Materials Standards for Metal Injection Molded Parts



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MPIF Standard 35 s Standards for Metal Injection Molded Parts Issued 1993 Revised 2000 and 2007 Scope MPIF Standard 35 is issued to provide the design and materials engineer with the information necessary for specifying powder metal (PM) materials that have been developed by the PM parts manufacturing industry. This section of Standard 35 deals with products manufactured by Metal Injection Molding (MIM). It does not apply to conventional PM structural materials, PM self-lubricating bearings or powder forged (PF) materials which are covered in separate editions of MPIF Standard 35. Each section of this standard is divided into subsections based on the various types of MIM materials in common commercial use within that section. Notes at the beginning of each subsection discuss the characteristics of that material. The same materials may appear in more than one section of the standard depending upon their common use, e.g., some low-alloy or stainless steel materials may also be used in soft-magnetic applications. The use of any MPIF Standard is entirely voluntary. MPIF Standards are issued and adopted in the public interest. They are designed to eliminate misunderstandings between the manufacturer and the purchaser and to assist the purchaser in selecting and obtaining the proper material for a particular product. Existence of MPIF Standards does not in any respect preclude any member or non-member of MPIF from manufacturing or selling products that use materials or testing procedures not included in MPIF Standards. Other such materials may be commercially available. By publication of these Standards, no position is taken with respect to the validity of any patent rights nor does the MPIF undertake to ensure anyone utilizing the Standards against liability for infringement of any Letters Patent or accept any such liability. Neither MPIF nor any of its members assumes or accepts any liability resulting from use or non-use of any MPIF Standard. In addition, MPIF does not accept any liability or responsibility for the compliance of any product with any standard, the achievement of any minimum or typical values by any supplier, or for the results of any testing or other procedure undertaken in accordance with any Standard. MPIF Standards are subject to periodic review and may be revised. Users are cautioned to refer to the latest edition. New, approved materials and property data may be posted periodically on the MPIF Web site. Between published editions, go to www.mpif.org to access data that will appear in the next printed edition of this standard. Both the purchaser and manufacturer should, in order to avoid possible misconceptions or misunderstandings, agree on the following conditions prior to the manufacture of a MIM component: material selection, chemical composition, minimum property values and any other processes, that may affect the part application. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, without the prior permission of the publisher. Copyright 2007 ISBN-13: 978-0-9762057-9-1 ISBN-10: 0-9762057-9-3 Published by Metal Powder Industries Federation 105 College Road East Princeton, New Jersey 08540-6692 U.S.A. Tel: (609) 452-7700 Fax: (609) 987-8523 E-mail: info@mpif.org Web site: www.mpif.org 1

MPIF Standard 35 s Standards for Metal Injection Molded Parts* *For structural parts made by the powder metallurgy (PM) process, see MPIF Standard 35, s Standards for PM Structural Parts. *For bearings and bushings made by the PM process, see MPIF Standard 35, s Standards for PM Self- Lubricating Bearings. *For steel components made by the powder forging (PF) process, see MPIF Standard 35, s Standards for P/F Steel Parts. Table of Contents 2007 Edition EXPLANATORY NOTES AND DEFINITIONS Minimum Value Concept 3 Minimum Mechanical Property Values 3 Minimum Magnetic Property Values 3 Minimum Controlled-Expansion Property Values 3 Practical Methods of Demonstrating Part Performance 3 Typical Values 4 Chemical Composition 4 Mechanical Properties 4 Heat Treatment 4 Surface Finish 4 Microstructure 4 MIM Designation 4 Selection 4 Grade Selection 5 Density 5 Ultimate Tensile Strength 5 Yield Strength 5 Elongation 6 Elastic Constants 6 Young s Modulus (E) 6 Shear Modulus (G) 6 Poisson s Ratio (ν) 6 Impact Energy 6 Macrohardness (Apparent) 6 Microindentation Hardness 6 Corrosion Resistance 6 Sulfuric Acid Testing 6 Copper Sulfate Testing 7 Boiling Water Testing 7 Soft Magnetic Properties 7 Magnetizing Field (H) 7 Induction (B) 7 Maximum Induction (B m ) 7 Maximum Permeability (µ max ) 7 Coercive Field (H c ) 7 Residual Induction (B r ) 7 Controlled-Expansion Alloys/Coefficient of Thermal Expansion (CTE) 7 SI Units 7 Comparable Standard 7 DATA TABLES INCH-POUND UNITS Low-Alloy Steels 8-9 Stainless Steels 10-11 Soft-Magnetic Alloys 12-13 Controlled-Expansion Alloys 14-15 DATA TABLES SI UNITS Low-Alloy Steels 16-17 Stainless Steels 18-19 Soft-Magnetic Alloys 20-21 Controlled-Expansion Alloys 22-23 SI Units Conversion Table Quantities/Terms Used in MPIF Standards 24 Index Alphabetical Listing & Guide to Systems & Designation Codes Used in MPIF Standard 35 25 Standards Availability/MPIF Standing Order Form 29 2

MPIF Standard 35 2007 s Standards for Metal Injection Molded Parts Explanatory Notes and Definitions Minimum Value Concept The Metal Powder Industries Federation has adopted the concept of minimum property values for metal injection molded (MIM) materials. These values may be used to determine the material best suited to the particular application as it is manufactured by the metal injection molding (MIM) process. As an aid to the user in selecting materials, in addition to minimum property values, typical values for other properties are listed. This makes it possible for the user to select and specify the exact MIM material and properties most suitable for a specific application. The data provided define minimum values for listed materials and display typical properties achieved under commercial manufacturing procedures. Enhanced mechanical properties and other improvements in performance characteristics may be attained through more complex processing. To select a material optimum in both properties and cost effectiveness, it is essential that the part application be discussed with the MIM parts manufacturer. Minimum Mechanical Property Values The minimum mechanical property values for MIM materials are expressed in terms of yield strength (0.2% offset method), ultimate tensile strength and percent elongation for all materials in the as-sintered and/or heat treated conditions. MIM materials exhibit properties similar to wrought materials because they are processed to near full density. The tensile properties utilized for establishing this Standard were obtained from tensile specimens prepared specifically for evaluating MIM materials. (See MPIF Standard 50 for additional details on MIM tensile test specimens.) Tensile properties of test specimens machined from commercial parts or from non-standard MIM test specimens, may vary from those obtained from specimens prepared according to MPIF Standard 50. Minimum Magnetic Property Values The minimum magnetic property values for MIM materials are expressed in terms of part density, maximum permeability, maximum coercive force and magnetic saturation. The specified minimum magnetic saturation is measured with an applied field of 25 oersteds. All magnetic test data reported are for DC testing only. The magnetic properties utilized for establishing this Standard were obtained from specimens prepared and tested in accordance with ASTM A 773. Minimum Controlled-Expansion Property Values A minimum density level is expressed for the MIM controlled-expansion alloys due to their use in electronics applications to provide hermetic seals with materials such as glasses and ceramics. Practical Methods of Demonstrating Part Performance For structural parts, the practical method of demonstrating minimum values is through the use of a static or dynamic proof test by the manufacturer and the purchaser using the first production lot of parts and a mutually agreed upon method of stressing the part. For example, from the design of a given part, it is agreed that the breaking load should be greater than a given force. If that force is exceeded in proof tests, the minimum strength is demonstrated. The first lot of parts can also be tested in service and demonstrated to be acceptable. The static or dynamic load to fracture is determined separately and these data are statistically analyzed to determine a minimum breaking force for future production lots. Exceeding that minimum force on future lots is proof that the specified strength has been met. For parts that require minimum magnetic characteristics, the practical method of demonstrating acceptable magnetic properties is through the use of a magnetic proof test. For example, from the design of a given part, it is agreed that the magnetic force generated by the part when a specified magnetic field is applied should be greater than a mutually agreed upon value between the parties concerned. If that force is exceeded in proof tests, the minimum magnetic performance is demonstrated. Exceeding this minimum value on future lots is proof that the specific magnetic properties have been met. Utilization of MPIF Standard 35 to specify a MIM material means that unless the purchaser and manufacturer have agreed otherwise, the material will have the minimum value specified in the Standard. (See Properties beginning on page 8.) 3

