Ferthaul Florida RS LLC PO #: null 6311 Inducon Corporate Drive, Ste. 5 Client Project #: Lake Apopka Sanborn,NY 14132 Date Sampled: Jan 21, 2015 Feb 13, 2015; Invoice: 256750 Invoice Description Amount Units Extension DWPPCB-FL 675.00 1 675.00 DWPrimarySecondary_NoGA 315.00 1 315.00 DWVOC502 75.00 1 75.00 Paid -1,065.00 1-1,065.00 TOTAL 0.00 This invoice is due upon receipt. VISA, MasterCard, and American Express cards will be accepted. There will be a 1.5% service charge per month on all unpaid balances.
Florida Department of Environmental Protection Safe Drinking Water Program Laboratory Reporting Format PUBLIC WATER SYSTEM INFORMATION (to be completed by sampler - please type or pring legibly) System Name: PWS I.D. #: System Type (check one): Community Nontransient Noncommunity Transient Noncommunity Address: City: ZIP Code: Phone #: Fax #: E-Mail Address: SAMPLE INFORMATION (to be completed by sampler) Sample Number: 256750SW1 Sample Date: Sample Time: AM PM (Circle One) Sample Location (be specific): Location Code: Treated Disinfectant Residual (required when reporting trihalomethanes and haloacetic acids): mg/l Field ph: Sample Type (Check Only One) Reason(s) for Sample (Check all that apply) Distribution Routine Compliance (with 62-550) Replacement (of Invalidated Sample) Entry Point (to Distribution) Confirmation of MCL Exceedance* Special (not for compliance with 62-550) Plant Tap (not for compliance with 62-550) Composite of Multiple Sites ** Clearance (permitting) Raw (at well or intake) Max Residence Time Other: Sampling Procedure Used or Other Comments: Avg Residence Time Near First Customer * See 62-550.500(6) for requirements and restrictions ** See 62-550.550(4) for requirements and And 62-550.512(3) for nitrate or nitrite exceedances. attach a results page for each site. SAMPLER CERTIFICATION I,,, do HEREBY CERTIFY (Print Name) that the above public water system and collection information is complete and correct. (Print Title) Signature: Date: Certified Operator #: Phone #: Sampler's Fax: Sampler's E-Mail: Page 1 of 6
Florida Department of Environmental Protection Safe Drinking Water Program Laboratory Reporting Format LABORATORY CERTIFICATION INFORMATION (to be completed by lab - please type or print legibly) Lab Name: Flowers Chemical Laboratories, Inc. Florida DOH Certification #: E83018 Certification Expiration Date: 6/30/2015 ATTACH CURRENT DOH ANALYTE SHEET* Address: P. O. Box 150597, Altamonte Springs, FL 32715-0597 Phone #: 407-339-5984 Were any analyses subcontracted? Yes No If yes, please provide DOH certification number(s): ATTACH DOH ANALYTE SHEET FOR EACH SUBCONTRACTED LAB* ANALYSIS INFORMATION(to be completed by lab) Date Sample(s) Received: 01/21/15 PWS ID (From Page 1): Sample Number (From Page 1): 256750SW1 Lab Assigned Report # or Job ID: 256750 Group(s) analyzed and results attached for compliance with Chapter 62-550, F.A.C. (check all that apply) Inorganics Synthetic Organics Volatile Organics Disinfection Byproducts Radionuclides Secondaries All Except Asbestos All 30 All 21 Trihalomethanes Single Sample All 14 Partial All Except Dioxin Partial Haloacetic Acids Qtrly Composite** Partial Nitrate Partial Chlorite Nitrite Dioxin Only Bromate Asbestos LAB CERTIFICATION I, Jefferson S. Flowers, Technical Director, do HEREBY CERTIFY that all attached analytical data are correct and unless noted meet all requirements of the National Environmental Laboratory Accreditation Conference (NELAC). Signature: Date: 02/13/15 * Failure to provide a valid and current Florida DOH certification number and a current Analyte Sheet for the attached analysis results will result in rejection of the report and possible enforcement against the public water system for failure to sample, and may result in notification of the DOH Bureau of Laboratory Services. ** Please provide radiological sample dates & locations for each quarter. CONFIRMATION AND NOTIFICATION IS REQUIRED WITHIN 24 HRS FOR NITRATE MCL EXCEEDANCES NON-DETECTS ARE TO BE REPORTED AS THE MDL WITH A "U" QUALIFIER. (Non-detects reported as "BDL" or with a "<" are not acceptable.) Compliance Determination (to be completed by DEP or DOH - attach notes as necessary) Sample Collection & Analysis Satisfactory Yes No Replacement Sample or Report Requested (circle or highlight group(s) above) Person Notified: Date Notified: DEP/DOH Reviewing Official: Page 2 of 6
Florida Department of Environmental Protection Safe Drinking Water Program Laboratory Reporting Format INORGANIC CONTAMINANTS Report Number / Job ID: 256750SW1 62-550.310(1) PWS ID (From Page 1): Lake Apopka Contam Analysis Analytical Lab Analysis Analysis DOH Lab ID Contam Name MCL Units Result Qualifier Method MDL Date Time Cert # 1040 Nitrate (as N) 10 mg/l 0.200 U EPA300.0 0.200 01/22/15 12:30 PM E83018 1041 Nitrite (as N) 1 mg/l 0.200 U EPA300.0 0.200 01/22/15 12:30 PM E83018 1005 Arsenic 0.010 mg/l 0.00410 EPA200.8 0.00100 01/22/15 E83018 1010 Barium 2 mg/l 0.00200 U EPA200.8 0.00200 01/22/15 E83018 1015 Cadmium 0.005 mg/l 0.00100 U EPA200.8 0.00100 01/22/15 E83018 1020 Chromium 0.1 mg/l 0.00100 U EPA200.8 0.00100 01/22/15 E83018 1024 Cyanide 0.2 mg/l 0.00500 U SM4500CN-E 0.00500 01/23/15 E83018 1025 Fluoride 4.0 mg/l 0.354 EPA300.0 0.200 01/22/15 E83018 1030 Lead 0.015 mg/l 0.00840 EPA200.8 0.00100 01/22/15 E83018 1035 Mercury 0.002 mg/l 0.0000200 U EPA245.1 0.0000200 01/27/15 E83018 1036 Nickel 0.1 mg/l 0.00110 EPA200.8 0.00100 01/22/15 E83018 1045 Selenium 0.05 mg/l 0.00200 U EPA200.8 0.00200 01/22/15 E83018 1052 Sodium 160 mg/l 16.8 EPA200.7 0.500 01/22/15 E83018 1074 Antimony 0.006 mg/l 0.00100 U EPA200.8 0.00100 01/22/15 E83018 1075 Beryllium 0.004 mg/l 0.000500 U EPA200.8 0.000500 01/22/15 E83018 1085 Thallium 0.002 mg/l 0.00100 U EPA200.8 0.00100 01/22/15 E83018 Page 3 of 6
Florida Department of Environmental Protection Safe Drinking Water Program Laboratory Reporting Format SECONDARY CONTAMINANTS Report Number / Job ID: 256750SW1 62-550.320 PWS ID (From Page 1): Lake Apopka Contam Analysis Analytical Lab Analysis Analysis DOH Lab ID Contam Name MCL Units Result Qualifier Method MDL Date Time Cert # 1002 Aluminum 0.2 mg/l 0.0934 EPA200.8 0.0200 01/22/15 E83018 1017 Chloride 250 mg/l 44.0 EPA300.0 0.400 01/22/15 E83018 1022 Copper 1 mg/l 0.00900 EPA200.8 0.00100 01/22/15 E83018 1025 Fluoride 4.0 mg/l 0.354 EPA300.0 0.200 01/22/15 E83018 1028 Iron 0.3 mg/l 0.176 EPA200.7 0.0100 01/22/15 E83018 1032 Manganese 0.05 mg/l 0.0326 EPA200.7 0.0100 01/22/15 E83018 1050 Silver 0.1 mg/l 0.000500 U EPA200.8 0.000500 01/22/15 E83018 1055 Sulfate 250 mg/l 21.5 EPA300.0 1.00 01/22/15 E83018 1095 Zinc 5 mg/l 0.107 EPA200.8 0.0100 01/22/15 E83018 1905 Color 15 CU 50.0 SM2120 B 5.00 01/21/15 03:30 AM E83018 1925 ph 6.5-8.5 ph 7.82 SM4500-H B 0.0100 01/21/15 04:12 PM E83018 1930 Total Dissolved Solids 500 mg/l 322 SM2540 C 2.50 01/24/15 E83018 2905 Foaming Agents 0.5 mg/l 0.200 U SM5540 C 0.200 01/22/15 01:00 PM E83018 Page 4 of 6
Florida Department of Environmental Protection Safe Drinking Water Program Laboratory Reporting Format VOLATILE ORGANICS 62-550.310(2)(b) Report Number / Job ID: 256750SW1 PWS ID (From Page 1): Lake Apopka Contam Analysis Analytical Lab Analysis Analysis DOH Lab ID Contam Name MCL Units Result Qualifier Method MDL RDL Date Time Cert # 2378 1,2,4,-trichlorobenzene 70 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2380 cis-1,2-dichloroethylene 70 ug/l 0.200 U EPA502.2 0.200 0.5 01/27/15 E83018 2955 Xylenes 10000 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2964 Dichloromethane 5 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2968 o-dichlorobenzene 600 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2969 Para-dichlorobenzene 75 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2976 Vinyl Chloride 1 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2977 1,1-Dichloroethylene 7 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2979 trans-1,2-dichloroethylene 100 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2980 1,2-Dichloroethane 3 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2981 1,1,1-trichloroethane 200 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2982 Carbon tetrachloride 3 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2983 1,2-dichloropropane 5 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2984 Trichloroethylene 3 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2985 1,1,2-trichloroethane 5 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2987 Tetrachloroethylene 3 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2989 Monochlorobenzene 100 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2990 Benzene 1 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2991 Toluene 1000 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2992 Ethylbenzene 700 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 2996 Styrene 100 ug/l 0.500 U EPA502.2 0.500 0.5 01/27/15 E83018 Page 5 of 6
