Module 3 Detecting the Presence 1 OCCUPANCY/LOCATION OCCUPANCY & LOCATION CONTAINER SHAPES MARKINGS & COLORS PLACARDS & LABELS

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1 OCCUPANCY & LOCATION CONTAINER SHAPES MARKINGS & COLORS PLACARDS & LABELS SHIPPING PAPERS & OTHER DOCUMENTATION SENSES OCCUPANCY/LOCATION CAN YOU IDENTIFY THE PLACES AND/OR BUSINESSES IN YOUR COMMUNITY WHERE HAZARDOUS MATERIALS ARE STORED? Module 3 Detecting the Presence 1

2 CONTAINER SHAPES BE ALERT TO THE VARIOUS SHAPES AND SIZES OF THE CONTAINERS UTILIZED TO STORE OR TRANSPORT HAZARDOUS MATERIALS OVAL SHAPE LARGER CIRCULAR SHAPE LOOK FOR: SMALLER CIRCULAR SHAPE ROUNDED ENDS PRESSURE TANK CARS LOW PRESSURE TANK CARS Module 3 Detecting the Presence 2

3 SOME HAZARDOUS MATERIALS REQUIRE SPECIALIZED CONTAINMENT ACTUAL SHAPE AND/OR APPEARANCE OF THE CONTAINER MAY GIVE A CLUE AS TO ITS CONTENTS INDIVIDUAL CONTAINERS PRIMARILY UTILIZED AND CONSTRUCTED TO FACILITATE PRODUCT USAGE MARKINGS & COLORS 1075 Module 3 Detecting the Presence 3

4 Blue Represents Health 4 - Deadly 3 - Extremely Hazardous 2 - Hazardous 1- Slightly Hazardous 0 - Normal Material White Field- Specific Hazard OXY - Oxidizer ACID - Acid ALK - Alkali COR - Corrosive W Use no Water P - Polymerizes NFPA 704 System Red Represents Fire (Flammability) 4 - Below 73 F 3 - Below 100 F 2 - Below 200 F 1- Above 200 F 0 - Will not Burn Yellow Represents- Reactivity Chemical Compatibility 4 - May Detonate 3 - May Detonate w/ Heat or Shock 2 - Violent Chem. Change 1- Not Stable if Heated 0 - Stable REGISTRATION NUMBER MARKINGS ON RAIL TANK CARS WORKING TEST PRESSURE HOT 3257 Module 3 Detecting the Presence 4

5 PIPELINE / UNDERGROUND UTILITY MARKINGS UNDERGROUND UTILITIES UNIFORM COLOR CODE BLUE - WATER GREEN - SEWER RED - ELECTRIC WHITE - PROPOSED EXCAVATION PINK - TEMPORARY SURVEY MARKINGS YELLOW - GAS, OIL, PETROLEUM PRODUCTS ORANGE - TELEPHONE, CABLE TV, COMMUNICATIONS Military Marking REMEMBER, COMPRESSED GAS CYLINDERS ARE NOT ALL COLOR CODED. Module 3 Detecting the Presence 5

6 PLACARDS & LABELS INTERNATIONALLY RECOGNIZED SYSTEM OF COLORS, SYMBOLS AND NUMBERS THAT CORRESPOND TO SPECIFIC HAZARDOUS MATERIALS PLACARDS & LABELS U.S. Dept. of Transportation Nine (9) Classes) 1 Explosives 2 Gases 3 Flammable Liquids 4 Flammable Solids 5 Oxidizer 6 Poisons 7 Corrosive 8 Radioactive 9 Other Regulated Material (ORM) PLACARDS & LABELS U.S. Dept. of Transportation DOT ID Number Color 1993 RESIDUE Symbol DOT Hazard Class Module 3 Detecting the Presence 6

7 What if no UN ID number or chemical name can be found but I can see a generic DOT placard? Use the multi colored pictures of placards to be pointed to a guide page in the orange section What if? Module 3 Detecting the Presence 7

8 C opy right 1996 G alac tic Software. Student Handout FOR MIXED LOADS OF TABLE 2 MATERIALS DANGEROUS 1000 lbs rule NOT USED ON CARGO TANK TRUCKS DO NOT LOAD IN PASSENGER AIRCRAFT KEEP AWAY FROM AIRCRAFT COMPASS DETECTOR UNIT LABELS THIS END UP Chlorine, UN1017 To: Justin Time 123 Main St. Yourtown, NJ u n 4G/X30/S/91 USA/+GS0001 Module 3 Detecting the Presence 8

9 Student Handout SHIPPING PAPERS AND/OR OTHER DOCUMENTATION EVERY TRANSPORTER OF HAZARDOUS MATERIALS MUST HAVE, IN THEIR POSSESSION, DOCUMENTATION IDENTIFYING THE GOODS THEY ARE TRANSPORTING. DOCUMENTATION OF HAZARDOUS MATERIALS ALL SHOULD FOLLOW A RECOGNIZED AND APPROVED FORMAT THE THREE MOST COMMON TYPES WITH ROADWAY TRANSPORT ARE: SHIPPING PAPERS CAT BILLS OF LADING MANIFESTS (HAZARDOUS WASTES) 1 TRUCK, SLUDGE, UN3578, 3,500GAL. IMPORTANT INFORMATION FOUND ON SHIPPING PAPERS CHEMTREC EMERGENCY CONTACT TELEPHONE NUMBER NO. PACKAGES HM DESCRIPTION OF ARTICLES AND SPECIFICATIONS WEIGHT 2 drums X Allyl Alcohol, 6.1, UN 1098, PG I, Poison-Inhalation Hazard, Zone B 100 lbs. 25 pkg X Sodium Phosphide, 4.3, UN 1432, PG I, Dangerous When Wet 2,000 lbs. 20 pkg RQ Sulfuric Acid, 8, UN 1830, PGII 1,304 lbs. SHIPPING NA ME DIVISION NUMBER ID NO. PACKING GROUP # 15 cases X Zinc Cyanide, 6.1, UN 1713, PG I, Poison-Inhalation Hazard, (Marine Pollutant) 150 lbs. PACKING GROUP I = VERY DANGEROUS MATERIALS PACKING GROUP II = MODERATE DANGER PACKING GROUP III = MINOR DANGER HAZARD ZONES A & B = EXTREME DANGER SMALL CONCENTRATIONS HAZARD ZONE C = VERY DANGEROUS LARGER CONCENTRATIONS HAZARD ZONE D = DANGEROUS LARGER CONCENTRATIONS Module 3 Detecting the Presence 9

10 MATERIAL SAFETY DATA SHEETS (M.S.D.S.) REQUIRED BY O.S.H.A. 29 CFR PROVIDES INFORMATION ON THE PROPERTIES OF THE MATERIALS AND IMMEDIATE ACTIONS WHICH SHOULD BE TAKEN IN THE EVENT OF A MISHAP. SENSES THE LEAST ACCEPTABLE WAY OF IDENTIFYING HAZMAT. BY THE TIME YOU SEE, SMELL, HEAR, OR FEEL IT, IT S PROBABLY TOO LATE!! Let s test your knowledge! How would you obtain hazard information for the following incidents? FIXED FACILITY TRANSPORTATION Module 3 Detecting the Presence 10

11 Let s test your knowledge! How would you obtain hazard information for the following incidents? FIXED FACILITY Occupancy/location Container shapes MSDSs Site manager Emergency Planning documents Markings/Colors Senses TRANSPORTATION Occupancy/location Container shapes Shipping papers Placards/Labels Responsible party Senses Module 3 Detecting the Presence 11