MPIF Standard 35, Metal Injection Molded Parts 2007 Edition Typical Values For each MIM material listed, a set of typical values is shown for properties, e.g., density, hardness, elongation, etc., some or all of which may be important for a specific application. Typical values are shown for properties, e.g., elongation, hardness, coercive field, etc., some or all of which may be important for a specific application. The property data were compiled from test specimens processed by individual MIM producers. The typical values are listed for general guidance only. They should not be considered minimum values. While achievable through normal manufacturing processing, they may vary somewhat depending upon the area of the component chosen for evaluation, or the specific manufacturing process utilized. Those properties listed under the typical value section for each material which are required by the purchaser should be thoroughly discussed with the MIM parts manufacturer before establishing the specification. Required property values, other than those expressed as minimum should be separately specified for each MIM part, based on its intended use. Chemical Composition The chemical composition of each material lists its principal elements and allowable ranges. Mechanical Properties Mechanical property data indicate the minimum and typical properties that may be expected from test specimens conforming to the density and chemical composition criteria listed. It should be understood that mechanical properties used in this standard were derived from individual test specimens prepared specifically for material evaluation and sintered under commercial production conditions. Hardness values of heat treated specimens are given first as apparent hardness and second, when available, as equivalent particle or matrix hardness values. Residual porosity found in MIM components will slightly affect the apparent hardness readings. Microhardness values shown as Rockwell C were converted from 100 g load (0.981 N) Knoop microhardness measurements. Heat Treatment MIM materials may be heat treated to increase strength, hardness and wear resistance. The percentages of carbon, alloying elements and residual porosity determine the degree of hardening possible. Tempering or stress relief is required after quenching for optimum strength and durability. Ferrous MIM parts processed with little or no final carbon may be surface carburized for increased surface hardness while retaining core toughness. Martensitic and precipitation hardening stainless steels may also be heat treated for increased hardness and strength. Most MIM materials respond well to normal wrought heat treating practices and procedures. It is recommended that the heat-treatment procedures for any MIM material be established in cooperation with the MIM part manufacturer to achieve the desired balance of final properties in the finished part. Surface Finish The overall finish and surface reflectivity of MIM materials depends on density, tool condition, particle size and secondary operations. Effective surface smoothness of as-sintered MIM components is usually better than an investment cast surface. Surface finish can be further improved by secondary operations such as coining, honing, burnishing or grinding. The surface finish requirements and methods of determination must be established by mutual agreement between purchaser and producer. (See MPIF Standard 58 for additional details.) Microstructure MIM materials generally contain less than 5% porosity, approaching the density of wrought materials. The examination of the microstructure of a MIM part can serve as a diagnostic tool and reveal the degree of sintering and other metallurgical information critical to the metal injection molding process. There are several observations common to most sintered MIM materials, as briefly described below. Comments on specific materials will be found in the subsections devoted to those particular materials. Sintered parts are normally examined first in the unetched condition. With a proper sinter, there will be no original particle boundaries seen at 200X. Small, uniformly distributed, well rounded discrete pores lead to higher strength, ductility and impact resistance. MIM Designation The Metal Injection Molding Association has chosen to use the designation system similar to AISI-SAE where applicable. These designations were chosen because MIM parts are likely to be used as replacements for wrought products already in service. When specifying a material made by the MIM process, it should be so designated with a MIM prefix to the material grade. For example, a part fabricated from Type 316L stainless steel by MIM would be designated as "MIM 316L". Selection Before a particular material can be selected, a careful analysis is required of the design of the part and its end use. In addition, the final property requirements of the finished part should be agreed upon by the manufacturer and the purchaser of the MIM part. Issues such as static 4

MPIF Standard 35, Metal Injection Molded Parts 2007 Edition and dynamic loading, wear resistance, machinability and corrosion resistance may also be specified. Grade Selection For certain magnetic materials, the material designaion will specify the material as either Grade 1 or Grade 2. The Grade 1 material, as compared with Grade 2, will exhibit improved magnetic characteristics. The difference between a Grade 1 and Grade 2 material can usually be found in the material s microstructure, with a high density, large grain size and low amounts of interstitials (carbon, oxygen, nitrogen, etc.) all contributing to improved magnetic properties. A careful analysis of the design and function of the part should determine what grade material is required for a given application. It is recommended that a discussion of the required magnetic performance take place between the manufacturer and the purchaser before the final grade selection. Density Density is expressed in grams per cubic centimeter (g/cm 3 ). MIM materials generally contain less than 5% porosity, so impregnation is not applicable. (See MPIF Standard 42 for additional details.) A method commonly used is as follows: Where: A ρ w D = A - C + E D = density, in grams per cubic centimeter A = mass of the specimen in air, in grams C = mass of the specimen in water, in grams E = mass (tare) of the suspending wire or basket, in water, in grams ρ w = density of water at test temperature, in grams per cubic centimeter Note 1: Masses A, C & E shall be determined to within 1 milligram. Note 2: The effect of the surface tension of water in weighing the test sample should be minimized with the addition of a wetting agent to the water in the amount of 0.1%. Note 3: Water density is determined as follows: Effect of Temperature on Water Density Temperature ρ w Temperature ρ w C g/cm 3 F g/cm 3 * 15 0.9991 60 0.9990 15.5 0.9990 61 0.9989 16 0.9989 62 0.9988 16.5 0.9988 63 0.9987 17 0.9988 64 0.9986 17.5 0.9987 65 0.9985 18 0.9986 66 0.9984 18.5 0.9985 67 0.9983 19 0.9984 68 0.9982 19.5 0.9983 69 0.9981 20 0.9982 70 0.9980 20.5 0.9981 71 0.9978 21 0.9980 72 0.9977 21.5 0.9979 73 0.9975 22 0.9978 74 0.9974 22.5 0.9976 75 0.9973 23 0.9975 76 0.9972 23.5 0.9974 77 0.9970 24 0.9973 78 0.9969 24.5 0.9972 79 0.9967 25 0.9970 80 0.9966 25.5 0.9969 81 0.9964 26 0.9968 82 0.9963 26.5 0.9966 83 0.9961 27 0.9965 84 0.9959 27.5 0.9964 85 0.9958 28 0.9962 86 0.9956 28.5 0.9961 29 0.9959 *Interpolated 29.5 0.9958 from C data 30 0.9956 NOTE: The values of ρ w shown are taken from, Metrological Handbook 145, Quality Assurance for Measurements, 1990, NIST, pp 9,10, and represent the values in air at one atmosphere pressure. Another method of density determination may be by gas pycnometer as agreed upon between purchaser and producer. (See MPIF Standard 63 for additional details.) Ultimate Tensile Strength Ultimate tensile strength, expressed in 10 3 psi (MPa) is the ability of a test specimen to resist fracture when a pulling force is applied in a direction parallel to its longitudinal axis. It is equal to the maximum load divided by the original cross-sectional area. (See MPIF Standard 50 for additional details.) Yield Strength Yield Strength, expressed in 10 3 psi, is the load at which a material exhibits a 0.2% offset from proportionality on a stress-strain tension curve divided by the original cross- 5

MPIF Standard 35, Metal Injection Molded Parts 2007 Edition sectional area. (See MPIF Standard 50 for additional details.) Elongation Elongation (plastic), expressed as a percentage of the original gage length (typically 1.0 in. [25.4mm]), is based on measuring the increase in gage length after fracture, providing the fracture takes place within the gage length. Elongation can also be measured with a break-away extensometer on the tensile specimen. The recorded stress strain-curve displays total elongation (elastic and plastic). The elastic strain at the 0.2% yield strength must be subtracted from the total elongation to give the plastic elongation. (See MPIF Standard 59 for additional details.) Elastic Constants Data for the elastic constants in this standard were generated from resonant frequency testing. An equation relating the three elastic constants is: E ν = 1 2G Young s Modulus (E) Young s modulus, expressed in 10 6 psi (GPa), is the ratio of normal stress to corresponding strain for tensile or compressive stresses below the proportional limit of the material. Shear Modulus (G) Shear modulus, expressed in 10 6 psi (GPa), is the ratio of shear stress to corresponding shear strain below the proportional limit of the material. Poisson s Ratio (ν) Poisson s ratio is the absolute value of the ratio of transverse strain to the corresponding axial strain resulting from uniformly distributed axial stress below the proportional limit of the material. Impact Energy Impact energy, measured in foot-pounds-force (Joules), is a measure of the energy absorbed in fracturing a specimen in a single blow. An unnotched 5 mm X 10 mm crosssection Charpy specimen was used to establish the MIM impact energy values. (See MPIF Standard 59 for additional details.) Macrohardness (Apparent) The hardness value of a MIM part when using a conventional indentation hardness tester is referred to as "apparent hardness" because it represents a combination of matrix hardness plus effect of residual porosity. The effect of residual porosity on hardness values is minor for MIM parts. Apparent hardness measures the resistance to indentation. Following is a recommended procedure for measuring the apparent hardness of a MIM material: A. Specify a region for evaluation. B. Remove any burrs that might affect the indentation hardness reading by coming in contact with the indentor or support surfaces. C. Obtain a minimum of five hardness readings. D. Average the readings. E. Report the average results to the nearest whole number. The manufacturer and the purchaser should agree on the hardness, the measuring procedure, and the hardness scale for each part tested. (See MPIF Standard 43 for additional details.) Microindentation Hardness Microindentation hardness is determined by utilizing Knoop (HK) or Vickers (HV) indentors with a microindentation hardness tester. It measures the true hardness of the structure by eliminating the effect of porosity, and thus is a measure of resistance to abrasive and adhesive wear. Microindentation hardness measurements are convertible to equivalent Rockwell hardness values for comparison with other materials. Care should be taken in converting Knoop to HRC because the conversion chart listed in ASTM E 140 is based on a 500 gf load, while the recommended load for a MIM or (PM) material is 100 gf. A description of the microstructure must be reported. The specimen shall be polished to reveal the porosity and lightly etched to view the phases in the microstructure and to determine where to place the hardness indenation. If the indentor strikes an undisclosed pore, the diamond mark will exhibit curved edges and the reading must be discarded. Since the data tend to be scattered compared with pore-free material, it is recommended that a minimum of 5 indentations be made, anomalous readings discarded, and an average taken of the remainder. (See MPIF Standard 51 for additional details.) Corrosion Resistance Three media and test methods were used to rate the resistance of the MIM stainless steel alloys to corrosion. Sulfuric Acid Testing Standard 5 mm X 10 mm X 55 mm test specimens were immersed in a 2% sulfuric acid solution at room temperature (72 F ± 4 F [22 C ± 2 C]) for 1,000 hours. Two replicates were tested. The loss in mass for each was determined and then converted into a mass loss per surface area (in dm 2 ) per day factor, in units of g (dm 2 ) (day) 6

