Advanced Materials. Raising performance in composites bonding

Transcription

1 Advanced Materials Raising performance in composites bonding Quarter, 205

2 Table of contents Choosing adhesives for composites assembly Araldite adhesives A comprehensive product range Typical mechanical properties Epoxy adhesives Methacrylate adhesives Polyurethane adhesives Selection for CFRP bonding Araldite 205 Araldite 203 Araldite AW 4858 / HW 4858 Araldite AW 4859 / HW 4859 Araldite Araldite 2048 Compared properties Selection for specific requirements Araldite solutions for transportation For railway industry For automotive industry Advanced Materials 2

3 Choosing adhesives for composites assembly Adhesives are the st class choice!! Assembly of similar and dissimilar substrates!! Weight reduction compared to other mechanical assembly!! Reduce the stress concentration!! Superior fatigue resistance!! Easily processable (manually / automatically)!! No damage to the substrates (no holes)!! Sealed joints!! Compensation of dimensional tolerances!! Aesthetic aspect Requirements for composites bonding!! Good adhesion to the substrates!! High mechanical resistance!! High peel resistance!! High temperature resistance!! High toughness!! Good chemical / environmental resistance!! Low temperature cure Advanced Materials 3

4 Araldite adhesives Huntsman s comprehensive range of epoxy, polyurethane, methyl methacrylate and phenolic adhesives meets a wide variety of application requirements across industries. Whenever long open times for large area applications, fast-curing adhesives for early removal from fixtures and rapid through-put, resistance to high temperature, water and chemicals, thixotropy for gap-filling or vertical applications, toughness and impactresistance or elasticity to cope with different thermal expansions when bonding larger structures of dissimilar materials are needed, many customers have been relying on Araldite product capabilities. Our adhesives are available in different packaging including easy-to-use cartridges and working packs for manual applications or hobbocks and drums for higher volume applications. As a pioneer in the adhesive technologies, Huntsman keeps on updating the Araldite range to meet the newest industry trends and requirements. On top we ensure close proximity and support to our customers through an extended distribution network. Advanced Materials 4

5 Araldite adhesives Typical mechanical properties Advanced Materials 5

6 Araldite adhesives Epoxy adhesives Main benefits!! Excellent adhesion to metals and thermoset composites!! High strength and high stiffness!! High creep resistance!! High fatigue resistance!! High temperature resistance (up to 20 C)!! Excellent chemical resistance and long-term durability!! Low shrinkage over curing Advanced Materials 6

7 Araldite adhesives Methacrylate adhesives Main benefits!! Excellent adhesion to metals, thermoset composites and most thermoplastics!! Good adhesion with minimum surface preparation!! Tolerant to mix ratio variations!! Mechanical properties from rigid to flexible!! Wide spectrum of available reactivity!! Optimum ratio open time / cure time!! Good chemical resistance and long term durability!! Possibility for hardener lacquer and no mix methods Advanced Materials 7

8 Araldite adhesives Polyurethane adhesives Main benefits!! Excellent adhesion to most composite materials and plastics!! Good adhesion to metals!! Mechanical properties from rigid to flexible!! High fatigue resistance!! Good long-term durability Advanced Materials 8

9 Araldite 205 2K epoxy adhesive (: v/v) Main properties!! High mechanical performance!! Gap filling!! Toughened!! Bonds well dissimilar substrates Benefits!! Ideal for dynamic loading!! Good thermal resistance (Tg! 65 C)!! Good impact resistance Advanced Materials 9

10 Araldite 203 2K epoxy adhesive (: v/v) Main properties!! High mechanical performances!! Mat black!! Toughened!! Multipurpose Benefits!! Ideal for big parts!! Good thermal resistance (Tg! 65 C)!! Good adhesion to polyamide Advanced Materials 0

11 Araldite AW 4858 / HW K epoxy adhesive (2: v/v) Main properties!! High LSS on metal and FRP!! High peel resistance, toughened!! Shiny black, gap filling!! Multipurpose Benefits!! Ideal for big CFRP parts assembly (open time > 60 min)!! Outstanding resilient bondlines!! Ideal for dissimilar substrates bonding, impact resistant Advanced Materials