Florida Department of Environmental Protection Safe Drinking Water Program Laboratory Reporting Format SYNTHETIC ORGANICS 62-550.310(2)(c) Report Number / Job ID: 256750SW1 PWS ID (From Page 1): Lake Apopka Contam Analysis Analytical Lab Extraction Analysis Analysis DOH Lab ID Contam Name MCL Units Result Qualifier Method MDL RDL Date Date Time Cert # 2005 Endrin 2 ug/l 0.0100 U EPA505 0.0100 0.01 01/28/15 01/29/15 E83018 2010 Lindane 0.2 ug/l 0.0100 U EPA505 0.0100 0.02 01/28/15 01/29/15 E83018 2015 Methoxychlor 40 ug/l 0.0500 U EPA505 0.0500 0.1 01/28/15 01/29/15 E83018 2020 Toxaphene 3 ug/l 0.500 U EPA505 0.500 1 01/28/15 01/29/15 E83018 2031 Dalapon 200 ug/l 0.100 U EPA515.4 0.100 1 01/23/15 02/02/15 E83018 2032 Diquat 20 ug/l 0.400 U EPA549.2 0.400 0.4 01/26/15 01/28/15 E83018 2033 Endothall 100 ug/l 9.00 U EPA548.1 9.00 9 02/03/15 02/06/15 E83018 2034 Glyphosate 700 ug/l 6.00 U EPA547 6.00 6 01/23/15 E83018 2035 Di(2-ethylhexyl) adipate 400 ug/l 0.600 U EPA525.2 0.600 0.6 02/04/15 02/11/15 E83018 2036 Oxamyl (Vydate) 200 ug/l 2.00 U EPA531.1 2.00 2.0 02/04/15 E83018 2037 Simazine 4 ug/l 0.0700 U EPA507 0.0700 0.07 01/29/15 02/11/15 E83018 2039 Di(2-ethylhexyl)phthalate 6 ug/l 10.1 EPA525.2 0.600 0.6 02/04/15 02/11/15 E83018 2040 Picloram 500 ug/l 0.100 U EPA515.4 0.100 0.1 01/23/15 02/02/15 E83018 2041 Dinoseb 7 ug/l 0.200 U EPA515.4 0.200 0.2 01/23/15 02/02/15 E83018 2042 Hexachlorocyclopentadiene 50 ug/l 0.100 U EPA505 0.100 0.1 01/28/15 01/29/15 E83018 2046 Carbofuran 40 ug/l 0.900 U EPA531.1 0.900 0.9 02/04/15 E83018 2050 Atrazine 3 ug/l 0.100 U EPA507 0.100 0.1 01/29/15 02/11/15 E83018 2051 Alachlor 2 ug/l 0.200 U EPA507 0.200 0.2 01/29/15 02/11/15 E83018 2065 Heptachlor 0.4 ug/l 0.0100 U EPA505 0.0100 0.04 01/28/15 01/29/15 E83018 2067 Heptachlor epoxide 0.2 ug/l 0.0100 U EPA505 0.0100 0.02 01/28/15 01/29/15 E83018 2105 2,4-D 70 ug/l 0.100 U EPA515.4 0.100 0.1 01/23/15 02/02/15 E83018 2110 2,4,5-TP 50 ug/l 0.200 U EPA515.4 0.200 0.2 01/23/15 02/02/15 E83018 2274 Hexachlorobenzene 1 ug/l 0.100 U EPA505 0.100 0.1 01/28/15 01/29/15 E83018 2306 Benzo(a)pyrene 0.2 ug/l 0.0200 U EPA525.2 0.0200 0.02 02/04/15 02/11/15 E83018 2326 Pentachlorophenol 1 ug/l 0.0400 U EPA515.4 0.0400 0.04 01/23/15 02/02/15 E83018 2383 PolychlorinatedbiphenylsPCB 0.5 ug/l 0.100 U EPA505 0.100 0.1 01/28/15 01/29/15 E83018 2931 Dibromochloropropane 0.2 ug/l 0.0194 U EPA504.1 0.0194 0.02 01/28/15 01/29/15 E83018 2946 Ethylene Dibromide 0.02 ug/l 0.00969 U EPA504.1 0.00969 0.01 01/28/15 01/29/15 E83018 2959 Chlordane 2 ug/l 0.0100 U EPA505 0.0100 0.2 01/28/15 01/29/15 E83018 Page 6 of 6
Ferthaul Florida RS LLC PO #: n/a 6311 Inducon Corporate Drive, Ste. 5 Client Project #: Lake Apopka Sanborn,NY 14132 Date Sampled: Jan 20, 2015 Jan 26, 2015; Invoice: 256748 Invoice Description Amount Units Extension EPA200.7 - Calcium 12.00 2 24.00 EPA200.7 - Iron 12.00 2 24.00 EPA200.7 - Magnesium 12.00 2 24.00 EPA200.7 - Manganese 12.00 2 24.00 EPA200.7 - Potassium 12.00 2 24.00 EPA200.7 - Sodium 12.00 2 24.00 EPA200.8 - Aluminum 12.00 2 24.00 EPA200.8 - Arsenic 12.00 2 24.00 EPA200.8 - Barium 12.00 2 24.00 EPA200.8 - Cadmium 12.00 2 24.00 EPA200.8 - Chromium 12.00 2 24.00 EPA200.8 - Lead 12.00 2 24.00 EPA200.8 - Molybdenum 12.00 2 24.00 EPA200.8 - Nickel 12.00 2 24.00 EPA200.8 - Selenium 12.00 2 24.00 EPA200.8 - Silver 12.00 2 24.00 EPA200.8 - Zinc 12.00 2 24.00 Paid -408.00 1-408.00 TOTAL 0.00 This invoice is due upon receipt. VISA, MasterCard, and American Express cards will be accepted. There will be a 1.5% service charge per month on all unpaid balances. FLDOH: E83018 (Main Lab) FLDOH: E86562 (South Lab) FLDOH: E82405 (North Lab) NJDEP: FL015
Ferthaul Florida RS LLC PO #: n/a 6311 Inducon Corporate Drive, Ste. 5 Client Project #: Lake Apopka Sanborn,NY 14132 Date Sampled: Jan 20, 2015 Jan 26, 2015; Invoice: 256748 Report Summary Date Received: Jan 21, 2015 FCL Project Manager: Michelle M. Garver Laboratory # Sample Description Analysis Chemist Location SampleMatrix 256748SW1 Raw EPA200.7 EVB Main Lab Surface Water EPA200.8 EVB Main Lab 256748SW2 Treated EPA200.7 EVB Main Lab Surface Water EPA200.8 EVB Main Lab Certificate of Results Sample integrity was certified prior to analysis. Test results meet all requirements of the NELAC Standards except as noted in the Quality Control Report. Uncertainties for these data are available on request. This report may not be reproduced in part; results relate only to items tested. FLDOH: E83018 (Main Lab) FLDOH: E86562 (South Lab) FLDOH: E82405 (North Lab) NJDEP: FL015 Page 1 of 7
Ferthaul Florida RS LLC PO #: n/a 6311 Inducon Corporate Drive, Ste. 5 Client Project #: Lake Apopka Sanborn,NY 14132 Date Sampled: Jan 20, 2015 Jan 26, 2015; Invoice: 256748 Analysis Report Lab #: 256748SW1 Sampled: 01/20/15 11:03 AM Desc: Raw Parameter Result Units DF MDL PQL QC Batch Method CAS # Analyzed Calcium 443 mg/l 5.00 0.500 1.00 10272931 EPA200.7 7440-70-2 01/22/15 Iron 110 mg/l 5.00 0.0500 0.100 10272931 EPA200.7 7439-89-6 01/22/15 Magnesium 71.9 mg/l 5.00 0.0500 0.100 10272931 EPA200.7 7439-95-4 01/22/15 Manganese 1.50 mg/l 5.00 0.0500 0.100 10272931 EPA200.7 7439-96-5 01/22/15 Potassium 18.0 mg/l 5.00 2.50 5.00 10272931 EPA200.7 7440-09-7 01/22/15 Sodium 26.8 mg/l 5.00 2.50 5.00 10272931 EPA200.7 7440-23-5 01/22/15 Aluminum 47.8 mg/l 1.00 0.0100 0.0200 10272940 EPA200.8 7429-90-5 01/22/15 Arsenic 0.175 mg/l 1.00 0.00100 0.00200 10272940 EPA200.8 7440-38-2 01/22/15 Barium 0.647 mg/l 1.00 0.00200 0.00400 10272940 EPA200.8 7440-39-3 01/22/15 Cadmium 0.000200 U mg/l 1.00 0.000200 0.000400 10272940 EPA200.8 7440-43-9 01/22/15 Chromium 0.0487 mg/l 1.00 0.00100 0.00200 10272940 EPA200.8 7440-47-3 01/22/15 Lead 0.282 mg/l 1.00 0.00100 0.00200 10272940 EPA200.8 7439-92-1 01/22/15 Molybdenum 0.457 mg/l 1.00 0.00100 0.00200 10272940 EPA200.8 7439-98-7 01/22/15 Nickel 0.0907 mg/l 1.00 0.00100 0.00200 10272940 EPA200.8 7440-02-0 01/22/15 Selenium 0.00200 U mg/l 1.00 0.00200 0.00400 10272940 EPA200.8 7782-49-2 01/22/15 Silver 0.000500 U mg/l 1.00 0.000500 0.00100 10272940 EPA200.8 7440-22-4 01/22/15 Zinc 8.75 mg/l 1.00 0.0100 0.0200 10272940 EPA200.8 7440-66-6 01/22/15 Lab #: 256748SW2 Sampled: 01/21/15 10:30 AM Desc: Treated Parameter Result Units DF MDL PQL QC Batch Method CAS # Analyzed Calcium 37.3 mg/l 1.00 0.100 0.200 10272934 EPA200.7 7440-70-2 01/22/15 Iron 0.195 mg/l 1.00 0.0100 0.0200 10272934 EPA200.7 7439-89-6 01/22/15 Magnesium 15.5 mg/l 1.00 0.0100 0.0200 10272934 EPA200.7 7439-95-4 01/22/15 Manganese 0.0362 mg/l 1.00 0.0100 0.0200 10272934 EPA200.7 7439-96-5 01/22/15 Potassium 8.36 mg/l 1.00 0.500 1.00 10272934 EPA200.7 7440-09-7 01/22/15 Sodium 18.7 mg/l 1.00 0.500 1.00 10272934 EPA200.7 7440-23-5 01/22/15 Aluminum 0.104 mg/l 1.00 0.0100 0.0200 10272940 EPA200.8 7429-90-5 01/22/15 FLDOH: E83018 (Main Lab) FLDOH: E86562 (South Lab) FLDOH: E82405 (North Lab) NJDEP: FL015 Page 2 of 7
Ferthaul Florida RS LLC PO #: n/a 6311 Inducon Corporate Drive, Ste. 5 Client Project #: Lake Apopka Sanborn,NY 14132 Date Sampled: Jan 20, 2015 Jan 26, 2015; Invoice: 256748 Lab #: 256748SW2 Sampled: 01/21/15 10:30 AM Desc: Treated Parameter Result Units DF MDL PQL QC Batch Method CAS # Analyzed Arsenic 0.00460 mg/l 1.00 0.00100 0.00200 10272940 EPA200.8 7440-38-2 01/22/15 Barium 0.0293 mg/l 1.00 0.00200 0.00400 10272940 EPA200.8 7440-39-3 01/22/15 Cadmium 0.000200 U mg/l 1.00 0.000200 0.000400 10272940 EPA200.8 7440-43-9 01/22/15 Chromium 0.00100 U mg/l 1.00 0.00100 0.00200 10272940 EPA200.8 7440-47-3 01/22/15 Lead 0.00930 mg/l 1.00 0.00100 0.00200 10272940 EPA200.8 7439-92-1 01/22/15 Molybdenum 0.0156 mg/l 1.00 0.00100 0.00200 10272940 EPA200.8 7439-98-7 01/22/15 Nickel 0.00120 I mg/l 1.00 0.00100 0.00200 10272940 EPA200.8 7440-02-0 01/22/15 Selenium 0.00200 U mg/l 1.00 0.00200 0.00400 10272940 EPA200.8 7782-49-2 01/22/15 Silver 0.000500 U mg/l 1.00 0.000500 0.00100 10272940 EPA200.8 7440-22-4 01/22/15 Zinc 0.119 mg/l 1.00 0.0100 0.0200 10272940 EPA200.8 7440-66-6 01/22/15 FLDOH: E83018 (Main Lab) FLDOH: E86562 (South Lab) FLDOH: E82405 (North Lab) NJDEP: FL015 Page 3 of 7
Ferthaul Florida RS LLC PO #: n/a 6311 Inducon Corporate Drive, Ste. 5 Client Project #: Lake Apopka Sanborn,NY 14132 Date Sampled: Jan 20, 2015 Jan 26, 2015; Invoice: 256748 Quality Control Batch: 10272934 Analyst: EVB Blank Result Units Calcium 0.100U mg/l Magnesium 0.0100U mg/l Potassium 0.500U mg/l Sodium 0.500U mg/l Quality Report Laboratory Control Sample Result Units Spike %REC %REC Lim Calcium 5.09 mg/l 5.00 101.72 83.48-116.15 Magnesium 5.45 mg/l 5.00 109.06 86.59-116.04 Potassium 5.44 mg/l 5.00 108.80 79.31-118.21 Sodium 5.44 mg/l 5.00 108.71 74.97-117.25 Matrix Spike Result Units Spike %REC %REC Lim Sample Calcium 65.1 mg/l 5.00 99.04 47.14-155.80 60.1 Magnesium 11.6 mg/l 5.00 112.63 59.48-144.06 6.02 Potassium 6.71 mg/l 5.00 112.58 45.10-147.16 1.08 Sodium 20.7 mg/l 5.00 105.90 39.47-153.02 15.4 Matrix Spike Duplicate Result Units Spike %REC %REC Lim Sample RPD RPD Lim Calcium 66.0 mg/l 5.00 118.78 47.14-155.80 60.1 1.51 16.77 Magnesium 11.4 mg/l 5.00 108.26 59.48-144.06 6.02 1.89 23.14 Potassium 6.28 mg/l 5.00 103.99 45.10-147.16 1.08 6.62 27.75 Sodium 20.7 mg/l 5.00 105.16 39.47-153.02 15.4 0.18 25.12 Quality Control Batch: 10272940 Analyst: EVB Blank Result Units Arsenic 0.00100U mg/l FLDOH: E83018 (Main Lab) FLDOH: E86562 (South Lab) FLDOH: E82405 (North Lab) NJDEP: FL015 Page 4 of 7
