A Review of Gel Polymer Treatments in the Arbuckle Formation of Kansas



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A Review of Gel Polymer Treatments in the Arbuckle Formation of Kansas For West Coast PTTC Workshop Hyatt Valencia Conference Center Valencia, California Thursday, January 23, 2003 Rich Pancake Tertiary Oil Recovery Project University of Kansas

Acknowledgements Wish to thank TIORCO and Gel-Tec for help in collecting treatment data and with operator contacts. Vess Oil Company and Murfin Drilling Company for help in collecting data and for permission to share that data. Trilobite well testing for BHP surveys.

Presentation Outline Background on TORP and Kansas Arbuckle Formation/Production Review of Kansas Arbuckle Polymer Treatments TORP s Efforts in Evaluating Arbuckle Polymer Treatments Future TORP/PTTC Activities Related to Arbuckle Polymer Treatments

What is TORP? TORP is the Tertiary Oil Recovery Project. TORP was established in 1974 to help producers apply EOR in Kansas reservoirs. TORP is affiliated with the Chemical and Petroleum Engineering Department at the University of Kansas. TORP employs 7 full-time staff and 6 to 12 graduate students/post doctorates per year.

What is TORP? TORP is guided by an advisory board of Kansas producers, petroleum consultants, service company personal, and petroleum scholars. TORP conducts laboratory and field research geared towards maximizing production from Kansas reservoirs. TORP conducts tech transfer via a biennial Oil Recovery Conference and its affiliation with the North Midcontinent Resource Center of PTTC.

What is TORP? Current TORP Activities University Research Laboratory research on perm modification (gel polymers) Computer reservoir simulation Crude oil minimum miscibility pressure (MMP) measurements for CO 2 flooding Field Research/Field Demonstrations Gel polymer treatments in the Arbuckle formation Miscible CO 2 flooding in Central Kansas Technology Transfer North MidContinent Resource Center of PTTC

Arbuckle Formation/Production Formation covers most of Kansas. Dolomite formation having Karst features. 3000 to 3500 feet deep in major producing area. First oil production in +/- 1920 s. Most prolific producing horizon in Kansas. Strong water-drive reservoir. Geology not well understood. Debate as to whether flow is from fracture or highperm streaks. High volume wells > 1000 BPD w/ 1% oil or less.

Kansas Geologic Features Heart of Arbuckle Production Courtesy of the Kansas Geological Survey

Kansas Arbuckle Structure Heart of Arbuckle Production Courtesy of the Kansas Geological Survey

Kansas Arbuckle Production Over 1.6 billion bbls of oil produced from Arbuckle formation as of 1998. Ellis County, Kansas Courtesy of the Kansas Geological Survey

Typical Arbuckle Well Drilled anywhere from 1930 s to present day. Arbuckle 100 to 500 ft thick. Oil column 50 to 100 ft. Only top 5 to 20 ft completed. On older wells, csg set to top of Arb and cable tooled in. On newer wells, casing set 20 to 50 ft in and perforated. Little to no stimulation. Older wells IP d > 2000 BOPD w/ little to no water. Early production prorated at +/- 25 BOPD. Current production > 1000 BWPD, +/- 10 BOPD. Production limited by lift and disposal capacity and economics.

Presentation Outline Background on TORP and Kansas Arbuckle Formation/Production Review of Kansas Arbuckle Polymer Treatments TORP s Efforts in Evaluating Arbuckle Polymer Treatments Future TORP/PTTC Activities Related to Arbuckle Polymer Treatments

Review of Arbuckle Polymer Treatments +/- 130 MARCIT technology polymer jobs pumped in the Arbuckle since 2000 +/- 75 by TIORCO +/- 55 by Gel-Tec Treatment locations +/- 60 % of jobs pumped in Bemis-Shutts Field Remainder pumped in Marcotte, Star Northwest, Northampton, Jelinek, Ogallah, Trapp, Geneseo- Edwards, and other fields

Star Northwest Bemis-Shutts Hays, KS Ellis County fields with polymer treatments Courtesy of the Kansas Geological Survey