Copper Sulfate Testing - The copper sulfate test consists of mixing 22.5 ml of distilled water with 1 g cupric sulfate crystals and 2.5 g sulfuric acid. Specimens are immersed in this solution for 6 minutes at a temperature between 63 and 67 F (17 and 19 C). Specimens that show no visual signs of copper plating are classified as passing this test. (See ASTM F 1089 for additional details.) Boiling Water Testing - The boiling water test consists of immersing the specimen in boiling, distilled water for 30 minutes. After 30 minutes, the heat source is shut off and the specimen remains in the water for 3 hours. The specimen is then removed and left to dry for 2 hours. Specimens that show no visual corrosion are classified as passing this test. (See ASTM F 1089 for additional details.) MPIF Standard 35, Metal Injection Molded Parts 2007 Edition Soft-Magnetic Properties The magnetic data presented in this standard were developed in accordance with ASTM Standard A 773. Magnetizing Field (H) The magnetic field applied to a test specimen, measured in oersteds (Oe) or amperes/metre (A/m). Induction (B) The measured magnetic field generated in a test specimen due to an applied magnetic field, measured in kilogauss (kg) or tesla (T). Maximum Induction (B m ) The maximum value of induction in a DC hysteresis loop. This value depends on the magnetizing field applied. Data are reported at magnetizing fields of 25 Oe and 500 Oe, (1,990 A/m and 39,800 A/m), in units of kilogauss (kg) or tesla (T). Maximum Permeability (µ max ) The slope of the line from the origin to the knee of the initial B-H magnetization curve. This parameter is dimensionless. Coercive Field (H c ) The DC magnetizing field required to restore the magnetic induction to zero after the material has been symmetrically, cyclically magnetized, measured in Oe (A/m). Residual Induction (B r ) The retained magnetism in the specimen after the applied field has been reduced to zero Oe (A/m). This is reported in kg or T. Idealized Magnetic Hysteresis Curve Reference: Soft Magnetism, Fundamentals for Powder Metallurgy and Metal Injection Molding, Chaman Lall, Metal Powder Industries Federation, 1992, p.11. Controlled-Expansion Alloys Coefficient of Thermal Expansion (CTE) See pages 15 and 23. SI Units (See page 24) Data were determined in inch-pound units and converted to SI units in accordance with IEEE/ASTM SI 10. Comparable Standard Standards for metal injection molded parts have been issued by ASTM. The ASTM standard was adapted from MPIF Standard 35 and uses the MPIF MIM nomenclature system. ASTM B 883 Standard Specification for Metal Injection Molding (MIM) Ferrous s Additional MIM materials and property data are under development. When available, data will be published in subsequent editions of this Standard. New, approved materials and property data may be posted periodically on the MPIF Web site. Between published editions, go to www.mpif.org to access data that will appear in the next printed edition of this standard. 7

MIM Section 2007 MPIF Standard 35 Low-Alloy Steels This subsection covers MIM materials manufactured from both prealloys and admixtures of iron powder and other alloying elements such as nickel, molydenum, and carbon. The proportions of each element used and heat treat conditions may be varied to achieve a range of properties. Alloys may be hardened for very high strength with moderate ductility. Lower carbon alloys may be case hardened for wear resistance while achieving a tough core. Characteristics Complete diffusion of alloying elements normally takes place during sintering. The homogeneous structure imparts exceptional strength properties. The high density attained through MIM processing also gives these materials good ductility. Application Low-alloy steels are generally used for structural applications, especially when carburized. They are specified for applications where high strength and hardness are necessary. Microstructure Residual pores should be small, discrete, well distributed and rounded. The microstructure will vary with composition and heat treatment. Chemical Composition, % Low-Alloy Steels Designation Code Fe Ni Mo C Si (max) MIM-2200 (1) Bal. 1.5 2.5 0.5 max 0.1 max 1.0 MIM-2700 Bal. 6.5 8.5 0.5 max 0.1 max 1.0 MIM-4605 (2) Bal. 1.5 2.5 0.2 0.5 0.4 0.6 1.0 Other Elements: Total may not exceed 1.0% combined. (1) Formerly designated as MIM-4600 (2) Formerly designated MIM-4650 with the addition of a minimum 0.2% Mo. To select a material optimum in both properties and cost effectiveness, it is essential that the part application be discussed with the MIM parts manufacturer. (See Explanatory Notes: Minimum Value Concept page 2.) Both the purchaser and manufacturer should, in order to avoid possible misconceptions or misunderstandings, agree on the following conditions prior to the manufacture of a MIM component: material selection, chemical composition, minimum property values and any other processes, that may affect the part application 8

Low-Alloy Steels MIM Properties 9 MINIMUM VALUES TYPICAL VALUES Tensile Properties Tensile Properties Elastic Constants Hardness Unnotched Designation Yield Yield Charpy Micro- Code Ultimate Strength Elongation Ultimate Strength Elongation Young s Poisson s Impact Macro indentation Energy (condition) Strength (0.2%) (in 1 in.) Density Strength (0.2%) (in 1 in.) Modulus Ratio (A) (apparent) (converted) 10 3 psi 10 3 psi % g/cm 3 10 3 psi 10 3 psi % 10 6 psi ft lbf Rockwell MIM-2200 37 16 20.0 7.65 42 18 40.0 28.0 0.28 100 45 HRB N/D (as-sintered) MIM-2700 55 30 20.0 7.6 60 37 26.0 28.0 0.28 130 69HRB N/D (as-sintered) MIM-4605 55 25 11.0 7.5 64 30 15.0 29.0 0.28 50 62 HRB N/D (as-sintered) MIM-4605 215 190 <1.0 7.5 240 215 2.0 29.5 0.28 40 48HRC 55 HRC (quenched & tempered) NOTES: (A) Impact energy values derived from an un-notched 5 mm x 10 mm cross-section Charpy specimen (see MPIF Standard 59). N/D Not determined for the purposes of this standard. 2007 Edition Approved: 1992 Revised: 2000, 2007

MIM Section 2007 MPIF Standard 35 Stainless Steels This subsection covers MIM materials manufactured from prealloyed or elementally blended stainless steels. Included are austenitic, ferritic and precipitation hardening grades. Characteristics High densities achieved by the MIM process enhance the strength, ductility and corrosion resistance of these materials. Application There are several grades of MIM stainless steels. Each has specific properties which cover a wide variety of applications: MIM-316L Austenitic Grade This grade is used in applications which require extremly good corrosion resistance. Parts made from this material have a good combination of strength and ductility. MIM-420 Martensitic Grade This martensitic stainless steel combines high strength, hardness and wear resistance with moderate corrosion resistance. A range of properties and hardness can be achieved though modifications of the carbon content and heat-treating condition. MIM-430L Ferritic Grade This ferritic stainless steel combines good magnetic response with corrosion resistance. It is suitable for applications in a corrosive environment where protective coatings are impractical. (See page 12 for additional information for this material in the soft-magnetic alloys section.) MIM-17-4 PH Precipitation Hardening Grade The precipitation hardening grade of stainless is used where a high level of strength and hardness is necessary. It generally has better corrosion resistance than the 400 series stainless steels because of low carbon content. A range of properties and hardness can be achieved through modifications of the aging temperature during heat treatment. Microstructure All materials should exhibit wrought-like microstructures except that MIM materials have evenly dispersed, well rounded pores. There should be no evidence of original particle boundaries. Internal oxides, nitrides and chromium carbides are detrimental to properties. Chemical Composition, % Stainless Steels Designation Code Fe Ni Cr Mo C Cu Nb + Ta Mn (max) Si (max) MIM-316L Bal. 10 14 16 18 2 3 0.03 max 2.0 1.0 MIM-420 Bal. 12 14 0.15 0.4 1.0 1.0 MIM-430L Bal. 16 18 0.05 max 1.0 1.0 MIM-17-4 PH Bal. 3 5 15.5 17.5 0.07 max 3 5 0.15 0.45 1.0 1.0 Other Elements: Total may not exceed 1.0% combined. To select a material optimum in both properties and cost effectiveness, it is essential that the part application be discussed with the MIM parts manufacturer. (See Explanatory Notes: Minimum Value Concept page 2.) Both the purchaser and manufacturer should, in order to avoid possible misconceptions or misunderstandings, agree on the following conditions prior to the manufacture of a MIM component: material selection, chemical composition, minimum property values and any other processes, that may affect the part application 10

Stainless Steels MIM Properties 11 MINIMUM VALUES TYPICAL VALUES Tensile Properties Tensile Properties Elastic Constants Hardness Corrosion Resistance Unnotched Designation Yield Yield Charpy Micro- Code Ultimate Strength Elongation Ultimate Strength Elongation Young s Poisson s Impact Macro indentation Energy Boil (condition) Strength (0.2%) (in 1 in.) Density Strength (0.2%) (in 1 in.) Modulus Ratio (A) (apparent) (converted) H 2 SO 4 Test 10 3 psi 10 3 psi % g/cm 3 10 3 psi 10 3 psi % 10 6 psi ft lbf Rockwell g/dm 2 /day CuSO 4 (H 2 O) MIM-316L 65 20 40.0 7.6 75 25 50.0 28.0 0.28 140 67 HRB N/D <0.005 Pass Pass (as-sintered) MIM-420 180 (B) (C) 7.4 200 174 <1.0 28.0 0.30 30 44 HRC 50 HRC N/D N/D Pass (heat-treated)** MIM-430L 50 30 20.0 7.55 60 35 25.0 30.0 0.29 110 65 HRB N/D 0.125 Pass Pass (as-sintered) MIM-17-4 PH 115 94 4.0 7.5 130 106 6.0 28.0 0.29 100 27 HRC N/D <0.005 Pass Pass (as-sintered) MIM-17-4 PH 155 140 4.0 7.5 172 158 6.0 28.0 0.29 100 33 HRC 40 HRC <0.005 Pass Pass (heat treated)* *Heat-treated MIM-17-4 PH parts were aged at 900 F (482 C). **Heat-treated MIM-420 parts were austenitized and tempered at 400 F (204 C) for a minimum of 1 hour. NOTES: (A) Impact energy values derived from an un-notched 5 mm x 10 mm cross-section Charpy specimen (see MPIF Standard 59). (B) Heat-treated MIM-420-SS may not show any yield point based on a 0.2% offset. (C) There may be no measurable elongation for the MIM-420-SS heat-treated material. N/D Not determined for the purposes of this standard. 2007 Edition Approved: 1992 Revised: 2000, 2007