Ferthaul Florida RS LLC PO #: n/a 6311 Inducon Corporate Drive, Ste. 5 Client Project #: Lake Apopka Sanborn,NY 14132 Date Sampled: Jan 20, 2015 Jan 26, 2015; Invoice: 256748 Quality Control Batch: 10272940 Analyst: EVB Blank Result Units Barium 0.200U mg/l Cadmium 0.00100U mg/l Chromium 0.00100U mg/l Lead 0.00100U mg/l Selenium 0.00200U mg/l Silver 0.000500U mg/l Zinc 0.0100U mg/l Laboratory Control Sample Result Units Spike %REC %REC Lim Arsenic 0.102 mg/l 0.100 102.40 76.69-122.02 Barium 0.0921 mg/l 0.100 92.10 76.34-147.17 Cadmium 0.0986 mg/l 0.100 98.60 83.55-122.24 Chromium 0.0876 mg/l 0.100 87.60 87.30-123.19 Lead 0.109 mg/l 0.100 109.40 90.62-122.65 Selenium 0.106 mg/l 0.100 106.10 83.76-121.21 Silver 0.0959 mg/l 0.100 95.90 73.58-125.68 Zinc 0.109 mg/l 0.100 108.70 80.98-122.30 Matrix Spike Result Units Spike %REC %REC Lim Sample Arsenic 0.138 mg/l 0.100 138.20 72.43-140.81 0.00100U Barium 0.107 mg/l 0.100 106.90 77.22-161.82 0.200U Cadmium 0.124 mg/l 0.100 123.60 77.67-136.39 0.00100U Chromium 0.0993 mg/l 0.100 99.30 68.85-144.78 0.00100U Lead 0.122 mg/l 0.100 121.60 73.93-150.56 0.00100U Selenium 0.157 mg/l 0.100 156.80 65.85-157.62 0.00200U Silver 0.0736 mg/l 0.100 73.60 49.42-144.48 0.000500U Zinc 0.139 mg/l 0.100 111.70 54.51-142.91 0.0271 Matrix Spike Duplicate Result Units Spike %REC %REC Lim Sample RPD RPD Lim FLDOH: E83018 (Main Lab) FLDOH: E86562 (South Lab) FLDOH: E82405 (North Lab) NJDEP: FL015 Page 5 of 7
Ferthaul Florida RS LLC PO #: n/a 6311 Inducon Corporate Drive, Ste. 5 Client Project #: Lake Apopka Sanborn,NY 14132 Date Sampled: Jan 20, 2015 Jan 26, 2015; Invoice: 256748 Quality Control Batch: 10272940 Analyst: EVB Matrix Spike Duplicate Result Units Spike %REC %REC Lim Sample RPD RPD Lim Arsenic 0.121 mg/l 0.100 120.60 72.43-140.81 0.00100U 13.60 33.14 Barium 0.0966 mg/l 0.100 96.60 77.22-161.82 0.200U 10.12 42.16 Cadmium 0.108 mg/l 0.100 107.90 77.67-136.39 0.00100U 13.56 30.49 Chromium 0.0854 mg/l 0.100 85.40 68.85-144.78 0.00100U 15.05 32.41 Lead 0.107 mg/l 0.100 107.00 73.93-150.56 0.00100U 12.77 24.91 Selenium 0.137 mg/l 0.100 137.10 65.85-157.62 0.00200U 13.41 27.04 Silver 0.0780 mg/l 0.100 78.00 49.42-144.48 0.000500U 5.80 22.29 Zinc 0.135 mg/l 0.100 107.70 54.51-142.91 0.0271 2.92 24.70 FLDOH: E83018 (Main Lab) FLDOH: E86562 (South Lab) FLDOH: E82405 (North Lab) NJDEP: FL015 Page 6 of 7
Ferthaul Florida RS LLC PO #: n/a 6311 Inducon Corporate Drive, Ste. 5 Client Project #: Lake Apopka Sanborn,NY 14132 Date Sampled: Jan 20, 2015 Jan 26, 2015; Invoice: 256748 Narrative Report Sample Handling Sample handling and holding time criteria were met for all samples. Samples collected by submitter. No unusual events occurred during analysis. Results are reported on a wet weight basis for aqueous matrices and on a dry weight basis for sludge and soil matrices unless otherwise noted. Sample results reported as dissolved were field filtered. Quality Control Enclosed analyses met method or FCL criteria, unless otherwise denoted on the sample results. Applied data qualifiers are defined below. Attachments Chain of Custody Qualifier U J J1 J2 J3 J4 Q L V ZTNTC A P T M G S O I B Y Meaning Compound was analyzed for but not detected. One or more QC samples associated with this data value exceeded QC limits. Surrogate recovery limits have been exceeded. No known quality control criteria exist for the component. Reported value failed to meet established quality control criteria for either precision or accuracy. Sample matrix interfered with the ability to make an accurate determination on the spiked sample. Sample held beyond the accepted holding time. Off-scale high; reported concentration exceeds the highest standard. Analyte was detected in both the sample and the associated method blank. Too numerous to count. Numeric value represents filtration volume. Absent Present Value reported is less than the statistical method detection limit. Reported for informational purposes only. Value reported is greater than the statistical method detection limit, but less than the reported MDL. The greatest of the dilutions performed did not yield sufficient oxygen depletion for valid data. The least of the dilutions performed did not yield sufficient oxygen residual for valid data. Result is greater than (over) the specified value. Reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. Results based upon colony plate count outside ideal range. The laboratory analysis was from an improperly preserved sample. The data may not be accurate. FLDOH: E83018 (Main Lab) FLDOH: E86562 (South Lab) FLDOH: E82405 (North Lab) NJDEP: FL015 Page 7 of 7
Ferthaul Florida RS LLC PO #: n/a 6311 Inducon Corporate Drive, Ste. 5 Client Project #: Lake Apopka Sanborn,NY 14132 Date Sampled: Jan 20, 2015 Jan 23, 2015; Invoice: 256745 Invoice Description Amount Units Extension Paid -100.00 1-100.00 TP 25.00 4 100.00 TOTAL 0.00 This invoice is due upon receipt. VISA, MasterCard, and American Express cards will be accepted. There will be a 1.5% service charge per month on all unpaid balances. FLDOH: E83018 (Main Lab) FLDOH: E86562 (South Lab) FLDOH: E82405 (North Lab) NJDEP: FL015
Ferthaul Florida RS LLC PO #: n/a 6311 Inducon Corporate Drive, Ste. 5 Client Project #: Lake Apopka Sanborn,NY 14132 Date Sampled: Jan 20, 2015 Jan 23, 2015; Invoice: 256745 Report Summary Date Received: Jan 21, 2015 FCL Project Manager: Michelle M. Garver Laboratory # Sample Description Analysis Chemist Location SampleMatrix 256745SW1 Raw#1 EPA365.4 VLB Main Lab Surface Water 256745SW2 Raw#2 EPA365.4 VLB Main Lab Surface Water 256745SW3 Treated#1 EPA365.4 VLB Main Lab Surface Water 256745SW4 Treated#2 EPA365.4 VLB Main Lab Surface Water Certificate of Results Sample integrity was certified prior to analysis. Test results meet all requirements of the NELAC Standards except as noted in the Quality Control Report. Uncertainties for these data are available on request. This report may not be reproduced in part; results relate only to items tested. FLDOH: E83018 (Main Lab) FLDOH: E86562 (South Lab) FLDOH: E82405 (North Lab) NJDEP: FL015 Page 1 of 4
Ferthaul Florida RS LLC PO #: n/a 6311 Inducon Corporate Drive, Ste. 5 Client Project #: Lake Apopka Sanborn,NY 14132 Date Sampled: Jan 20, 2015 Jan 23, 2015; Invoice: 256745 Analysis Report Lab #: 256745SW1 Sampled: 01/20/15 11:00 AM Desc: Raw#1 Parameter Result Units DF MDL PQL QC Batch Method CAS # Analyzed Total Phosphorus(as P) 7.58 mg/l 10.0 0.400 0.400 10272899 EPA365.4 7723-14-0 01/23/15 Lab #: 256745SW2 Sampled: 01/20/15 11:00 AM Desc: Raw#2 Parameter Result Units DF MDL PQL QC Batch Method CAS # Analyzed Total Phosphorus(as P) 7.58 mg/l 10.0 0.400 0.400 10272899 EPA365.4 7723-14-0 01/23/15 Lab #: 256745SW3 Sampled: 01/21/15 10:00 AM Desc: Treated#1 Parameter Result Units DF MDL PQL QC Batch Method CAS # Analyzed Total Phosphorus(as P) 0.239 mg/l 1.00 0.0400 0.0400 10272899 EPA365.4 7723-14-0 01/23/15 Lab #: 256745SW4 Sampled: 01/21/15 10:00 AM Desc: Treated#2 Parameter Result Units DF MDL PQL QC Batch Method CAS # Analyzed Total Phosphorus(as P) 0.222 mg/l 1.00 0.0400 0.0400 10272899 EPA365.4 7723-14-0 01/23/15 FLDOH: E83018 (Main Lab) FLDOH: E86562 (South Lab) FLDOH: E82405 (North Lab) NJDEP: FL015 Page 2 of 4
Ferthaul Florida RS LLC PO #: n/a 6311 Inducon Corporate Drive, Ste. 5 Client Project #: Lake Apopka Sanborn,NY 14132 Date Sampled: Jan 20, 2015 Jan 23, 2015; Invoice: 256745 FLDOH: E83018 (Main Lab) FLDOH: E86562 (South Lab) FLDOH: E82405 (North Lab) NJDEP: FL015 Page 3 of 4
Ferthaul Florida RS LLC PO #: n/a 6311 Inducon Corporate Drive, Ste. 5 Client Project #: Lake Apopka Sanborn,NY 14132 Date Sampled: Jan 20, 2015 Jan 23, 2015; Invoice: 256745 Narrative Report Sample Handling Sample handling and holding time criteria were met for all samples. Samples collected by submitter. No unusual events occurred during analysis. Results are reported on a wet weight basis for aqueous matrices and on a dry weight basis for sludge and soil matrices unless otherwise noted. Sample results reported as dissolved were field filtered. Quality Control Enclosed analyses met method or FCL criteria, unless otherwise denoted on the sample results. Applied data qualifiers are defined below. Attachments Chain of Custody Qualifier U J J1 J2 J3 J4 Q L V ZTNTC A P T M G S O I B Y Meaning Compound was analyzed for but not detected. One or more QC samples associated with this data value exceeded QC limits. Surrogate recovery limits have been exceeded. No known quality control criteria exist for the component. Reported value failed to meet established quality control criteria for either precision or accuracy. Sample matrix interfered with the ability to make an accurate determination on the spiked sample. Sample held beyond the accepted holding time. Off-scale high; reported concentration exceeds the highest standard. Analyte was detected in both the sample and the associated method blank. Too numerous to count. Numeric value represents filtration volume. Absent Present Value reported is less than the statistical method detection limit. Reported for informational purposes only. Value reported is greater than the statistical method detection limit, but less than the reported MDL. The greatest of the dilutions performed did not yield sufficient oxygen depletion for valid data. The least of the dilutions performed did not yield sufficient oxygen residual for valid data. Result is greater than (over) the specified value. Reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. Results based upon colony plate count outside ideal range. The laboratory analysis was from an improperly preserved sample. The data may not be accurate. FLDOH: E83018 (Main Lab) FLDOH: E86562 (South Lab) FLDOH: E82405 (North Lab) NJDEP: FL015 Page 4 of 4
