MATERIAL SAFETY DATA SHEET LIQUID LAUNDRY DETERGENT LA PARISIENNE Effective date:27-anl-2016

Transcription

1 SECTION 1 : IDENTIFICATION Product name: Chemical name : Product Use: Chemical family : Supplier s name: Address : LA PARISIENNE OX1 & TOTAL BRIGHT Mixture of tensio-active agents Laundry detergent Mixture of tensio-active agents LAVO Inc Boul. Saint-Jean Baptiste Montréal, Québec Canada H1C 2J3 Telephone : or Emergency phone : CANUTEC (transport) SECTION 2 : HAZARD IDENTIFICATION Emergency Overview CAUTION / IRRITANT MAY CAUSE EYES IRRITATION. MAY CAUSE SKIN IRRITATION. POTENTIAL HEALTH EFFECTS: Signs and symptoms of short-term (acute) exposure Eyes : Skin : Ingestion : Inhalation : Target organs: Effects of long-term (chronic) exposure : Signs and symptoms: Potential environmental effect : May cause irritation. May cause irritation. May cause stomach distress, nausea or vomiting. May cause respiratory tract irritation. Eyes. Skin. Prolonged or repeated contact may cause drying, cracking and de-fatting of the skin. Symptoms may include redness, oedema, drying, de fatting and cracking of the skin. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Components of this product have been identified as having potential environmental concerns. SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS Ingredients CAS Percentage Sodium Carbonate anhydre < 3 % Sulfonic alkyl benzene acid < 5 % Sodium laureth sulfate < 5 % Etoxylated alcohols C12-C % SECTION 4 : FIRST AID MEASURES Eye contact : Skin contact: Ingestion : Inhalation : Notes for physician : Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention if irritation develops or persists. Flush with cool water. Obtain medical attention if irritation persists. Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Treat symptomatically. General advice: If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children /2418 Page 1 / 5

2 SECTION 5 : FIRE FIGHTING MEASURES Fire hazards/conditions of flammability: Extinguishing media: Protection of firefighters Specific hazards arising from the chemical: Protective equipment for firefighters: Hazardous combustion products : Not flammable by WHMIS criteria Treat for surrounding material. Firefighters should wear full protective clothing including self contained breathing apparatus. SECTION 6 : ACCIDENTAL RELEASE MEASURES Personal precautions: Environmental precautions: Methods for containment: Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. Do not discharge into lakes, streams, ponds or public waters. Stop leak if you can do so without risk. Prevent entry into waterways, Sewers, basements or confined areas. Methods for cleaning up : Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labeled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re-use. SECTION 7 : HANDLING AND STORAGE Safe Handling procedures: Storage requirements : Storage temperature: Use good industrial hygiene practices in handling this material. Avoid contact with eyes and skin. Keep out of reach of children C. Do not freeze. Avoid high temperature. SECTION 8 : EXPOSITION CONTROL/PERSONAL PROTECTION Exposition limit values ACGIH TLV OSHA PEL Ingredients CAS TWA PEL STEL Sodium Carbonate anhydre Not available N/D Sulfonic alkyl benzene acid Not available Sodium laureth sulfate Not available Etoxylated alcohols C12-C Not available Engineering controls: Eye/Face protection: Skin and body protection: Respiratory protection: General hygiene considerations: General ventilation normally adequate. Safety glasses or a facial screen if eye contact is possible. Rubber gloves. Confirm with a reputable supplier first. Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands before breaks and immediately after handling the product /2418 Page 2 / 5