MIM Section 2007 MPIF Standard 35 Soft-Magnetic Alloys This subsection covers MIM materials manufactured from prealloyed powder or admixtures of iron and other elements such as nickel, chromium, cobalt and silicon. These alloys are classified as soft-ferromagnetic materials, that allows them to be easily magnetized and demagnetized. Characteristics Complete diffusion of alloying elements normally takes place during sintering. A homogeneous microstructure, low levels of interstitials and high sintered density will enhance magnetic properties. Grade Selection Certain materials in this standard with the same nominal composition have been assigned two grades. When selecting a material, a comparison should be made between the magnetic properties required and the properties of each grade. Application There are several MIM soft-magnetic alloys. Each has specific properties that covers a wide range of applications. MIM-2200 Used in applications requiring high magnetic output, comparable to iron, but with improved strength. MIM-Fe-3%Si Exhibits low core losses and high electrical resistivity in AC and DC applications (e.g., solenoids, armatures, relays). Since this alloy readily work hardens, it is particularly suited to net-shape forming via MIM. MIM-Fe-50%Ni High permeability and low coercive field are the hallmark magnetic properties for this alloy. It is used in motors, switches and relays, and for magnetic shielding applications. MIM-Fe-50%Co The iron-cobalt alloys produce the highest magnetic saturation, surpassing pure iron. This material is suitable for small components required to carry high magnetic flux densities. MIM-430L This ferritic stainless steel combines good magnetic response with corrosion resistance. It is suitable for applications in a corrosive environment where protective coatings are impractical. Microstructure The unetched structures exhibit small, uniformly distributed, well-rounded pores that are not interconnected. In the etched condition, the microstructure is well-homogenized with little or no evidence of carbides or oxides. Chemical Composition, % Soft-Magnetic Alloys Designation Code Fe Ni Cr Co Si C (max) Mn V MIM-2200 Bal. 1.5 2.5 1.0 max 0.1 MIM-Fe-3%Si Bal. 2.5 3.5 0.05 MIM-Fe50%Ni Bal. 49 51 1.0 max 0.05 MIM-Fe50%Co Bal. 48 50 1.0 max 0.05 2.5 max MIM-430L Bal. 16 18 1.0 max 0.05 1.0 max Other Elements: Total may not exceed 1.0% combined. To select a material optimum in both properties and cost effectiveness, it is essential that the part application be discussed with the MIM parts manufacturer. (See Explanatory Notes: Minimum Value Concept page 2.) Both the purchaser and manufacturer should, in order to avoid possible misconceptions or misunderstandings, agree on the following conditions prior to the manufacture of a MIM component: material selection, chemical composition, minimum property values and any other processes, that may affect the part application 12

Soft-Magnetic Alloys MIM Properties 13 MINIMUM VALUES TYPICAL VALUES Magnetic Properties Tensile Properties Maximum Maximum Yield Macro- Designation Permeability Hc B 25 ability H c B r B 25 B 500 Density Strength (0.2%) (in 1 in.) (apparent) Maximum Perme- Ultimate Strength Elongation hardness Code Density as-sintered g/cm 3 µmax Oe kg µ max Oe kg kg kg g/cm 3 10 3 psi 10 3 psi % HRB MIM-2200 7.60 2,000 2.0 14.0 2,300 1.5 8.0 14.5 20.0 7.65 42 18 40.0 45 MIM-Fe-50% Ni-Grade 1* 7.70 40,000 0.15 13.0 47,500 0.13 10.0 14.0 15.0 7.75 66 23 30.0 50 -Grade 2* 7.70 20,000 0.25 13.0 27,000 0.20 10.0 14.0 15.0 7.75 66 23 30.0 50 MIM-Fe-3% Si-Grade 1 7.60 8,000 0.75 14.0 8,500 0.7 12.0 14.5 19.5 7.62 77 57 24.0 80 -Grade 2 7.45 5,500 1.1 14.0 6,000 1.0 12.0 14.5 19.0 7.50 77 57 24.0 80 MIM-Fe-50% Co 7.70 4,800 2.0 19.0 5,200 1.5 14.0 20.0 22.0 7.75 30 20 <1.0 80 MIM-430L 7.50 1,000 2.3 11.0 1,500 1.8 5.5 11.5 15.8 7.55 60 35 25.0 65 *Interstitials (oxygen, nitrogen) content and grain size affect magnetic response. 2007 Edition Approved: 2000 Revised: 2007

MIM Section 2007 MPIF Standard 35 Controlled-Expansion Alloys This subsection covers MIM materials manufactured from pre-alloyed powder and/or admixtures of iron, nickel and cobalt. The proportions of the elements iron, nickel and cobalt may be varied to meet the requirements of the coefficient of thermal expansion. Application Controlled-expansion alloys are used in electronics applications to provide hermetic seals with materials such as glasses and ceramics. MIM-F-15 This low expansion alloy is used for glass-to metal sealing applications. It provides hermetic seals for electronic fiber optic and microwave packages, such as splitters, dual in-line packages and micro-electronic mechanical systems. Characteristics Complete diffusion of alloying elements normally takes place during sintering. The homogeneous microstructure and high sintered density provide for exceptional hermeticity and controlled thermal expansion. Microstructure The un-etched structures exhibit small, uniformly distributed, well-rounded pores that are not interconnected. In the etched condition, the microstructure is well-homogenized with little or no evidence of carbides or oxides. Nominal Chemical Composition, % Controlled-Expansion Alloys Designation Fe Ni Co Mn Si C Al Mg Zr Ti Cu Cr Mo max max max max max max max max max max MIM-F15 Bal. 29 17 0.50 0.20 0.04 0.10 0.10 0.10 0.10 0.20 0.20 0.20 Other Elements: Aluminum, magnesium, zirconium and titanium may not exceed 0.20% combined. Total may not exceed 1% combined. To select a material optimum in both properties and cost effectiveness, it is essential that the part application be discussed with the MIM parts manufacturer. (See Explanatory Notes: Minimum Value Concept page 2.) Both the purchaser and manufacturer should, in order to avoid possible misconceptions or misunderstandings, agree on the following conditions prior to the manufacture of a MIM component: material selection, chemical composition, minimum property values and any other processes, that may affect the part application 14

Controlled-Expansion Alloys MIM Properties MINIMUM VALUES TYPICAL VALUES Tensile Properties Hardness Designation Yield Micro- Code Ultimate Strength Elongation Young s Macro indentation (condition) Density Density Strength (0.2%) (in 1 in.) Modulus (apparent) (converted) g/cm 3 g/cm 3 10 3 psi 10 3 psi % 10 6 psi Rockwell MIM-F-15 7.7 7.8 67 43 25 17 65 HRB N/D (as-sintered) 15 Coefficient of Thermal Expansion (CTE) The coefficient of thermal expansion was determined for the MIM-F-15 alloy in accordance with ASTM E 228. A push-rod dilatometer was used for these tests, using a 3.6 F/minute heating rate in a nitrogen atmosphere. The average coefficient of thermal expansion was determined from room temperature (68 F) up to a series of temperatures. NOTES: N/D Not determined for the purposes of this standard. From 68 F Average CTE To: (X 10-6 / F) 212 F 3.7 302 F 3.4 392 F 3.2 482 F 3.1 572 F 3.0 2007 Edition Approved: 2007

SI UNITS MIM Section 2007 MPIF Standard 35 Low-Alloy Steels This subsection covers MIM materials manufactured from both prealloys and admixtures of iron powder and other alloying elements such as nickel, molydenum, and carbon. The proportions of each element used and heat treat conditions may be varied to achieve a range of properties. Alloys may be hardened for very high strength with moderate ductility. Lower carbon alloys may be case hardened for wear resistance while achieving a tough core. Characteristics Complete diffusion of alloying elements normally takes place during sintering. The homogeneous structure imparts exceptional strength properties. The high density attained through MIM processing also gives these materials good ductility. Application Low-alloy steels are generally used for structural applications, especially when carburized. They are specified for applications where high strength and hardness are necessary. Microstructure Residual pores should be small, discrete, well distributed and rounded. The microstructure will vary with composition and heat treatment. Chemical Composition, % Low-Alloy Steels Designation Code Fe Ni Mo C Si (max) MIM-2200 (1) Bal. 1.5 2.5 0.5 max 0.1 max 1.0 MIM-2700 Bal. 6.5 8.5 0.5 max 0.1 max 1.0 MIM-4605 (2) Bal. 1.5 2.5 0.2 0.5 0.4 0.6 1.0 Other Elements: Total may not exceed 1.0% combined. (1) Formerly designated as MIM-4600 (2) Formerly designated MIM-4650 with the addition of a minimum 0.2% Mo. To select a material optimum in both properties and cost effectiveness, it is essential that the part application be discussed with the MIM parts manufacturer. (See Explanatory Notes: Minimum Value Concept page 2.) Both the purchaser and manufacturer should, in order to avoid possible misconceptions or misunderstandings, agree on the following conditions prior to the manufacture of a MIM component: material selection, chemical composition, minimum property values and any other processes, that may affect the part application 16