DIVISN-EAR-2015-01-21-01 Serial Number: 0078684 Page 1 of 16 DIVISN-EAR-2015-01-21-01 Florida Department of Environmental Protection Central Laboratory 2600 Blair Stone Road Tallahassee, FL 32399-2400 DOH Accreditation E31780 Event Description: Request ID: Customer: Project ID: Lake Apopka Project-ORL RQ-2015-01-12-44 DIVISN-EAR OTHER-EAR Send Reports to: FL Dept. of Environmental Protection 3319 Maguire Blvd Orlando, FL 32803-6767 Attn: Rob Renk For additional information please contact Timothy W. Fitzpatrick Liang-Tsair Lin, Ph.D. Colin Wright, Ph.D. Thekkekalathil Chandrasekhar, PhD, QA Officer Phone (850) 245-8085 Certified by: Liang Lin, Environmental Administrator Date Certified: 05-FEB-2015 14:56
DIVISN-EAR-2015-01-21-01 Serial Number: 0078684 Page 2 of 16 Job: TLH-2015-01-21-33 Job: TLH-2015-01-21-34 Job: TLH-2015-01-21-35 Group: Metals Group: Nutrients Group: Pesticides
DIVISN-EAR-2015-01-21-01 Serial Number: 0078684 Page 3 of 16 Sample Location: LAKE APOPKA INFLUENT Collection Date/Time: 01/20/2015 13:20 Field ID: LAKE APOPKA INFLUENT Matrix: W-SURF-FRH Sample ID Ref. Method Component Result Code Units Batch ID QC Failures 1668600 EPA 200.7 Rev. 4.4 Iron 2.91E+04 ug/l EPA 200.8 Rev. 5.4 Aluminum 1.79E+04 ug/l Arsenic 61.5 ug/l Lead 85.1 ug/l 1668601 EPA 350.1 Rev. 2.0 Ammonia-N 0.29 mg N/L EPA 351.2 Rev. 2.0 Kjeldahl Nitrogen 150 mg N/L EPA 353.2 Rev. 2.0 NO2NO3-N 0.007 I mg N/L EPA 365.1 Rev. 2.0 Total-P 8.0 mg P/L 1668602 SM 2540 D-97 TSS 5.30E+03 A mg/l 1668603 DEP SOP: GC-011-5 (based on EPA 608 and 617) Aldrin 0.0019 U ug/l Alpha-BHC 0.0019 U ug/l Beta-BHC 0.0019 U ug/l Delta-BHC 0.0019 U ug/l Gamma-BHC 0.0019 U ug/l P279339 P279339 P279339 P279339 P279484 P279620 P279404 P279504 P279590 Carbophenothion 0.0056 UJ ug/l CCV Chlordane 0.44 ug/l Chlorothalonil 0.0075 UJ ug/l CCV Cypermethrin 0.011 U ug/l DDD-p,p' 0.012 U ug/l DDE-p,p' 0.29 ug/l DDT-p,p' 0.0086 U ug/l Dicofol 0.096 UJ ug/l CCV Dieldrin 0.0062 U ug/l Endosulfan I 0.0019 U ug/l Endosulfan II 0.0019 U ug/l Endosulfan Sulfate 0.0038 U ug/l Endrin 0.0038 U ug/l Endrin Aldehyde 0.0042 U ug/l Heptachlor 0.0019 U ug/l Heptachlor Epoxide 0.0019 U ug/l Methoxychlor 0.0094 U ug/l Mirex 0.0038 U ug/l Permethrin 0.0094 U ug/l Toxaphene 0.094 U ug/l PCB-1016 0.019 U ug/l PCB-1221 0.019 U ug/l PCB-1232 0.019 U ug/l PCB-1242 0.019 U ug/l PCB-1248 0.019 U ug/l PCB-1254 0.019 U ug/l PCB-1260 0.019 U ug/l Trifluralin 0.0075 U ug/l 1668604 EPA 8270D Ametryn** 2.0 U ng/l MS
DIVISN-EAR-2015-01-21-01 Serial Number: 0078684 Page 4 of 16 Field ID: LAKE APOPKA INFLUENT Matrix: W-SURF-FRH Sample ID Ref. Method Component Result Code Units Batch ID QC Failures 1668604 EPA 8270D Atrazine** 6.5 I ng/l Chlorpyrifos Ethyl** 0.98 U ng/l Chlorpyrifos Methyl** 1.2 U ng/l Disulfoton** 4.9 U ng/l Ethion** 0.98 U ng/l Ethoprop** 0.98 U ng/l Hexazinone** 9.8 U ng/l Malathion** 1.2 U ng/l Metribuzin** 2.5 U ng/l Mevinphos** 2.5 U ng/l MS Norflurazon** 9.8 U ng/l MS Phorate** 2.5 U ng/l Prometryn** 2.5 U ng/l Simazine** 2.5 U ng/l Atrazine Desethyl** 2.5 U ng/l MS Fipronil** 4.9 U ng/l MS Molinate** 2.9 U ng/l Pendimethalin** 4.9 U ng/l Terbufos** 0.98 U ng/l EPTC** 2.9 U ng/l Terbuthylazine** 2.0 U ng/l Bromacil** 4.9 U ng/l Fipronil Sulfide** 2.0 U ng/l Fipronil Sulfone** 2.0 U ng/l Ref. Method and Comment: EPA 200.8 Rev. 5.4: The arsenic and lead results were confirmed on 02/03/2015. SM 2540 D-97: Sample has large amount of particulate matter. DEP SOP: GC-011-5 (based on EPA 608 and 617): MDL for Dicofol, Endrin aldehyde, Dieldrin, DDD-p,p' and DDT-p,p' elevated due to matrix interference. Quality control failure(s) observed. EPA 8270D: MDLs are elevated due to sample dilution. MS accuracy for Atrazine could not be assessed due to high content of the analyte in the spiked sample. Quality Assurance Report Method Blank Results Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Batch ID: Component Result Code Units Aldrin 0.0020 U ug/l Alpha-BHC 0.0020 U ug/l Beta-BHC 0.0020 U ug/l Carbophenothion 0.0060 U ug/l Chlordane 0.020 U ug/l Chlorothalonil 0.0080 U ug/l Cypermethrin 0.012 U ug/l DDD-p,p' 0.0040 U ug/l DDE-p,p' 0.0040 U ug/l DDT-p,p' 0.0040 U ug/l Delta-BHC 0.0020 U ug/l Dicofol 0.024 U ug/l
Quality Assurance Report Method Blank Results DIVISN-EAR-2015-01-21-01 Serial Number: 0078684 Page 5 of 16 Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Batch ID: Component Result Code Units Dieldrin 0.0020 U ug/l Endosulfan I 0.0020 U ug/l Endosulfan II 0.0020 U ug/l Endosulfan Sulfate 0.0040 U ug/l Endrin 0.0040 U ug/l Endrin Aldehyde 0.0040 U ug/l Gamma-BHC 0.0020 U ug/l Heptachlor 0.0020 U ug/l Heptachlor Epoxide 0.0020 U ug/l Methoxychlor 0.010 U ug/l Mirex 0.0040 U ug/l PCB-1016 0.020 U ug/l PCB-1221 0.020 U ug/l PCB-1232 0.020 U ug/l PCB-1242 0.020 U ug/l PCB-1248 0.020 U ug/l PCB-1254 0.020 U ug/l PCB-1260 0.020 U ug/l Permethrin 0.010 U ug/l Toxaphene 0.10 U ug/l Trifluralin 0.0080 U ug/l Reference Method: EPA 200.7 Rev. 4.4 Batch ID: P279339 Component Result Code Units Iron 30 U ug/l Reference Method: EPA 200.8 Rev. 5.4 Batch ID: P279339 Component Result Code Units Aluminum 5.0 U ug/l Arsenic 0.25 U ug/l Lead 0.20 U ug/l Reference Method: EPA 350.1 Rev. 2.0 Batch ID: P279484 Component Result Code Units Ammonia-N 0.002 U mg N/L Reference Method: EPA 351.2 Rev. 2.0 Batch ID: P279620 Component Result Code Units Kjeldahl Nitrogen 0.080 U mg N/L Reference Method: EPA 353.2 Rev. 2.0 Batch ID: P279404 Component Result Code Units
Quality Assurance Report Method Blank Results DIVISN-EAR-2015-01-21-01 Serial Number: 0078684 Page 6 of 16 Reference Method: EPA 353.2 Rev. 2.0 Batch ID: P279404 Component Result Code Units NO2NO3-N 0.004 U mg N/L Reference Method: EPA 365.1 Rev. 2.0 Batch ID: P279504 Component Result Code Units Total-P 0.002 U mg P/L Reference Method: EPA 8270D Batch ID: Component Result Code Units Ametryn 0.20 U ng/l Atrazine 0.25 U ng/l Atrazine Desethyl 0.25 U ng/l Bromacil 0.50 U ng/l Chlorpyrifos Ethyl 0.10 U ng/l Chlorpyrifos Methyl 0.12 U ng/l Disulfoton 0.50 U ng/l EPTC 0.30 U ng/l Ethion 0.10 U ng/l Ethoprop 0.10 U ng/l Fipronil 0.50 U ng/l Fipronil Sulfide 0.20 U ng/l Fipronil Sulfone 0.20 U ng/l Hexazinone 1.0 U ng/l Malathion 0.12 U ng/l Metribuzin 0.25 U ng/l Mevinphos 0.25 U ng/l Molinate 0.30 U ng/l Norflurazon 1.0 U ng/l Pendimethalin 0.50 U ng/l Phorate 0.25 U ng/l Prometryn 0.25 U ng/l Simazine 0.25 U ng/l Terbufos 0.10 U ng/l Terbuthylazine 0.20 U ng/l Reference Method: SM 2540 D-97 Batch ID: P279590 Component Result Code Units TSS 2 U mg/l Quality Assurance Report Laboratory Control Sample Accuracy Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Batch ID:
Quality Assurance Report Laboratory Control Sample Accuracy DIVISN-EAR-2015-01-21-01 Serial Number: 0078684 Page 7 of 16 Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Batch ID: Toxaphene 112 105 P/P 70-125 Reference Method: EPA 200.7 Rev. 4.4 Batch ID: P279339 Iron 105 P 85-115 Reference Method: EPA 200.8 Rev. 5.4 Batch ID: P279339 Aluminum 91.1 P 85-115 Arsenic 90.2 P 85-115 Lead 90.8 P 85-115 Reference Method: EPA 350.1 Rev. 2.0 Batch ID: P279484 Ammonia-N 103 P 90-110 Reference Method: EPA 351.2 Rev. 2.0 Batch ID: P279620 Kjeldahl Nitrogen 101 P 90-110 Reference Method: EPA 353.2 Rev. 2.0 Batch ID: P279404 NO2NO3-N 102 P 90-110 Reference Method: EPA 365.1 Rev. 2.0 Batch ID: P279504 Total-P 95.7 P 90-110 Reference Method: EPA 8270D Batch ID: Ametryn 98.1 94.0 P/P 50-130 Atrazine 91.3 90.2 P/P 50-130 Atrazine Desethyl 55.0 53.0 P/P 33-92.0 Bromacil 85.5 82.6 P/P 35-117 Chlorpyrifos Ethyl 68.7 67.8 P/P 50-130 Chlorpyrifos Methyl 41.9 42.0 P/P 32-100 Disulfoton 72.5 71.3 P/P 50-130 EPTC 76.3 68.2 P/P 50-130
