APPENDIX L META ENVIRONMENTAL FORENSIC REPORTS N:\11173291.00000\WORD\Auburn RI (Final-June 2008).doc
Environmental Forensic Report NYSEG - Auburn SDG: UR060920 Report To: URS Corporation 77 Goodell Street Suite 5 Buffalo, NY 14203-1243 Report By: D2/P2 (dialkyldibenzothiophenes/dialkylphenanthrenes) 0.14 0.13 0.12 0.11 Figure 1. Double Ratio Plot source 3 source 4 0.10 source 1 source 2 0.09 source 6 spill 8 0.08 source 5 spill 7 0.07 spill 10 11spill 9 0.06 spill 12 Potential source samples include 1 to 6 Spill samples include samples 7 to 12 0.05 0.09 0.11 0.13 0.15 0.17 0.19 0.21 D3/P3 (trialkyldibenzothiophenes/trialkylphenanthrenes) META Environmental, Inc. 49 Clarendon Street Watertown, MA 02472 October 30, 2006 Identifying and allocating sources of pollutants in complex environments. META ENGINEERING & CHEMISTRY Environmental, Inc.
Final Laboratory Report META Environmental, Inc. 49 Clarendon Street Watertown, MA 02472 Phone: 617-923-4662 Fax: 617-923-4610 E-Mail meta@metaenv.com Certification This certifies that this package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed herein. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager and Quality Assurance Officer, as verified by the following signatures. James A. Roush Environmental Scientist, Laboratory Manager October 30, 2006 Date David M. Mauro Senior Scientist, Quality Assurance Officer October 30, 2006 Date UR060920 Report Page 1 10/30/2006
Sample Delivery Group Narrative Project: NYSEG - Auburn URS Corporation 77 Goodell Street Suite 5 Buffalo, NY 14203-1243 Report Contact: Mike Gutmann Dates of Receipt: September 20, 2006 SDG: Sample Summary: META Project Number: UR060920 The sample received for this project is summarized in the attached sample login forms. U03008 Chain of Custody The samples were received in good condition. The internal temperature of the shipment containers were as follows: Sample received: 09/20/06 1.8 C Internal chain of custody procedures were followed after sample receipt. Samples were stored in a locked refrigerator. A sample custody logbook contains the record of sample removal from the secure sample storage area to the sample preparation laboratory. The custody record for the sample extracts is present on the sample extraction logbook page. The disposal of samples and extracts will be authorized one month after the release of this data report. Sample disposal will be documented. UR060920 Report Page 2 10/30/2006
Methods The sediment samples were prepared by solvent extraction (EPA 3570) using dichloromethane (DCM). The extracts were spiked with internal standard and analyzed by GC/FID (EPA 8100M), GC/ECD (EPA 8082M) and GC/MS/SIM (EPA 8270M). Results Sample results are presented in summary forms (CLP Form 1 equivalent) which follow this narrative. Quality Control Analyte Flags The detection limits were determined as the sample equivalent of the lowest linear initial calibration standard. Analytes measured between 50% and 100% of the lowest standard were reported as "estimated" and flagged with the letter "J." Undetected analytes were reported as null and flagged with the letter, "U." Analytes marked with a "B" were detected in the associated blank and should be reviewed for a possible positive bias. Holding Times The samples were extracted within holding times. The samples and extracts were stored at 4 C ± 2 C prior to extraction and analysis. The extracts were analyzed within 40 days of sample preparation. Surrogate Spikes Extraction surrogates were added to all samples prior to extraction. All surrogate compounds were recovered within the 50%-120% acceptable criterion. Blanks No target compounds were detected in the method blank. UR060920 Report Page 3 10/30/2006
Blank Spikes A Blank Spike sample was extracted with the sample batch. All spiked compounds were recovered within criteria (50 120%). Duplicates A duplicate analysis was performed on sample SED-21 (0-1 ). Many relative percent differences (RPDs) were greater than 50%. Interpretation SED-21 (0-1) Sample SED-21 (0-1) contained pyrogenic and petrogenic material (see definitions). The pyrogenic material was indicated by the prominent 3-, 4-, and 5-ring unsubstituted polycyclic aromatic hydrocarbons (PAHs). The concentration of total PAHs was 51 mg/kg. The ratio of fluoranthene to pyrene (1.238; see Table 1) was similar to other sediment samples collected from the site (3). The petrogenic material was present at low relative concentrations. It was indicated by the broad unresolved complex mixture (UCM) late in the chromatogram (Appendix B) and the presence of biomarker compounds (Appendix E). These petrogenic characteristics are consistent with urban background. SED-23 (0-1) This sample is similar to sample SED-21 (0-1). The concentration of total PAHs was 183 mg/kg. SED-26 (0-1) This sample is similar to sample SED-21 (0-1). The concentration of total PAHs was 32.1 mg/kg. Discussion All three sediment samples show very similar characteristics in both the GC/FID fingerprints (Appendix B) and the diagnostic ratios (Table 1). These include a pyrogenic pattern of high molecular weight PAHs and a UCM characteristic of urban background. Also, the diagnostic ratios of the three sediment samples were similar to the sediment sample diagnostic ratios discussed in reference 3 and summarized in Table 2. The PAH patterns of the sediment samples are not the same as those of the NAPL and soil samples collected on the former Clark St MGP site, as discussed in reference 3. UR060920 Report Page 4 10/30/2006
