MATERIAL SAFETY DATA SHEET. 1. Product and Company Identification. 2. Hazards Identification

Transcription

1 MATERIAL SAFETY DATA SHEET 1 Product and Company Identification Product Name CAS # Product use Manufacturer Thawrox Mixture De-icer North American Salt Company A Compass Minerals Company 99 West 19th Street, Suite 1 Overland Park, KS 6621 US Phone: Supplier Sifto Canada, Inc 67 Century Ave, Suite 22 Mississauga, ON L5N 6A4 Canada Phone: (95) CHEMTREC CANUTEC Emergency overview Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms 2 Hazards Identification Contact may cause eye and skin irritation Eye, Skin contact, Inhalation, Ingestion May cause irritation May cause irritation Dusts of this product may cause irritation of the nose, throat, and respiratory tract May cause stomach distress, nausea or vomiting Eyes Skin Respiratory system Prolonged or repeated exposure can cause drying, defatting and dermatitis Symptoms may include redness, edema, drying, defatting and cracking of the skin Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting OSHA Regulatory Status This product is NOT known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR Potential environmental effects See section 12 3 Composition / Information on Ingredients Ingredient(s) CAS # Percent Mixture 3-7 First aid procedures Eye contact Skin contact Inhalation Ingestion General advice 4 First Aid Measures Flush with cool water Remove contact lenses, if applicable, and continue flushing Obtain medical attention if irritation persists Brush away excess of dry material Flush with water Obtain medical attention if irritation persists If symptoms develop move victim to fresh air If symptoms persist, obtain medical attention Do not induce vomiting Never give anything by mouth if victim is unconscious, or is convulsing Obtain medical attention If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration If you feel unwell, seek medical advice (show the label where possible) Keep out of reach of children #17295 Page 1 of 6

2 5 Fire Fighting Measures Flammable properties Not flammable by WHMIS/OSHA criteria Extinguishing media Suitable extinguishing media Treat for surrounding material Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Chlorine Oxides of sodium 6 Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Handling Storage Exposure limits Ingredient(s) Avoid dust generation Do not discharge into lakes, streams, ponds or public waters Stop the flow of material, if this is without risk Before attempting clean up, refer to hazard data given above Use broom or dry vacuum to collect material for proper disposal without raising dust Rinse area with water Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice 7 Handling and Storage Use good industrial hygiene practices in handling this material Avoid breathing dusts from this material Wash thoroughly after handling Keep out of reach of children Store in a closed container away from incompatible materials 8 Exposure Controls / Personal Protection Exposure Limits ACGIH-TLV OSHA-PEL ACGIH-TLV OSHA-PEL #17295 Page 2 of 6

3 Engineering controls TWA PEL: No specific limits have been established for sodium chloride (a soluble substance) As a guideline, OSHA (United States) has established the following limits which are generally recognized for inert or nuisance dust Particulates Not Otherwise Regulated (PNOR): 5mg/cum Respirable Dust 8-Hour TWA PEL, 15mg/cum Total Dust 8-Hour TWA PEL Personal protective equipment Eye / face protection Hand protection Skin and body protection TWA TLV: No specific limits have been established for sodium chloride (a soluble substance) As a guideline, ACGIH (United States) has established the following limits which are generally recognized for inert or nuisance dust Particulates (insolubles) Not Otherwise Classified (PNOC): 1mg/cum Inhalable Particulate 8-Hours TWA TLV, 3mg/cum Respirable Particulate TWA TLV Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits If user operations generate dust, fumes, or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit Safety glasses if eye contact is possible If there is constant skin contact, rubber gloves are recommended As required by employer code Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator or NIOSH-approved filtering facepiece General hygiene considerations Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink Wash hands before breaks and immediately after handling the product 9 Physical and Chemical Properties Appearance Color Form Odor Odor threshold Physical state ph Melting point Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, lower, % by volume Flammability limits in air, upper, % by volume Vapor pressure Vapor density Specific gravity Octanol/water coefficient Viscosity Percent volatile Crystalline Variable Crystals Odorless Solid Not applicable Not applicable Not applicable 1 Stability and Reactivity Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Reactive with oxidizing agents, acids, lithium, bromine trifluoride Hazardous polymerization does not occur Stable under recommended storage conditions Do not mix with incompatible materials Acids Oxidizers Lithium Bromine trifluoride #17295 Page 3 of 6

4 Hazardous decomposition products May include and are not limited to: Chlorine Oxides of sodium 11 Toxicological Information Component analysis - LC5 Ingredient(s) Component analysis - Oral LD5 Ingredient(s) Effects of acute exposure Eye Skin Inhalation Ingestion Sensitization Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products LC5 > 21 mg/m3 rat LD5 3 mg/kg rat; 4 mg/kg mouse 1493 mg/kg rat May cause irritation May cause irritation Dusts of this product may cause irritation of the nose, throat, and respiratory tract May cause stomach distress, nausea or vomiting Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria Not classified or listed by IARC, NTP, OSHA and ACGIH Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria 12 Ecological Information Ecotoxicity May be harmful to freshwater aquatic species and to plants that are not saline tolerant Ecotoxicity - Freshwater Fish - Acute Toxicity Data Hr LC5 Lepomis macrochirus: mg/l [flow-through]; 96 Hr LC5 Lepomis macrochirus: mg/l [static]; 96 Hr LC5 Pimephales promelas: mg/l [static]; 96 Hr LC5 Pimephales promelas: 75 mg/l [semi-static]; 96 Hr LC5 Pimephales promelas: mg/l [static]; 96 Hr LC5 Oncorhynchus mykiss: mg/l [flow-through] Ecotoxicity - Water Flea - Acute Toxicity Data Hr EC5 Daphnia magna: 1 mg/l; 48 Hr EC5 Daphnia magna: mg/l [Static] Persistence / degradability Bioaccumulation / accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Chemical fate information Other adverse effects 13 Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging Waste must be disposed of in accordance with federal, state/provincial and local environmental control regulations #17295 Page 4 of 6

5 14 Transport Information US Department of Transportation (DOT) Not regulated as dangerous goods Transportation of Dangerous Goods (TDG - Canada) Not regulated as dangerous goods 15 Regulatory Information Canadian federal regulations WHMIS status 29 CFR hazardous chemical US Federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations Not Controlled Occupational Safety and Health Administration (OSHA) No This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR CERCLA (Superfund) reportable quantity None Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Section 32 extremely No hazardous substance Section 311 hazardous chemical No Clean Water Act (CWA) State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm Inventory name Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Severe Serious Moderate Slight Minimal LEGEND HMIS/NFPA Disclaimer Effective date Expiry date Health 16 Other Information Flammability Physical Hazard Personal Protection / 1 A 1 Information contained herein was obtained from sources considered technically accurate and reliable While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document 19-Apr-216 #17295 Page 5 of 6

6 Prepared by Dell Tech Laboratories Ltd (519) Other information This MSDS conforms to the ANSI Z41/Z Standard #17295 Page 6 of 6