Low-Alloy Steels MIM Properties 17 MINIMUM VALUES TYPICAL VALUES Tensile Properties Tensile Properties Elastic Constants Hardness Unnotched Designation Yield Yield Charpy Micro- Code Ultimate Strength Elongation Ultimate Strength Elongation Young s Poisson s Impact Macro indentation Energy (condition) Strength (0.2%) (in 25.4 mm) Density Strength (0.2%) (in 25.4 mm) Modulus Ratio (A) (apparent) (converted) MPa MPa % g/cm 3 MPa MPa % GPa J Rockwell MIM-2200 255 110 20.0 7.65 290 125 40.0 190 0.28 135 45 HRB N/D (as-sintered) MIM-2700 380 205 20.0 7.6 415 255 26.0 190 0.28 175 69 HRB N/D (as-sintered) MIM-4605 380 170 11.0 7.5 440 205 15.0 200 0.28 70 62 HRB N/D (as-sintered) MIM-4605 1,480 1,310 <1.0 7.5 1,655 1,480 2.0 205 0.28 55 48 HRC 55 HRC (quenched & tempered) NOTES: (A) Impact energy values derived from an un-notched 5 mm x 10 mm cross-section Charpy specimen (see MPIF Standard 59). N/D Not determined for the purposes of this standard. 2007 Edition Approved: 2000 Revised: 2000, 2007 SI UNITS

SI UNITS MIM Section 2007 MPIF Standard 35 Stainless Steels This subsection covers MIM materials manufactured from prealloyed or elementally blended stainless steels. Included are austenitic, ferritic and precipitation hardening grades. Characteristics High densities achieved by the MIM process enhance the strength, ductility and corrosion resistance of these materials. Application There are several grades of MIM stainless steels. Each has specific properties which cover a wide variety of applications: MIM-316L Austenitic Grade This grade is used in applications which require extremly good corrosion resistance. Parts made from this material have a good combination of strength and ductility. MIM-420 Martensitic Grade This martensitic stainless steel combines high strength, hardness and wear resistance with moderate corrosion resistance. A range of properties and hardness can be achieved though modifications of the carbon content and heat-treating condition. MIM-430L Ferritic Grade This ferritic stainless steel combines good magnetic response with corrosion resistance. It is suitable for applications in a corrosive environment where protective coatings are impractical. (See page 20 for additional information for this material in the soft magnetic alloys section.) MIM-17-4 PH Precipitation Hardening Grade The precipitation hardening grade of stainless is used where a high level of strength and hardness is necessary. It generally has better corrosion resistance than the 400 series stainless steels because of low carbon content. A range of properties and hardness can be achieved through modifications of the aging temperature during heat treatment. Microstructure All materials should exhibit wrought-like microstructures except that MIM materials have evenly dispersed, well rounded pores. There should be no evidence of original particle boundaries. Internal oxides, nitrides and chromium carbides are detrimental to properties. Chemical Composition, % Stainless Steels Designation Code Fe Ni Cr Mo C Cu Nb + Ta Mn (max) Si (max) MIM-316L Bal. 10 14 16 18 2 3 0.03 max 2.0 1.0 MIM-420 Bal. 12 14 0.15 0.4 1.0 1.0 MIM-430L Bal. 16 18 0.05 max 1.0 1.0 MIM-17-4 PH Bal. 3 5 15.5 17.5 0.07 max 3 5 0.15 0.45 1.0 1.0 Other Elements: Total may not exceed 1.0% combined. To select a material optimum in both properties and cost effectiveness, it is essential that the part application be discussed with the MIM parts manufacturer. (See Explanatory Notes: Minimum Value Concept page 2.) Both the purchaser and manufacturer should, in order to avoid possible misconceptions or misunderstandings, agree on the following conditions prior to the manufacture of a MIM component: material selection, chemical composition, minimum property values and any other processes, that may affect the part application 18

Stainless Steels MIM Properties 19 MINIMUM VALUES TYPICAL VALUES Tensile Properties Tensile Properties Elastic Constants Hardness Corrosion Resistance Unnotched Designation Yield Yield Charpy Micro- Code Ultimate Strength Elongation Ultimate Strength Elongation Young s Poisson s Impact Macro indentation Energy Boil (condition) Strength (0.2%) (in 25.4 mm) Density Strength (0.2%) (in 25.4 mm) Modulus Ratio (A) (apparent) (converted) H 2 SO 4 Test MPa MPa % g/cm 3 MPa MPa % GPa J Rockwell g/dm 2 /day CuSO 4 (H 2 O) MIM-316L 450 140 40.0 7.6 520 175 50.0 190 0.28 190 67 HRB N/D <0.005 Pass Pass (as-sintered) MIM-420 1240 (B) (C) 7.4 1,380 1,200 <1.0 190 0.30 40 44 HRC 50 HRC N/D N/D Pass (heat-treated)** MIM-430L 350 210 20.0 7.55 410 240 25.0 210 0.29 150 65 HRB N/D 0.125 Pass Pass (as-sintered) MIM-17-4 PH 790 650 4.0 7.5 900 730 6.0 190 0.29 140 27 HRC N/D <0.005 Pass Pass (as-sintered) MIM-17-4 PH 1,070 970 4.0 7.5 1,190 1,090 6.0 190 0.29 140 33 HRC 40 HRC <0.005 Pass Pass (heat treated)* *Heat-treated MIM-17-4 PH parts were aged at 482 C (900 F). **Heat-treated MIM-420 parts were austenitized and tempered at 204 C (400 F) for a minimum of 1 hour. NOTES: (A) Impact energy values derived from an un-notched 5 mm x 10 mm cross-section Charpy specimen (see MPIF Standard 59). (B) Heat-treated MIM-420-SS may not show any yield point based on a 0.2% offset. (C) There may be no measurable elongation for the MIM-420-SS heat-treated material. N/D Not determined for the purposes of this standard. 2007 Edition Approved: 2000 Revised: 2007 SI UNITS

SI UNITS MIM Section 2007 MPIF Standard 35 Soft-Magnetic Alloys This subsection covers MIM materials manufactured from prealloyed powder or admixtures of iron and other elements such as nickel, chromium, cobalt and silicon. These alloys are classified as soft-ferromagnetic materials, that allows them to be easily magnetized and demagnetized. Characteristics Complete diffusion of alloying elements normally takes place during sintering. A homogeneous microstructure, low levels of interstitials and high sintered density will enhance magnetic properties. Grade Selection Certain materials in this standard with the same nominal composition have been assigned two grades. When selecting a material, a comparison should be made between the magnetic properties required and the properties of each grade. Application There are several MIM soft-magnetic alloys. Each has specific properties that covers a wide range of applications. MIM-2200 Used in applications requiring high magnetic output, comparable to iron, but with improved strength. MIM-Fe-3%Si Exhibits low core losses and high electrical resistivity in AC and DC applications (e.g., solenoids, armatures, relays). Since this alloy readily work hardens, it is particularly suited to net-shape forming via MIM. MIM-Fe-50%Ni High permeability and low coercive field are the hallmark magnetic properties for this alloy. It is used in motors, switches and relays, and for magnetic shielding applications. MIM-Fe-50%Co The iron-cobalt alloys produce the highest magnetic saturation, surpassing pure iron. This material is suitable for small components required to carry high magnetic flux densities. MIM-430L This ferritic stainless steel combines good magnetic response with corrosion resistance. It is suitable for applications in a corrosive environment where protective coatings are impractical. Microstructure The unetched structures exhibit small, uniformly distributed, well-rounded pores that are not interconnected. In the etched condition, the microstructure is well-homogenized with little or no evidence of carbides or oxides. Chemical Composition, % Soft-Magnetic Alloys Designation Code Fe Ni Cr Co Si C (max) Mn V MIM-2200 Bal. 1.5 2.5 1.0 max 0.1 MIM-Fe-3%Si Bal. 2.5 3.5 0.05 MIM-Fe50%Ni Bal. 49 51 1.0 max 0.05 MIM-Fe50%Co Bal. 48 50 1.0 max 0.05 2.5 max MIM-430L Bal. 16 18 1.0 max 0.05 1.0 max Other Elements: Total may not exceed 1.0% combined. To select a material optimum in both properties and cost effectiveness, it is essential that the part application be discussed with the MIM parts manufacturer. (See Explanatory Notes: Minimum Value Concept page 2.) Both the purchaser and manufacturer should, in order to avoid possible misconceptions or misunderstandings, agree on the following conditions prior to the manufacture of a MIM component: material selection, chemical composition, minimum property values and any other processes, that may affect the part application 20

Soft-Magnetic Alloys MIM Properties 21 MINIMUM VALUES TYPICAL VALUES Magnetic Properties Tensile Properties Maximum Maximum Ultimate Yield Macro- Designation Permeability Hc B 1,990 ability H c B r B 1,990 B 39,800 Density Strength (0.2%) (in 25.4 mm) (apparent) Maximum Perme- Tensile Strength Elongation hardness Code Density as-sintered g/cm 3 µ max A/m T µ max A/m T T T g/cm 3 MPa MPa % HRB MIM-2200 7.60 2,000 160 1.40 2,300 120 0.80 1.45 2.00 7.65 290 125 40.0 45 MIM-Fe-50% Ni-Grade 1* 7.70 40,000 10 1.30 47,500 10 1.00 1.40 1.50 7.75 455 160 30.0 50 -Grade 2* 7.70 20,000 20 1.30 27,000 16 1.00 1.40 1.50 7.75 455 160 30.0 50 MIM-Fe-3% Si-Grade 1 7.60 8,000 60 1.40 8,500 56 1.20 1.45 1.95 7.62 530 390 24.0 80 -Grade 2 7.45 5,500 90 1.40 6,000 80 1.20 1.45 1.90 7.50 530 390 24.0 80 MIM-Fe-50% Co 7.70 4,800 160 1.90 5,200 120 1.40 2.00 2.20 7.75 205 140 <1.0 80 MIM-430L 7.50 1,000 185 1.10 1,500 140 0.55 1.15 1.58 7.55 415 240 25.0 65 *Interstitials (oxygen, nitrogen) content and grain size affect magnetic response. 2007 Edition Approved: 2000 Revised: 2007 SI UNITS

