Unison Solutions, Inc. Biogas Quality and Conditioning
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1 Unison Solutions, Inc. Biogas Quality and Conditioning CHP Operators Workshop University of Iowa November 6, 2014
2 Unison Solutions, Inc. Overview Company founded on January 1, 2000 Located in Dubuque, Iowa 40 Employees (10 Engineers) 45,000 sq. ft. Manufacturing Facility 205 systems sold worldwide, 170+ in Operation Biogas Conditioning System Design and Fabrication Custom System Design and Fabrication
3 Unison Solutions, Inc. Overview
4 Biogas Conditioning Systems What is driving the need for increased gas treatment on biogas fueled generation and direct use projects? Equipment Damage & Performance Issues
5 Getting Started on a Biogas to Energy Project
6 System Design Checklist Site Conditions Inlet Gas Conditions (gas testing) Discharge Gas Conditions End-use Technology
7 Gas Quality Limits To Need Treatment Equipment H2S Siloxanes MicroTurbine <5,000 ppmv <100 ppbv IC Engine < ppmv <100-1,000 ppbv Boiler < ppmv <500-2,000 ppbv Vehicle Fuel Non-Detect <100 ppbv
8 Hydrogen Sulfide Removal Systems Digester or Landfill Hydrogen Sulfide Removal Gas Compression/ Moisture Removal Siloxane/VOC Removal MicroTurbines IC Engines Boilers
9 Hydrogen Sulfide Removal Systems Why Hydrogen Sulfide Removal? Equipment Damage from Corrosion (Hydrosulfuric Acid) SOx Emissions Health and Safety Issues (1000ppm will cause an individual to lose consciousness) Odor Control Causes fouling of Siloxane Removal Media
10 Hydrogen Sulfide Removal Systems Technologies SulfaTreat Systems Iron Sponge Systems Biological/Iron Sponge Systems Biological Systems
11 Hydrogen Sulfide Removal Systems SulfaTreat/Iron Sponge Process Biogas containing Hydrogen sulfide (H 2 S) Media: Sulfatreat or Iron Sponge Water to Drain Biogas free of Hydrogen Sulfide (H 2 S)
12 Hydrogen Sulfide Removal Systems Biological/Iron Sponge Systems Features Hydrated iron oxide on a wood shavings and chips carrier. Water is re-circulated through the system. Oxygen is injected into the system.
13 Hydrogen Sulfide Removal Systems Biological Systems Typically used on applications with high H 2 S levels
14 Gas Blower and Compressor Systems Skid Mounted Equipment Digester or Landfill Hydrogen Sulfide Removal Gas Compression/ Moisture Removal Siloxane/VOC Removal MicroTurbines IC Engines Boilers
15 Gas Blower Systems Generation Supported Internal Combustion Engines Caterpillar GE Jenbacher GE Waukesha Cummins MWM Liebherr MAN Tech 3 Direct Use Boiler Fuel Cells
16 Gas Blower Systems Major Components Gas Blower Inlet Moisture/ Particulate Filter Rotary Lobe Positive Displacement Blower OR Multistage Centrifugal Blower Forced Air To Gas Heat Exchanger (Optional) Dual Core Heat Exchanger Glycol Chiller
17 Gas Blower Systems Skid Mounted Equipment Rotary Lobe Positive Displacement Blower System Multistage Centrifugal Blower System
18 Gas Compressor Systems Generation Supported Turbines Capstone Solar Direct Use Boiler Direct Use Pipeline Fuel Cells
19 Gas Compressor Systems Major Components Pre-Cooler Gas Compressor Inlet Moisture/ Particulate Filter Oil/Gas Separator Gas To Gas Heat Exchanger Oil Flooded Twin Screw Compressor Gas To Glycol Heat Exchanger Glycol Chiller Moisture Separator
20 Gas Compressor Systems Skid Mounted Equipment Oil Flooded Twin Screw Compressor System
21 Siloxane Removal Systems Digester or Landfill Hydrogen Sulfide Removal Gas Compression/ Moisture Removal Siloxane/VOC Removal MicroTurbines IC Engines Boilers
22 Siloxane Removal Systems What Are Siloxanes? What is a Siloxane? Silica and organic compounds are combined (Organosilicon) Used in many consumer and *industrial products (Listed as Silicones as the ingredient on products) Shampoo Conditioner Deodorant * Dry Cleaning Solutions * Windshield Cleaning Products * RTV Silicone Cleaner Siloxanes break down in landfills and digesters, and combine with the methane gas
23 Siloxane Removal Systems Siloxane Impact on Engines
24 Siloxane Removal Systems Siloxane and VOC Removal Biogas with siloxanes and other VOC s Biogas free of siloxanes Carbon Media Through adsorption organics are attracted to the surface and pores of the carbon media
25 Siloxane Removal Systems Siloxane and VOC Removal Carbon Media - Type is determined based on siloxane levels Biogas with siloxanes - H 2 S has been removed Biogas - ready for use
26 Gas Testing/Sampling Sampling and Shipping Supplies Box with Limited Quantity Label Metal Can, Lid and Sealing Ring Hose Barb Fitting Tedlar Bag with Valve Flexible Tubing Chain of Custody
27 Budgetary Biogas System Costs 50scfm Systems Low Pressure Ranges From: $200,000 to $325,000 High Pressure Ranges From: $230,000 to $340, scfm Systems Low Pressure Ranges From: $230,000 to $400,000 High Pressure Ranges From: $240,000 to $380, scfm Systems Low Pressure Ranges From: $270,000 to $580,000 High Pressure Ranges From: $310,000 to $600,000
28 BioCNG Vehicle Fueling System Process Flow Diagram Addition of Proprietary CO 2 Removal System Digester or Landfill BioCNG Gas Conditioning System CNG Vehicle Fueling Station CNG Vehicles MicroTurbines IC Engines Boilers Potential Energy Produced Vehicle Fuel Electricity Heat
29 Contact Information Thank You! Jan Scott
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