Definitions Pyrogenic substances are complex mixtures of primarily hydrocarbons produced from organic matter subjected to high temperatures but with insufficient oxygen for complete combustion. Pyrogenic materials are produced by fires, internal combustion engines, and furnaces. They also are formed when coke or gas are produced from coal or oil. Coal-tar based products, such as roofing, pavement sealers, waterproofing, pesticides, and some shampoos contain pyrogenic materials. Petrogenic substances include crude oil and crude oil derivatives such as gasoline, heating oil, and asphalt. Pitch is the semi-solid or solid material consisting of high molecular weight hydrocarbons that remain following coal tar distillation. References 1) Mauro, D.M., Chemical Source Attribution at former MGP Sites, EPRI Report 1000728, December 2000. 2) Chemical Fingerprinting of Hydrocarbons, in: Introduction to Environmental Forensics. B.L. Murphy and R.D. Morrison editors, Academic Press, San Diego, CA 2002. 3) Forensic Review of Sediment Data from the Owasco Lake Outlet near the former Clark Street Manufactured Gas Plant, META Environmental, Inc., May 17, 2006. UR060920 Report Page 5 10/30/2006
Table 1. Selected Source and Weathering Ratios Fl/Py D/F C17/Pris C18/Phy Pris/Phy C3D/C3PA C3D/C3PA BF/MP BeP/BaP BaA/C SED-21 (0-1) 1.238 0.623 4.658 2.976 1.854 0.279 0.158 0.670 0.634 0.962 SED-23 (0-1) 1.270 0.441 3.044 2.722 1.889 0.284 0.131 0.863 0.614 0.987 SED-26 (0-1) 1.146 0.941 2.804 3.079 1.474 0.389 0.204 0.528 0.646 0.987 SED-21 (0-1) dup 1.215 0.563 5.368 2.970 1.727 0.397 0.208 0.677 0.724 0.886 Ratios: Fl/Py D/F C17/Pris C18/Phy Pris/Phy C3D/C3PA C2D/C2PA BF/MP BeP/BaP BaA/C fluoranthene/pyrene dibenzofuran/fluorene heptadecane/pristane octadecane/phytane pristane/phytane trialkyldibenzothiophenes/trialkylphenanthrenes/anthracenes dialkyldibenzothiophenes/dialkylphenanthrenes/anthracenes benzofluorenes/methylpyrenes benzo(e)pyrene/benzo(a)pyrene benz(a)anthracene/chrysene Table 2. Summary statistics for selected ratios from Reference 3 Ratio Mean Sediment Samples Soil & NAPL Samples Literature Values Standard Deviation %RSD Mean Standard Deviation %RS D CWG 1 CC, CO, CR 1 Urban Background Soil 2 Fl/Py 1.2 0.091 7.5 0.74 0.013 1.8 0.5 0.9 1 1.17 ± 0.16 1.13 ± 0.18 D/F 0.46 0.11 23 0.13 0.037 29 0.12 0.46 0.39 1.11 NA BeP/BaP 0.61 0.049 8.0 0.54 0.036 6.7 NA NA 1.14 ± 0.51 BF/MP 0.95 0.54 57 0.52 0.17 33 NA NA NA BaA/C 0.96 0.12 12 1.2 0.067 5.5 1.1 ± 0.15 1.2 ± 0.26 0.63 ± 0.23 NA not available 1 Mauro, 2000 2 Mauro et al., 2006 UR060920 Report Page 6 10/30/2006
Figure 1. Selected Diagnostic Ratios D/F v. Fl/Py 1.400 1.200 T202, CC 1.000 Dibenzofuran/Fluorene 0.800 0.600 P066, PB Crude P128, #6 Fuel Oil P013, Gas Oil SED-26 (0-1) T060, CC T049, CO T185, CO T009, CC SED-21 (0-1) T124, CR 0.400 P065, Bunker C P127, #4 Fuel Oil P063, #2 Fuel oil SED-23 (0-1) P126, Diesel 0.200 T165, CWG T140, CWG T004, CWG 0.000 0.000 0.200 0.400 0.600 0.800 1.000 1.200 1.400 1.600 Fluoranthene/Pyrene TXXX/PXXX Reference samples from META s in house archive (the T or P number is the catalog number in META s archive database and identifies the sample and site from which it was collected) CC Coal Carbonization Tar CO Coke Oven Tar CR CWG Creosote Carbureted Water Gas Tar Field Samples UR060920 Report Page 7 10/30/2006
Figure 2. Selected Diagnostic Ratios C3D/C3PA v. C2D/C2PA 1.200 1.000 P065, Bunker C 0.800 P066, PB Crude C2D/C2PA 0.600 0.400 P013, Gas Oil P128, #6 Fuel Oil P127, #4 Fuel Oil T004, CWG SED-26 (0-1) 0.200 P126, Diesel SED-21 (0-1) SED-23 (0-1) T049, CO T124, CR 0.000 T140, CWG T202, CC T185, CO P063, #2 Fuel oil T165, CWG T009, CC T060, CC 0.000 0.500 1.000 1.500 2.000 2.500 C3D/C3PA TXXX/PXXX Reference samples from META s in house archive (the T or P number is the catalog number in META s archive database and identifies the sample and site from which it was collected) CC Coal Carbonization Tar CO Coke Oven Tar CR CWG Creosote Carbureted Water Gas Tar Field Samples UR060920 Report Page 8 10/30/2006
Figure 3. Comparison of SDG UR060920 PAH Ratios to All Site Samples 1.4 1.3 CSSB06080405 CSTT04040407 1.2 CSTT04040404 CSSB08100411 MW-06D-NAPL MW-09D-NAPL SED-17 1.1 SED-15 SED-06 SED-18 SED-14 SED-23 (0-1) BaA/C 1.0 0.9 SED-26 (0-1) SED-12 SED-07 SED-03 SED-16 SED-04 SED-10 SED-08 SED-01 SED-19 SED-21 (0-1) 0.8 SED-02 SED-13 SED-20 SED-05 SED-11 0.7 SED-09 0.6 0.5 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 Fl/Py Orange circles are sediment samples from SDG UR060920; blue diamonds are on-site soil and NAPL samples from the Clark Street former MGP site; green triangles are downstream sediments; pink circles are near-site sediments; and black squares are upstream sediments. Downstream, near-site, and upstream sediments are as defined in reference 3. UR060920 Report Page 9 10/30/2006
Appendix A Chains of Custody
Appendix B GC/FID Fingerprints
50000 46000 42000 38000 34000 30000 26000 GC/FID Fingerprint C092116.D\FID2B SS1 SS2 IS 1 benzene 2 toluene 3 ethylbenzene 4 m/p-xylene 5 styrene 6 o-xylene 7 1,2,4-trimethylbenzene 8 naphthalene 9 2-methylnaphthalene 10 1-methylnaphthalene 11 acenaphthylene 12 acenaphthene 13 dibenzofuran 14 fluorene 15 phenanthrene 16 anthracene 17 fluoranthene 18 pyrene 19 benz(a)anthracene 20 chrysene 21 benzo(b)fluoranthene 22 benzo(k)fluoranthene 23 benzo(a)pyrene 24 indeno(1,2,3-cd)pyrene 25 dibenz(a,h)anthracene 26 benzo(g,h,i)perylene 22000 18000 14000 10000 6000 15,16 17 18 19,20 21,22 23 UR060920.ppt IS 5-a-androstane SS1 2-Fluorobiphenyl SS2 o-terphenyl 8 12 14 2000 0.00 5.00 10.00 15.00 20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00 Time (min.) Field ID: SED-21 (0-1) Laboratory ID: UR060920-01 Method: EPA 8100 mod. META
