Measurement & Analytics Measurement made easy



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Measurement & Analytics Measurement made easy FTPA2000-SC Series Wet Process Analyzer designed to optimize your bath life without risk of contamination Solutions for semiconductor, FPD and solar cell manufacturing

Wet process analyzer built on customer demand Industry Leader With years of experience and thousands of process monitoring installations, ABB is the leading supplier of fiber optic-based spectrometers to the semiconductor industry. ABB s solution has the long-term stability required for endof-bath alarms and enabling effective closed-loop chemical dosing from trend analysis: A change in measured chemical levels will be real, not analyzer drift. Our analyzer features are exactly what process control engineers across many industries have requested over the last 15 years. Customers install the ABB solution because it is: cost effective for multiple tools and multiple bath compositions; tailored to fit end-user needs; easy to operate, install and maintain; a completely non-intrusive sampling design, there is no risk of bath contamination SEZ looks for process analyzers which have the lowest cost of ownership and enforce our process performance. We have found ABB analytical instruments to be of value to our operations. SEZ Michael Roth Director, Global Marketing Communications and Operations 2 Solutions for Semiconductor, FPD and Solar Cell manufacturing FTPA2000-SC Series

Wet process analyzer Wet Process Analyzer (WPA) The FTPA2000-SC Series (WPA) measures up to eight baths. The baths can be on single or multiple tools and of the same or different chemistries. It can be mounted anywhere within 100 meters of the baths and communicates with the tools using ModBus, Ethernet or Isolated 4 20 ma analog outputs. The WPA generates trend charts, predicted properties, bath alarms and health alarms. Additional Product Lines Laboratory analyzers The same calibrations used with the WPA may be used on our MB Series analyzers for use in the laboratory or in the clean room near the process. In addition to measuring wet chemicals, the MB Series wide range of sampling accessories makes it the perfect tool for measuring wafer surfaces for hydrogen, interstitial oxygen, carbon, organic material and many other surface properties. IPA Dryer analyzer The ABB IPA dryer monitor measures IPA in nitrogen dryers. Extremely fast and reliable IPA concentration measurements mean an end to production loss due to residue spots. Sampling The WPA sample interface is a unique cell that has no wetted parts. It is easy to install just clip it on to an existing ¾ or ½ PVA tube. It is constructed of TeflonTM and connected to the WPA via TeflonTM -protected fiber optic cables. The bath cannot be contaminated! FTPA2000-SC Series Solutions for Semiconductor, FPD and Solar Cell manufacturing 3

Wet process analyzer specifications Baths Monitored Etch Baths Monitored A70 Etch Acetic / HF / Nitric BHF (HF+NH4F) BOE A70 Cyantek CR-7S Acetic / HF / Nitric Glycol/HF H3PO4 BHF (HF+NH4F) / H202 H3PO4 BOE /Nitric / HF HCI Cyantek + FeCI3 CR-7S Glycol/HF Hot H3PO4 Phos/ H202 Hot H3PO4 SPM/Nitric / HF Mixed HCI + FeCI3 Acids Enchants Organic HF Acids PAD Hot Phos PAN Hot SPM Sulfuric Mixed Acids /HF Enchants Sulfuric/H3PO4/Nitric/HF Organic Acids TMAH PAD PAN Sulfuric /HF Clean Aqua Regia Clean BDG DHF DMSO / MEA Aqua Regia H3PO4 BDG HCI / HF Kanto DHF Deer Clean Microstrip DMSO / MEA 5002 Mixed H3PO4 Acids NH4OH HCI / HF/ H2O2 / H2O Kanto Deer Clean Oganic Microstrip Acids5002 SC2 Mixed Acids SCI NH4OH / H2O2 / SPM H2O ST250 Oganic Acids SC2 SCI SPM ST250 PR & Ash Removal ACT PR & Ash Removal Aleg -310 CLK -888 DSP ACT EKC Aleg -310 H2S04 H3PO2 CLK -888 Rezi-38 DSP ST250 EKC TMAH H2S04 / H202 H3PO2 Rezi-38 ST250 TMAH / H202 Sulfuric/H3PO4/Nitric/HF Custom TMAH calibration models In addition to the chemical baths mentioned, ABB offers custom calibration development services. The WPA can be used to monitor almost every wet chemical bath used today. Furthermore, end-user have the option of creating their own calibration models and ABB offers the appropriate training services to assist our customers. Wet Station Solar Plating Solar Sulfuric in Ni Bath Sulfuric in Cu Bath Texturing Plating HF / Nitric Sulfuric in Ni Bath HF / Phosp / Nitric HCI Sulfuric in Cu Bath Thinning Texturing K0H HF / / IPA Nitric K0H HF / Phosp / Nitric Na0H HCI Thinning K0H / IPA K0H Na0H FPD BDG FPD DMSO / MEA Mixed Acids BDG DMSO / MEA Mixed Acids 1. The Clippir is designed to be clipped directly around the recirculating line and is self supporting. However, an optional bracket can be provided. 2. 15.2 cm minimum clearance around the Clippir. 3. Teflon TM tubing protecting fiber optics: 1.5 m long. 4. 2.5cm access hole required. 5. Standard bulkhead fitting. 6. Standard 10-100m fiber optic cables housed in PVC tubing. Chemical Bath 1 Wet Station 2 3 Pump Filter Chemical Bath 1 2 43 5 6 Pump Filter 5 4 6 4 Solutions for Semiconductor, FPD and Solar Cell manufacturing FTPA2000-SC Series