Polymer Treatments in Bemis-Shutts Sec 12, 1 job Sec 7, 2 jobs Sec 13, 2 jobs Sec 21, 7 jobs Sec 21, 1 job Sec 22, 6 jobs Sec 23, 1 job Sec 24, 2 jobs Sec 30, 1 job Sec 29, 1 job Sec 26, 1 job Sec 29, 3 jobs 29 Polymer Jobs Shown Sec 11, 1 job Courtesy of the Kansas Geological Survey

Review of Arbuckle Polymer Treatments Well selection criteria Well drilled up structure Well originally had high, water-free IP Well at its economic limit because of high WOR Well has very high fluid level Well has high calculated flow potential

Review of Arbuckle Polymer Treatments Treatment design criteria Vender 1 For high fluid level wells, pump 2x well s daily production, up to 4000 bbls. For low fluid level wells, pump 1x well s daily production. Surface treating pressure not to exceed 200 psig. Vender 2 Gel volume pumped to be near well s calculated maximum inflow, up to 4000 bbls. Surface treating pressure to be between 200 and 400 psig.

Review of Arbuckle Polymer Treatments Typical treatment design Pull pump & tbg. Sand pump well. RIH w/ tbg & packer. Set pkr +/- 100 ft above interval. Acidize well w/ between 250 & 1500 gals 15% HCl. Recent trend appears to be towards the larger, 1500 gal acid jobs. Pump polymer down tbg. Small job - 1000 to 1600 bbls. Large job - 3000 to 4100 bbls. Larger jobs are typically in Bemis. Recent trend may be to pump even larger jobs.

Review of Arbuckle Polymer Treatments Typical treatment design (cont d) Pump polymer down tbg (cont d). Gel loadings increase in 3 to 4 stages 3500, 4000, 5000, and 6500 ppm. Recent trend appears to be to increase gel loading at end of job to 7500 or 8500 ppm. Flush tbg w/ oil or water. Typically 100 bbl water flush. Typically 50 to 100 bbl oil flush. Philosophy of oil or water flush varies among operators. Shut-in well 7 to 14 days. Return well to production.

Review of Arbuckle Polymer Treatments Polymer treatment examples Average to below average jobs

Example of Nice Initial Response Murfin's Johnson B #3A Polymer Job August 2-3, 2001 (1621 bbls gel, 97% of job treated on a vacuum, 51 psig max treating press) 1000 100 Before Treatment SPM - 12.5 SL - 120 in Pump - 2.0 in FL - 834' above zone in March 1997 10 After Treatment SPM - 6.0 SL - 120 in Pump - 1.5 in FL - as indicated These fluid levels questionable 1 4/10/2001 6/10/2001 8/10/2001 10/10/2001 12/10/2001 2/10/2002 4/10/2002 6/10/2002 8/10/2002 Oil Production (BOPD) Water Production (BWPD) WOR Fluid above zone (ft)

Example of Average to Good Response Murfin's Hadley BC #10 Polymer Job August 14-18, 2001 (3806 bbls gel, 100% of job treated on a vacuum, 0 psig max treating press) 10000 1000 Before Treatment SPM - 12.5 SL - 120 in Pump - 3.25 in FL -? SPM - increase 2/19/02 to 7.5 Pump - increase 5/2/02 to 2 inch 100 After Treatment SPM - 6.0 SL - 120 in Pump - 1.5 in FL - as indicated 10 1 12/20/2000 2/20/2001 4/20/2001 6/20/2001 8/20/2001 10/20/2001 12/20/2001 2/20/2002 4/20/2002 6/20/2002 Oil Production (BOPD) Water Production (BWPD) WOR Fluid above zone (ft)

Example of Average to Good Response Murfin's Jorgensen #4 Polymer Job August 6-9, 2001 (3805 bbls gel, 58% of job treated on a vacuum, 102 psig max treating press) 10000 Pump - increase 5/2/02 to 2 inch 1000 Before Treatment SPM - 10.5 SL - 120 in Pump - 2.75 in FL -? SPM - increase 11/15/01 to 9.5 SPM - increase 2/19/02 to 11.75 100 After Treatment SPM - 7.5 SL - 120 in Pump - 1.5 in FL - as indicated 10 1 2/6/2001 4/6/2001 6/6/2001 8/6/2001 10/6/2001 12/6/2001 2/6/2002 4/6/2002 Oil Production (BOPD) Water Production (BWPD) WOR Fluid above zone (ft)