50000 46000 42000 38000 34000 30000 26000 GC/FID Fingerprint C092118.D\FID2B SS1 SS2 17 IS 1 benzene 2 toluene 3 ethylbenzene 4 m/p-xylene 5 styrene 6 o-xylene 7 1,2,4-trimethylbenzene 8 naphthalene 9 2-methylnaphthalene 10 1-methylnaphthalene 11 acenaphthylene 12 acenaphthene 13 dibenzofuran 14 fluorene 15 phenanthrene 16 anthracene 17 fluoranthene 18 pyrene 19 benz(a)anthracene 20 chrysene 21 benzo(b)fluoranthene 22 benzo(k)fluoranthene 23 benzo(a)pyrene 24 indeno(1,2,3-cd)pyrene 25 dibenz(a,h)anthracene 26 benzo(g,h,i)perylene 22000 18 18000 14000 10000 15,16 19,20 21,22 23 24,25 26 6000 UR060920.ppt IS 5-a-androstane SS1 2-Fluorobiphenyl SS2 o-terphenyl 8 12 14 2000 0.00 5.00 10.00 15.00 20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00 Time (min.) Field ID: SED-23 (0-1) Laboratory ID: UR060920-02 Method: EPA 8100 mod. META
60000 55000 50000 45000 40000 35000 30000 GC/FID Fingerprint C092117.D\FID2B SS1 SS2 IS 1 benzene 2 toluene 3 ethylbenzene 4 m/p-xylene 5 styrene 6 o-xylene 7 1,2,4-trimethylbenzene 8 naphthalene 9 2-methylnaphthalene 10 1-methylnaphthalene 11 acenaphthylene 12 acenaphthene 13 dibenzofuran 14 fluorene 15 phenanthrene 16 anthracene 17 fluoranthene 18 pyrene 19 benz(a)anthracene 20 chrysene 21 benzo(b)fluoranthene 22 benzo(k)fluoranthene 23 benzo(a)pyrene 24 indeno(1,2,3-cd)pyrene 25 dibenz(a,h)anthracene 26 benzo(g,h,i)perylene 25000 20000 15000 10000 5000 17 18 19,20 GO060920.ppt 0.00 5.00 10.00 15.00 20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00 Time (min.) IS 5-a-androstane SS1 2-Fluorobiphenyl SS2 o-terphenyl Field ID: SED-26 (0-1) Laboratory ID: UR060920-03 Method: EPA 8100 mod. META
50000 46000 42000 38000 34000 30000 26000 GC/FID Fingerprint C092105.D\FID2B SS1 SS2 IS 1 benzene 2 toluene 3 ethylbenzene 4 m/p-xylene 5 styrene 6 o-xylene 7 1,2,4-trimethylbenzene 8 naphthalene 9 2-methylnaphthalene 10 1-methylnaphthalene 11 acenaphthylene 12 acenaphthene 13 dibenzofuran 14 fluorene 15 phenanthrene 16 anthracene 17 fluoranthene 18 pyrene 19 benz(a)anthracene 20 chrysene 21 benzo(b)fluoranthene 22 benzo(k)fluoranthene 23 benzo(a)pyrene 24 indeno(1,2,3-cd)pyrene 25 dibenz(a,h)anthracene 26 benzo(g,h,i)perylene 22000 18000 14000 10000 6000 GO060921.ppt 2000 0.00 5.00 10.00 15.00 20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00 IS 5-a-androstane SS1 2-Fluorobiphenyl SS2 o-terphenyl Time (min.) Field ID: Soil Blank Laboratory ID: GO060921-SB Method: EPA 8100 mod. META
Appendix C MAH/PAH Concentrations
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: SED-21 (0-1) Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID UR060920-01 File ID: E092119.D Matrix: Soil Preservation: None Date Sampled: 9/19/2006 Decanted: None Date Received: 9/20/2006 Date Prepared: 9/20/2006 Sample Size (g): 2.20 Date Cleanup: NA Percent Solid: 85% Date Analyzed: 9/22/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments MAH & PAH COMPOUNDS: Benzene 0.066 0.054 0.027 Toluene 0.212 0.054 0.027 Ethylbenzene 0.034 0.011 0.005 m/p-xylenes 0.181 0.011 0.005 Styrene 0.049 0.011 0.005 o-xylene 0.028 0.011 0.005 Isopropylbenzene 0.006 J 0.011 0.005 n-propylbenzene 0.011 0.011 0.005 1,3,5-Trimethylbenzene 0.016 0.011 0.005 1,2,4-Trimethylbenzene 0.035 0.011 0.005 t-butylbenzene U 0.011 0.005 sec-butylbenzene U 0.011 0.005 p-isopropyltoluene 0.017 0.011 0.005 n-butylbenzene 0.014 0.011 0.005 C1 - Benzene 0.147 0.054 0.027 C2 - Benzene 0.124 0.011 0.005 C3 - Benzene 0.060 0.011 0.005 C4 - Benzene 0.054 0.011 0.005 C5 - Benzene 0.040 0.011 0.005 trans-decalin 0.009 J 0.011 0.005 cis-decalin U 0.011 0.005 Naphthalene 0.413 0.011 0.005 2-Methylnaphthalene 0.211 0.011 0.005 1-Methylnaphthalene 0.164 0.011 0.005 C1 - Naphthalene 0.237 0.011 0.005 C2 - Naphthalene 0.293 0.011 0.005 C3- Naphthalene 0.278 0.011 0.005 C4- Naphthalene 0.158 0.011 0.005 Acenaphthylene 0.509 0.011 0.005 Acenaphthene 0.455 0.011 0.005 Dibenzofuran 0.379 0.011 0.005 Fluorene 0.608 0.011 0.005 C1 - Fluorene 0.229 0.011 0.005 C2 - Fluorene 0.278 0.011 0.005 C3 - Fluorene 0.439 0.011 0.005 Phenanthrene 5.78 0.011 0.005 Anthracene 1.69 0.011 0.005 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: SED-21 (0-1) Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID UR060920-01 File ID: E092119.D Matrix: Soil Preservation: None Date Sampled: 9/19/2006 Decanted: None Date Received: 9/20/2006 Date Prepared: 9/20/2006 Sample Size (g): 2.20 Date Cleanup: NA Percent Solid: 85% Date Analyzed: 9/22/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments C1 - Phenanthrene/Anthracene 2.24 0.011 0.005 C2 - Phenanthrene/Anthracene 1.25 0.011 0.005 C3 - Phenanthrene/Anthracene 0.469 0.011 0.005 C4 - Phenanthrene/Anthracene 0.160 0.011 0.005 Dibenzothiophene 0.339 0.011 0.005 C1 - Dibenzothiophene 0.185 0.011 0.005 C2 - Dibenzothiophene 0.197 0.011 0.005 C3 - Dibenzothiophene 0.131 0.011 0.005 C4 - Dibenzothiophene 0.076 0.011 0.005 Benzo(b)naphtho(2,1-d)thiophene 0.512 0.011 0.005 Fluoranthene 9.01 0.011 0.005 Pyrene 7.28 0.011 0.005 C1 - Fluoranthene/Pyrene 3.4 0.011 0.005 C2 - Fluoranthene/Pyrene 1.74 0.011 0.005 C3 - Fluoranthene/Pyrene 0.649 0.011 0.005 Benz[a]anthracene 4.02 0.011 0.005 Chrysene* 4.18 0.011 0.005 C1 - Benz(a)anthracene/Chrysene 1.49 0.011 0.005 C2 - Benz(a)anthracene/Chrysene 0.607 0.011 0.005 C3 - Benz(a)anthracene/Chrysene 0.347 0.011 0.005 C4 - Benz(a)anthracene/Chrysene 0.167 0.011 0.005 Benzo[b]fluoranthene 3.42 0.011 0.005 Benzo[j/k]fluoranthene 