SAFETY DATA SHEET. Skin corrosion/irritation Serious eye damage/eye irritation Not classified. Not classified.

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Product code Synonyms Recommended use Recommended restrictions Brandt Ferrous Sulfate - Coarse Granular FERROUS SULFATE MONOHYDRATE ne known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Brandt Consolidated, Inc. Address 2935 South Koke Mill Road Springfield, IL Telephone United States Corporate Office Website msds@brandt.co Contact person EH&S / Regulatory Department Emergency phone number CHEMTREC (24 hours): USA, Canada, Puerto Rico Virgin Islands International Maritime +1 (703) Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements t classified. Acute toxicity, oral Skin corrosion/irritation Serious eye damage/eye irritation t classified. t classified. Category 4 Category 2 Category 2 Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Warning Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves. Wear eye/face protection. If swallowed: Call a poison center/doctor if you feel unwell. If on skin: Wash with plenty of water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see this label). Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Store away from incompatible materials. Dispose of contents/container in accordance with local/regional/national/international regulations. ne known. ne. 1 / 8

2 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % FERROUS SULFATE Other components below reportable levels 10 - < 20 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods General fire hazards Move to fresh air. Call a physician if symptoms develop or persist. Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical advice/attention if you feel unwell. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim under observation. Symptoms may be delayed. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Use water spray to cool unopened containers. Use standard firefighting procedures and consider the hazards of other involved materials. unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Stop the flow of material, if this is without risk. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Avoid contact with eyes, skin, and clothing. Do not taste or swallow. When using, do not eat, drink or smoke. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). 2 / 8

3 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Material Brandt Ferrous Sulfate - Coarse Granular (CAS ) Type TWA US. NIOSH: Pocket Guide to Chemical Hazards Material Type Value 1 mg/m3 Value Brandt Ferrous Sulfate - Coarse Granular (CAS ) Biological limit values Appropriate engineering controls TWA biological exposure limits noted for the ingredient(s). 1 mg/m3 Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Face shield is recommended. Wear safety glasses with side shields (or goggles). Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Wear appropriate chemical resistant gloves. Wear appropriate chemical resistant clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate thermal protective clothing, when necessary. Keep away from food and drink. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold ph Solid. Solid. Granular. Grey (5% Solution) Salt-Out / Crystallization Temp Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure < kpa at 25 C hpa estimated 3 / 8

4 Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Bulk density Molecular formula Molecular weight 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products lb/ft3 (Typical) Fe.H2-O4-S g/mol The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Contact with incompatible materials. Strong oxidizing agents. hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Harmful if swallowed. Inhalation Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Product adverse effects due to inhalation are expected. Causes skin irritation. Causes serious eye irritation. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Harmful if swallowed. Species Brandt Ferrous Sulfate - Coarse Granular (CAS ) Acute Dermal LD50 Oral LD50 Other LD50 Mouse Rat Dog Mouse Rat Dog Mouse Test Results 60.3 mg/kg 155 mg/kg 600 mg/kg 1520 mg/kg 319 mg/kg 79 mg/kg 65 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Serious eye damage/eye irritation Causes skin irritation. Causes serious eye irritation. 4 / 8

5 Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity This product is not expected to cause skin sensitization. data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR ) t listed. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard 12. Ecological information Ecotoxicity This product is not expected to cause reproductive or developmental effects. t classified. t classified. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence and degradability data is available on the degradability of this product. Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information data available. data available. other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. General t DOT regulated in domestic (USA ground) transportation in package sizes less than 1,111 lbs. DOT Regulated Marine Pollutant. DOT Shipping tes: 40 CFR (f)(9) For Class 9, a CLASS 9 placard is not required for domestic (USA ground) transportation, however shipments with packaging exceeding the Reportable Quantity (RQ) or bulk packaging must be marked with the appropriate identification number on a CLASS 9 placard, an orange panel, or a white square-on-point display configuration as required. Since the Class 9 placard is not required (although it may be used) the hazardous material endorsement is also not required on a Commercial Drivers License. DOT Basic shipping requirements: UN number UN3077 Proper shipping name Environmentally hazardous substances, solid, n.o.s. (FERROUS SULFATE RQ = 1111 lbs) Hazard class 9 Packing group III Environmental hazards Marine pollutant Special precautions Read safety instructions, SDS and emergency procedures before handling. Additional information: Special provisions 8, 146, 335, A112, B54, IB8, IP3, N20, T1, TP33 Packaging exceptions 155 Packaging non bulk 213 Packaging bulk / 8

6 tes DOT Shipping tes: 40 CFR (f)(9) For Class 9, a CLASS 9 placard is not required for domestic (USA ground) transportation, however shipments with packaging sizes exceeding the Reportable Quantity (RQ) or bulk packaging must be marked with the appropriate identification number on a CLASS 9 placard, an orange panel, or a white square-on-point display configuration as required. Since the Class 9 placard is not required (although it may be used) the hazardous material endorsement is also not required on a Commercial Drivers License. IATA t regulated as dangerous goods. IMDG t regulated as dangerous goods. General information DOT t DOT regulated in domestic (USA ground) transportation in package sizes less than 1,111 lbs. DOT Regulated Marine Pollutant. Marine pollutant DOT Marine pollutant 6 / 8

7 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR One or more components are not listed on TSCA. TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) t regulated. CERCLA Hazardous Substance List (40 CFR 302.4) FERROUS SULFATE (CAS ) SARA 304 Emergency release notification Listed. t regulated. OSHA Specifically Regulated Substances (29 CFR ) t listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - SARA 302 Extremely hazardous substance t listed. SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) t regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List t regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) t regulated. Clean Water Act (CWA) Section 112(r) (40 CFR ) Safe Drinking Water Act (SDWA) US state regulations Hazardous substance t regulated. US. Massachusetts RTK - Substance List FERROUS SULFATE (CAS ) US. New Jersey Worker and Community Right-to-Know Act t listed. US. Pennsylvania Worker and Community Right-to-Know Law FERROUS SULFATE (CAS ) US. Rhode Island RTK FERROUS SULFATE (CAS ) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) 7 / 8

8 Country(s) or region Inventory name On inventory (yes/no)* Japan Inventory of Existing and New Chemical Substances (ENCS) Korea New Zealand Philippines United States & Puerto Rico Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Revision date Version # 03 Disclaimer Revision Information The information in the sheet was written based on the best knowledge and experience currently available. This document has undergone significant changes and should be reviewed in its entirety. 8 / 8