SI UNITS MIM Section 2007 MPIF Standard 35 Controlled-Expansion Alloys This subsection covers MIM materials manufactured from pre-alloyed powder and/or admixtures of iron, nickel and cobalt. The proportions of the elements iron, nickel and cobalt may be varied to meet the requirements of the coefficient of thermal expansion. Application Controlled-expansion alloys are used in electronics applications to provide hermetic seals with materials such as glasses and ceramics. MIM-F-15 This low expansion alloy is used for glass-to metal sealing applications. It provides hermetic seals for electronic fiber optic and microwave packages, such as splitters, dual in-line packages and micro-electronic mechanical systems. Characteristics Complete diffusion of alloying elements normally takes place during sintering. The homogeneous microstructure and high sintered density provide for exceptional hermeticity and controlled thermal expansion. Microstructure The un-etched structures exhibit small, uniformly distributed, well-rounded pores that are not interconnected. In the etched condition, the microstructure is well-homogenized with little or no evidence of carbides or oxides. Nominal Chemical Composition, % Controlled-Expansion Alloys Designation Fe Ni Co Mn Si C Al Mg Zr Ti Cu Cr Mo max max max max max max max max max max MIM-F15 Bal. 29 17 0.50 0.20 0.04 0.10 0.10 0.10 0.10 0.20 0.20 0.20 Other Elements: Aluminum, magnesium, zirconium and titanium may not exceed 0.20% combined. Total may not exceed 1% combined. To select a material optimum in both properties and cost effectiveness, it is essential that the part application be discussed with the MIM parts manufacturer. (See Explanatory Notes: Minimum Value Concept page 2.) Both the purchaser and manufacturer should, in order to avoid possible misconceptions or misunderstandings, agree on the following conditions prior to the manufacture of a MIM component: material selection, chemical composition, minimum property values and any other processes, that may affect the part application 22

Controlled-Expansion Alloys MIM Properties MINIMUM VALUES TYPICAL VALUES Tensile Properties Hardness Designation Yield Micro- Code Ultimate Strength Elongation Young s Macro indentation (condition) Density Density Strength (0.2%) (in 25.4 mm) Modulus (apparent) (converted) g/cm 3 g/cm 3 MPa MPa % GPa Rockwell MIM-F-15 7.7 7.8 460 300 25 120 65 HRB N/D (as-sintered) 23 Coefficient of Thermal Expansion (CTE) The coefficient of thermal expansion was determined for the MIM-F-15 alloy in accordance with ASTM E 228. A push-rod dilatometer was used for these tests, using a 2 C/minute heating rate in a nitrogen atmosphere. The average coefficient of thermal expansion was determined from room temperature (20 C) up to a series of temperatures. NOTES: N/D Not determined for the purposes of this standard. From 20 C Average CTE To: (X 10-6 / C) 100 C 6.6 150 C 6.2 200 C 5.8 250 C 5.5 300 C 5.4 2007 Edition Approved: 2007 SI UNITS

SI Units Conversion Table Quantities/Terms Used in MPIF Standards Approx. Conversion Quantity Designation Inch-Pound Units Preferred Working Unit Symbol to SI Units* Apparent Density ρ a g/cm 3 gram per cubic centimetre g/cm 3 -- Applied Magnetic Field H oersteds (Oe) amperes-turns/metre A/m X 79.6 Atmosphere Flow -- ft 3 /min cubic centimetre per second cm 3 /s X 472.0 CFH cubic centimetre per second cm 3 /s X 7.867 Belt Speed -- ipm millimetre per minute mm/min X 25.40 Bulk Density -- lbm/ft 3 gram per cubic centimetre g/cm 3 X 0.016 lbm/gal gram per cubic centimetre g/cm 3 X 0.120 Coercive Field H c oersteds (Oe) ampere-turns/metre A/m X 79.6 Compacting Pressure -- tsi megapascals MPa X 13.79 Crush Strength K 10 3 psi megapascals MPa X 6.895 Flow Time -- s/50 g second per 50 grams s/50 g -- Green Density ρ g g/cm 3 gram per cubic centimetre g/cm 3 -- Green Strength -- psi megapascals MPa X 0.0069 Heating Rate -- degree Fahrenheit per second ( F/sec) degree Celsius per second C/s X 0.556 Impact Energy -- ft lbf joule J X 1.356 Magnetic Induction B kilogauss (kg) tesla T X 0.1 Particle Size -- 10-3 in. micrometre µm -- Powder Mass -- pound (lbm) kilogram kg X 0.454 ton megagram Mg X 0.907 ton metric ton t X 0.907 Sintered Density ρ s g/cm 3 gram per cubic centimetre g/cm 3 -- Specific Surface -- m 2 /g square metre per gram m 2 /g -- Surface Finish -- microinches micrometre µm X 0.0254 Tap Density ρ t g/cm 3 gram per cubic centimetre g/cm 3 -- Temperature -- degree Fahrenheit ( F) degree Celsius C 5/9 ( F -32) Tensile Strength -- 10 3 psi megapascals MPa X 6.895 Transverse Rupture Strength -- 10 3 psi megapascals MPa X 6.895 Yield Strength -- 10 3 psi megapascals MPa X 6.895 Young's Modulus -- 10 6 psi gigapascals GPa X 6.895 * Example: 1 psi = 0.0069 MPa If 100,000 psi, then MPa = 0.0069 X 100,000 = 690 MPa 24

Index Alphabetical Listing & Guide to Systems & Designation Codes Used in MPIF Standard 35 The MPIF Standard 35 family of publications comprises four separate publications dealing with materials for: metal injection molded parts, conventional PM structural parts, PM self-lubricating bearings and powder forged (PF) steel parts. The same materials may appear in more than one publication or section of the standard depending upon their common use, e.g. some structural materials may also be used in bearing applications and vice versa and stainless steel materials may be manufactured by more than one PM process, such as MIM or conventional PM, dependent upon part design and use. The following indices provide the user with a reference tool to more easily locate the information on the standardized material needed for a specific application. INDEX 1 (35MIM1-2007) provides information on materials contained in this edition of MPIF Standard 35, s Standards for Metal Injection Molded Parts. The standardized material designation codes are listed alphabetically, followed by the name of the specific material system section of the standard where the chemical composition and/or mechanical property data can be found. Information is also provided for the starting page numbers of the material system and is listed for the inchpound and SI units sections of this standard. INDEX 2 (35MIM2-2007) provides similar information on the other three MPIF Standard 35 publications. Since MPIF standards may be revised at any time by the specific industry group responsible for its development, page numbers are not listed in this index. MPIF Standard 35 Publication: KEY MIM s Standards for Metal Injection Molded Parts PF s Standards for P/F Steel Parts SLB s Standards for PM Self-Lubricating Bearings SP s Standards for PM Structural Parts INDEX 1. (35MIM1-2007) s Standards for Metal Injection Molded Parts Page # Section Inch-Pound Page # Designation Code System Units SI Units Key MIM-17-4 PH Stainless Steels 10 18 MIM MIM-2200 Low-Alloy Steels 8 16 MIM MIM-2200 Soft-Magnetic Alloys 12 20 MIM MIM-2700 Low-Alloy Steels 8 16 MIM MIM-316L Stainless Steels 10 18 MIM MIM-420 Stainless Steels 10 18 MIM MIM-430L Stainless Steels 10 18 MIM MIM-430L Soft-Magnetic Alloys 12 20 MIM MIM-4605 Low-Alloy Steels 8 16 MIM MIM-F-15 Controlled-Expansion Alloys 14 22 MIM MIM-Fe-3% Si Soft-Magnetic Alloys 12 20 MIM MIM-Fe-50% Co Soft-Magnetic Alloys 12 20 MIM MIM-Fe-50% Ni Soft-Magnetic Alloys 12 20 MIM 25

MPIF Standard 35 Publication KEY MIM s Standards for Metal Injection Molded Parts SLB s Standards for PM Self-Lubricating Bearings PF s Standards for P/F Steel Parts SP s Standards for PM Structural Parts INDEX 2. (35MIM2-20007) Section Designation Code System Key C-0000 Copper and Copper Alloys SP CFTG-3806-K Diluted Bronze Bearings SLB CNZ-1818 Copper and Copper Alloys SP CNZP-1816 Copper and Copper Alloys SP CT-1000 Copper and Copper Alloys SP CT-1000-K Bronze Bearings SLB CTG-1001-K Bronze Bearings SLB CTG-1004-K Bronze Bearings SLB CZ-1000 Copper and Copper Alloys SP CZ-2000 Copper and Copper Alloys SP CZ-3000 Copper and Copper Alloys SP CZP-1002 Copper and Copper Alloys SP CZP-2002 Copper and Copper Alloys SP CZP-3002 Copper and Copper Alloys SP F-0000 Iron and Carbon Steel SP F-0000-K Iron and Iron-Carbon Bearings SLB F-0005 Iron and Carbon Steel SP F-0005-K Iron and Iron-Carbon Bearings SLB F-0008 Iron and Carbon Steel SP F-0008-K Iron and Iron-Carbon Bearings SLB FC-0200 Iron-Copper and Copper Steel SP FC-0200-K Iron-Copper Bearings SLB FC-0205 Iron-Copper and Copper Steel SP FC-0205-K Iron-Copper-Carbon Bearings SLB FC-0208 Iron-Copper and Copper Steel SP FC-0208-K Iron-Copper-Carbon Bearings SLB FC-0505 Iron-Copper and Copper Steel SP FC-0508 Iron-Copper and Copper Steel SP FC-0508-K Iron-Copper-Carbon Bearings SLB FC-0808 Iron-Copper and Copper Steel SP FC-1000 Iron-Copper and Copper Steel SP FC-1000-K Iron-Copper Bearings SLB FC-2000-K Iron-Copper Bearings SLB FC-2008-K Iron-Copper-Carbon Bearings SLB FCTG-3604-K Diluted Bronze Bearings SLB FD-0200 Diffusion-Alloyed Steel SP FD-0205 Diffusion-Alloyed Steel SP FD-0208 Diffusion-Alloyed Steel SP FD-0400 Diffusion-Alloyed Steel SP FD-0405 Diffusion-Alloyed Steel SP 26

