MATERIAL SAFETY DATA SHEET. 1. Product and Company Identification

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1 MATERIAL SAFETY DATA SHEET 1 Product and Company Identification Product Name FINISH ALL-IN-1 GELPACS - All Scents UPC CODES Refer to section 16 CAS # Product Use Distributed by LEGEND HMIS/NFPA Severe Serious 4 3 Moderate 2 Slight 1 Minimal 0 Mixture Dishwasher detergent Reckitt Benckiser (Canada) Inc 1680 Tech Avenue Unit #2 Mississauga, ON L4W 5S9 In Case of Emergency: Transportation Emergencies: 24 Hour Number: North America: CHEMTREC: Outside North America: Health / 1 Flammability 0 Physical Hazard 0 Personal Protection B Emergency Overview Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms 2 Hazards Identification Avoid contact with eyes and skin Keep out of reach of children Eye, Skin contact, Ingestion None expected during normal conditions of use May cause eye irritation upon direct contact with the eyes None expected during normal conditions of use Not expected to be a skin sensitizer None expected during normal conditions of use Health injuries are not known or expected under normal use Eyes Skin The finished product is not expected to have chronic health effects None expected during normal conditions of use 3 Composition/Information on Ingredients A-Amylase (EC# 3211) CAS # Percent < First aid procedures Eye contact Skin contact Inhalation 4 First Aid Measures If in eyes, IMMEDIATELY rinse eyes with plenty of water Remove any contact lenses and continue rinsing eyes for at least 15 minutes If irritation occurs, get medical attention immediately If on skin, wash with plenty of soap and water Get medical attention if irritation persists Move to fresh air If symptoms persist, call a physician Immediate medical attention is not required #19916 Page 1 of 6 Issue date 05-Apr-2010

2 Ingestion Notes to physician If swallowed, call a Poison Control Centre or doctor immediately DO NOT induce vomiting Contains Polycarboxylates and enzymes General advice Treat patient symptomatically If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes and skin Keep out of reach of children 5 Fire-fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighers Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Not flammable by WHMIS criteria Treat for surrounding material Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon 6 Accidental Release Measures Personal precautions Methods for containment Methods for cleaning up Handling Avoid contact with skin and eyes Use personal protective equipment Stop leak if you can do so without risk Prevent entry into waterways, sewers, basements or confined areas Pick up and transfer to properly labelled containers 7 Handling and Storage Hands must be dry before handling Do not unwrap or cut GELPAC Storage Avoid contact with eyes, skin and clothing Do not ingest Keep out of reach of children Exposure limit values A-Amylase (EC# 3211) Keep in properly labelled containers Keep containers tightly closed in a cool, well-ventilated place 8 Exposure Controls / Personal Protection Exposure limit values ACGIH-TLV Not established ACGIH-TLV Not established Engineering controls Personal protective equipment Eye/Face protection ACGIH-TLV Ceiling: mg/m3 General ventilation normally adequate tightly fitting safety goggles Emergency responders should wear full eye and face protection #19916 Page 2 of 6 Issue date 05-Apr-2010

3 Hand protection Skin and body protection Follow standard industrial hygiene practices Emergency responders should wear impermeable gloves Usual safety precautions while handling the product will provide adequate protection against injury or irritation Emergency responders should wear impermeable clothing and footwear when responding to a situation where contact with the liquid is possible Follow label directions carefully Respiratory protection Not normally required if good ventilation is maintained Emergency responders should wear self-contained breathing apparatus (SCBA) to avoid inhalation of vapours generated by this product during a spill or other clean-up operations General hygiene considerations Avoid contact with skin, eyes and clothing Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink 9 Physical and Chemical Properties Appearance Colour Form Odour Odour threshold Liquid Blue Liquid gel in a soluble capsule Perfume Physical state Liquid ph 86 ± 02 (10%) Freezing point Boiling point Pour point Flash point > 100 C (> F) Evaporation Rate Flammability limits in air, lower, % by volume Flammability Limits in Air, Upper, % by Volume Vapour pressure Vapour density Specific gravity 127 Octanol/water coefficient Auto-ignition temperature Viscosity mpas 10 Stability and Reactivity Chemical stability Conditions to avoid Stable under recommended storage conditions Do not use with other detergents Do not mix with chlorine bleach Protect from sunlight and do not expose to temperatures exceeding 50 C (120 F) Incompatible materials Caustics Acids Hazardous decomposition products May include and are not limited to: Oxides of carbon Possibility of hazardous reactions Hazardous polymerisation does not occur 11 Toxicological Information Component analysis - LC50 A-Amylase (EC# 3211) LC50 #19916 Page 3 of 6 Issue date 05-Apr-2010

4 Component analysis - Oral LD50 LD50 A-Amylase (EC# 3211) Effects of acute exposure Eye Skin Inhalation Ingestion Sensitisation Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Synergistic Materials 7500 mg/kg rat 1200 mg/kg rat None expected during normal conditions of use May cause eye irritation upon direct contact with the eyes None expected during normal conditions of use Not expected to be a skin sensitizer None expected during normal conditions of use Health injuries are not known or expected under normal use The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects 12 Ecological Information Ecotoxicity Environmental effects Aquatic toxicity Persistence and degradability Bioaccumulation/accumulation Partition coefficient Mobility in environmental media Chemical fate information Other adverse effects Waste codes Disposal instructions Waste from residues / unused products Contaminated packaging 13 Disposal Considerations Discard after single use Review federal, state/provincial, and local government requirements prior to disposal Discard with solid waste Dispose in accordance with all applicable regulations #19916 Page 4 of 6 Issue date 05-Apr-2010

5 UN/ID No 14 Transport Information US Department of Transportation (DOT): Classification: Not regulated Proper shipping name US DOT Hazard Class Subsidiary Risk DOT RQ (lbs) ERG NO Transportation of Dangerous Goods (TDG - Canada): Classification: Not regulated Proper shipping name Status IMDG (Marine Transport): Classification: Not regulated Proper shipping name Class Subsidiary Risk IMDG Page Marine pollutant EMS MFAG Maximum Quantity #19916 Page 5 of 6 Issue date 05-Apr-2010

6 IATA/ICAO (Air): Classification: Not regulated Proper shipping name Class Subsidiary Risk: Maximum Quantity Canadian federal regulations 15 Regulatory Information This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations Product Registration: Not registered WHMIS classification Exempt - Consumer product Inventory Status Country(s) or region Canada Canada Inventory Name Domestic Substances List (DSL) Non-Domestic Substances List (NDSL) On Inventory (Yes/No)* No Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Disclaimer Further information Issue date Effective Date 16 Other Information This product should only be used as directed on the label and for the purpose intended To the best of our knowledge, the information contained herein is accurate However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein Final determination of suitability of any material is the sole responsibility of the user All materials may present unknown hazards and should be used with caution Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist ct - FINISH ALL-IN-1 GELPACS Orange Blossom ct - FINISH ALL-IN-1 GELPACS Orange Blossom ct - FINISH ALL-IN-1 GELPACS Orange Scent ct - FINISH ALL-IN-1 GELPACS Orange Scent 05-Apr Apr-2010 Expiry Date 01-Apr-2013 Prepared by Reckitt Benckiser Regulatory Department Other Information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document #19916 Page 6 of 6 Issue date 05-Apr-2010

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