Example of Average to Good Response Murfin's Peavey A-6 Polymer Job August 10-13, 2001 (3806 bbls gel, 64% of job treated on a vacuum, 446 psig max treating press) 10000 Pump - increase 5/3/02 to 2 inch 1000 100 Before Treatment SPM - 12 SL - 100 in Pump - 3.25 in FL -? SPM - increase 2/19/02 to 9.5 10 After Treatment SPM - 7.5 SL - 100 in Pump - 1.5 in FL - as indicated 1 12/16/2000 2/16/2001 4/16/2001 6/16/2001 8/16/2001 10/16/2001 12/16/2001 2/16/2002 4/16/2002 6/16/2002 Oil Production (BOPD) Water Production (BWPD) WOR Fluid above zone (ft)

Example of Poorer Response Vess's Colahan A #41 Polymer Job August 18-21, 2001 (2988 bbls gel, 8.2% of job treated on a vacuum, 923 psig max treating press) 10000 Before Treatment SPM - 13.5 SL - 86 in Pump - 2.25 in FL - as indicated 1000 Pump - increase 12/1/01 to 2 inch 100 After Treatment SPM - 6.5 SL - 62 in Pump - 1.5 in FL - as indicated 10 1 4/16/2001 6/16/2001 8/16/2001 10/16/2001 12/16/2001 2/16/2002 4/16/2002 6/16/2002 8/16/2002 Oil Production (BOPD) Water Production (BWPD) WOR Fluid above zone (ft)

Example of Poorer Response Vess's Colahan A #2 Polymer Job August 26-30, 2001 (4093 bbls gel, 29% of job treated on a vacuum, 591 psig max treating press) 10000 1000 Before Treatment SPM - 7.8 SL - 86 in Pump - 2.75 in FL - as indicated Changed PU 12/19/01. SL 48 in SPM - increase 4/25/02 to 7.5 100 10 After Treatment SPM - 5.0 SL - 50 in Pump - 1.5 in FL - as indicated 1 4/16/2001 6/16/2001 8/16/2001 10/16/2001 12/16/2001 2/16/2002 4/16/2002 6/16/2002 8/16/2002 Oil Production (BOPD) Water Production (BWPD) WOR Fluid above zone (ft)

Example of Poorest Response Murfin's Glathart #1 Polymer Job December 8-9, 2001 (1007 bbls gel, 0% of job treated on a vacuum, 200 psig max treating press) 1000 SPM - decrease 1/10/02 to 9.2 100 Before Treatment SPM - 16.9 SL - 54 in Pump - 2.25 in FL -? 10 After Treatment SPM - 12.35 SL - 54 in Pump - 2.0 in FL - pumped off 1 8/15/2001 10/15/2001 12/15/2001 2/15/2002 4/15/2002 6/15/2002 Oil Production (BOPD) Water Production (BWPD) WOR Fluid above zone (ft)

Review of Arbuckle Polymer Treatments Job costs Gel cost $35 M to $45 M for larger jobs (+/- 4,000 bbl) $15 M to $20 M for smaller jobs (+/- 1,500 bbl) Rig & acid costs $5 M to $10 M depending on rig time & volume acid Total costs $40 to 55 M for large jobs $20 to 30 M for small jobs

Review of Arbuckle Polymer Treatments Pay-out (based only on incremental oil recovery, water reduction savings not considered) 3 to 6 month pay-out for average performing jobs Assumptions +/- 18 BOPD/well incremental oil recovery for 6 months $22/bbl oil price $45 M job cost Three poorest performing jobs did not pay-out Assumptions +/- 6 BOPD/well incremental oil recovery for 6 months $22/bbl oil price $45 M job cost