3.6 0.011 0.005 Benzo(e)pyrene 2.65 0.011 0.005 Benzo[a]pyrene 4.18 0.011 0.005 Perylene 1.03 0.011 0.005 Indeno[1,2,3-cd]pyrene 2.86 0.011 0.005 Dibenz[a,h]anthracene 0.661 0.011 0.005 Benzo[g,h,i]perylene 2.34 0.011 0.005 Coronene 0.604 0.011 0.005 Retene 0.079 0.011 0.005 Benzo(b/c)fluorenes 0.661 0.011 0.005 2-Methylpyrene 0.428 0.011 0.005 4-Methylpyrene 0.305 0.011 0.005 1-Methylpyrene 0.254 0.011 0.005 Heptadecane 0.354 0.011 0.005 Pristane 0.076 0.011 0.005 Octadecane 0.122 0.011 0.005 Phytane 0.041 0.011 0.005 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: SED-21 (0-1) Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID UR060920-01 File ID: E092119.D Matrix: Soil Preservation: None Date Sampled: 9/19/2006 Decanted: None Date Received: 9/20/2006 Date Prepared: 9/20/2006 Sample Size (g): 2.20 Date Cleanup: NA Percent Solid: 85% Date Analyzed: 9/22/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments 2,6,10-trimethyldodecane 0.018 0.011 0.005 2,6,10-trimethyltridecane 0.035 0.011 0.005 Norpristane 0.028 0.011 0.005 Total PAH (16) 51.0 0.011 0.005 Total PAH (42) 70.4 0.011 0.005 Extraction Surrogate Recoveries (%) Limits Toluene-d8 86 50-120 Phenanthrene-d10 98 50-120 Perylene-d12 104 50-120 NA - Not applicable. B - Analyte detected in the Blank. J - Estimated value; detected between the RL and DL. U - Analyte not detected above DL. D - Analyte reported from a diluted extract. E - Estimate, result detected above calibration range. I - Concentration/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concentration. EDL - Estimated detection limit is 50% of RL. * - Triphenylene is known to coelute with this compound. 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: SED-23 (0-1) Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID UR060920-02 File ID: E092121.D Matrix: Soil Preservation: None Date Sampled: 9/19/2006 Decanted: None Date Received: 9/20/2006 Date Prepared: 9/20/2006 Sample Size (g): 2.17 Date Cleanup: NA Percent Solid: 60% Date Analyzed: 9/22/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments MAH & PAH COMPOUNDS: Benzene 0.222 0.077 0.038 Toluene 0.858 0.077 0.038 Ethylbenzene 0.069 0.015 0.008 m/p-xylenes 1.01 0.015 0.008 Styrene 0.115 0.015 0.008 o-xylene 0.036 0.015 0.008 Isopropylbenzene 0.011 J 0.015 0.008 n-propylbenzene 0.027 0.015 0.008 1,3,5-Trimethylbenzene 0.018 0.015 0.008 1,2,4-Trimethylbenzene 0.046 0.015 0.008 t-butylbenzene U 0.015 0.008 sec-butylbenzene U 0.015 0.008 p-isopropyltoluene 0.077 0.015 0.008 n-butylbenzene 0.051 0.015 0.008 C1 - Benzene 0.585 0.077 0.038 C2 - Benzene 0.567 0.015 0.008 C3 - Benzene 0.106 0.015 0.008 C4 - Benzene 0.133 0.015 0.008 C5 - Benzene 0.079 0.015 0.008 trans-decalin 0.013 J 0.015 0.008 cis-decalin U 0.015 0.008 Naphthalene 0.539 0.015 0.008 2-Methylnaphthalene 0.297 0.015 0.008 1-Methylnaphthalene 0.257 0.015 0.008 C1 - Naphthalene 0.353 0.015 0.008 C2 - Naphthalene 0.713 0.015 0.008 C3- Naphthalene 0.946 0.015 0.008 C4- Naphthalene 0.768 0.015 0.008 Acenaphthylene 0.876 0.015 0.008 Acenaphthene 1.36 0.015 0.008 Dibenzofuran 0.824 0.015 0.008 Fluorene 1.87 0.015 0.008 C1 - Fluorene 0.820 0.015 0.008 C2 - Fluorene 1.18 0.015 0.008 C3 - Fluorene 1.37 0.015 0.008 Phenanthrene 17.1 0.015 0.008 Anthracene 7.31 0.015 0.008 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: SED-23 (0-1) Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID UR060920-02 File ID: E092121.D Matrix: Soil Preservation: None Date Sampled: 9/19/2006 Decanted: None Date Received: 9/20/2006 Date Prepared: 9/20/2006 Sample Size (g): 2.17 Date Cleanup: NA Percent Solid: 60% Date Analyzed: 9/22/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments C1 - Phenanthrene/Anthracene 8.16 0.015 0.008 C2 - Phenanthrene/Anthracene 4.93 0.015 0.008 C3 - Phenanthrene/Anthracene 2.0 0.015 0.008 C4 - Phenanthrene/Anthracene 0.632 0.015 0.008 Dibenzothiophene 0.882 0.015 0.008 C1 - Dibenzothiophene 0.734 0.015 0.008 C2 - Dibenzothiophene 0.644 0.015 0.008 C3 - Dibenzothiophene 0.567 0.015 0.008 C4 - Dibenzothiophene 0.311 0.015 0.008 Benzo(b)naphtho(2,1-d)thiophene 1.9 0.015 0.008 Fluoranthene 33.4 D 0.015 0.008 Pyrene 26.3 D 0.015 0.008 C1 - Fluoranthene/Pyrene 13.8 0.015 0.008 C2 - Fluoranthene/Pyrene 5.84 0.015 0.008 C3 - Fluoranthene/Pyrene 2.46 0.015 0.008 Benz[a]anthracene 15.3 0.015 0.008 Chrysene* 15.5 0.015 0.008 C1 - Benz(a)anthracene/Chrysene 5.48 0.015 0.008 C2 - Benz(a)anthracene/Chrysene 2.31 0.015 0.008 C3 - Benz(a)anthracene/Chrysene 1.33 0.015 0.008 C4 - Benz(a)anthracene/Chrysene 0.683 0.015 0.008 Benzo[b]fluoranthene 12.8 0.015 0.008 Benzo[j/k]fluoranthene 13.1 0.015 0.008 Benzo(e)pyrene 9.64 0.015 0.008 Benzo[a]pyrene 15.7 0.015 0.008 Perylene 4.08 0.015 0.008 Indeno[1,2,3-cd]pyrene 10.5 0.015 0.008 Dibenz[a,h]anthracene 2.59 0.015 0.008 Benzo[g,h,i]perylene 8.42 0.015 0.008 Coronene 2.04 0.015 0.008 Retene 0.324 0.015 0.008 Benzo(b/c)fluorenes 3.2 0.015 0.008 2-Methylpyrene 1.63 0.015 0.008 4-Methylpyrene 1.11 0.015 0.008 1-Methylpyrene 0.968 0.015 0.008 Heptadecane 0.414 0.015 0.008 Pristane 0.136 0.015 0.008 Octadecane 0.196 0.015 0.008 Phytane 0.072 0.015 0.008 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: SED-23 (0-1) Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID UR060920-02 File ID: E092121.D Matrix: Soil Preservation: None Date Sampled: 9/19/2006 Decanted: None Date Received: 9/20/2006 Date Prepared: 9/20/2006 Sample Size (g): 2.17 Date Cleanup: NA Percent Solid: 60% Date Analyzed: 9/22/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments 2,6,10-trimethyldodecane 0.094 0.015 0.008 2,6,10-trimethyltridecane 0.166 0.015 0.008 Norpristane 0.049 0.015 0.008 Total PAH (16) 183 0.015 0.008 Total PAH (42) 254 0.015 0.008 Extraction Surrogate Recoveries (%) Limits Toluene-d8 89 50-120 Phenanthrene-d10 102 50-120 Perylene-d12 112 50-120 NA - Not applicable. B - Analyte detected in the Blank. J - Estimated value; detected between the RL and DL. U - Analyte not detected above DL. D - Analyte reported from a diluted extract. E - Estimate, result detected above calibration range. I - Concentration/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concentration. EDL - Estimated detection limit is 50% of RL. * - Triphenylene is known to coelute with this compound. 