ALBERDINGK LUX220 - A w/b UV-Curable Binder with High Performance Properties for Wood Furniture/Parquet and PVC Flooring/Plastics

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1 ALBERDINGK LUX220 - A w/b UV-Curable Binder with High Performance Properties for Wood Furniture/Parquet and PVC Flooring/Plastics customer seminar Taiwan, 2014 Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 1

2 Table of contents! Alberdingk w/b UV-curable binders in current market! High properties of w/b UV-curable binder Alberdingk LUX 220! Product data of Alberdingk LUX 220! Formulation for Alberdingk LUX 220! Properties evaluation of Alberdingk LUX 220 in pigmented and transparent systems applied on wood, ABS plastic, PVC floor, etc.! Application of Alberdingk LUX 220 DEMO panels! Highlights of Alberdingk LUX 220 Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 2

3 Market development of w/b UV binders At present, the market for w/b UV binders is growing up quickly! Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 3

4 Our preparation for this market Alberdingk Boley has developed w/b UV-curable binders since many years w/b UV acrylic dispersions Alberdingk LUX 515, LUX 855, etc. w/b UV polyurethane-acrylic dispersions Alberdingk LUX 560, LUX 572, LUX399, LUX484, etc. w/b UV polyester-polyurethane dispersions Alberdingk LUX 260, LUX 250, LUX221, and LUX 220, etc. Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 4

5 Challenges for UV-curable dispersions in pigmented coatings High UV reactivity in certain colours (yellow, orange,etc.) High chemical resistance (kitchen) High scratch resistance Good adhesion properties Alberdingk LUX220 can achieve! Strong physical drying prior to UV-curing Much Higher Scratch resistance High resistances even in shadow areas Safer handling of coated parts High UV-crosslinking density Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 5

6 Polymer structure of ALBERDINGK LUX 220 /UV-curable polyurethanes Stabilized polymer particle + Diisocyanate urethane group (hard segment) chain extender urea group (hard segment) dimethylolpropionic acid acid group (hard segment) UV reactive segment e.g. 2-, 3-, 4-funcional Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 6

7 ALBERDINGK LUX 220 technical data solvent-free, hard-elastic, UV-curable polyester-polyurethane dispersion Solids content: % ph-value: Viscosity: mpa.s MFFT: Hardness prior to UV cure: Hardness after UV cure: 0 ᵒC approx. 50 sec. approx. 180 sec. Suitable for crosslinking with polyisocyanates (dual-cure) Suggested for transparent and pigmented coating system Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 7

8 Formulate with ALBERDINGK LUX 220 /film formation, curing process IR 1.Physical drying Water molecule /wb systems Water molecule Polymerparticle Physically dry lacquer-film Substrate Substrate Highly crosslinked lacquer-film Substrate Polymer particle Photoinitiator UV R Substrate 2. UV-curing /wb systems Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 8

9 Formulate with ALBERDINGK LUX 220 /film formation_reaction mechanism Water based UV-Systems: IR Water needs to evaporate completely before UV curing UV-light cracks photoinitiator into radicals Polymers contain C=C double bonds which crosslink with those radicals UV R Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 9

10 Formulate with ALBERDINGK LUX 220 /UV-wave length used for curing IR UV R curing range (taken from: ) Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 10

11 Formulate with ALBERDINGK LUX 220 /photoinitialors For surface curing, absorption spectrum: nm wavelength IR Benzophenon (BP), (Noted: yellowing tendency / smell) Hydroxy-cyclohexyl-phenyl-ketone e.g. Irgacure184 Benzophenon + Hydroxy-cyclohexyl-phenyl-ketone : e.g. Irgacure500 For depth curing, absorption spectrum: nm wavelength w/b dispersion of Bis-Acyl-Phosphine Oxide (BAPO) e.g. Irgacure819 DW UV R Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 11

12 Formulate with ALBERDINGK LUX 220 /curing conditions Pre-drying: min at 50 C, convection dryer Feed: 5m/min (depending on number of lamps) UV-curing: Pigmented 1 x Ga-doped lamp per 120 W/cm 1 x Ga-doped + Hg-doped lamp, each per 120 W/cm Clear 1 x Hg-doped lamp, 120 W/cm Hg lamps: for transparent and surface cure Ga lamps: for pigmented depth cure Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 12