3 SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES MATERIAL SAFETY DATA SHEET Physical state Liquid Appearance Viscous colored liquid Odor Fragrant various Odor threshold Not available ph 8-10 Water Solubility Completely miscible Boiling point Not available Evaporation Rate Not available Freezing point Not available Viscosity (@20 C) Not available Vapor Pressure Not available Auto-ignition temperature Not available Flash point / Poor point Not available Flammability limits in air, lower Not available Density Flammability limits in air, upper Not available Repartition Coefficient water/oil Not available Vapor density Not available SECTION 10 : STABILITY AND REACTIVITY Reactivity: Possibility of hazardous reactions: Chemical stability: Conditions to avoid: Incompatible materials: Hazardous decomposition products: This product may react with strong acids. Hazardous polymerization does not occur. Stable under recommended storage conditions. Do not mix with other chemicals. Acids. May include and are not limited to: Oxides of carbon. SECTION 11 : TOXICOLOGICAL INFORMATION Ingredients CAS LC50(4hr)inh, rat LD50 (Oral, rat) LD50 (Rat, dermal) Sodium Carbonate anhydre (2hr) 2.3 mg/l (rat) >2000mg/kg 2000mg/kg Sulfonic alkyl benzene acid Not available 530 mg/kg 530 mg/kg Sodium laureth sulfate >2030mg/kg >5000mg/kg Not available Etoxylated alcohols C12-C Low >300 mg/kg >2000mg/k Effects of acute exposure: eyes : May cause irritation. Skin : May cause irritation. Inhalation: May cause respiratory tract irritation. Ingestion : May cause stomach distress, nausea or vomiting. Sensitization to material : Chronic effects: Carcinogenicity : Reproductive effects: Teratogenicity : Mutagenicity: Synergistic Products : SECTION 12 : ECOLOGICAL INFORMATION Ingredient: CAS Ecotoxicity - Freshwater Fish - Acute Toxicity Data Sodium Carbonate anhydre Sulfonic alkyl benzene acid LC50 Oncorhynchus mykiss : 3 mg/l Sodium laureth sulfate Low acute toxicity to aquatic organisms. Etoxylated alcohols C12-C h [static] LC50 Oncorhynchus mykiss: 1 à 10 mg/l /2418 Page 3 / 5

4 SECTION 12 : ECOLOGICAL INFORMATION (CONT D) Ingredient: CAS Ecotoxicity - Freshwater Fish - Acute Toxicity Data Sodium Carbonate anhydre Sulfonic alkyl benzene acid LC50 Oncorhynchus mykiss : 3 mg/l Sodium laureth sulfate Low acute toxicity to aquatic organisms. Etoxylated alcohols C12-C h [static] LC50 Oncorhynchus mykiss: 1 à 10 mg/l Ingredient: CAS Ecotoxicity - Water Flea - Acute Toxicity Data Sodium Carbonate anhydre h TLM Daphnia magna: mg/l Sulfonic alkyl benzene acid Sodium laureth sulfate Low acute toxicity to aquatic organisms. Etoxylated alcohols C12-C h [static] EC50 Daphnia magna: 0.1 à 2.7 mg/l Persistence and degradability: Bioaccumulation Potential: Mobility in environmental media : Environmental effects: Aquatic toxicity: Partition coefficient Chemical fate information : Other adverse effects ; SECTION 13 : DISPOSAL CONSIDERATIONS Disposal instructions: Waste from residues / Unused products: Contaminated packaging Dispose in accordance with all applicable federal, state, provincial and local regulations. SECTION 14 : TRANSPORT INFORMATION Transportation of Dangerous Goods (TDG - Canada) : Not regulated as dangerous goods. SECTION 15 : REGULATORY INFORMATION Canadian federal regulations : WHMIS classification : WHMIS status: WHMIS labeling: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Class D 2B Controlled Canadian Inventory Status: All components of this product are either on the Domestic Substances List (DSL), the Non Domestic Substances List (NDSL) or exempt /2418 Page 4 / 5

5 SECTION 16 : OTHER INFORMATION HMIS Rating; Chronic hazard: 0- Minimal 1-Slight 2-Moderate 3-Serious Disclaimer of liability: Other information : Prepared by : Health : 1 Flammability : 0 Reactivity : 0 The information in the Material Safety Data Sheet is offered for your consideration and guidance when exposed to this product. Lavo Inc. expressly disclaims all expressed or implied warranties for the accuracy or completeness of the data contained herein and assumes no responsibilities for any involved damages by above data. Product s users have to do their own tests to establish the applicability of the information for a specific use of the product. MSDS data does not apply to use with any other product or in any other process. For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. References: MSDS of suppliers SIMDUT regulation Lavo Inc Boul. Saint-Jean Baptiste Montreal, QC, Canada H1C 2J3 Téléphone : Issuing date : 27-Jan-2016 Due date : Jan /2418 Page 5 / 5