SAFETY DATA SHEET EPOXY THIXOTROPIC INJECTION GROUT RESIN COMPONENT

Transcription

1 1/6 EPOXY THIXOTROPIC INJECTION GROUT RESIN COMPONENT 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME EPOXY THIXOTROPIC INJECTION GROUT RESIN COMPONENT PRODUCT NO. TG89, TG90, TG119 (SDS 20586) SUPPLIER CONSTRUCTION PRODUCTS SOLUTIONS INTERNATIONAL LTD. Unit 3, Haslemere Industrial Estate, Pig Lane, Bishop s Stortford, Hertfordshire. CM23 3HG. United Kingdom. Tel: +44(0) Fax: +44(0) e mail: info@surecps-group.com Company Reg VAT Reg. GB Emergency Information +44(0) (Office hours Mon - Fri then diverts to an appropriate call centre) 2 HAZARDS IDENTIFICATION Irritating to eyes and skin. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. CLASSIFICATION (1999/45) Xi;R36/38. R43. N;R51/53. 3 COMPOSITION/INFORMATION ON INGREDIENTS Name EC No. CAS-No. Content Classification OXYRONE, MONO(C12-C14 ALKOXYMETHYL) DERIVATIVES REACTION PRODUCT BIS A- (EPICHLORHYDRIN) EPOXY RESIN (NUMBER AVERAGE MOL WT<=700) 10-30% Xi;R36/38. N;R51/53. R % Xi;R36/38. N;R51/53. R43. REACTION PRODUCT BIS F - (EPICHLORHYDRIN); EPOXY RESIN (NUMBER AVERAGE MOL WT <=700) 10-30% Xi;R36/38. N;R51/53. R43. The Full Text for all R-Phrases are Displayed in Section 16 CAS-No

2 2/6 4 FIRST-AID MEASURES INHALATION General first aid, rest, warmth and fresh air. Get medical attention if any discomfort continues. INGESTION DO NOT induce vomiting. Get medical attention immediately. Immediately rinse mouth and drink plenty of water ( ml). SKIN CONTACT Remove contaminated clothing immediately and wash skin with soap and water. EYE CONTACT Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids widely. If irritation persists: Seek medical attention and bring along these instructions. 5 FIRE-FIGHTING MEASURES 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Extinguish with foam, carbon dioxide, dry powder or water fog. SPECIAL FIRE FIGHTING PROCEDURES Keep run-off water out of sewers and water sources. Dike for water control. UNUSUAL FIRE & EXPLOSION HAZARDS No unusual fire or explosion hazards noted. SPECIFIC HAZARDS In case of fire, toxic and corrosive gases may be formed. PROTECTIVE MEASURES IN FIRE Self contained breathing apparatus and full protective clothing must be worn in case of fire. 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation of vapours and contact with skin and eyes. ENVIRONMENTAL PRECAUTIONS Do not discharge into drains, water courses or onto the ground. SPILL CLEAN UP METHODS For waste disposal, see section 13. Dam and absorb spillage with sand, sawdust or other absorbent.

3 3/6 7 HANDLING AND STORAGE USAGE PRECAUTIONS Ensure there is sufficient ventilation in work area. Observe good chemical hygiene practices. USAGE DESCRIPTION Do not use outside manufacturers specification. STORAGE PRECAUTIONS Store in tightly closed original container in a dry and cool place. STORAGE CLASS Unspecified storage. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION INGREDIENT COMMENTS No exposure limits noted for ingredient(s). PROTECTIVE EQUIPMENT RESPIRATORY EQUIPMENT No specific recommendations. HAND PROTECTION The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. EYE PROTECTION Wear approved safety goggles. HYGIENE MEASURES Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. SKIN PROTECTION Avoid skin contact 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Creamy liquid COLOUR White / off-white ODOUR Characteristic SOLUBILITY Insoluble in water Soluble in: Organic solvents BOILING POINT ( C) >200@760mg Hg MELTING POINT ( C) -5 RELATIVE DENSITY 1.13g/ml VISCOSITY mpas 25 FLASH POINT ( C) >140 C Not noted.