13 Formulate with ALBERDINGK LUX 220 /formulation proposals UV 220/01 (white) and UV 220/02 (yellow) Po s. Raw Materials Amount (UV ) Amount (UV 220/02) Supplier 1 ALBERDINGK LUX 220 VP Alberdingk Boley 2 Tego Foamex Evonik Tego Chemie 3 Tego Airex 902 W Evonik Tego Chemie 4 Byk BYK Chemie 5a Pigment paste white Quantity of TiO 2 : 17.94%, Alberdingk-formulation CT-231 5b Pigment paste yellow AQ Quantity of yellow: 7.00%, Ralston Color & Coatings 6 Dowanol DPM * Dow Chemical 7 Water (deion.) * Irgacure BASF 9 Irgacure 819 DW BASF 10 Rheolate 288 (50% in EDG/water) Elementis Total * Pos. 6~7: pre-mixing before adding in Curing conditions: Pre-drying: min at 50 C, convection dryer Feed: 5 m/min UV-curing: 1 x Ga-doped lamp per 120 W/cm 1 x Ga-doped + Hg-doped lamp, each per 120 W/cm Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 13

14 UV220/01 white & UV220/02 yellow pigmented lacquers /chemical resistance 5=best Ethanol (48%) NH4OH (10%) Water (deion.) Coffee (4%) Tea (1%) Red wine Cola Na2CO3 (10%) Fatty acid UV 220/02 (yellow) UV 220/01 (white) Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 14

15 UV220/01 white & UV220/02 yellow pigmented lacquers /chemical resistance 5=best LUX220 vs. LUX481, and competitor Comp.1 [yellow] LUX 481 [yellow] LUX 220 [yellow] Comp.1 [white] LUX 481 [white] LUX 220 [white] Ethanol [48%] 1h Coffee (16h) Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 15

16 ALBERDINGK LUX 220 /formulation proposals UV 220/05 (transparent high gloss) Pos. Raw Materials Amount (UV ) Supplier 1 ALBERDINGK LUX Alberdingk Boley 2 Water (deion.) * Butyl cellosolve (BG) * 2.00 (Commercial) 4 Tego Foamex Evonik Tego Chemie 5 Irgacure BASF 6 Tafigel PUR Münzing Chemie 7 Byk BYK Chemie Total Curing conditions: * Pos. 2~3: pre-mixing before adding in Pre-drying: min at 50 C, convection dryer Feed: 5 m/min UV-curing: 1 x Hg-doped lamp per 90 W/cm Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 16

17 UV 220/05 transparent high gloss lacquer /hardness LUX220 vs. LUX250, LUX399, LUX484 Pencil Hardness (MITSU-BISHI) Wet 100g/m 2 x 2layers on walnut veneer Pendulum Hardness Wet 100um on glass Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 17

18 UV 220/05 transparent high gloss lacquer /chemical resistance Chemical resistance of LUX220 high-gloss clear lacquer Wet 100g/m 2 x 2layers on walnut veneer Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 18

19 UV 220/05 transparent high gloss lacquer /abrasion resistance Loss /mg LUX220 vs. several w/b UV, and 100% UV binders Taber 5130 Abrasion Tester Test condition: CS-17 Wheel x 2, 1kg / wheel 1000 cycles epoxy acrylic Urethane/ polyester acrylic Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 19

20 UV 220/05 transparent high gloss lacquer /RCA paper wear resistance, on ABS LUX220 vs. several w/b UV binders LUX220 LUX221 LUX484 LUX260 LUX250 LUX255 LUX399 CONTROL Film building-up: Substrate: Black ABS Primer: wet 80g/m 2 x 1layer of AC 2742 white lacquer Finish: wet 80g/m 2 x 1layer of w/b UV glossy lacquer Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 20

21 UV 220/05 transparent high gloss lacquer /RCA paper wear resistance, on ABS Test results : No visible damage No visible damage Abrasive damage, but no substrate exposed Substrate exposed No visible damage Substrate exposed Abrasive damage, but no black exposed Substrate exposed Test condition: 175g load (unit. Circles) Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 21

22 UV 220/05 transparent high gloss lacquer /anti-cigarette burnig, on pine wood LUX220 vs. LUX250, LUX399, LUX484 LUX399 LUX250 LUX484 LUX220 Comparison of resistance to cigarette burns on LUX220, LUX484, LUX250 and LUX399 clear lacquers (Wet 100g/m 2 x 2layers, on pine wood) Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 22

23 Formulate with ALBERDINGK LUX 220 /formulation proposal UV 220/05-szmodt22 (transparent high gloss with improving film appearance) Pos. Raw Material Amount (UV220/05-szmodt22) Supplier 1 Alberdingk LUX Alberdingk Boley 2 Tego Foamex Evonik Tego Chemie 3 Twin Evonik Tego Chemie 4 Alberdingk LUX Alberdingk Boley 5 Water (deion.) * Propylene Glycol * 4.00 (commercial) 7 Butyl Cellosolve * 2.00 (commercial) 8 DMEA * 0.20 (commercial) 9 Glide Evonik Tego Chemie 10 Irgacure BASF Total * Pos.5~8: Pre-mixing before adding Curing conditions: Pre-drying: min at 50 C, convection dryer Feed: 5 m/min UV-curing: 1 x Hg-doped lamp per 90 W/cm Initial vis.:47.9 KU 60⁰ gloss:89 % (100µm wet on contrast paper) Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 23