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: SED-26 (0-1) Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID UR060920-03 File ID: E092122.D Matrix: Soil Preservation: None Date Sampled: 9/19/2006 Decanted: None Date Received: 9/20/2006 Date Prepared: 9/20/2006 Sample Size (g): 2.23 Date Cleanup: NA Percent Solid: 47% Date Analyzed: 9/22/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments MAH & PAH COMPOUNDS: Benzene 0.350 0.096 0.048 Toluene 0.423 0.096 0.048 Ethylbenzene 0.068 0.019 0.010 m/p-xylenes 1.3 0.019 0.010 Styrene 0.127 0.019 0.010 o-xylene 0.054 0.019 0.010 Isopropylbenzene 0.015 J 0.019 0.010 n-propylbenzene 0.059 0.019 0.010 1,3,5-Trimethylbenzene 0.021 0.019 0.010 1,2,4-Trimethylbenzene 0.065 0.019 0.010 t-butylbenzene U 0.019 0.010 sec-butylbenzene U 0.019 0.010 p-isopropyltoluene 0.041 0.019 0.010 n-butylbenzene 0.101 0.019 0.010 C1 - Benzene 0.287 0.096 0.048 C2 - Benzene 0.722 0.019 0.010 C3 - Benzene 0.128 0.019 0.010 C4 - Benzene 0.139 0.019 0.010 C5 - Benzene 0.091 0.019 0.010 trans-decalin 0.010 J 0.019 0.010 cis-decalin U 0.019 0.010 Naphthalene 0.265 0.019 0.010 2-Methylnaphthalene 0.154 0.019 0.010 1-Methylnaphthalene 0.145 0.019 0.010 C1 - Naphthalene 0.192 0.019 0.010 C2 - Naphthalene 0.330 0.019 0.010 C3- Naphthalene 0.331 0.019 0.010 C4- Naphthalene 0.274 0.019 0.010 Acenaphthylene 0.305 0.019 0.010 Acenaphthene 0.221 0.019 0.010 Dibenzofuran 0.209 0.019 0.010 Fluorene 0.222 0.019 0.010 C1 - Fluorene 0.195 0.019 0.010 C2 - Fluorene 0.498 0.019 0.010 C3 - Fluorene 0.516 0.019 0.010 Phenanthrene 2.21 0.019 0.010 Anthracene 0.626 0.019 0.010 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: SED-26 (0-1) Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID UR060920-03 File ID: E092122.D Matrix: Soil Preservation: None Date Sampled: 9/19/2006 Decanted: None Date Received: 9/20/2006 Date Prepared: 9/20/2006 Sample Size (g): 2.23 Date Cleanup: NA Percent Solid: 47% Date Analyzed: 9/22/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments C1 - Phenanthrene/Anthracene 1.74 0.019 0.010 C2 - Phenanthrene/Anthracene 1.64 0.019 0.010 C3 - Phenanthrene/Anthracene 0.815 0.019 0.010 C4 - Phenanthrene/Anthracene 0.278 0.019 0.010 Dibenzothiophene 0.161 0.019 0.010 C1 - Dibenzothiophene 0.351 0.019 0.010 C2 - Dibenzothiophene 0.334 0.019 0.010 C3 - Dibenzothiophene 0.317 0.019 0.010 C4 - Dibenzothiophene 0.197 0.019 0.010 Benzo(b)naphtho(2,1-d)thiophene 0.361 0.019 0.010 Fluoranthene 5.89 0.019 0.010 Pyrene 5.14 0.019 0.010 C1 - Fluoranthene/Pyrene 3.42 0.019 0.010 C2 - Fluoranthene/Pyrene 2.04 0.019 0.010 C3 - Fluoranthene/Pyrene 0.868 0.019 0.010 Benz[a]anthracene 2.96 0.019 0.010 Chrysene* 3.0 0.019 0.010 C1 - Benz(a)anthracene/Chrysene 1.59 0.019 0.010 C2 - Benz(a)anthracene/Chrysene 0.910 0.019 0.010 C3 - Benz(a)anthracene/Chrysene 0.585 0.019 0.010 C4 - Benz(a)anthracene/Chrysene 0.352 0.019 0.010 Benzo[b]fluoranthene 2.3 0.019 0.010 Benzo[j/k]fluoranthene 2.46 0.019 0.010 Benzo(e)pyrene 1.84 0.019 0.010 Benzo[a]pyrene 2.85 0.019 0.010 Perylene 0.673 0.019 0.010 Indeno[1,2,3-cd]pyrene 1.79 0.019 0.010 Dibenz[a,h]anthracene 0.459 0.019 0.010 Benzo[g,h,i]perylene 1.44 0.019 0.010 Coronene 0.350 0.019 0.010 Retene 0.058 0.019 0.010 Benzo(b/c)fluorenes 0.594 0.019 0.010 2-Methylpyrene 0.460 0.019 0.010 4-Methylpyrene 0.370 0.019 0.010 1-Methylpyrene 0.295 0.019 0.010 Heptadecane 0.314 0.019 0.010 Pristane 0.112 0.019 0.010 Octadecane 0.234 0.019 0.010 Phytane 0.076 0.019 0.010 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: SED-26 (0-1) Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID UR060920-03 File ID: E092122.D Matrix: Soil Preservation: None Date Sampled: 9/19/2006 Decanted: None Date Received: 9/20/2006 Date Prepared: 9/20/2006 Sample Size (g): 2.23 Date Cleanup: NA Percent Solid: 47% Date Analyzed: 9/22/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments 2,6,10-trimethyldodecane 0.050 0.019 0.010 2,6,10-trimethyltridecane 0.097 0.019 0.010 Norpristane 0.051 0.019 0.010 Total PAH (16) 32.1 0.019 0.010 Total PAH (42) 52.8 0.019 0.010 Extraction Surrogate Recoveries (%) Limits Toluene-d8 89 50-120 Phenanthrene-d10 105 50-120 Perylene-d12 109 50-120 NA - Not applicable. B - Analyte detected in the Blank. J - Estimated value; detected between the RL and DL. U - Analyte not detected above DL. D - Analyte reported from a diluted extract. E - Estimate, result detected above calibration range. I - Concentration/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concentration. EDL - Estimated detection limit is 50% of RL. * - Triphenylene is known to coelute with this compound. 