DIVISN-EAR-2015-01-21-01 Serial Number: 0078684 Page 8 of 16 Quality Assurance Report Laboratory Control Sample Accuracy Reference Method: EPA 8270D Batch ID: Ethion 80.2 81.6 P/P 50-130 Ethoprop 86.2 84.9 P/P 50-130 Fipronil 104 102 P/P 50-130 Fipronil Sulfide 88.0 86.7 P/P 50-130 Fipronil Sulfone 87.3 85.4 P/P 50-130 Hexazinone 95.0 89.1 P/P 50-130 Malathion 90.6 91.5 P/P 50-130 Metribuzin 85.0 83.3 P/P 50-130 Mevinphos 87.2 81.3 P/P 33-110 Molinate 81.8 75.4 P/P 50-130 Norflurazon 88.7 88.4 P/P 50-130 Pendimethalin 79.3 80.8 P/P 50-130 Phorate 73.3 73.4 P/P 50-130 Prometryn 95.7 92.6 P/P 50-130 Simazine 91.6 78.6 P/P 50-130 Terbufos 73.5 71.5 P/P 50-130 Terbuthylazine 95.3 91.7 P/P 50-130 Quality Assurance Report Matrix Spike Accuracy Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Batch ID: Spiked Sample 1669154 Toxaphene 115 113 P/P 70-125 Reference Method: EPA 200.7 Rev. 4.4 Batch ID: P279339 Spiked Sample 1667508 1668147 Iron 107 107 P/P 80-120 Iron 108 P 80-120 Reference Method: EPA 200.8 Rev. 5.4 Batch ID: P279339 Spiked Sample 1667508 1667508 1667508 1668147 1668147 1668147 Aluminum 91.4 89.5 P/P 80-120 Arsenic 91.2 90.6 P/P 80-120 Lead 92.0 91.0 P/P 80-120 Aluminum 93.0 P 80-120 Arsenic 92.4 P 80-120 Lead 93.6 P 80-120 Reference Method: EPA 350.1 Rev. 2.0 Batch ID: P279484 Spiked Sample 1668569 Ammonia-N 99.9 102 P/P 90-110
Quality Assurance Report Matrix Spike Accuracy DIVISN-EAR-2015-01-21-01 Serial Number: 0078684 Page 9 of 16 Reference Method: EPA 351.2 Rev. 2.0 Batch ID: P279620 Spiked Sample 1669714 Kjeldahl Nitrogen 99.5 101 P/P 90-110 Reference Method: EPA 353.2 Rev. 2.0 Batch ID: P279404 Spiked Sample 1668568 NO2NO3-N 99.0 P 90-110 Reference Method: EPA 365.1 Rev. 2.0 Batch ID: P279504 Spiked Sample 1668907 Total-P 96.8 92.5 P/P 90-110 Reference Method: EPA 8270D Batch ID: Spiked Sample Ametryn 136 F 50-130 Atrazine Desethyl 113 F 33-92.0 Bromacil 76.8 P 35-117 Chlorpyrifos Ethyl 62.7 P 50-130 Chlorpyrifos Methyl 47.8 P 32-100 Disulfoton 113 P 50-130 EPTC 92.3 P 50-130 Ethion 81.1 P 50-130 Ethoprop 96.8 P 50-130 Fipronil 42.9 F 50-130 Fipronil Sulfide 126 P 50-130 Fipronil Sulfone 90.9 P 50-130 Hexazinone 102 P 50-130 Malathion 89.3 P 50-130 Metribuzin 99.4 P 50-130 Mevinphos 112 F 33-110 Molinate 111 P 50-130 Norflurazon 163 F 50-130 Pendimethalin 128 P 50-130 Phorate 94.2 P 50-130 Prometryn 121 P 50-130 Simazine 124 P 50-130 Terbufos 89.3 P 50-130 Terbuthylazine 107 P 50-130 Quality Assurance Report Precision Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Batch ID: Replicated Lab Sample Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits
DIVISN-EAR-2015-01-21-01 Serial Number: 0078684 Page 10 of 16 Quality Assurance Report Precision Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Batch ID: Replicated Lab Sample 1669154 Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits Toxaphene 1.51 Spike P 0-30 Toxaphene 6.17 LCS P 0-30 Reference Method: EPA 200.7 Rev. 4.4 Batch ID: P279339 Replicated Lab Sample 1667508 Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits Iron 0.706 Spike P 0-20 Reference Method: EPA 200.8 Rev. 5.4 Batch ID: P279339 Replicated Lab Sample 1667508 1667508 1667508 Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits Aluminum 2.03 Spike P 0-20 Arsenic 0.633 Spike P 0-20 Lead 1.08 Spike P 0-20 Reference Method: EPA 350.1 Rev. 2.0 Batch ID: P279484 Replicated Lab Sample 1668569 Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits Ammonia-N 1.58 Spike P 0-20 Reference Method: EPA 351.2 Rev. 2.0 Batch ID: P279620 Replicated Lab Sample 1669714 Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits Kjeldahl Nitrogen 1.11 Spike P 0-20 Reference Method: EPA 353.2 Rev. 2.0 Batch ID: P279404 Replicated Lab Sample 1668568 Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits NO2NO3-N 0.483 Spike P 0-20 Reference Method: EPA 365.1 Rev. 2.0 Batch ID: P279504 Replicated Lab Sample 1668907 Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits Total-P 4.42 Spike P 0-20
DIVISN-EAR-2015-01-21-01 Serial Number: 0078684 Page 11 of 16 Quality Assurance Report Precision Reference Method: EPA 8270D Batch ID: Replicated Lab Sample Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits Ametryn 4.20 LCS P 0-30 Atrazine 1.20 LCS P 0-30 Atrazine Desethyl 3.71 LCS P 0-30 Bromacil 3.41 LCS P 0-30 Chlorpyrifos Ethyl 1.41 LCS P 0-30 Chlorpyrifos Methyl 0.279 LCS P 0-30 Disulfoton 1.60 LCS P 0-30 EPTC 11.2 LCS P 0-30 Ethion 1.62 LCS P 0-30 Ethoprop 1.56 LCS P 0-30 Fipronil 2.27 LCS P 0-30 Fipronil Sulfide 1.55 LCS P 0-30 Fipronil Sulfone 2.18 LCS P 0-30 Hexazinone 6.44 LCS P 0-30 Malathion 1.06 LCS P 0-30 Metribuzin 2.09 LCS P 0-30 Mevinphos 6.94 LCS P 0-30 Molinate 8.11 LCS P 0-30 Norflurazon 0.422 LCS P 0-30 Pendimethalin 1.95 LCS P 0-30 Phorate 0.262 LCS P 0-30 Prometryn 3.37 LCS P 0-30 Simazine 15.3 LCS P 0-30 Terbufos 2.73 LCS P 0-30 Terbuthylazine 3.85 LCS P 0-30 Reference Method: SM 2540 D-97 Batch ID: P279590 Replicated Lab Sample 1668602 Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits TSS 1.51 Sample P 0-10 * Sample, spike and/or laboratory control sample precision (LCS) is reported. Replicate spike precision may be reported when sample results are below quantifiable levels. Quality Assurance Report Surrogates Lab Sample ID: 1668603 Field Sample ID: LAKE APOPKA INFLUENT Reference Method Surrogate % Rec. Pass/Fail Control Limits DEP SOP: GC-011-5 (based on EPA 608 and Decachlorobiphenyl 57.5 P 43-126 617) Lab Sample ID: 1668604 Field Sample ID: LAKE APOPKA INFLUENT Reference Method Surrogate % Rec. Pass/Fail Control Limits EPA 8270D 5-Nitroquinoline 94.6 P 49-144
Quality Assurance Report Calibration Verification DIVISN-EAR-2015-01-21-01 Serial Number: 0078684 Page 12 of 16 Reference Method: EPA 353.2 Rev. 2.0 Run ID: A60722 Included Lab Sample IDs: 1668601 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits NO2NO3-N 103 104 P/P 90-110 Reference Method: EPA 350.1 Rev. 2.0 Run ID: A60753 Included Lab Sample IDs: 1668601 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Ammonia-N 103 102 P/P 90-110 Reference Method: EPA 200.7 Rev. 4.4 Run ID: A60762 Included Lab Sample IDs: 1668600 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Iron 102 105 P/P 90-110 Reference Method: EPA 365.1 Rev. 2.0 Run ID: A60785 Included Lab Sample IDs: 1668601 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Total-P 98.2 97.5 P/P 90-110 Reference Method: EPA 200.8 Rev. 5.4 Run ID: A60812 Included Lab Sample IDs: 1668600 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Arsenic 94.9 96.6 P/P 90-110 Lead 94.3 94.6 P/P 90-110 Reference Method: EPA 351.2 Rev. 2.0 Run ID: A60829 Included Lab Sample IDs: 1668601 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Kjeldahl Nitrogen 104 106 P/P 90-110 Reference Method: EPA 200.8 Rev. 5.4 Run ID: A60839 Included Lab Sample IDs: 1668600 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Aluminum 100 98.8 P/P 90-110 Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Run ID: A60866 Included Lab Sample IDs: 1668603 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Aldrin 88.6 91.6 P/P 85-115
Quality Assurance Report Calibration Verification DIVISN-EAR-2015-01-21-01 Serial Number: 0078684 Page 13 of 16 Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Run ID: A60866 Included Lab Sample IDs: 1668603 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Alpha-BHC 92.5 99.5 P/P 85-115 Beta-BHC 91.4 96.6 P/P 85-115 Carbophenothion 88.9* 97.6 F/P 90-110 Chlordane 101 102 P/P 85-115 Chlorothalonil 98.7 116* P/F 90-110 Cypermethrin 89.6 106 P/P 85-115 DDD-p,p' 89.6 86.7 P/P 85-115 DDE-p,p' 99.7 93.2 P/P 85-115 DDT-p,p' 97.9 86.1 P/P 85-115 Delta-BHC 94.8 103 P/P 85-115 Dicofol 104 117* P/F 90-110 Dieldrin 89.2 91.2 P/P 85-115 Endosulfan I 90.1 87.2 P/P 85-115 Endosulfan II 91.7 89.3 P/P 85-115 Endosulfan Sulfate 92.8 86.0 P/P 85-115 Endrin 89.8 115 P/P 85-115 Endrin Aldehyde 92.7 92.9 P/P 85-115 Gamma-BHC 88.5 95.4 P/P 85-115 Heptachlor 88.2 87.2 P/P 85-115 Heptachlor Epoxide 90.3 93.5 P/P 85-115 Methoxychlor 98.1 99.3 P/P 90-110 Mirex 102 107 P/P 90-110 Permethrin 95.6 106 P/P 90-110 Toxaphene 104 105 P/P 85-115 Trifluralin 99.0 105 P/P 90-110 Reference Method: EPA 8270D Run ID: A60914 Included Lab Sample IDs: 1668604 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Ametryn 95.3 P 80-120 Atrazine 97.2 P 80-120 Atrazine Desethyl 88.8 P 80-120 Bromacil 99.2 P 80-120 Chlorpyrifos Ethyl 97.0 P 80-120 Chlorpyrifos Methyl 97.1 P 80-120 Disulfoton 87.8 P 80-120 EPTC 98.1 P 80-120 Ethion 99.8 P 80-120 Ethoprop 90.8 P 80-120 Fipronil 110 P 80-120 Fipronil Sulfide 99.4 P 80-120 Fipronil Sulfone 102 P 80-120 Hexazinone 103 P 80-120 Malathion 86.4 P 80-120 Metribuzin 93.5 P 80-120 Mevinphos 80.1 P 80-120 Molinate 101 P 80-120 Norflurazon 102 P 80-120 Pendimethalin 93.7 P 80-120
