Specific target organ toxicity, repeated exposure

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Blackhawk Precast Release 50 Other means of identification Recommended use Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company Name Address After hours telephone number Normal work hours telephone number Website Emergency 24-hour telephone number Information on operation hours ErgonArmor, a division of Ergon Asphalt & Emulsions, Inc Lakeland Drive Jackson, MS USA [email protected] CHEMTREC: North America International :00 a.m. to 5:00 p.m. 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Flammable liquids Germ cell mutagenicity Carcinogenicity Specific target organ toxicity, repeated exposure Aspiration hazard Category 4 Category 1B Category 1B Category 1 Category 1 Label elements Signal word Hazard statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Danger May be fatal if swallowed and enters airways. Combustible liquid. Causes damage to organs through prolonged or repeated exposure. May cause cancer. May cause genetic defects. Observe good industrial hygiene practices. Wash thoroughly after handling. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Do not eat, drink or smoke when using this product. Wear protective gloves/eye protection/face protection. Do not breathe mist or vapor. IF SWALLOWED: Immediately call a POISON CENTER/doctor. Wash hands after handling. Get medical advice/attention if you feel unwell. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. In case of fire: Use appropriate media for extinction. IF exposed or concerned: Get medical advice/attention. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of waste and residues in accordance with local authority requirements. Dispose of contents/container in accordance with local/regional/national/international regulations. None known. Not applicable. 1 / 7

2 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % STODDARD SOLVENT > 75 Other components below reportable levels 25 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information Move to fresh air. Call a physician if symptoms develop or persist. Wash off with soap and water. Get medical attention if irritation develops and persists. Rinse with water. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur. Treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods General fire hazards 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. No unusual fire or explosion hazards noted. Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. For personal protection, see section 8 of the SDS. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Avoid prolonged exposure. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Store in original tightly closed container. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). 2 / 7

3 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Components Type Value STODDARD SOLVENT (CAS ) US. ACGIH Threshold Limit Values Components PEL Type 2900 mg/m3 500 ppm Value STODDARD SOLVENT (CAS ) TWA US. NIOSH: Pocket Guide to Chemical Hazards Components Type 100 ppm Value STODDARD SOLVENT (CAS ) Biological limit values Appropriate engineering controls Ceiling TWA No biological exposure limits noted for the ingredient(s) mg/m3 350 mg/m3 Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Hand protection Skin protection Other Respiratory protection Thermal hazards General hygiene considerations Wear protective gloves. Wear appropriate chemical resistant clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold ph Clear, colorless liquid. Liquid. Liquid. Colorless. Hydrocarbon-like. Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) 212 F (100 C) estimated F (67.2 C) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density 0.9 % estimated 6 % estimated 3 / 7

4 Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 11. Toxicological information 450 F ( C) estimated Information on likely routes of exposure Ingestion Inhalation Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Strong oxidizing agents. No hazardous decomposition products are known. Expected to be a low ingestion hazard. Prolonged inhalation may be harmful. No adverse effects due to skin contact are expected. Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Prolonged skin contact may cause temporary irritation. This product is not expected to cause skin sensitization. No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity STODDARD SOLVENT (CAS ) 3 Not classifiable as to carcinogenicity to humans. US. OSHA Specifically Regulated Substances (29 CFR ) Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects 12. Ecological information Ecotoxicity This product is not expected to cause reproductive or developmental effects. Prolonged inhalation may be harmful. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. 4 / 7

5 Partition coefficient n-octanol / water (log Kow) STODDARD SOLVENT Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information No data available. No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. DOT UN number UN1268 UN proper shipping name Petroleum distillates, n.o.s. or Petroleum products, n.o.s. (STODDARD SOLVENT) Transport hazard class(es) Class 3 Subsidiary risk - Label(s) 3 Packing group III Special precautions for Read safety instructions, SDS and emergency procedures before handling. user Special provisions 144, B1, IB3, T4, TP1, TP29 Packaging exceptions 150 Packaging non bulk 203 Packaging bulk 242 IATA UN number UN1268 UN proper shipping name Petroleum products, n.o.s. Transport hazard class(es) Class 3 Subsidiary risk - Packing group III Environmental hazards No. ERG Code 3L Special precautions for Read safety instructions, SDS and emergency procedures before handling. user Other information Passenger and cargo Allowed. aircraft Cargo aircraft only Allowed. IMDG UN number UN1268 UN proper shipping name PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. Transport hazard class(es) Class 3 Subsidiary risk - Packing group III Environmental hazards Marine pollutant No. EmS F-E, S-E Special precautions for Read safety instructions, SDS and emergency procedures before handling. user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 5 / 7

6 DOT IATA; IMDG 15. Regulatory information US federal regulations All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) CERCLA Hazardous Substance List (40 CFR 302.4) US. OSHA Specifically Regulated Substances (29 CFR ) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Other federal regulations No Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Safe Drinking Water Act (SDWA) US state regulations US. Massachusetts RTK - Substance List STODDARD SOLVENT (CAS ) US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania RTK - Hazardous Substances STODDARD SOLVENT (CAS ) US. Rhode Island RTK US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. 6 / 7

7 International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) Non-Domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of Notified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Version # 01 No No Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 7 / 7