12 Araldite AW 4859 / HW K epoxy adhesive (2: v/v) Main properties!! High LSS on metals and FRP!! High toughness!! Black, gap filling!! Multipurpose Benefits!! Resistant up to 45 C (Tg! 25 C)!! Outstanding combination of high toughness and high mechanical performance!! Outstanding chemical resistance Advanced Materials 2

13 Araldite K polyurethane adhesive (: v/v) Main properties!! High LSS on metal and FRP!! Gap filling!! Flexible (> 40% elongation)!! Multipurpose Benefits!! Ideal for big parts bonding!! High performance polyurethane, flexible!! Tg! 28 C Advanced Materials 3

14 Araldite K MMA adhesive (0: v/v) Main properties!! High LSS on metal and most of thermoplastics!! Gap filling!! Flexible (>90% elongation)!! Multipurpose Benefits!! Quick setting!! Ideal for composite / thermoplastic assemblies!! Good balance of flexibility and temperature resistance (Tg! 65 C) Advanced Materials 4

15 Araldite adhesives for CFRP bonding Performance on composites Lap shear strength at 23 C (MPa) - ISO 4587 Advanced Materials 5

16 Araldite adhesives for CFRP bonding Performance * versus temperature Lap shear strength (MPa) - ISO 4587 * Lap shear strength on aluminum Advanced Materials 6

17 Araldite adhesives for CFRP bonding Performance on metals Lap shear strength at 23 C (MPa) - ISO 4587 Advanced Materials 7

18 Araldite adhesives for CFRP bonding Strength on aluminum : comparison to epoxy adhesive references Peel strength (N/mm) / Lap shear strength (MPa) / Service temperature (LSS > 5 MPa) () 2K rigid epoxy - RT cure (2) K epoxy - 80 C cure Advanced Materials 8

19 Araldite adhesives for CFRP bonding Assembly of composites : main properties overview Araldite 205 Araldite 203 Araldite AW 4858 / HW 4858 Araldite AW 4859 / HW 4859 Araldite Araldite 2048 Advanced Materials 9

20 Araldite adhesives for CFRP bonding Assembly of composites : main properties overview Product designation LSS performance Peel performance Thermal resistance Chemical resistance Elongation at break Handling time RT curing Araldite 205 Araldite 203 Araldite AW 4858 / Hardener HW 4858 Araldite AW 4859 / Hardener HW 4859 Araldite Araldite 2048 Ideal Recommended Advanced Materials 20

21 Selection for specific requirements High service temperature!! Araldite AW 450 / Hardener HW 45 LSS () > 5 MPa at 200 C Flame retardant properties!! Araldite 2033 UL 94 V0, F2 & I2 NF F 6-0/02 and EN tested Fast curing epoxy!! Araldite AW 20 / Hardener HW min gel time - 60 min handling time Fast curing methacrylates!! Araldite 202, Araldite min gel time, 5-20 min handling time, tolerant to surface preparation () LSS : lap shear strength on aluminum (ISO 4587) Advanced Materials 2

22 Araldite solutions for railway industry Advanced Materials 22

23 Lights and control boxes Trackside traffic control box Signal light box Advanced Materials 23

24 Lights and control boxes Body assembly, lens assembly Your needs > Very good weathering resistance > Electrical insulation > Good thermal resistance > Flame retardancy Our solutions Araldite 203 Araldite 205 Araldite 202 Araldite 2022 Araldite 2033 Araldite Non exclusive selection Ask our experts for other solutions Trackside traffic control box Signal light box Advanced Materials 24

25 Carriage structure Carriage structure Advanced Materials 25

26 Carriage structure Frame and ceiling reinforcement Your needs > Improve the fatigue resistance of the metal assemblies > Reduce overall weight of structure > Prevent and reduce corrosion > Improve stiffness and shock resistance of the assemblies Our solutions Araldite 204- Araldite 205 Araldite AV 70 Araldite AV 4600 Araldite AW 4858 / HW 4858 Araldite AW 4859 / HW 4859 Non exclusive selection Ask our experts for other solutions Carriage structure Advanced Materials 26