INDEX 2. (35MIM2-20007) Section Designation Code System Key FD-0408 Diffusion-Alloyed Steel SP FF-0000 Soft-Magnetic Alloys SP FG-0303-K Iron-Graphite Bearings SLB FG-0308-K Iron-Graphite Bearings SLB FL-4005 Prealloyed Steel SP FL-4205 Prealloyed Steel SP FL-4400 Prealloyed Steel SP FL-4405 Prealloyed Steel SP FL-4605 Prealloyed Steel SP FL-4805 Prealloyed Steel SP FL-48105 Prealloyed Steel SP FL-4905 Prealloyed Steel SP FL-5208 Prealloyed Steel SP FL-5305 Prealloyed Steel SP FLC-4608 Sinter-Hardened Steel SP FLC-4805 Sinter-Hardened Steel SP FLC-48108 Sinter-Hardened Steel SP FLC-4908 Sinter-Hardened Steel SP FLC2-4808 Sinter-Hardened Steel SP FLDN2-4908 Diffusion-Alloyed Steel SP FLDN4C2-4905 Diffusion-Alloyed Steel SP FLN-4205 Hybrid Low-Alloy Steel SP FLN-48108 Sinter-Hardened Steel SP FLN2-4400 Hybrid Low-Alloy Steel SP FLN2-4405 Hybrid Low-Alloy Steel SP FLN2-4408 Sinter-Hardened Steel SP FLN2C-4005 Hybrid Low-Alloy Steel SP FLN4-4400 Hybrid Low-Alloy Steel SP FLN4-4405 Hybrid Low-Alloy Steel SP FLN4-4408 Sinter Hardened Steel SP FLN4C-4005 Hybrid Low-Alloy Steel SP FLN6-4405 Hybrid Low-Alloy Steel SP FLN6-4408 Sinter-Hardened Steel SP FLNC-4405 Hybrid Low-Alloy Steel SP FLNC-4408 Sinter-Hardened Steel SP FN-0200 Iron-Nickel and Nickel Steel SP FN-0205 Iron-Nickel and Nickel Steel SP FN-0208 Iron-Nickel and Nickel Steel SP FN-0405 Iron-Nickel and Nickel Steel SP FN-0408 Iron-Nickel and Nickel Steel SP FN-5000 Soft-Magnetic Alloys SP FS-0300 Soft-Magnetic Alloys SP FX-1000 Copper-Infiltrated Iron and Steel SP FX-1005 Copper-Infiltrated Iron and Steel SP 27

INDEX 2. (35MIM2-20007) Section Designation Code System Key FX-1008 Copper-Infiltrated Iron and Steel SP FX-2000 Copper-Infiltrated Iron and Steel SP FX-2005 Copper-Infiltrated Iron and Steel SP FX-2008 Copper-Infiltrated Iron and Steel SP FY-4500 Soft-Magnetic Alloys SP FY-8000 Soft-Magnetic Alloys SP P/F-1020 Carbon Steel PF P/F-1040 Carbon Steel PF P/F-1060 Carbon Steel PF P/F-10C40 Copper Steel PF P/F-10C50 Copper Steel PF P/F-10C60 Copper Steel PF P/F-1140 Carbon Steel PF P/F-1160 Carbon Steel PF P/F-11C40 Copper Steel PF P/F-11C50 Copper Steel PF P/F-11C60 Copper Steel PF P/F-4220 Low-Alloy P/F-42XX Steel PF P/F-4240 Low-Alloy P/F-42XX Steel PF P/F-4260 Low-Alloy P/F-42XX Steel PF P/F-4620 Low-Alloy P/F-46XX Steel PF P/F-4640 Low-Alloy P/F-46XX Steel PF P/F-4660 Low-Alloy P/F-46XX Steel PF P/F-4680 Low-Alloy P/F-46XX Steel PF SS-303L Stainless Steel - 300 Series Alloy SP SS-303N1 Stainless Steel - 300 Series Alloy SP SS-303N2 Stainless Steel - 300 Series Alloy SP SS-304H Stainless Steel - 300 Series Alloy SP SS-304L Stainless Steel - 300 Series Alloy SP SS-304N1 Stainless Steel - 300 Series Alloy SP SS-304N2 Stainless Steel - 300 Series Alloy SP SS-316H Stainless Steel - 300 Series Alloy SP SS-316L Stainless Steel - 300 Series Alloy SP SS-316N1 Stainless Steel - 300 Series Alloy SP SS-316N2 Stainless Steel - 300 Series Alloy SP SS-409L Stainless Steel - 400 Series Alloy SP SS-409LE Stainless Steel - 400 Series Alloy SP SS-410 Stainless Steel - 400 Series Alloy SP SS-410L Stainless Steel - 400 Series Alloy SP SS-430L Stainless Steel - 400 Series Alloy SP SS-430N2 Stainless Steel - 400 Series Alloy SP SS-434L Stainless Steel - 400 Series Alloy SP SS-434LCb Stainless Steel - 400 Series Alloy SP SS-434N2 Stainless Steel - 400 Series Alloy SP 28

TEAR OUT AND FOLD IN 1/3 AND MAIL LATEST EDITION STANDARDS AVAILABLE FROM MPIF Is Your Company in Compliance? MPIF s Standards: The latest editions of MPIF Standard 35 materials standards are available for purchase in a variety of formats, including printed hard copy, on CDROM and in pdf electronic format. Quantity discounts are available. The following are the materials standards that are immediately available: The MPIF Standard 35 Family of s Standards See INDEX in this standard to view material systems covered in each of the following: For components made by the metal injection molding (MIM) process, see MPIF Standard 35, s Standards for Metal Injection Molded Parts For structural parts made by the PM (powder metallurgy) process, see MPIF Standard 35, s Standards for P/M Structural s For bearings and bushings made by the PM process, see MPIF Standard 35, s Standards for PM Self-Lubricating Bearings For steel components made by the powder forging (PF) process, see MPIF Standard 35, s Standards for P/F Steel Parts Standard Test Methods for Metal Powders and Powder Metallurgy Products Contains over 35 standards covering terminology and recommended methods of test dealing with metal powders, powder metal (PM) and metal injection molded (MIM) parts, metallic filters and powder metallurgy equipment. The standards represent the latest reference source for agreement between producer and end-use customer. Comparable standards are listed, along with sources for specialized equipment cited in the standards. Available for purchase in a variety of formats, including printed hard copy, on CDROM and in pdf electronic format. Quantity discounts are available. Do You Have the Latest Industry Standards? YES! Enter me in the Standing Order Plan for ALL MPIF Standards Hard Copy CDROM PDF Enter me in the MPIF Standing Order Plan for the following standards only (check those that apply) MPIF Std.35, Metal Injection Molded Parts Hard Copy CDROM PDF MPIF Std. 35, PM Structural s Hard Copy CDROM PDF MPIF Std. 35, PM Self-Lubricating Bearings Hard Copy CDROM PDF MPIF Std. 35, PF Steel Parts Hard Copy CDROM PDF MPIF Test Method Standards Hard Copy CDROM PDF Purchase Order # required: Name Company Address City State Country Zip/Postal Code Phone # Fax # E-mail: To order or for more information on the latest powder metallurgy standards or other PM publications, please contact the MPIF Publications Department at: Phone: (609) 945-0009 Standing Order Plan Be Assured of Being in Compliance with the Latest Standards! As soon as any new edition of MPIF standards is published, the previous or any prior editions of that standard become obsolete. Enter MPIF s Standing Order Plan and be assured that your company has the latest edition of materials or test method standards. Standards will be shipped and billed immediately upon publication. Fax: (609) 987-8523 Web site: www.mpif.org E-mail: info@mpif.org MPIF, 105 College Road East Princeton, NJ 08540-6692, USA Visit the Publications section of the MPIF Web site at www.mpif.org or contact the Publications Department by calling 609-945-0009. 29 35MIM-07 This form may be photocopied and mailed with purchase order.