24 UV 220/05-szmodt22 transparent high gloss lacquer /Improvement of film appearance on ABS Photos were taken by the USB Digital Microscope, 200X Bad Good Film Appearance of LUX220 High-Gloss Clear Lacquer on ABS Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 24

25 UV 220/05-szmodt22 transparent high gloss lacquer /Adhesion on ABS 0 is best LUX220 vs. several w/b UV binders LUX220 LUX250 LUX260 LUX484 LUX399 storing in RT x 24 before test Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 25

26 UV 220/05-szmodt22 transparent high gloss lacquer /adhesion on PVC sheet (extremely slippery surface with artificial wood grain) 0 = best LUX250 LUX484 LUX220 : CUR995 =3:1 Initial Adhesion Adhesion after boiling x1h + RTx2 Initial adhesion after boiling x 1h Initial adhesion Adhesion after boiling x1h + RTx2 Initial adhesion after boiling x 1h Adhesion after70ᵒcx24h Adhesion after70ᵒcx24h Adhesion of several w/b UV High-Gloss Clear Lacquers on PVC Sheet Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 26

27 Formulate with ALBERDINGK LUX 220 /formulation proposal UV 220-sz2-t3 (matt with better anti-settling) Pos. Raw Material Amount (UV220-sz-t3) Supplier 1 Alberdingk LUX Alberdingk Boley 2 Tego Foamex Evonik Tego Chemie 3 Tego Twin Evonik Tego Chemie 4 Tego Glide Evonik Tego Chemie 5 Tego Visplus Evonik Tego Chemie 6 Tego Visplus Evonik Tego Chemie 7 Butyl Cellosolve* 5.00 (commercial) 8 Water(deion)* Irgacure BASF 10 TS100 paste ** Total *Pos. 7~8: pre-mixing before adding in Initial Vis.:62.4KU 60⁰gloss:9 %(100µm wet on contrast paper) Curing conditions: Pre-drying: min at 50 C, convection dryer Feed: 5 m/min UV-curing: 1 x Hg-doped lamp per 90 W/cm Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 27

28 Formulate with ALBERDINGK LUX 220 /formulation proposal UV 220-sz2-t3 (matt) ** TS100 paste Pos. Raw Material Amount (TS100 paste) Supplier 1 Diethylene Glycol (EDG) (commercial) 2 Tego Foamex Evonik Tego Chemie 3 Tego Dispers Evonik Tego Chemie 4 DMEA 0.50 (commercial) 5 Water (deion.) TS Evonik 7 Aerosil R Evonik 8 DMEA 0.50 (commercial) 9 Tego Foamex Evonik Tego Chemie Total Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 28

29 UV 220-sz2-t3 transparent and matt /settling resistance Stored at RT x 7d, out of direct sunlight settling 1% of Aerosil R816 Control of without Aerosil R816 Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 29

30 UV 220-sz2-t3 transparent and matt /chemical resistance 5=best, Wet 100g/m 2 x 2layers on walnut veneer Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 30

31 PVC floor application /DEMO panel of matt clear coating on PVC sheet " Outstanding chemical and stain resistance " Iodine resistant " Shoe polish resistant " Excellent adhesion properties " Very high abrasion resistance (approx. 10 mg on ABS, 300µm wet) " Hard but flexible *Kiwi black shoe polish **white spirit Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 31

32 Application of ALBERDINGK LUX 220 on wood furniture /DEMO panel of high gloss clear coating on pine Substrate:Pine wood Wiping stain: LUR 3/DB Linseed oil Sanding sealer: AC 3630 Glossy clear finish: LUX 220 Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 32

33 Application of ALBERDINGK LUX 220 on wood furniture /DEMO panel of matt white pigmented coating on MDF Substrate: MDF MDF white filler: AC 2782 White topcoat: LUX 220 Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 33

34 Application of ALBERDINGK LUX 220 on wood furniture /DEMO panel of high gloss clear coating on birch/oak veneer Substrate: Birch/oak veneer First sealer: AC 3630, or AC 2742 Wiping stain: LUR 3/DB linseed oil Sanding primer: AC 3630 Spray shading stain: AC 3630, or CUR995 Top coating: LUX 220 Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 34

35 Highlights of ALBERDINGK LUX 220 " Very high hardness & scratch resistance prior to UV cure " Outstanding chemcial and stain resistances " Highly scratch resistant immediately after UV-curing " Excellent abrasion and scratch resistance " Crosslinkable with polyisocyanates for dual cure coatings " Easy to formulate in transparent and pigmented systems " Excellent adhesion properties on different substrates Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 Chart 35

36 Thank You for Your Attention! For more details, please contact with us. André Harmsen Senior Technical Marketing Manager SEA Alberdingk Resins (Shenzhen) Co., Ltd. ALBERDINGK LUX220 36