27 Roofs, doors, floors and semi-structural bonding Outer / inner door Window Floor coverings HVAC Air dam Advanced Materials 27

28 Roofs, doors, floors and semi-structural bonding Floor coverings, seats attachment to floor, doors frames, hinges, HVAC Your needs > Multimaterial assemblies > Ease of application > Toughness, shock resistance > Aesthetical design Our solutions Araldite 420 Araldite 203 Araldite 205 Araldite Araldite AW 4858 / HW 4858 Araldite AW 4859 / HW 4859 Non exclusive selection Ask our experts for other solutions Outer / inner door Window Floor coverings HVAC Air dam Advanced Materials 28

29 Insulated rail joints Rail joint Advanced Materials 29

30 Insulated rail joints Insulated rail joints Your needs > Very good weathering resistance > Fast curing > High fatigue and vibration resistance > Electrical insulation Our solutions Araldite 203 Araldite 204- Araldite 205 Araldite 203 Araldite Araldite AW 20 / HW 295 Non exclusive selection Ask our experts for other solutions Rail joint Advanced Materials 30

31 Interior furnishings Driving cabin Window Luggage carrier Table / chair Kitchen and sanitary blocks Advanced Materials 3

32 Interior furnishings Fold tables, equipment boxes on carriages, handles, mirrors, luggage racks, ceiling liners Your needs > Multimaterial assemblies > Reduce overall weight > Ease of application > Flame retardancy > Aesthetical design Our solutions Araldite 205 Araldite 2022 Araldite Araldite 2033 Araldite Araldite 2048 Non exclusive selection Ask our experts for other solutions Driving cabin Window Luggage carrier Table / chair Kitchen and sanitary blocks Advanced Materials 32

33 Brake bonding Brake system Advanced Materials 33

34 Brake bonding Brake shoes, brake pads, dip-coating Your needs > Very high temperature resistance > Very good adhesion to friction material > Very good adhesion to steel and aluminum Our solutions Araldite 64- Araldite 7 Non exclusive selection Ask our experts for other solutions Brake system Advanced Materials 34

35 Sandwich panels laminating and assembly Sandwich panels Advanced Materials 35

36 Sandwich panels laminating and assembly Wall cabinets, partition walls, panelling Your needs > Multimaterial assemblies > Long open time for large parts laminating > Controlled rheology > Fast curing for panels assembly > Design freedom Our solutions For laminating Araldite AW 46 / HV 957 XB / Arathane HY 56- XD 4465 / Arathane HY 56- For assembly Araldite 420 Araldite 203 Araldite 205 Araldite Araldite 2033 Araldite AW 4858 / HW 4858 Non exclusive selection Ask our experts for other solutions Sandwich panels Advanced Materials 36

37 Electrical components assembly Transformer Advanced Materials 37

38 Electrical components assembly Transformers, drivers control panel, cables Your needs > Multimaterial assemblies > Good thermal resistance > Weathering resistance > Electrical insulation Our solutions Araldite 203 Araldite 204- Araldite 2033 Agomet F 305 A/B Agomet F 330 Non exclusive selection Ask our experts for other solutions Transformer Advanced Materials 38

39 Araldite solutions for automotive industry Advanced Materials 39

40 Structural / semi-structural assemblies Bumpers Motor parts Door modules Structural modules Advanced Materials 40

41 Structural / semi-structural assemblies Door modules, composite shells, transmission shafts, structural modules Your needs > Improve the fatigue resistance of the metal assemblies > Reduce the overall structure weight > Prevent and reduce metal corrosion > Uniform stress distribution and larger stress bearing areas > High toughness > Gap filling > Very high fatigue, and thermal shock resistance > Excellent moisture and chemical resistance > Easy automation Our solutions Araldite 204- Araldite 205 Araldite 203 Araldite Araldite AW 4858 / HW 4858 Araldite AW 4859 / HW 4859 Non exclusive selection Ask our experts for other solutions Bumpers Motor parts Door modules Structural modules Advanced Materials 4