In-line wet process analyzing of chemical baths Reducing excursion events and chemical usage is best obtained through process control, which requires real-time end-of-bath monitoring and bath spiking. The WPA is based on FT-IR technology a minimal drift system enabling reliable process control. One WPA for Multiple s and 8 Baths per WPA CanBus, ModBus or CanOpen to Work Station Work Station Remote Access from home, office or ABB service SC1 MAE DHF HF/HNO3 Work Station Fiber Optic Interface 10-100 meters PR Strip SPM HOT PHOS Ash Clean FTPA2000-SC Series Solutions for Semiconductor, FPD and Solar Cell manufacturing 5 1.10 2.00 1.80

In-line PR wet SPM HOT process Ash analyzing of chemical baths Strip PHOS Clean Work Station ess from home, service SC1 MAE DHF HF/HNO3 ABB s world-renowned Wet Process Analyzer provides guaranteed performance Extensively field proven. Rugged design Fiber Optic and Interface construction combined with superior manufacturing 10-100 methods meters guarantee unsurpassed analyzer stability. Results obtained in less than one minute, with simultaneous analysis of multiple bath properties. Easy-to-use, operato friendly, with very low analysis cost. Higher analytical precision (increased repeatability, Work Station reproducibility and stability) and full I/O capacity enable advanced process control. Very little training required for use by FAB personnel in a routine operations environment. Real-time and drift-free monitoring of wet chemical baths enable effective end-of-bath alarms and closed-loop PR SPM HOT dosing Strip routines. PHOS Clean Ash Simplified sampling without cutting into tool fluidics means no risk of contamination. Up to eight baths, multiple chemistries, multiple tools and can be mounted up to 100 meters from the tool. 1.10 2.00 0.90 1.80 1.60 Conc. (NH 4 OH) 0.80 0.70 0.60 1.40 1.20 0.80 Conc. (H 2 O 2 ) 0.50 0.40 0.60 0.40 0.30 0.20 9.00 1 13.00 15.00 17.00 Time A. U. NH 4 OH H 2 O 2 1.10 2.00 0.90 1.80 1.60 Conc. (NH 4 OH) 0.80 0.70 0.60 1.40 1.20 0.80 Conc. (H 2 O 2 ) 0.50 0.40 0.60 0.40 0.30 0.20 9.00 1 13.00 15.00 17.00 Time A. U. NH 4 OH H 2 O 2 6 Solutions for Semiconductor, FPD and Solar Cell manufacturing FTPA2000-SC Series

ABB Analytical ABB Analytical is one of the major ABB manufacturing centers for laboratory and process analytical systems with more than 35 years of experience in developing FT-IR and FT-NIR spectrometers for industrial, military and space applications. As part of our portfolio of products and services for process optimization, we are able to offer a full range of custom calibration modeling services and application support for industrial applications. ABB also provides extensive, globally distributed after-sales support and engineering services, as well as a full customer training program. IR & NIR Spectroscopy Knowledge Management Application support and spectroscopy training Calibration and chemometrics development training On-site services including hardware and calibration maintenance Up-Time Insurance Program Preventive maintenance Extended warranty services Tailor-made service contracts Chemometrics services Installations / Start-ups & Analyzer Life Cycle Program Process spectrometer start-ups Laboratory spectrometer installations Spectrometer and laboratory / process software exchanges / upgrades Extended process and lab spectrometer warrantees FTPA2000-SC Series Solutions for Semiconductor, FPD and Solar Cell manufacturing 7

Contact us ABB Inc. Process Automation Measurement & Analytics 3400, Rue Pierre-Ardouin Quebec (Quebec) G1P 0B2 Canada Tel.: +1 418 877-2944 1 800 858-3847 (North America) Fax: +1 418 877-2834 E-Mail: ftir@ca.abb.com www.abb.com/analytical Note We reserve the right to make technical changes or modify the contents of this document without prior notice. With regard to purchase orders, the agreed particulars shall prevail. ABB does not accept any responsibility whatsoever for potential errors or possible lack of information in this document. We reserve all rights in this document and in the subject matter and illustrations contained therein. Any reproduction, disclosure to third parties or utilization of its contents in whole or in parts is forbidden without prior written consent of ABB. Copyright 2016 ABB All rights reserved PB/FTPA2000/SC-EN Rev. A 01.2016 Sales Service