Michigan Tech s Wood to Wheels Initiative. David D. Reed, Ph.D. Vice President for Research



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Michigan Tech s Wood to Wheels Initiative David D. Reed, Ph.D. Vice President for Research

Wood-to-Wheels (W2W) Bioprocessing Sustainable Decisions CO 2 Biomass Development Engines/Vehicles

W2W Mission To create and disseminate knowledge/ technologies related to W2W Woody Biomass Development/Recovery Biochemical/Thermochemical Processing Engine/Vehicle Systems Sustainable Decisions To facilitate the creation and promote the growth of businesses engaged in the W2W value chain

What is W2W? Research initiatives: Address the entire W2W value chain: Forest resources Æ Harvesting/logistics Æ Biochemical Processing Æ Biofueled vehicles Engaging researchers from across entire Michigan Tech campus: Forestry, Engineering, Sciences, Business Educational programs: New multi-disciplinary approach to graduate education Broader issues: professional development, leadership, entrepreneurship, sustainability concepts Impact on undergraduate curricula and courses Technologies that support commercial-scale production

Woody Biomass Development Bio-Processing Wood-to-Wheels Vehicle/Engine Systems Fuels, Fertilizers, Other inputs* Sustainable Decisions Fuel Fuel Acid, Lime, Nutrients, Woody Biomass, Enzymes Fuel Biomass Cultivation Biomass Harvesting Transport of Biomass Ethanol Production Transport of Ethanol Ethanol Use in Vehicular Transport Wastes, Emissions Wastes, Emissions, Erosion Wastes, Emissions Wastes, Emissions Wastes, Emissions Emissions

Biomass Development: Inventory How much gasoline could biofuels replace? The Billion Ton Vision The 1.8 Million Ton Vision Enough biomass is available in the US to replace 30% of current gasoline consumption Energy Crops 464 million dry tons Forest Resources 368 million dry tons Agricultural Residues 534 million dry tons If on average the 315,000 UP residents use 482 gal/yr, this corresponds to: 151.7 mil gal gasoline 182.7 mil gal E85 155.3 mil gal ethanol 1.8 mil dry tons of lignocellulosic biomass Can we recover this much biomass? Prof. Robert Froese School of Forest Resources and Environmental Science

Just forest residues can replace 75% of U.P. gasoline consumption with E85 Biomass Feedstock Biomass Feedstock Supply in the Michigan Upper Peninsula, in dry tons per year and $2005 Potential Supply Currently Available and Unutilized Available at $25/ton Farmgate Price Sawmill and pulp mill residues 1,493,601 Negl. 343,528 Forestry Logging residues 503,243 503,243 65,422 Thinning residues 853,800 853,800 110,994 Forestry Total 2,850,644 1,357,043 519,944 Urban Wood Waste 41,962 41,962 5,455 Dedicated Energy Crops 606,219 Negl. 6,062 Grand Total 3,498,825 1,399,005 531,461 Sources: USDA, DOE, Walsh (2006, unpublished) and MTU Forest Resources and Environmental Science

A successful biofuel industry depends on a reliable and sustainable feedstock supply 200.0 180.0 160.0 140.0 120.0 100.0 US National Biomass Feedstock Supply Curves Logging Residues Other Forest Removals Mill Residues Urban Wood Waste Switchgrass SRWC The lack of credible data on price, location, quality and quantity of biomass creates uncertainty for investors and developers of emerging biorefinery technologies. (Office of the Biomass Program, U.S. Dept. of Energy 2005) 80.0 60.0 40.0 20.0 0.0 0 20 40 60 80 Feedstock Price - Roadside, US $2005 "Feedstock cost and potential supply are very sensitive to tradeoffs among competing land uses and competing resource values, such as wildlife habitat." (De La Torre Ugarte et al. 2006)

Initiatives relating to Woody Biomass: Geographic Information System (GIS) Analysis and Modeling Land use/cover maps Spatial inventory of available woody biomass Optimization and validation of forestry models for biomass and carbon Biotechnology Faster growing trees Optimized woody components for cellulose based enzyme consumption

Forest Functional Genomics & Biotechnology Our Our expertise: expertise: Micropropagation Micropropagation Gene Gene transformation transformation Molecular Molecular bio biocchheemistry mistry Whole-genome microarra Whole-genome microarray y and and metabolite metabolite profiling profiling Research Research areas: areas: Wood Wood formation formation Defen Defenssee & & fitn fitness ess Natural Natural variations variations Carbon Carbon sequestration sequestration Metabolite Profiling & Chemical Fingerprinting Microarray Gene Expression Analysis

Cellulosic Biomass Conversion to Ethanol Pretreatment Enzymatic hydrolysis Sugar fermentation Ethanol recovery Harvesting, storage, size reduction Biomass production Residue utilization Waste treatment

Goals of Bioprocessing Research Increase efficiency and yields: Increase ethanol yields from 70-100 gal / dry ton Decrease processing time from 7 days to 2 days Flexible processes to handle biomass mixtures Optimize use of process energy, water, & nutrients Reduce production costs for ethanol Technological Innovations: Establish pretreatment conditions to maximize sugar yields Engineer more active and selective enzymes Discover / develop better microbial strains