Murfin s Hadley A #3 Polymer Job

TIORCO s Polymer Injection Equipment

TIORCO s Polymer Mixing Hopper

Gel-Tec Polymer Job on an Elysium Well

Pumping into well

Tri-plex pump and crosslinker storage

Computer Monitors

Presentation Outline Background on TORP and Kansas Arbuckle Formation/Production Review of Kansas Arbuckle Polymer Treatments TORP s Efforts in Evaluating Arbuckle Polymer Treatments Future TORP/PTTC Activities Related to Arbuckle Polymer Treatments

TORP s Efforts Objective help operators maximize gel polymer treatment performance. Develop comprehensive database by which to compare all Arbuckle gel polymer treatments. Hope to spot trends that lead to improved treatments. Have contacted several operators requesting information on gel polymer treatments. Getting some positive feedback and information.

TORP s Efforts Conduct and analyze pre and post-treatment build-up tests using TORP s computerized Echometer. Measure formation kh and skin. Determine if reservoir flow is linear (through fracture) or radial (through matrix). For pre-treatment build-ups, attempt to predict how much polymer a well will take. Have performed pre-treatment build-ups on 7 Arbuckle wells. 5 in Bemis-Shutts 2 in Geneseo-Edwards

Build-up Test on Vess Oil s McCord A #4

TORP s Efforts Pre-treatment build-up on Vess Oil s Hall B #4. Bemis Shutts Field Ellis County Depth 3423 ft Net pay open 10 ft Water production 611 BPD Oil production 6 BPD Static BHP 935.3 psig Producing BHP 501.0 psig

Build-up Analysis Hall B #4 1000 900 800 Data Simulated Pressure, psia 700 600 500 400 Perm= 500 md h=50 ft Partial penetration Interval open-8 ft 300 0.01 0.1 1 10 100 Time, hours Analysis courtesy of Professor Paul Willhite

TORP s Efforts * Analyze bottom-hole pressure (BHP) surveys run on 6 wells. Bottom-hole pressure measured (via pressure bomb on slickline) before, during, and after gel treatment. Hope to gain insights into the gel/rock interface, which should help in sizing treatments and setting maximum treating pressures. Hope to determine a friction coefficient for pumping gel down tubing. * With financial assistance from vendors and oil companies

Trilobite Testing s Slickline Trailer at Vess Oil s Hall B #4

TORP s Efforts * Hall B #4 Gel Treatment w/ bottom-hole pressure measurement (entire treatment went on vacuum). 0.75 BPM (1080 BPD) Down tubing on packer 976 bbl @ 3500 ppm 988 bbl @ 5000 ppm 264 bbl @ 6500 ppm 100 bbl oil overflush Shut in

1200 BHP Data Hall B #4 Bottom Hole Pressure, psig 1100 1000 900 0 5 10 15 20 25 30 35 40 45 Slide courtesy of Professor Paul Willhite 3500 ppm 5000 ppm Time, hours

1260 BHP Data Hall B #4 1240 Bottomhole Pressure, psig 1220 1200 1180 1160 1140 1120 6500 ppm 1100 41 42 43 44 45 46 47 48 Slide courtesy of Professor Paul Willhite Time, hours

1300 BHP Data Hall B #4 Oil Overflush Shut-in Bottomhole Pressure, psig 1200 1100 1000 900 47 48 49 50 51 Slide courtesy of Professor Paul Willhite Time, hours

Presentation Outline Background on TORP and Kansas Arbuckle Formation/Production Review of Kansas Arbuckle Polymer Treatments TORP s Efforts in Evaluating Arbuckle Polymer Treatments Future TORP/PTTC Activities Related to Arbuckle Polymer Treatments

Future TORP/PTTC Activities Conduct post-treatment build-ups on same 7 wells hope to document how reservoir changes after treatment. Sponsor operator forum for those operators who have pumped jobs February 4, 2003. PTTC to conduct gel polymer workshop Summer 2003. Publish case studies relative to gel polymer treatments Fall 2003. Put gel polymer database online Fall 2003.

View from Vess Oil s Colahan A #8