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: Soil Blank Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID GO060920-SB File ID: E092105.D Matrix: Soil Preservation: None Date Sampled: NA Decanted: None Date Received: NA Date Prepared: 9/20/2006 Sample Size (g): 2.00 Date Cleanup: NA Percent Solid: 100% Date Analyzed: 9/21/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments MAH & PAH COMPOUNDS: Benzene U 0.050 0.025 Toluene U 0.050 0.025 Ethylbenzene U 0.010 0.005 m/p-xylenes U 0.010 0.005 Styrene U 0.010 0.005 o-xylene U 0.010 0.005 Isopropylbenzene U 0.010 0.005 n-propylbenzene U 0.010 0.005 1,3,5-Trimethylbenzene U 0.010 0.005 1,2,4-Trimethylbenzene U 0.010 0.005 t-butylbenzene U 0.010 0.005 sec-butylbenzene U 0.010 0.005 p-isopropyltoluene U 0.010 0.005 n-butylbenzene U 0.010 0.005 C1 - Benzene U 0.050 0.025 C2 - Benzene U 0.010 0.005 C3 - Benzene U 0.010 0.005 C4 - Benzene U 0.010 0.005 C5 - Benzene U 0.010 0.005 trans-decalin U 0.010 0.005 cis-decalin U 0.010 0.005 Naphthalene U 0.010 0.005 2-Methylnaphthalene U 0.010 0.005 1-Methylnaphthalene U 0.010 0.005 C1 - Naphthalene U 0.010 0.005 C2 - Naphthalene U 0.010 0.005 C3- Naphthalene U 0.010 0.005 C4- Naphthalene U 0.010 0.005 Acenaphthylene U 0.010 0.005 Acenaphthene U 0.010 0.005 Dibenzofuran U 0.010 0.005 Fluorene U 0.010 0.005 C1 - Fluorene U 0.010 0.005 C2 - Fluorene U 0.010 0.005 C3 - Fluorene U 0.010 0.005 Phenanthrene U 0.010 0.005 Anthracene U 0.010 0.005 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: Soil Blank Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID GO060920-SB File ID: E092105.D Matrix: Soil Preservation: None Date Sampled: NA Decanted: None Date Received: NA Date Prepared: 9/20/2006 Sample Size (g): 2.00 Date Cleanup: NA Percent Solid: 100% Date Analyzed: 9/21/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments C1 - Phenanthrene/Anthracene U 0.010 0.005 C2 - Phenanthrene/Anthracene U 0.010 0.005 C3 - Phenanthrene/Anthracene U 0.010 0.005 C4 - Phenanthrene/Anthracene U 0.010 0.005 Dibenzothiophene U 0.010 0.005 C1 - Dibenzothiophene U 0.010 0.005 C2 - Dibenzothiophene U 0.010 0.005 C3 - Dibenzothiophene U 0.010 0.005 C4 - Dibenzothiophene U 0.010 0.005 Benzo(b)naphtho(2,1-d)thiophene U 0.010 0.005 Fluoranthene U 0.010 0.005 Pyrene U 0.010 0.005 C1 - Fluoranthene/Pyrene U 0.010 0.005 C2 - Fluoranthene/Pyrene U 0.010 0.005 C3 - Fluoranthene/Pyrene U 0.010 0.005 Benz[a]anthracene U 0.010 0.005 Chrysene* U 0.010 0.005 C1 - Benz(a)anthracene/Chrysene U 0.010 0.005 C2 - Benz(a)anthracene/Chrysene U 0.010 0.005 C3 - Benz(a)anthracene/Chrysene U 0.010 0.005 C4 - Benz(a)anthracene/Chrysene U 0.010 0.005 Benzo[b]fluoranthene U 0.010 0.005 Benzo[j/k]fluoranthene U 0.010 0.005 Benzo(e)pyrene U 0.010 0.005 Benzo[a]pyrene U 0.010 0.005 Perylene U 0.010 0.005 Indeno[1,2,3-cd]pyrene U 0.010 0.005 Dibenz[a,h]anthracene U 0.010 0.005 Benzo[g,h,i]perylene U 0.010 0.005 Coronene U 0.010 0.005 Retene U 0.010 0.005 Benzo(b/c)fluorenes U 0.010 0.005 2-Methylpyrene U 0.010 0.005 4-Methylpyrene U 0.010 0.005 1-Methylpyrene U 0.010 0.005 Heptadecane U 0.010 0.005 Pristane U 0.010 0.005 Octadecane U 0.010 0.005 Phytane U 0.010 0.005 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: Soil Blank Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID GO060920-SB File ID: E092105.D Matrix: Soil Preservation: None Date Sampled: NA Decanted: None Date Received: NA Date Prepared: 9/20/2006 Sample Size (g): 2.00 Date Cleanup: NA Percent Solid: 100% Date Analyzed: 9/21/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments 2,6,10-trimethyldodecane U 0.010 0.005 2,6,10-trimethyltridecane U 0.010 0.005 Norpristane U 0.010 0.005 Total PAH (16) U 0.010 0.005 Total PAH (42) U 0.010 0.005 Extraction Surrogate Recoveries (%) Limits Toluene-d8 89 50-120 Phenanthrene-d10 93 50-120 Perylene-d12 75 50-120 NA - Not applicable. B - Analyte detected in the Blank. J - Estimated value; detected between the RL and DL. U - Analyte not detected above DL. D - Analyte reported from a diluted extract. E - Estimate, result detected above calibration range. I - Concentration/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concentration. EDL - Estimated detection limit is 50% of RL. * - Triphenylene is known to coelute with this compound. 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: Soil Blank Spike Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID GO060920-SBS File ID: E092106.D Matrix: Soil Preservation: None Date Sampled: NA Decanted: None Date Received: NA Date Prepared: 9/20/2006 Sample Size (g): 2.00 Date Cleanup: NA Percent Solid: 100% Date Analyzed: 9/21/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments MAH & PAH COMPOUNDS: Spike Amount % Recovery Benzene 1.00 0.795 0.050 0.025 80 % Toluene 1.00 0.837 0.050 0.025 84 % Ethylbenzene 1.00 0.864 0.010 0.005 86 % m/p-xylenes 1.00 0.833 0.010 0.005 83 % Styrene 1.00 0.800 0.010 0.005 80 % o-xylene 1.00 0.861 0.010 0.005 86 % Isopropylbenzene 1.00 0.818 0.010 0.005 82 % n-propylbenzene 1.00 0.861 0.010 0.005 86 % 1,3,5-Trimethylbenzene 1.00 0.852 0.010 0.005 85 % 1,2,4-Trimethylbenzene 1.00 0.834 0.010 0.005 83 % t-butylbenzene U 0.010 0.005 sec-butylbenzene 1.00 0.875 0.010 0.005 88 % p-isopropyltoluene 1.00 0.829 0.010 0.005 83 % n-butylbenzene 1.00 0.863 0.010 0.005 86 % C1 - Benzene U 0.050 0.025 C2 - Benzene U 0.010 0.005 C3 - Benzene U 0.010 0.005 C4 - Benzene U 0.010 0.005 C5 - Benzene U 0.010 0.005 trans-decalin U 0.010 0.005 cis-decalin U 0.010 0.005 Naphthalene 1.00 0.880 0.010 0.005 88 % 2-Methylnaphthalene 1.00 0.878 0.010 0.005 88 % 1-Methylnaphthalene 1.00 0.887 0.010 0.005 89 % C1 - Naphthalene U 0.010 0.005 C2 - Naphthalene U 0.010 0.005 C3- Naphthalene U 0.010 0.005 C4- Naphthalene U 0.010 0.005 Acenaphthylene 1.00 0.841 0.010 0.005 84 % Acenaphthene 1.00 0.892 0.010 0.005 