC 2251 0.020 d 0.020 (MtBE) d Monochlorobenzene (Chlorobenzene) If Detected Gasoline additive Kidney or liver damage; increased risk of cancer 705.01 (b) VOC 2989 0.1 If Detected Industrial solvent Liver or kidney Styrene 705.01 (b) VOC 2996 0.1 If Detected Plastic mfg; resins used in H2O treatment equip Liver, kidney, or circulatory system Tetrachloroethylene 705.01 (b) VOC 2987 0.005 If Detected Dry cleaning, industrial solvent Liver ; increased risk of cancer Toluene 705.01 (b) VOC 2991 1 If Detected Gas additive; Industrial solvent Kidney, nervous system, or liver 1,1,1-Trichloroethane 705.01 (b) VOC 2981 0.2 If Detected Industrial solvent/degreaser Nervous system, circulatory, or liver 1,2,4-Trichlorobenzene 705.01 (b) VOC 2378 0.07 If Detected Mfg of herbicides, dye carrier Adrenal gland 1,1,2-Trichloroethane 705.01 (b) VOC 2985 0.005 If Detected Industrial solvent Kidney, liver, or immune system Trichloroethylene 705.01 (b) VOC 2984 0.005 If Detected Waste from dry cleaning materials; industrial solvent Vinyl chloride 705.01 (b) VOC 2976 0.002 If Detected Leaching from PVC pipes; plastics factory discharge Xylene (total) 705.01 (b) VOC 2955 10 If Detected Paint and Ink solvent: gas refining byproduct Liver ; increased risk of cancer Nervous system damage Chloroform (Trichloromethane) f,m 705.03 (c) DBP 2941 combined 0.080 f,m Disinfection by product Bromoform f,m 705.03 (d) DBP 2942 combined 0.080 f,m Disinfection by product Bromodichloromethane f,m 705.03 (d) DBP 2943 combined 0.080 f,m Disinfection by product Chlorodibromomethane 705.03 (d) DBP 2944 combined Disinfection by product (Dibromochloromethane) f,m 0.080 f,m 5

Total Trihalomethanes f,m 705.03 (c) DBP 2950 0.080 f,m Disinfection by product Bromate m 705.03 (c) DBP 1011 0.010 m Disinfection by product (from ozonation process) Chlorite m 705.03 (c) DBP 1009 1.0 m Disinfection by product (from use of chlorine dioxide) Haloacetic Acids m 705.03 (c) DBP 2456 0.060 m Di-isopropyl ether (DIPE) e VOCU 0006 n.e. e Gasoline additive Ethyl tertiary butyl ether (ETBE) e VOCU 0005 n.e. e Gasoline additive Tertiary amyl methyl ether VOCU 0003 n.e. e Gasoline additive (TAME) e Tertiary butyl alcohol (TBA) e VOCU 0004 n.e. e Gasoline additive Abbreviations: SDWIS Safe Drinking Water Information System - Maximum Contaminant Level Bio - biological parameter Rad - radiological parameter IOC - inorganic compound SOC - synthetic organic compound VOC - volatile organic compound VOCU - volatile organic compound - unregulated DBP - disinfection by-product n.e. - not established-reporting is required Footnotes: a Fluoride has a primary of 4.0 mg/l (Env-Dw 704.02) and a secondary of 2.0 mg/l (Env-Dw 706.01) b ph is expressed in units of hydrogen ion activity c Lead and Copper samples are collected in tap water throughout the distribution system: Env-Dw 714 d Aesthetic Regulated Secondary s: Env-Dw 706 e Recommended additional reporting parameters f TTHM combined equals 0.080 mg/l; DBP Group samples are collected in tap water throughout the distribution system: Env-Dw 705.03 and Env-Dw 715 g MtBE has a primary of 0.013 mg/l (Env-Dw 705.01) and a secondary of 0.020 mg/l (Env-Dw 706.01) h Sampling required only as part of the initial pumping test and water quality sampling program required by Env-Dw 301 or Env-Dw 302, as applicable; Env-Dw 705.02(c) i Testing required only for systems deemed vulnerable by DES and notified that testing is mandatory j Monitoring for Asbestos is conducted every 9 years for systems containing asbestos lined pipes: Env-Dw 711 k Radon testing only required for initial water quality of new wells: Env-Dw 710.05 l Secondary s waived after initial water quality testing: Env-Dw 706.02(b) m Only applicable to systems that add a chemical disinfectant in the treatment process: Env-Dw 705.03 and Env-Dw 715 n Monitoring and reporting requirements for nickel remain even though the and G were removed from state/federal regulations o s have been federally established for Aldicarbs but no monitoring is required: Env-Dw 712.10 p Bio Group samples are collected during the initial pumping test and then in tap water throughout the distribution system (Env-Dw 709) or source water (Env-Dw 717) q Presence of Total Coliform may trigger additional requirements (Env-Dw 709, 717, & 720) r Special Sodium requirements mandate periodic sampling and reporting (Env-Dw 713.08) s:\wd-drinkingwatergroundwater\monitoring\programs\monitoring\sdwa lists\sdwalist update jan 2016.doc Nervous system, increased risk of anemia 6