From To: Publications Department Metal Powder Industries Federation 105 College Road East Princeton, NJ 08540-6692 U.S.A. Metal Powder Industries Federation 105 College Road East, Princeton, NJ 08540-6692 U.S.A. 1.5M-3/2007

N E W MATERIALS STANDARD from April 2012 Release The information contained in this free-access document includes a new, standardized material designation code, information and property data. The information represents an addendum to the existing standard, MPIF Standard 35, s Standards for Metal Injection Molded Parts, 2007 Edition the referenced document. This information will be included as a new subsection in the next printed edition of the referenced standard and will remain on the MPIF Web site until that time. Between the publication of editions of the standard, check this site for updates on additional, new standardized materials and property data that may be posted periodically. CONTENTS of NEW STANDARD: Copper Introduction, Chemical Composition & Data Tables (Inch-Pound & SI Units) for New MIM-Cu as-sintered material Both the purchaser and the manufacturer should, in order to avoid possible misconceptions or misunderstandings, agree on the following conditions prior to the manufacture of a MIM part: material selection, chemical composition, minimum property values and any other processes that may affect the part application. MPIF Standard 35 is issued to provide the design and materials engineer with the information necessary for specifying powder metal (PM) materials that have been developed by the PM parts manufacturing industry. The data posted herein deals with products manufactured by the Metal Injection Molding (MIM) process by MIM parts manufacturers. The use of any MPIF Standard is entirely voluntary. MPIF Standards are issued and adopted in the public interest. They are designed to eliminate misunderstandings between the manufacturer and the purchaser and to assist the purchaser in selecting and obtaining the proper material for a particular product. Existence of MPIF Standards does not in any respect preclude any member or non-member of MPIF from manufacturing or selling products that use materials or testing procedures not included in MPIF Standards. Other such materials may be commercially available. By publication of these Standards, no position is taken with respect to the validity of any patent rights nor does MPIF undertake to insure anyone utilizing the Standards against liability for infringement of any Letters Patent or accept any such liability. Neither MPIF nor any of its members assumes or accepts any liability resulting from use or non-use of any MPIF Standard. In addition, MPIF does not accept any liability or responsibility for the compliance of any product with any standard, the achievement of any minimum or typical values by any supplier, or for the results of any testing or other procedure undertaken in accordance with any Standard.

MIM Section MPIF Standard 35 Copper This subsection covers MIM copper. MIM copper is made using commercially pure copper powder. Characteristics MIM copper has the typical color of copper and is commonly used for its excellent thermal and electrical conductivity. Applications Pure copper parts are used in applications requiring excellent thermal or electrical conductivity. Sintered copper parts can be treated like a wrought copper part in the annealed condition and can be machined, plated, brazed, crimped, and staked. Microstructure Copper will sinter to a point where very few original particle boundaries are observable. The un-etched microstructure will exhibit small, uniformly distributed, well-rounded pores that are not interconnected. In the etched condition, the microstructure is homogenous with little to no evidence of oxides or contaminants. Nominal Chemical Composition, % - Copper Designation Cu MIM-Cu 99.8 Minimum 100.0 Maximum Other Elements: 0.2% max, excluding silver Approved: 2012

Copper MIM Properties Inch-Pound Units MINIMUM VALUES TYPICAL VALUES Tensile Properties Designation Thermal Thermal Yield Code Conductivity Conductivity Ultimate Strength Elongation (condition) Density (at 77 F) Density (at 77 F) Strength (0.2%) (in 1 inch) g/cm3 Btu ft/(h ft2 F) g/cm3 Btu ft/(h ft2 F) 103 psi 103 psi % MIM-Cu 8.50 190 8.75 208 30 10 30 (as-sintered) Coefficient of Thermal Expansion The coefficient of thermal expansion was determined for the MIM-Cu in accordance with ASTM E228. A push-rod dilatometer was used for these tests, using a 1.8 F/minute heating rate in air atmosphere. The average coefficient of thermal expansion was determined from room temperature (68 F) up to a series of temperatures. From 68 F Average CTE To: (X 10-6 / F) 100 F 8.7 150 F 8.9 200 F 9.1 250 F 9.3 300 F 9.4 Approved: 2012

Copper MIM Properties SI Units MINIMUM VALUES TYPICAL VALUES Tensile Properties Designation Thermal Thermal Yield Code Conductivity Conductivity Ultimate Strength Elongation (condition) Density (at 25 C) Density (at 25 C) Strength (0.2%) (in 25 mm) g/cm3 W/(m K) g/cm3 W/(m K) MPa MPa % MIM-Cu 8.50 330 8.75 360 207 69 30 (as-sintered) Coefficient of Thermal Expansion The coefficient of thermal expansion was determined for the MIM-Cu in accordance with ASTM E228. A push-rod dilatometer was used for these tests, using a 1 C/minute heating rate in air atmosphere. The average coefficient of thermal expansion was determined from room temperature (20 C) up to a series of temperatures. From 20 C Average CTE To: (X 10-6 / C) 38 C 15.7 66 C 16.0 93 C 16.4 121 C 16.7 149 C 16.9 Approved: 2012

N E W MATERIALS STANDARD from March 2009 Release The information contained in this free-access document includes a new, standardized material designation code, information and property data. The information represents an addendum to the existing standard, MPIF Standard 35, s Standards for Metal Injection Molded Parts, 2007 Edition the referenced document. This information will be included in the next printed edition of the referenced standard and will remain on the MPIF Web site until that time. Between the publication of editions of the standard, check this site for updates on additional, new standardized materials and property data that may be posted periodically. CONTENTS of NEW STANDARD: Low-Alloy Steel Chemical Composition & Data Tables (Inch-Pound & SI Units) for New MIM-4140 quenched and tempered material Both the purchaser and the manufacturer should, in order to avoid possible misconceptions or misunderstandings, agree on the following conditions prior to the manufacture of a MIM part: material selection, chemical composition, minimum property values and any other processes that may affect the part application. MPIF Standard 35 is issued to provide the design and materials engineer with the information necessary for specifying powder metal (PM) materials that have been developed by the PM parts manufacturing industry. The data posted herein deals with products manufactured by the Metal Injection Molding (MIM) process by MIM parts manufacturers. The use of any MPIF Standard is entirely voluntary. MPIF Standards are issued and adopted in the public interest. They are designed to eliminate misunderstandings between the manufacturer and the purchaser and to assist the purchaser in selecting and obtaining the proper material for a particular product. Existence of MPIF Standards does not in any respect preclude any member or non-member of MPIF from manufacturing or selling products that use materials or testing procedures not included in MPIF Standards. Other such materials may be commercially available. By publication of these Standards, no position is taken with respect to the validity of any patent rights nor does MPIF undertake to insure anyone utilizing the Standards against liability for infringement of any Letters Patent or accept any such liability. Neither MPIF nor any of its members assumes or accepts any liability resulting from use or non-use of any MPIF Standard. In addition, MPIF does not accept any liability or responsibility for the compliance of any product with any standard, the achievement of any minimum or typical values by any supplier, or for the results of any testing or other procedure undertaken in accordance with any Standard.

MIM Section MPIF Standard 35 Low-Alloy Steels REFERENCE: MPIF Standard 35, s Standards for Metal Injection Molded Parts 2007 Edition Pages 8 & 16 Chemical Composition, % Low-Alloy Steels Designation Code Fe Ni Mo C Cr Si (max) Mn (max) MIM-4140 Bal. 0.2 0.3 0.3 0.5 0.8 1.2 0.6 1.0 Other Elements: Total may not exceed 1.0% combined. Approved: 2009

Low-Alloy Steels MIM Properties Inch-Pound Units REFERENCE: MPIF Standard 35, s Standards for Metal Injection Molded Parts, 2007 Edition, Low-Alloy Steels Section Page 9 MINIMUM VALUES TYPICAL VALUES Tensile Properties Tensile Properties Elastic Constants Hardness Designation Yield Yield Unnotched Charpy Micro- Code Ultimate Strength Elongation Ultimate Strength Elongation Young s Poisson s Impact Macro indentation Energy (condition) Strength (0.2%) (in 1 inch) Density Strength (0.2%) (in 1 inch) Modulus Ratio (A) (apparent) (converted) 10 3 psi 10 3 psi % g/cm. 10 3 psi 10 3 psi % 10 3 psi ft lbf Rockwell MIM-4140 200 155 3 7.5 240 180 5 29.5 0.28 55 46 HRC N/D (quenched & tempered) NOTES: (A) Impact energy values derived from an un-notched 5 mm x 10 mm cross-section Charpy specimen (see MPIF Standard 59). Approved: 2009 N/D Not determined for the purposes of this standard.

Low-Alloy Steels MIM Properties SI Units REFERENCE: MPIF Standard 35, s Standards for Metal Injection Molded Parts, 2007 Edition, Low-Alloy Steels Section Page 17 MINIMUM VALUES TYPICAL VALUES Tensile Properties Tensile Properties Elastic Constants Hardness Designation Yield Yield Unnotched Charpy Micro- Code Ultimate Strength Elongation Ultimate Strength Elongation Young s Poisson s Impact Macro indentation Energy (condition) Strength (0.2%) (in 25.0 mm) Density Strength (0.2%) (in 25.0 mm) Modulus Ratio (A) (apparent) (converted) MPa MPa % g/cm 3 MPa MPa % GPa J Rockwell MIM-4140 1,380 1,070 3 7.5 1,650 1,240 5 205 0.28 75 46 HRC N/D (quenched & tempered) NOTES: (A) Impact energy values derived from an un-notched 5 mm x 10 mm cross-section Charpy specimen (see MPIF Standard 59). Approved: 2009 N/D Not determined for the purposes of this standard.

MATERIALS STANDARDS AVAILABLE FROM MPIF The latest editions of MPIF materials standards are available for purchase in a variety of formats, including printed hard copy, on CD-ROM and in pdf electronic format. Quantity discounts are available. Visit the Publications section of the MPIF Web site at www.mpif.org or contact the Publications Department by calling 609-945-0009. The following are the materials standards that are immediately available: The MPIF Standard 35 Family of s Standards For components made by the metal injection molding (MIM) process, see MPIF Standard 35, s Standards for Metal Injection Molded Parts For structural parts made by the PM (powder metallurgy) process, see MPIF Standard 35, s Standards for PM Structural s For bearings and bushings made by the PM process, see MPIF Standard 35, s Standards for PM Self-Lubricating Bearings For steel components made by the powder forging (PF) process, see MPIF Standard 35, s Standards for P/F Steel Parts MPIF Standard 35 is Published and Copyrighted by Metal Powder Industries Federation 105 College Road East Princeton, New Jersey 08540-6692 U.S.A. Tel: 609-452-7700 Fax: 609-987-8523 E-mail: info@mpif.org Web site: www.mpif.org