4 4/6 10 STABILITY AND REACTIVITY STABILITY Stable under normal temperature conditions and recommended use. CONDITIONS TO AVOID Avoid frost. HAZARDOUS POLYMERISATION May polymerise. POLYMERISATION DESCRIPTION Will polymerise with amines MATERIALS TO AVOID Amines HAZARDOUS DECOMPOSITION PRODUCTS In case of fire, toxic gases (CO, CO2, NOx) may be formed. 11 TOXICOLOGICAL INFORMATION INHALATION May cause irritation to the respiratory system. INGESTION May cause discomfort if swallowed. SKIN CONTACT Irritating to skin. May cause sensitisation by skin contact. EYE CONTACT Irritating to eyes. 12 ECOLOGICAL INFORMATION Dangerous for the environment: May cause long-term adverse effects in the aquatic environment. Harmful to Fish EC 50, 48 Hrs, DAPHNIA, mg/l 2.8 DEGRADABILITY The product is not readily biodegradable. 13 DISPOSAL CONSIDERATIONS GENERAL INFORMATION Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority. DISPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements.

5 5/6 14 TRANSPORT INFORMATION PROPER SHIPPING NAME Environmentally Hazardous Substance, Liquid, NOS (Epoxide Resin) UN NO. ROAD 3082 ADR CLASS NO. 9 ADR PACK GROUP III ADR LABEL NO. 9 RID CLASS NO. 9 RID PACK GROUP III UN NO. SEA 3082 IMDG CLASS 9 IMDG PACK GR. III MARINE POLLUTANT No. UN NO. AIR 3082 AIR CLASS 9 AIR PACK GR. III 15 REGULATORY INFORMATION LABELLING Irritant Dangerous for the environment CONTAINS OXYRONE, MONO(C12-C14 ALKOXYMETHYL) DERIVATIVES REACTION PRODUCT BIS A-(EPICHLORHYDRIN) EPOXY RESIN (NUMBER AVERAGE MOL WT <=700) REACTION PRODUCT BIS F -(EPICHLORHYDRIN); EPOXY RESIN (NUMBER AVERAGE MOL WT <=700) RISK PHRASES R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. SAFETY PHRASES S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves. S57 Use appropriate containment to avoid environmental contamination. S60 This material and its container must be disposed of as hazardous waste. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. UK REGULATORY REFERENCES The Control of Substances Hazardous to Health Regulations ENVIRONMENTAL LISTING Control of Pollution (Special Waste Regulations) Act EU DIRECTIVES Dangerous Preparations Directive 1999/45/EC. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, ncluding amendments.

6 6/6 15 REGULATORY INFORMATION (cont.) STATUTORY INSTRUMENTS Chemicals (Hazard Information and Packaging) Regulations. Control of Substances Hazardous to Health. APPROVED CODE OF PRACTICE Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations. GUIDANCE NOTES Workplace Exposure Limits EH40. CHIP for everyone HSG(108). NATIONAL REGULATIONS Workplace Exposure Limits 2005 (EH40) 16 OTHER INFORMATION REVISION DATE 03/06/2015 REV. NO./REPL. SDS GENERATED 3 SDS NO. SDS RISK PHRASES IN FULL R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. DISCLAIMER This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company s knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user s responsibility to satisfy himself as to the suitability of such information for his own particular use. CONSTRUCTION PRODUCTS SOLUTIONS INTERNATIONAL LTD. Unit 3, Haslemere Industrial Estate, Pig Lane, Bishop s Stortford, Hertfordshire. CM23 3HG. United Kingdom. Tel: +44(0) Fax: +44(0) e mail: info@surecps-group.com - Company Reg VAT Reg. GB