Quality Assurance Report Calibration Verification DIVISN-EAR-2015-01-21-01 Serial Number: 0078684 Page 14 of 16 Reference Method: EPA 8270D Run ID: A60914 Included Lab Sample IDs: 1668604 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Phorate 98.4 P 80-120 Prometryn 99.7 P 80-120 Simazine 92.6 P 80-120 Terbufos 92.3 P 80-120 Terbuthylazine 97.7 P 80-120 * Pass/Fail determinations are made for each bracketing calibration verification check. Control limits for initial calibration checks may be different from those for continuing checks, depending on method requirements. Where they are different, both control limits are provided. Quality Assurance Report Summary Ref. Method Analyte LCS % Recovery MS % Recovery Precision LCS SMP MS DEP SOP: GC-011-5 (based on Toxaphene 112 105 115 113 6.17 1.51 EPA 608 and 617) EPA 200.7 Rev. 4.4 Iron 105 107 107 108 0.706 EPA 200.8 Rev. 5.4 Aluminum 91.1 91.4 89.5 93.0 2.03 Arsenic 90.2 91.2 90.6 92.4 0.633 Lead 90.8 92.0 91.0 93.6 1.08 EPA 350.1 Rev. 2.0 Ammonia-N 103 99.9 102 1.58 EPA 351.2 Rev. 2.0 Kjeldahl Nitrogen 101 99.5 101 1.11 EPA 353.2 Rev. 2.0 NO2NO3-N 102 99.0 0.483 EPA 365.1 Rev. 2.0 Total-P 95.7 96.8 92.5 4.42 EPA 8270D Ametryn 98.1 94.0 136 4.20 Atrazine 91.3 90.2 1.20 Atrazine Desethyl 55.0 53.0 113 3.71 Bromacil 85.5 82.6 76.8 3.41 Chlorpyrifos Ethyl 68.7 67.8 62.7 1.41 Chlorpyrifos Methyl 41.9 42.0 47.8 0.279 Disulfoton 72.5 71.3 113 1.60 EPTC 76.3 68.2 92.3 11.2 Ethion 80.2 81.6 81.1 1.62 Ethoprop 86.2 84.9 96.8 1.56 Fipronil 104 102 42.9 2.27 Fipronil Sulfide 88.0 86.7 126 1.55 Fipronil Sulfone 87.3 85.4 90.9 2.18 Hexazinone 95.0 89.1 102 6.44 Malathion 90.6 91.5 89.3 1.06 Metribuzin 85.0 83.3 99.4 2.09 Mevinphos 87.2 81.3 112 6.94 Molinate 81.8 75.4 111 8.11 Norflurazon 88.7 88.4 163 0.422 Pendimethalin 79.3 80.8 128 1.95 Phorate 73.3 73.4 94.2 0.262 Prometryn 95.7 92.6 121 3.37 Simazine 91.6 78.6 124 15.3 Terbufos 73.5 71.5 89.3 2.73 Terbuthylazine 95.3 91.7 107 3.85
DIVISN-EAR-2015-01-21-01 Serial Number: 0078684 Page 15 of 16 Quality Assurance Report Summary Ref. Method Analyte LCS % Recovery MS % Recovery Precision LCS SMP MS SM 2540 D-97 TSS 1.51 Reference Method Descriptions Method / NELAC Cert. # Description Associated Samples DEP SOP: GC-011-5 (based on EPA 608 and 617) / E31780 EPA 200.7 Rev. 4.4 / E31780 EPA 200.8 Rev. 5.4 / E31780 EPA 350.1 Rev. 2.0 / E31780 EPA 351.2 Rev. 2.0 / E31780 EPA 353.2 Rev. 2.0 / E31780 EPA 365.1 Rev. 2.0 / E31780 EPA 8270D / E31780 Organochlorine pesticides (low levels) in water matrices by GC/ECD. 1668603 Total Recoverable Metals analysis using ICP emission spectroscopy for aqueous 1668600 samples supporting Clean Water Act Projects Total Recoverable Metals analysis using ICP-MS for aqueous samples supporting 1668600 Clean Water Act Projects Ammonia in aqueous matrices as mg N/L 1668601 Total Kjeldahl Nitrogen in aqueous matrices 1668601 Nitrite/Nitrate in aqueous matrices as mg N/L 1668601 Total Phosphorus in aqueous matrices as mg P/L 1668601 Organonitrogen and phosphorus pesticides (ultra trace level) in water matrices by 1668604 GC/MS/MS SM 2540 D-97 / E31780 Total Suspended Solids in aqueous matrices 1668602
DIVISN-EAR-2015-01-21-01 Serial Number: 0078684 Page 16 of 16 Preparation and Analysis Log Ref. Method Received Date Prep Date/Time Prepared By Analysis Date/Time Analyzed By Associated Samples DEP SOP: GC-011-5 (based on 01/21/2015 01/23/2015 Rasheda Ghaffari 01/28/2015 Vandana T. Nagar 1668603 EPA 608 and 617) 01/21/2015 01/23/2015 Rasheda Ghaffari 01/29/2015 Vandana T. Nagar 1668603 EPA 200.7 Rev. 4.4 01/21/2015 01/21/2015 Elliott D. Healy 01/23/2015 Joshua Ayres 1668600 EPA 200.8 Rev. 5.4 01/21/2015 01/21/2015 Elliott D. Healy 01/27/2015 Charles J. Peterson 1668600 01/21/2015 01/21/2015 Elliott D. Healy 01/28/2015 Charles J. Peterson 1668600 EPA 350.1 Rev. 2.0 01/21/2015 01/23/2015 Diana M. Turner 1668601 EPA 351.2 Rev. 2.0 01/21/2015 01/28/2015 Christopher Armour 01/28/2015 Bryan A. Werth 1668601 EPA 353.2 Rev. 2.0 01/21/2015 01/22/2015 Peter D. Kaus 1668601 EPA 365.1 Rev. 2.0 01/21/2015 01/26/2015 Christopher Armour 01/27/2015 Lipi Saha 1668601 EPA 8270D 01/21/2015 01/26/2015 Fe-Val Siddell 01/29/2015 Irina Carbone 1668604 SM 2540 D-97 01/21/2015 01/26/2015 Sima Feizi 1668602
DIVISN-EAR-2015-01-22-01 Serial Number: 0078668 Page 1 of 16 DIVISN-EAR-2015-01-22-01 Florida Department of Environmental Protection Central Laboratory 2600 Blair Stone Road Tallahassee, FL 32399-2400 DOH Accreditation E31780 Event Description: Request ID: Customer: Project ID: Lake Apopka Project-ORL RQ-2015-01-12-44 DIVISN-EAR OTHER-EAR Send Reports to: FL Dept. of Environmental Protection 3319 Maguire Blvd Orlando, FL 32803-6767 Attn: Rob Renk For additional information please contact Timothy W. Fitzpatrick Liang-Tsair Lin, Ph.D. Colin Wright, Ph.D. Thekkekalathil Chandrasekhar, PhD, QA Officer Phone (850) 245-8085 Certified by: Timothy Fitzpatrick, Program Administrator Date Certified: 04-FEB-2015 11:06
DIVISN-EAR-2015-01-22-01 Serial Number: 0078668 Page 2 of 16 Job: TLH-2015-01-22-45 Job: TLH-2015-01-22-46 Job: TLH-2015-01-22-47 Group: Metals Group: Nutrients Group: Pesticides
DIVISN-EAR-2015-01-22-01 Serial Number: 0078668 Page 3 of 16 Sample Location: LAKE APOPKA_EFFLUENT (RETURN H2O) Collection Date/Time: 01/21/2015 09:40 Field ID: LAKE APOPKA_EFFLUENT (RETURN H Matrix: W-SURF-FRH Sample ID Ref. Method Component Result Code Units Batch ID QC Failures 1669109 EPA 200.7 Rev. 4.4 Iron 350 ug/l EPA 200.8 Rev. 5.4 Aluminum 201 ug/l Arsenic 4.56 ug/l Lead 9.79 ug/l 1669111 EPA 350.1 Rev. 2.0 Ammonia-N 0.11 mg N/L EPA 351.2 Rev. 2.0 Kjeldahl Nitrogen 4.4 mg N/L EPA 353.2 Rev. 2.0 NO2NO3-N 0.004 U mg N/L EPA 365.1 Rev. 2.0 Total-P 0.25 mg P/L 1669112 SM 2540 D-97 TSS 92 I mg/l 1669113 DEP SOP: GC-011-5 (based on EPA 608 and 617) Aldrin 0.0020 U ug/l Alpha-BHC 0.0020 U ug/l Beta-BHC 0.0020 U ug/l Delta-BHC 0.0020 U ug/l Gamma-BHC 0.0020 U ug/l P279418 P279418 P279418 P279418 P279487 P279620 P279546 P279566 P279589 Carbophenothion 0.0059 UJ ug/l CCV Chlordane 0.020 U ug/l Chlorothalonil 0.0078 UJ ug/l CCV Cypermethrin 0.012 U ug/l DDD-p,p' 0.0039 U ug/l DDE-p,p' 0.0039 U ug/l DDT-p,p' 0.0039 U ug/l Dicofol 0.023 UJ ug/l CCV Dieldrin 0.0020 U ug/l Endosulfan I 0.0020 U ug/l Endosulfan II 0.0020 U ug/l Endosulfan Sulfate 0.0039 U ug/l Endrin 0.0039 U ug/l Endrin Aldehyde 0.0039 U ug/l Heptachlor 0.0020 U ug/l Heptachlor Epoxide 0.0020 U ug/l Methoxychlor 0.0098 U ug/l Mirex 0.0039 U ug/l Permethrin 0.0098 U ug/l Toxaphene 0.098 U ug/l PCB-1016 0.020 U ug/l PCB-1221 0.020 U ug/l PCB-1232 0.020 U ug/l PCB-1242 0.020 U ug/l PCB-1248 0.020 U ug/l PCB-1254 0.020 U ug/l PCB-1260 0.020 U ug/l Trifluralin 0.0078 U ug/l EPA 8270D Ametryn** 2.7 IJ ng/l MS
DIVISN-EAR-2015-01-22-01 Serial Number: 0078668 Page 4 of 16 Field ID: LAKE APOPKA_EFFLUENT (RETURN H Matrix: W-SURF-FRH Sample ID Ref. Method Component Result Code Units Batch ID QC Failures EPA 8270D Atrazine** 14 ng/l Chlorpyrifos Ethyl** 0.10 U ng/l Chlorpyrifos Methyl** 0.12 U ng/l Disulfoton** 0.50 U ng/l Ethion** 0.10 U ng/l Ethoprop** 0.10 U ng/l Hexazinone** 1.0 U ng/l Malathion** 0.12 U ng/l Metribuzin** 1.0 U ng/l Mevinphos** 0.25 UJ ng/l MS Norflurazon** 4.0 UJ ng/l MS Phorate** 0.25 U ng/l Prometryn** 1.0 U ng/l Simazine** 2.5 U ng/l Atrazine Desethyl** 2.5 UJ ng/l MS Fipronil** 0.50 UJ ng/l MS Molinate** 1.2 U ng/l Pendimethalin** 2.0 U ng/l Terbufos** 0.10 U ng/l EPTC** 1.2 U ng/l Terbuthylazine** 0.80 U ng/l Bromacil** 0.84 T ng/l Fipronil Sulfide** 2.0 U ng/l Fipronil Sulfone** 0.80 U ng/l Ref. Method and Comment: EPA 200.8 Rev. 5.4: The lead matrix spike recovery data for one of two spiked samples is unavailable due to high analyte concentration in the QC sample. The lead result was confirmed in the undigested sample on 01/30/2015. SM 2540 D-97: The PQL was elevated due to sample matrix interference. DEP SOP: GC-011-5 (based on EPA 608 and 617): Quality control failure(s) observed. EPA 8270D: Quality control failure(s) observed. Quality Assurance Report Method Blank Results Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Batch ID: Component Result Code Units Aldrin 0.0020 U ug/l Alpha-BHC 0.0020 U ug/l Beta-BHC 0.0020 U ug/l Carbophenothion 0.0060 U ug/l Chlordane 0.020 U ug/l Chlorothalonil 0.0080 U ug/l Cypermethrin 0.012 U ug/l DDD-p,p' 0.0040 U ug/l DDE-p,p' 0.0040 U ug/l DDT-p,p' 0.0040 U ug/l Delta-BHC 0.0020 U ug/l Dicofol 0.024 U ug/l
Quality Assurance Report Method Blank Results DIVISN-EAR-2015-01-22-01 Serial Number: 0078668 Page 5 of 16 Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Batch ID: Component Result Code Units Dieldrin 0.0020 U ug/l Endosulfan I 0.0020 U ug/l Endosulfan II 0.0020 U ug/l Endosulfan Sulfate 0.0040 U ug/l Endrin 0.0040 U ug/l Endrin Aldehyde 0.0040 U ug/l Gamma-BHC 0.0020 U ug/l Heptachlor 0.0020 U ug/l Heptachlor Epoxide 0.0020 U ug/l Methoxychlor 0.010 U ug/l Mirex 0.0040 U ug/l PCB-1016 0.020 U ug/l PCB-1221 0.020 U ug/l PCB-1232 0.020 U ug/l PCB-1242 0.020 U ug/l PCB-1248 0.020 U ug/l PCB-1254 0.020 U ug/l PCB-1260 0.020 U ug/l Permethrin 0.010 U ug/l Toxaphene 0.10 U ug/l Trifluralin 0.0080 U ug/l Reference Method: EPA 200.7 Rev. 4.4 Batch ID: P279418 Component Result Code Units Iron 30 U ug/l Reference Method: EPA 200.8 Rev. 5.4 Batch ID: P279418 Component Result Code Units Aluminum 5.0 U ug/l Arsenic 0.25 U ug/l Lead 0.20 U ug/l Reference Method: EPA 350.1 Rev. 2.0 Batch ID: P279487 Component Result Code Units Ammonia-N 0.002 U mg N/L Reference Method: EPA 351.2 Rev. 2.0 Batch ID: P279620 Component Result Code Units Kjeldahl Nitrogen 0.080 U mg N/L Reference Method: EPA 353.2 Rev. 2.0 Batch ID: P279546 Component Result Code Units