89 % Dibenzofuran 1.00 0.927 0.010 0.005 93 % Fluorene 1.00 0.918 0.010 0.005 92 % C1 - Fluorene U 0.010 0.005 C2 - Fluorene U 0.010 0.005 C3 - Fluorene U 0.010 0.005 Phenanthrene 1.00 0.911 0.010 0.005 91 % Anthracene 1.00 0.888 0.010 0.005 89 % 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: Soil Blank Spike Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID GO060920-SBS File ID: E092106.D Matrix: Soil Preservation: None Date Sampled: NA Decanted: None Date Received: NA Date Prepared: 9/20/2006 Sample Size (g): 2.00 Date Cleanup: NA Percent Solid: 100% Date Analyzed: 9/21/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments C1 - Phenanthrene/Anthracene U 0.010 0.005 C2 - Phenanthrene/Anthracene U 0.010 0.005 C3 - Phenanthrene/Anthracene U 0.010 0.005 C4 - Phenanthrene/Anthracene U 0.010 0.005 Dibenzothiophene 1.00 0.909 0.010 0.005 91 % C1 - Dibenzothiophene U 0.010 0.005 C2 - Dibenzothiophene U 0.010 0.005 C3 - Dibenzothiophene U 0.010 0.005 C4 - Dibenzothiophene U 0.010 0.005 Benzo(b)naphtho(2,1-d)thiophene U 0.010 0.005 Fluoranthene 1.00 0.920 0.010 0.005 92 % Pyrene 1.00 0.884 0.010 0.005 88 % C1 - Fluoranthene/Pyrene U 0.010 0.005 C2 - Fluoranthene/Pyrene U 0.010 0.005 C3 - Fluoranthene/Pyrene U 0.010 0.005 Benz[a]anthracene 1.00 0.781 0.010 0.005 78 % Chrysene* 1.00 0.862 0.010 0.005 86 % C1 - Benz(a)anthracene/Chrysene U 0.010 0.005 C2 - Benz(a)anthracene/Chrysene U 0.010 0.005 C3 - Benz(a)anthracene/Chrysene U 0.010 0.005 C4 - Benz(a)anthracene/Chrysene U 0.010 0.005 Benzo[b]fluoranthene 1.00 0.776 0.010 0.005 78 % Benzo[j/k]fluoranthene 1.00 0.818 0.010 0.005 82 % Benzo(e)pyrene 1.00 0.789 0.010 0.005 79 % Benzo[a]pyrene 1.00 0.720 0.010 0.005 72 % Perylene U 0.010 0.005 Indeno[1,2,3-cd]pyrene 1.00 0.767 0.010 0.005 77 % Dibenz[a,h]anthracene 1.00 0.802 0.010 0.005 80 % Benzo[g,h,i]perylene 1.00 0.766 0.010 0.005 77 % Coronene U 0.010 0.005 Retene U 0.010 0.005 Benzo(b/c)fluorenes U 0.010 0.005 2-Methylpyrene U 0.010 0.005 4-Methylpyrene U 0.010 0.005 1-Methylpyrene U 0.010 0.005 Heptadecane U 0.010 0.005 Pristane U 0.010 0.005 Octadecane U 0.010 0.005 Phytane U 0.010 0.005 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: Soil Blank Spike Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID GO060920-SBS File ID: E092106.D Matrix: Soil Preservation: None Date Sampled: NA Decanted: None Date Received: NA Date Prepared: 9/20/2006 Sample Size (g): 2.00 Date Cleanup: NA Percent Solid: 100% Date Analyzed: 9/21/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments 2,6,10-trimethyldodecane U 0.010 0.005 2,6,10-trimethyltridecane U 0.010 0.005 Norpristane U 0.010 0.005 Extraction Surrogate Recoveries (%) Limits Toluene-d8 84 50-120 Phenanthrene-d10 88 50-120 Perylene-d12 71 50-120 NA - Not applicable. B - Analyte detected in the Blank. J - Estimated value; detected between the RL and DL. U - Analyte not detected above DL. D - Analyte reported from a diluted extract. E - Estimate, result detected above calibration range. I - Concentration/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concentration. EDL - Estimated detection limit is 50% of RL. * - Triphenylene is known to coelute with this compound. 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: Duplicate of SED-21 (0-1) Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID UR060920-01DUP File ID: E092120.D Matrix: Soil Preservation: None Date Sampled: 9/19/2006 Decanted: None Date Received: 9/20/2006 Date Prepared: 9/20/2006 Sample Size (g): 2.05 Date Cleanup: NA Percent Solid: 85% Date Analyzed: 9/22/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments MAH & PAH COMPOUNDS: RPD Benzene 0.073 0.058 0.029 10.1 Toluene 0.433 0.058 0.029 68.5 Ethylbenzene 0.046 0.012 0.006 30 m/p-xylenes 0.146 0.012 0.006 21.4 Styrene 0.127 0.012 0.006 88.6 o-xylene 0.027 0.012 0.006 3.6 Isopropylbenzene 0.009 J 0.012 0.006 40 n-propylbenzene 0.011 J 0.012 0.006 0 1,3,5-Trimethylbenzene 0.011 J 0.012 0.006 37 1,2,4-Trimethylbenzene 0.024 0.012 0.006 37.3 t-butylbenzene U 0.012 0.006 NA sec-butylbenzene U 0.012 0.006 NA p-isopropyltoluene 0.019 0.012 0.006 11.1 n-butylbenzene 0.013 0.012 0.006 7.4 C1 - Benzene 0.294 0.058 0.029 66.7 C2 - Benzene 0.110 0.012 0.006 12 C3 - Benzene 0.048 0.012 0.006 22.2 C4 - Benzene 0.045 0.012 0.006 18.2 C5 - Benzene 0.030 0.012 0.006 28.6 trans-decalin U 0.012 0.006 NA cis-decalin U 0.012 0.006 NA Naphthalene 0.241 0.012 0.006 52.6 2-Methylnaphthalene 0.116 0.012 0.006 58.1 1-Methylnaphthalene 0.103 0.012 0.006 45.7 C1 - Naphthalene 0.141 0.012 0.006 50.8 C2 - Naphthalene 0.219 0.012 0.006 28.9 C3- Naphthalene 0.206 0.012 0.006 29.8 C4- Naphthalene 0.110 0.012 0.006 35.8 Acenaphthylene 0.226 0.012 0.006 77 Acenaphthene 0.246 0.012 0.006 59.6 Dibenzofuran 0.220 0.012 0.006 53.1 Fluorene 0.391 0.012 0.006 43.4 C1 - Fluorene 0.139 0.012 0.006 48.9 C2 - Fluorene 0.135 0.012 0.006 69.2 C3 - Fluorene 0.069 0.012 0.006 145.7 Phenanthrene 2.45 0.012 0.006 80.9 Anthracene 0.703 0.012 0.006 82.5 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: Duplicate of SED-21 (0-1) Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID UR060920-01DUP File ID: E092120.D Matrix: Soil Preservation: None Date Sampled: 9/19/2006 Decanted: None Date Received: 9/20/2006 Date Prepared: 9/20/2006 Sample Size (g): 2.05 Date Cleanup: NA Percent Solid: 85% Date Analyzed: 9/22/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments C1 - Phenanthrene/Anthracene 0.823 0.012 0.006 92.5 C2 - Phenanthrene/Anthracene 0.514 0.012 0.006 83.4 C3 - Phenanthrene/Anthracene 0.189 0.012 0.006 85.1 C4 - Phenanthrene/Anthracene 0.072 0.012 0.006 75.9 Dibenzothiophene 0.156 0.012 0.006 73.9 C1 - Dibenzothiophene 0.086 0.012 0.006 73.1 C2 - Dibenzothiophene 0.107 0.012 0.006 59.2 C3 - Dibenzothiophene 0.075 0.012 0.006 54.4 C4 - Dibenzothiophene 0.041 0.012 0.006 59.8 Benzo(b)naphtho(2,1-d)thiophene 0.223 0.012 0.006 78.6 Fluoranthene 3.67 0.012 0.006 84.2 Pyrene 3.02 0.012 0.006 82.7 C1 - Fluoranthene/Pyrene 1.37 0.012 0.006 85.1 C2 - Fluoranthene/Pyrene 0.651 0.012 0.006 91.1 C3 - Fluoranthene/Pyrene 0.250 0.012 0.006 88.8 Benz[a]anthracene 1.64 0.012 0.006 84.1 Chrysene* 1.85 0.012 0.006 77.3 C1 - Benz(a)anthracene/Chrysene 0.606 0.012 0.006 84.4 C2 - Benz(a)anthracene/Chrysene 0.257 0.012 0.006 81 C3 - Benz(a)anthracene/Chrysene 0.152 0.012 0.006 78.2 C4 - Benz(a)anthracene/Chrysene 0.081 0.012 0.006 69.4 Benzo[b]fluoranthene 1.68 0.012 0.006 68.2 Benzo[j/k]fluoranthene 1.66 0.012 0.006 73.8 Benzo(e)pyrene 1.34 0.012 0.006 65.7 Benzo[a]pyrene 1.85 0.012 0.006 77.3 Perylene 0.446 0.012 0.006 79.1 Indeno[1,2,3-cd]pyrene 1.36 0.012 0.006 71.1 Dibenz[a,h]anthracene 0.314 0.012 0.006 71.2 Benzo[g,h,i]perylene 1.16 0.012 0.006 67.4 Coronene 0.312 0.012 0.006 63.8 Retene 0.050 0.012 0.006 45 Benzo(b/c)fluorenes 0.272 0.012 0.006 83.4 2-Methylpyrene 0.168 0.012 0.006 87.2 4-Methylpyrene 0.130 0.012 0.006 80.5 1-Methylpyrene 0.104 0.012 0.006 83.8 Heptadecane 0.306 0.012 0.006 14.5 Pristane 0.057 0.012 0.006 28.6 Octadecane 0.098 0.012 0.006 21.8 Phytane 0.033 0.012 0.006 21.6 10/18/2006 UR060920.xls
Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc. Field ID: Duplicate of SED-21 (0-1) Client: URS Corporation Preparation Method: EPA 3570 Project: NYSEG Auburn Cleanup Method(s): NA Analysis Method: EPA 8270M Lab ID UR060920-01DUP File ID: E092120.D Matrix: Soil Preservation: None Date Sampled: 9/19/2006 Decanted: None Date Received: 9/20/2006 Date Prepared: 9/20/2006 Sample Size (g): 2.05 Date Cleanup: NA Percent Solid: 85% Date Analyzed: 9/22/2006 Extract Volume (µl): 2000 Instrument: El Camino Prep DF: 1.00 Operator: JAR Analysis DF: 1.00 Injection Volume (µl): 1.00 Batch QC: GO060920-SB Analyte Concentration (mg/kg dry wt.) RL EDL Comments 2,6,10-trimethyldodecane 0.014 0.012 0.006 25 2,6,10-trimethyltridecane 0.026 0.012 0.006 29.5 Norpristane 0.023 0.012 0.006 19.6 Total PAH (16) 22.5 0.012 0.006 77.6 Total PAH (42) 30.9 0.012 0.006 78 Extraction Surrogate Recoveries (%) Limits Toluene-d8 81 50-120 Phenanthrene-d10 90 50-120 Perylene-d12 93 50-120 NA - Not applicable. B - Analyte detected in the Blank. J - Estimated value; detected between the RL and DL. U - Analyte not detected above DL. D - Analyte reported from a diluted extract. E - Estimate, result detected above calibration range. I - Concentration/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concentration. EDL - Estimated detection limit is 50% of RL. * - Triphenylene is known to coelute with this compound. 10/18/2006 UR060920.xls
Appendix D Extended MAH/PAH Profiles Histograms
n-butylbenzene C1 - Benzene C2 - Benzene C3 - Benzene C4 - Benzene C5 - Benzene trans-decalin cis-decalin Fluoranthene Pyrene Chrysene* Benzo[b]fluoranthene Benzo[j/k]fluoranthene Benzo(e)pyrene Benzo[a]pyrene Perylene Indeno[1,2,3-cd]pyrene Dibenz[a,h]anthracene Benzo[g,h,i]perylene Coronene C3 - Benz(a)anthracene/Chrysene C4 - Benz(a)anthracene/Chrysene C1 - Benz(a)anthracene/Chrysene C2 - Benz(a)anthracene/Chrysene C2 - Fluoranthene/Pyrene C3 - Fluoranthene/Pyrene Benz[a]anthracene C1 - Fluoranthene/Pyrene Benzo(b)naphtho(2,1-d)thiophene C4 - Dibenzothiophene C2 - Dibenzothiophene C3 - Dibenzothiophene Dibenzothiophene C1 - Dibenzothiophene C3 - Phenanthrene/Anthracene C4 - Phenanthrene/Anthracene C1 - Phenanthrene/Anthracene C2 - Phenanthrene/Anthracene 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.000 SED-21 (0-1) UR060920-01 C2 - Naphthalene C3- Naphthalene C4- Naphthalene Acenaphthylene Acenaphthene Dibenzofuran Fluorene C1 - Fluorene C2 - Fluorene C3 - Fluorene Phenanthrene Anthracene 1-Methylnaphthalene C1 - Naphthalene Naphthalene 2-Methylnaphthalene sec-butylbenzene p-isopropyltoluene 1,2,4-Trimethylbenzene t-butylbenzene Isopropylbenzene n-propylbenzene 1,3,5-Trimethylbenzene Styrene o-xylene Ethylbenzene m/p-xylenes Benzene Toluene Concentration (mg/kg dry wt.)
n-butylbenzene C1 - Benzene C2 - Benzene C3 - Benzene C4 - Benzene C5 - Benzene trans-decalin cis-decalin Fluoranthene Pyrene Chrysene* Benzo[b]fluoranthene Benzo[j/k]fluoranthene Benzo(e)pyrene Benzo[a]pyrene Perylene Indeno[1,2,3-cd]pyrene Dibenz[a,h]anthracene Benzo[g,h,i]perylene Coronene C1 - Benz(a)anthracene/Chrysene C2 - Benz(a)anthracene/Chrysene C3 - Benz(a)anthracene/Chrysene C4 - Benz(a)anthracene/Chrysene C1 - Fluoranthene/Pyrene C2 - Fluoranthene/Pyrene C3 - Fluoranthene/Pyrene Benz[a]anthracene Benzo(b)naphtho(2,1-d)thiophene C4 - Dibenzothiophene C2 - Dibenzothiophene C3 - Dibenzothiophene Dibenzothiophene C1 - Dibenzothiophene C3 - Phenanthrene/Anthracene C4 - Phenanthrene/Anthracene C1 - Phenanthrene/Anthracene C2 - Phenanthrene/Anthracene 40.0 35.0 30.0 25.0 20.0 15.0 10.0 5.0 0.000 SED-23 (0-1) UR060920-02 C2 - Naphthalene C3- Naphthalene C4- Naphthalene Acenaphthylene Acenaphthene Dibenzofuran Fluorene C1 - Fluorene C2 - Fluorene C3 - Fluorene Phenanthrene Anthracene 1-Methylnaphthalene C1 - Naphthalene Naphthalene 2-Methylnaphthalene sec-butylbenzene p-isopropyltoluene 1,2,4-Trimethylbenzene t-butylbenzene Styrene o-xylene Isopropylbenzene n-propylbenzene 1,3,5-Trimethylbenzene Benzene Toluene Ethylbenzene m/p-xylenes Concentration (mg/kg dry wt.)