42 Exterior finishers / interior modules Cockpit Seats Door capping Exterior trims Spoiler Advanced Materials 42

43 Exterior finishers / interior modules Spoiler, door capping, side blade, exterior trim, seat, cockpit Your needs > Multimaterial assemblies > Ease of application > Toughness, shock resistance > Aesthetical design > Weathering resistance Our solutions Araldite 202 Araldite 205 Araldite 202 Araldite Araldite 2048 Agomet F300 A/B Non exclusive selection Ask our experts for other solutions Cockpit Seats Door capping Exterior trims Spoiler Advanced Materials 43

44 Lights / headlamps Headlamps, brake lights and reflector housings Advanced Materials 44

45 Lights / headlamps Headlights, brake lights, reflector housings Your needs > Multimaterial assemblies > Good adhesion to glass, PC, acrylics and thermoplastics > Minimal fogging > Aesthetical design, transparent adhesives Our solutions Araldite 208 Araldite 202 Araldite 2022 Araldite 2026 Araldite Non exclusive selection Ask our experts for other solutions Headlamps, brake lights and reflector housings Advanced Materials 45

46 Brake / clutch Brake shoes, pads and clutch friction material Advanced Materials 46

47 Brake / clutch Brake shoes, brake pads, friction lining material for clutches, dip-coating Your needs > Very high temperature resistance > Very good adhesion to friction material > Very good adhesion to steel and aluminum Our solutions Araldite 64- Araldite 7 Non exclusive selection Ask our experts for other solutions Brake shoes, pads and clutch friction material Advanced Materials 47

48 Electronics Electronics Advanced Materials 48

49 Electronics Control units, climate controls, navigation systems Your needs > Multimaterial assemblies (copper, ferrite, PCB ") > Good thermal resistance > Weathering resistance > Electrical insulation > Low outgasing > Flame retardancy Our solutions Araldite 204- Araldite 2033 Araldite 2048 Araldite Agomet F 300 A/B Araldite F 330 Non exclusive selection Ask our experts for other solutions Electronics Advanced Materials 49

50 Filters Filters Advanced Materials 50

51 Filters Hydraulic filters, oil filters, air filters Your needs > High chemical resistance > High temperature resistance > Self-levelling adhesives Our solutions Araldite 204- XD 4567 / XD 4568 Araldite AW 4752 / HW 4753 XB / Arathane HY 56- Non exclusive selection Ask our experts for other solutions Filters Advanced Materials 5

52 Repair / aftermarket Repair Advanced Materials 52

53 Repair / aftermarket Cracks repair, metal bonding, SMC bonding Your needs > Multimaterial assemblies > Very good weathering resistance > High fatigue and vibration resistance > Easy to use packaging Our solutions Araldite 20 Araldite 203 Araldite 2022 Araldite Araldite 2048 Araldite AW 20 / Hardener HW 295 Non exclusive selection Ask our experts for other solutions Repair Advanced Materials 53

54 Keep our products at your fingertips Find the right adhesive to fulfill your needs. Learn more about our products and access useful technical information. Mobile app on smartphone Select immediately the right adhesive for your specific need and contact a distributor. View our latest releases on SlideShare Find and download our latest brochures and white papers. Advanced Materials 54

55 For more information Europe Huntsman Advanced Materials (Switzerland) GmbH Klybeckstrasse 200 P.O. Box Basel Switzerland Tel Fax Advanced Materials 55

56 Legal Disclaimer Copyright 205 Huntsman Corporation or an affiliate thereof. All rights reserved. The use of the symbol herein signifies the registration of the associated trademark in one or more, but not all, countries. While the information and recommendations included in this publication are, to the best of Huntsman s knowledge, accurate as of the date of publication, nothing contained herein is to be construed as a representation or warranty of any kind, express or implied. Advanced Materials