Quality Assurance Report Method Blank Results DIVISN-EAR-2015-01-22-01 Serial Number: 0078668 Page 6 of 16 Reference Method: EPA 353.2 Rev. 2.0 Batch ID: P279546 Component Result Code Units NO2NO3-N 0.004 U mg N/L Reference Method: EPA 365.1 Rev. 2.0 Batch ID: P279566 Component Result Code Units Total-P 0.005 U mg P/L Total-P 0.002 U mg P/L Reference Method: EPA 8270D Batch ID: Component Result Code Units Ametryn 0.20 U ng/l Atrazine 0.25 U ng/l Atrazine Desethyl 0.25 U ng/l Bromacil 0.50 U ng/l Chlorpyrifos Ethyl 0.10 U ng/l Chlorpyrifos Methyl 0.12 U ng/l Disulfoton 0.50 U ng/l EPTC 0.30 U ng/l Ethion 0.10 U ng/l Ethoprop 0.10 U ng/l Fipronil 0.50 U ng/l Fipronil Sulfide 0.20 U ng/l Fipronil Sulfone 0.20 U ng/l Hexazinone 1.0 U ng/l Malathion 0.12 U ng/l Metribuzin 0.25 U ng/l Mevinphos 0.25 U ng/l Molinate 0.30 U ng/l Norflurazon 1.0 U ng/l Pendimethalin 0.50 U ng/l Phorate 0.25 U ng/l Prometryn 0.25 U ng/l Simazine 0.25 U ng/l Terbufos 0.10 U ng/l Terbuthylazine 0.20 U ng/l Reference Method: SM 2540 D-97 Batch ID: P279589 Component Result Code Units TSS 2 U mg/l Quality Assurance Report Laboratory Control Sample Accuracy
Quality Assurance Report Laboratory Control Sample Accuracy DIVISN-EAR-2015-01-22-01 Serial Number: 0078668 Page 7 of 16 Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Batch ID: Toxaphene 112 105 P/P 70-125 Reference Method: EPA 200.7 Rev. 4.4 Batch ID: P279418 Iron 108 P 85-115 Reference Method: EPA 200.8 Rev. 5.4 Batch ID: P279418 Aluminum 89.4 P 85-115 Arsenic 89.6 P 85-115 Lead 91.3 P 85-115 Reference Method: EPA 350.1 Rev. 2.0 Batch ID: P279487 Ammonia-N 102 P 90-110 Reference Method: EPA 351.2 Rev. 2.0 Batch ID: P279620 Kjeldahl Nitrogen 101 P 90-110 Reference Method: EPA 353.2 Rev. 2.0 Batch ID: P279546 NO2NO3-N 101 P 90-110 Reference Method: EPA 365.1 Rev. 2.0 Batch ID: P279566 Total-P 101 P 90-110 Reference Method: EPA 8270D Batch ID: Ametryn 98.1 94.0 P/P 50-130 Atrazine 91.3 90.2 P/P 50-130 Atrazine Desethyl 55.0 53.0 P/P 33-92.0 Bromacil 85.5 82.6 P/P 35-117 Chlorpyrifos Ethyl 68.7 67.8 P/P 50-130 Chlorpyrifos Methyl 41.9 42.0 P/P 32-100 Disulfoton 72.5 71.3 P/P 50-130 EPTC 76.3 68.2 P/P 50-130
DIVISN-EAR-2015-01-22-01 Serial Number: 0078668 Page 8 of 16 Quality Assurance Report Laboratory Control Sample Accuracy Reference Method: EPA 8270D Batch ID: Ethion 80.2 81.6 P/P 50-130 Ethoprop 86.2 84.9 P/P 50-130 Fipronil 104 102 P/P 50-130 Fipronil Sulfide 88.0 86.7 P/P 50-130 Fipronil Sulfone 87.3 85.4 P/P 50-130 Hexazinone 95.0 89.1 P/P 50-130 Malathion 90.6 91.5 P/P 50-130 Metribuzin 85.0 83.3 P/P 50-130 Mevinphos 87.2 81.3 P/P 33-110 Molinate 81.8 75.4 P/P 50-130 Norflurazon 88.7 88.4 P/P 50-130 Pendimethalin 79.3 80.8 P/P 50-130 Phorate 73.3 73.4 P/P 50-130 Prometryn 95.7 92.6 P/P 50-130 Simazine 91.6 78.6 P/P 50-130 Terbufos 73.5 71.5 P/P 50-130 Terbuthylazine 95.3 91.7 P/P 50-130 Quality Assurance Report Matrix Spike Accuracy Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Batch ID: Spiked Sample 1669154 Toxaphene 115 113 P/P 70-125 Reference Method: EPA 200.7 Rev. 4.4 Batch ID: P279418 Spiked Sample 1668639 1668843 Iron 108 109 P/P 80-120 Iron 108 P 80-120 Reference Method: EPA 200.8 Rev. 5.4 Batch ID: P279418 Spiked Sample 1668639 1668639 1668843 1668843 1668843 Aluminum 93.3 93.3 P/P 80-120 Arsenic 93.8 93.3 P/P 80-120 Aluminum 91.0 P 80-120 Arsenic 92.3 P 80-120 Lead 91.9 P 80-120 Reference Method: EPA 350.1 Rev. 2.0 Batch ID: P279487 Spiked Sample 1669111 Ammonia-N 102 102 P/P 90-110
Quality Assurance Report Matrix Spike Accuracy DIVISN-EAR-2015-01-22-01 Serial Number: 0078668 Page 9 of 16 Reference Method: EPA 351.2 Rev. 2.0 Batch ID: P279620 Spiked Sample 1669714 Kjeldahl Nitrogen 99.5 101 P/P 90-110 Reference Method: EPA 353.2 Rev. 2.0 Batch ID: P279546 Spiked Sample 1668911 NO2NO3-N 101 100 P/P 90-110 Reference Method: EPA 365.1 Rev. 2.0 Batch ID: P279566 Spiked Sample 1669111 Total-P 93.4 93.5 P/P 90-110 Reference Method: EPA 8270D Batch ID: Spiked Sample Ametryn 136 F 50-130 Atrazine Desethyl 113 F 33-92.0 Bromacil 76.8 P 35-117 Chlorpyrifos Ethyl 62.7 P 50-130 Chlorpyrifos Methyl 47.8 P 32-100 Disulfoton 113 P 50-130 EPTC 92.3 P 50-130 Ethion 81.1 P 50-130 Ethoprop 96.8 P 50-130 Fipronil 42.9 F 50-130 Fipronil Sulfide 126 P 50-130 Fipronil Sulfone 90.9 P 50-130 Hexazinone 102 P 50-130 Malathion 89.3 P 50-130 Metribuzin 99.4 P 50-130 Mevinphos 112 F 33-110 Molinate 111 P 50-130 Norflurazon 163 F 50-130 Pendimethalin 128 P 50-130 Phorate 94.2 P 50-130 Prometryn 121 P 50-130 Simazine 124 P 50-130 Terbufos 89.3 P 50-130 Terbuthylazine 107 P 50-130 Quality Assurance Report Precision Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Batch ID: Replicated Lab Sample Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits
DIVISN-EAR-2015-01-22-01 Serial Number: 0078668 Page 10 of 16 Quality Assurance Report Precision Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Batch ID: Replicated Lab Sample 1669154 Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits Toxaphene 1.51 Spike P 0-30 Toxaphene 6.17 LCS P 0-30 Reference Method: EPA 200.7 Rev. 4.4 Batch ID: P279418 Replicated Lab Sample 1668639 Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits Iron 0.822 Spike P 0-20 Reference Method: EPA 200.8 Rev. 5.4 Batch ID: P279418 Replicated Lab Sample 1668639 1668639 1668639 Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits Aluminum 0.0488 Spike P 0-20 Arsenic 0.434 Spike P 0-20 Lead 1.65 Spike P 0-20 Reference Method: EPA 350.1 Rev. 2.0 Batch ID: P279487 Replicated Lab Sample 1669111 Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits Ammonia-N 0.130 Spike P 0-20 Reference Method: EPA 351.2 Rev. 2.0 Batch ID: P279620 Replicated Lab Sample 1669714 Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits Kjeldahl Nitrogen 1.11 Spike P 0-20 Reference Method: EPA 353.2 Rev. 2.0 Batch ID: P279546 Replicated Lab Sample 1668911 Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits NO2NO3-N 0.301 Spike P 0-20 Reference Method: EPA 365.1 Rev. 2.0 Batch ID: P279566 Replicated Lab Sample 1669111 Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits Total-P 0.113 Spike P 0-20
DIVISN-EAR-2015-01-22-01 Serial Number: 0078668 Page 11 of 16 Quality Assurance Report Precision Reference Method: EPA 8270D Batch ID: Replicated Lab Sample Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits Ametryn 4.20 LCS P 0-30 Atrazine 1.20 LCS P 0-30 Atrazine Desethyl 3.71 LCS P 0-30 Bromacil 3.41 LCS P 0-30 Chlorpyrifos Ethyl 1.41 LCS P 0-30 Chlorpyrifos Methyl 0.279 LCS P 0-30 Disulfoton 1.60 LCS P 0-30 EPTC 11.2 LCS P 0-30 Ethion 1.62 LCS P 0-30 Ethoprop 1.56 LCS P 0-30 Fipronil 2.27 LCS P 0-30 Fipronil Sulfide 1.55 LCS P 0-30 Fipronil Sulfone 2.18 LCS P 0-30 Hexazinone 6.44 LCS P 0-30 Malathion 1.06 LCS P 0-30 Metribuzin 2.09 LCS P 0-30 Mevinphos 6.94 LCS P 0-30 Molinate 8.11 LCS P 0-30 Norflurazon 0.422 LCS P 0-30 Pendimethalin 1.95 LCS P 0-30 Phorate 0.262 LCS P 0-30 Prometryn 3.37 LCS P 0-30 Simazine 15.3 LCS P 0-30 Terbufos 2.73 LCS P 0-30 Terbuthylazine 3.85 LCS P 0-30 Reference Method: SM 2540 D-97 Batch ID: P279589 Replicated Lab Sample 1669167 Component % RSD/RPD Sample/Spike/LCS* Pass/Fail Control Limits TSS 5.88 Sample P 0-10 * Sample, spike and/or laboratory control sample precision (LCS) is reported. Replicate spike precision may be reported when sample results are below quantifiable levels. Quality Assurance Report Surrogates Lab Sample ID: 1669113 Field Sample ID: LAKE APOPKA_EFFLUENT (RETURN H Reference Method Surrogate % Rec. Pass/Fail Control Limits DEP SOP: GC-011-5 (based on EPA 608 and Tetrachloro-m-xylene 56.1 P 43-117 617) Lab Sample ID: Field Sample ID: LAKE APOPKA_EFFLUENT (RETURN H Reference Method Surrogate % Rec. Pass/Fail Control Limits EPA 8270D 5-Nitroquinoline 124 P 49-144
Quality Assurance Report Calibration Verification DIVISN-EAR-2015-01-22-01 Serial Number: 0078668 Page 12 of 16 Reference Method: EPA 350.1 Rev. 2.0 Run ID: A60753 Included Lab Sample IDs: 1669111 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Ammonia-N 103 102 P/P 90-110 Reference Method: EPA 353.2 Rev. 2.0 Run ID: A60775 Included Lab Sample IDs: 1669111 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits NO2NO3-N 102 102 P/P 90-110 Reference Method: EPA 200.7 Rev. 4.4 Run ID: A60780 Included Lab Sample IDs: 1669109 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Iron 103 102 P/P 90-110 Reference Method: EPA 365.1 Rev. 2.0 Run ID: A60791 Included Lab Sample IDs: 1669111 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Total-P 103 104 P/P 90-110 Reference Method: EPA 200.8 Rev. 5.4 Run ID: A60812 Included Lab Sample IDs: 1669109 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Aluminum 91.7 93.8 P/P 90-110 Arsenic 96.5 97.9 P/P 90-110 Lead 94.6 95.1 P/P 90-110 Reference Method: EPA 351.2 Rev. 2.0 Run ID: A60829 Included Lab Sample IDs: 1669111 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Kjeldahl Nitrogen 104 106 P/P 90-110 Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Run ID: A60866 Included Lab Sample IDs: 1669113 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Aldrin 88.6 91.6 P/P 85-115 Alpha-BHC 92.5 99.5 P/P 85-115 Beta-BHC 91.4 96.6 P/P 85-115 Carbophenothion 88.9* 97.6 F/P 90-110 Chlordane 101 102 P/P 85-115 Chlorothalonil 98.7 116* P/F 90-110 Cypermethrin 89.6 106 P/P 85-115