Size Scales for Bioprocessing Facilities Pilot Biorefinery Facility (Economic Feasibility) Forest Biomass Producers Industrial Enzyme Producers Fermentation Microorganism Developers Process Technology Vendors MTU Demo-Scale Facility (Technology Integration) MTU Laboratory Research (Basic Research) Process Data / Reports / Fuel Standards Biofuels to Engine / Auto Manufacturers Knowledge Workforce Patents

Engine/Vehicle Initiatives Prof. Jeff Naber Dept. of Mechanical Engineering

Ethanol as a Fuel Property 1 Gasoline Ethanol Impact of Ethanol Chemical Formula C4 C12 C 2 H 5 OH Oxygenated fuel Composition, Weight % (C, H, O) (86, 14, 0) (52, 13, 35) Slightly lower combustion temp. Lower Heating Value (Btu/gal) 115,000 76,000 Reduced MPG Octane Number (R+M)/2 86-90 100 Reduced knock, Improved efficiency Reid Vapor Pressure (psi) 8-15 2.3 Reduced start-ability Latent Heat of Vaporization (Btu/gal) 150 396 Volume % fuel in Stoich Mixture 2 6.5 Stoich air/fuel (weight) 14.7 9 Laminar Flame Speed (cm/s) 2 27 42 Increased charge cooling, Reduced start-ability Requires increase fuel vaporization & mixing Requires increased fuel vaporization & mixing Increased thermal efficiency, Increased EGR tolerance Ethanol: better SI engine fuel than gasoline from combustion standpoint Significant challenges in fuel preparation for E100 E85 helps but doesn t eliminate the problem. Æ Engine & fuel system should change for ethanol.

Indicated Engine Efficiency (%) 65 60 55 50 45 40 35 30 Potential of Ethanol Current Technology Gasoline Flex-Fuel Vehicles E00 Optimized DI SI Flex Fuel E100 25 6 8 10 12 14 16 18 20 22 Compression Ratio Diesel CV Comb. (fast) CP Comb. (slow) EPA has demonstrated a 20% improvement with E85, high CR and EGR MIT estimates 30% improvement with DI SI Gasoline/Ethanol, turbocharging & downsizing E85/E100 optimized SI engines should be nearly as efficient as diesels Lower engine cost Lower toxic emissions

Technology Solution for Flex- Fuel Hybrids is Required Current flex-fuel vehicles do not meet PZEV standards because of crank-start HC emissions. Hybrid applications amplify the problem because of increased start-stop cycles. Legislation requires hybrids to meet the PZEV standard. Technical solution required for PZEV Flex-Fuel Hybrid Company that develops robust cost effective solution will have market advantage US Emissions Standards * TIER I LEV (1997-03) TIER II LEV (2004 - ) TIER II SULEV (2004 - ) TIER II PZEV (2004 - ) * Standards in g/mi converted to g/km TIER 0 (1981-93) TIER 0 (1994-97)

Commercialization Status of Cellulosic Ethanol 15-20 Pilot Plants Worldwide, Mostly Small Batch Operations 2 Demonstration Plants Opened (Ottawa & Japan) with 2-3 Others to Open Later in 2007 15-20 Commercial Plants Being Built Worldwide Large Range of Feedstocks Proposed - Mostly Agricultural & Forestry Residues Prof. Barry Solomon Department of Social Sciences

State Interest: Regional Economic Effects Largest Cost Items: Capital & Feedstocks Capital Cost for Cellulosic Plants Higher than for Grain Ethanol Employment Needs Modest, Except During Construction Phase Very Few Studies Have Estimated Regional Economic Effects (Most Studies National) High Risk & Uncertainty with Cellulosic Ethanol Plants Owing to Lack of Commercial Experience

Results for one Scenario Assumes: 52 MGY & 20 Yr. Operations Jobs: 1,647 / yr. During Construction Phase Jobs: 526 / yr. During O & M Phase Mostly in Manufacturing, Services, Transportation, Trade Increased Real Disposable Income: Avg. $32 Million / yr Economic Output: $148 Million / yr Gross Regional Product: $65.9 Million / yr

Regional Economic Effect Conclusions: Effects of Commercial Cellulosic Ethanol Plants Increase with Scale of Production Range studied (.26 52 million gallons EtOH/yr) While MI is Behind MN & WI in Grain Ethanol it Can Catch up via Cellulosic Ethanol Industry Will not happen without strategic initiatives of State Government

W2W Summary: Outcomes Contribute to technical workforce with highly-skilled graduates -- balance perspective on research, lifecycle, and business issues. Trees and forests with increased productivity, carbon sequestration, and solar energy efficiency. Integrated bioprocesses, improved microorganisms and enzymes for the production of bio-based fuels. Vehicle systems that are optimized for bio-based fuels.

Displacement of Petroleum via Wood-to-Wheels Existing Technologies Improved Biomass Improved Bioprocessing Improved Engine/Vehicle Biofuel Petroleum The life-cycle and multi-disciplinary nature of W2W will allow us to realize a tremendous reduction in petroleum usage.