Quality Assurance Report Calibration Verification DIVISN-EAR-2015-01-22-01 Serial Number: 0078668 Page 13 of 16 Reference Method: DEP SOP: GC-011-5 (based on EPA 608 and 617) Run ID: A60866 Included Lab Sample IDs: 1669113 Component % Rec.1 % Rec.2 Pass/Fail* Control Limits DDD-p,p' 89.6 86.7 P/P 85-115 DDE-p,p' 95.5 92.7 P/P 85-115 DDT-p,p' 97.9 86.1 P/P 85-115 Delta-BHC 94.8 103 P/P 85-115 Dicofol 104 117* P/F 90-110 Dieldrin 89.2 91.2 P/P 85-115 Endosulfan I 90.1 87.2 P/P 85-115 Endosulfan II 91.7 89.3 P/P 85-115 Endosulfan Sulfate 92.8 86.0 P/P 85-115 Endrin 89.8 115 P/P 85-115 Endrin Aldehyde 92.7 92.9 P/P 85-115 Gamma-BHC 88.5 95.4 P/P 85-115 Heptachlor 88.2 87.2 P/P 85-115 Heptachlor Epoxide 90.3 93.5 P/P 85-115 Methoxychlor 98.1 99.3 P/P 90-110 Mirex 102 107 P/P 90-110 Permethrin 95.6 106 P/P 90-110 Toxaphene 104 105 P/P 85-115 Trifluralin 99.0 105 P/P 90-110 Reference Method: EPA 8270D Run ID: A60914 Included Lab Sample IDs: Component % Rec.1 % Rec.2 Pass/Fail* Control Limits Ametryn 101 P 80-120 Atrazine 98.9 P 80-120 Atrazine Desethyl 81.8 P 80-120 Bromacil 91.6 P 80-120 Chlorpyrifos Ethyl 97.0 P 80-120 Chlorpyrifos Methyl 97.1 P 80-120 Disulfoton 87.8 P 80-120 EPTC 99.7 P 80-120 Ethion 99.8 P 80-120 Ethoprop 90.8 P 80-120 Fipronil 110 P 80-120 Fipronil Sulfide 82.9 P 80-120 Fipronil Sulfone 85.6 P 80-120 Hexazinone 103 P 80-120 Malathion 86.4 P 80-120 Metribuzin 93.2 P 80-120 Mevinphos 80.1 P 80-120 Molinate 98.5 P 80-120 Norflurazon 96.5 P 80-120 Pendimethalin 89.2 P 80-120 Phorate 98.4 P 80-120 Prometryn 99.6 P 80-120 Simazine 99.6 P 80-120 Terbufos 92.3 P 80-120 Terbuthylazine 95.6 P 80-120
Quality Assurance Report Calibration Verification DIVISN-EAR-2015-01-22-01 Serial Number: 0078668 Page 14 of 16 * Pass/Fail determinations are made for each bracketing calibration verification check. Control limits for initial calibration checks may be different from those for continuing checks, depending on method requirements. Where they are different, both control limits are provided. Quality Assurance Report Summary Ref. Method Analyte LCS % Recovery MS % Recovery Precision LCS SMP MS DEP SOP: GC-011-5 (based on Toxaphene 112 105 115 113 6.17 1.51 EPA 608 and 617) EPA 200.7 Rev. 4.4 Iron 108 108 109 108 0.822 EPA 200.8 Rev. 5.4 Aluminum 89.4 93.3 93.3 91.0 0.0488 Arsenic 89.6 93.8 93.3 92.3 0.434 Lead 91.3 91.9 1.65 EPA 350.1 Rev. 2.0 Ammonia-N 102 102 102 0.130 EPA 351.2 Rev. 2.0 Kjeldahl Nitrogen 101 99.5 101 1.11 EPA 353.2 Rev. 2.0 NO2NO3-N 101 101 100 0.301 EPA 365.1 Rev. 2.0 Total-P 101 93.4 93.5 0.113 EPA 8270D Ametryn 98.1 94.0 136 4.20 Atrazine 91.3 90.2 1.20 Atrazine Desethyl 55.0 53.0 113 3.71 Bromacil 85.5 82.6 76.8 3.41 Chlorpyrifos Ethyl 68.7 67.8 62.7 1.41 Chlorpyrifos Methyl 41.9 42.0 47.8 0.279 Disulfoton 72.5 71.3 113 1.60 EPTC 76.3 68.2 92.3 11.2 Ethion 80.2 81.6 81.1 1.62 Ethoprop 86.2 84.9 96.8 1.56 Fipronil 104 102 42.9 2.27 Fipronil Sulfide 88.0 86.7 126 1.55 Fipronil Sulfone 87.3 85.4 90.9 2.18 Hexazinone 95.0 89.1 102 6.44 Malathion 90.6 91.5 89.3 1.06 Metribuzin 85.0 83.3 99.4 2.09 Mevinphos 87.2 81.3 112 6.94 Molinate 81.8 75.4 111 8.11 Norflurazon 88.7 88.4 163 0.422 Pendimethalin 79.3 80.8 128 1.95 Phorate 73.3 73.4 94.2 0.262 Prometryn 95.7 92.6 121 3.37 Simazine 91.6 78.6 124 15.3 Terbufos 73.5 71.5 89.3 2.73 Terbuthylazine 95.3 91.7 107 3.85 SM 2540 D-97 TSS 5.88 Reference Method Descriptions Method / NELAC Cert. # Description Associated Samples DEP SOP: GC-011-5 (based on EPA 608 and 617) / E31780 EPA 200.7 Rev. 4.4 / E31780 Organochlorine pesticides (low levels) in water matrices by GC/ECD. 1669113 Total Recoverable Metals analysis using ICP emission spectroscopy for aqueous samples supporting Clean Water Act Projects 1669109
DIVISN-EAR-2015-01-22-01 Serial Number: 0078668 Page 15 of 16 Reference Method Descriptions Method / NELAC Cert. # Description Associated Samples EPA 200.8 Rev. 5.4 / Total Recoverable Metals analysis using ICP-MS for aqueous samples supporting 1669109 E31780 Clean Water Act Projects EPA 350.1 Rev. 2.0 / Ammonia in aqueous matrices as mg N/L 1669111 E31780 EPA 351.2 Rev. 2.0 / Total Kjeldahl Nitrogen in aqueous matrices 1669111 E31780 EPA 353.2 Rev. 2.0 / Nitrite/Nitrate in aqueous matrices as mg N/L 1669111 E31780 EPA 365.1 Rev. 2.0 / Total Phosphorus in aqueous matrices as mg P/L 1669111 E31780 EPA 8270D / E31780 Organonitrogen and phosphorus pesticides (ultra trace level) in water matrices by GC/MS/MS SM 2540 D-97 / E31780 Total Suspended Solids in aqueous matrices 1669112
DIVISN-EAR-2015-01-22-01 Serial Number: 0078668 Page 16 of 16 Preparation and Analysis Log Ref. Method Received Date Prep Date/Time Prepared By Analysis Date/Time Analyzed By Associated Samples DEP SOP: GC-011-5 (based on 01/22/2015 01/23/2015 Rasheda Ghaffari 01/28/2015 Vandana T. Nagar 1669113 EPA 608 and 617) EPA 200.7 Rev. 4.4 01/22/2015 01/22/2015 Elliott D. Healy 01/26/2015 Joshua Ayres 1669109 EPA 200.8 Rev. 5.4 01/22/2015 01/22/2015 Elliott D. Healy 01/27/2015 Charles J. Peterson 1669109 EPA 350.1 Rev. 2.0 01/22/2015 01/23/2015 Diana M. Turner 1669111 EPA 351.2 Rev. 2.0 01/22/2015 01/28/2015 Christopher Armour 01/28/2015 Bryan A. Werth 1669111 EPA 353.2 Rev. 2.0 01/22/2015 01/26/2015 Peter D. Kaus 1669111 EPA 365.1 Rev. 2.0 01/22/2015 01/27/2015 Christopher Armour 01/27/2015 Lipi Saha 1669111 EPA 8270D 01/22/2015 01/26/2015 Fe-Val Siddell 01/29/2015 Irina Carbone 01/22/2015 01/26/2015 Fe-Val Siddell 01/30/2015 Irina Carbone SM 2540 D-97 01/22/2015 01/26/2015 Sima Feizi 1669112
DIVISN-EAR-2015-01-22-01 Serial Number: 0078695 Biological Analysis Report Page 1 of 4 Biological Analysis Report DIVISN-EAR-2015-01-22-01 Florida Department of Environmental Protection Central Laboratory 2600 Blair Stone Road Tallahassee, FL 32399-2400 DOH Accreditation E31780 Event Description: Request ID: Customer: Project ID: Lake Apopka Project-ORL RQ-2015-01-12-44 DIVISN-EAR OTHER-EAR Send Reports to: FL Dept. of Environmental Protection 3319 Maguire Blvd Orlando, FL 32803-6767 Attn: Rob Renk For additional information please contact David D. Whiting - Administrator J. Marshall Faircloth - Aquatic Toxicology Elizabeth Miller - Bench Biology Jacqueline Savage - Microbiology Loretta Wolfe - Molecular Biology Cheryl Swanson - Taxonomy (Invertebrate & Algal) Thekkekalathil Chandrasekhar, PhD, QA Officer Phone (850) 245-8177 Certified by: Elizabeth Miller, Environmental Manager Date Certified: 06-FEB-2015 15:39
DIVISN-EAR-2015-01-22-01 Serial Number: 0078695 Biological Analysis Report Page 2 of 4 Job: TLH-2015-01-22-44 Group: Toxicology
DIVISN-EAR-2015-01-22-01 Serial Number: 0078695 Biological Analysis Report Page 3 of 4 Sample Location: LAKE APOPKA_EFFLUENT (RETURN H2O) Collection Date/Time: 01/21/2015 09:40 Field ID: LAKE APOPKA_EFFLUENT (RETURN H Matrix: W-SURF-FRH Sample ID Ref. Method Component Result Code Units Batch ID QC Failures 1669107 EPA-821-R-02-012 Bioassay-Acute-Def-FW-Fish, LC50 100 L LC50 Bioassay-Acute-Def-FW-C.dubia, LC50 100 L LC50 Ref. Method and Comment: EPA-821-R-02-012: 100% survival in the Pimephales promelas test concentrations at 96 hours. EPA-821-R-02-012: 100% survival in the Ceriodaphnia dubia test concentrations at 96 hours. Sample Location: LAKE APOPKA @ INTAKE Collection Date/Time: 01/21/2015 10:15 Field ID: LAKE APOPKA @ INTAKE Matrix: W-SURF-FRH Sample ID Ref. Method Component Result Code Units Batch ID QC Failures 1669108 EPA-821-R-02-012 Bioassay-Acute-Def-FW-Fish, LC50 100 L LC50 Bioassay-Acute-Def-FW-C.dubia, LC50 100 L LC50 Ref. Method and Comment: EPA-821-R-02-012: 100% survival in the Pimephales promelas test concentrations at 96 hours. EPA-821-R-02-012: 100% survival in the Ceriodaphnia dubia test concentrations at 96 hours. Reference Method Descriptions Method / NELAC Cert. # Description Associated Samples EPA-821-R-02-012 / E31780 EPA-821-R-02-012 / E31780 Definitive acute toxicity test, FW--freshwater fish. 1669107, 1669108 Definitive acute toxicity test, FW--water flea. 1669107, 1669108
DIVISN-EAR-2015-01-22-01 Serial Number: 0078695 Biological Analysis Report Page 4 of 4 Preparation and Analysis Log Ref. Method Received Date Prep Date/Time Prepared By Analysis Date/Time Analyzed By Associated Samples EPA-821-R-02-012 01/22/2015 01/22/2015 12:10 Diane D. Power 1669107 01/22/2015 01/22/2015 12:30 Diane D. Power 1669108 01/22/2015 01/22/2015 14:15 Cassidy Reichert 1669107 01/22/2015 01/22/2015 14:30 Cassidy Reichert 1669108