SAFETY DATA SHEET. SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier Product name: Crude MCHM Product No.: EAN , P , P18717EA, P18717ET, E Relevant identified uses of the substance or mixture and uses advised against Identified uses: Industrial chemical., Fuel Blending, Mining Uses advised against: Details of the supplier of the safety data sheet Manufacturer / Supplier Eastman Chemical Company 200 South Wilcox Drive Kingsport, TN US Visit our website at or emnmsds@eastman.com Emergency telephone number: For emergency health, safety, and environmental information, call or For emergency transportation information, in the United States: call CHEMTREC at or call SECTION 2: Hazards identification Hazard Classification: Health Hazards Acute toxicity (Oral) Category 4 Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2A OSHA Specified Hazards: not applicable Warning label items including precautionary statement: Pictogram: Signal Words: WARNING! COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 1/11

2 Hazard Statement(s): H302: Harmful if swallowed. H315: Causes skin irritation. H319: Causes serious eye irritation. Precautionary Statement: Prevention: Response: Disposal: P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P280: Wear protective gloves/protective clothing/eye protection/face protection. P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330: Rinse mouth. P302+P352: IF ON SKIN: Wash with plenty of soap and water. P332+P313: If skin irritation occurs: Get medical advice/attention. P362: Take off contaminated clothing and wash before reuse. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. P501: Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Hazard(s) not otherwise classified (HNOC): SECTION 3: Composition/information on ingredients Substances / Mixtures General information: Chemical name Concentration Additional identification Notes 4-methylcyclohexanemethanol 68-89% CAS-No.: (methoxymethyl)cyclohexanemethan ol 4-22% CAS-No.: w ater 4-10% CAS-No.: methyl 4- methylcyclohexanecarboxylate 5% CAS-No.: % CAS-No.: methanol 1% CAS-No.: # 1-2% CAS-No.: * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. # This substance has w orkplace exposure limit(s). SECTION 4: First aid measures Description of first aid measures COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 2/11

3 Inhalation: Eye contact: Skin contact: Ingestion: Most important symptoms and effects, both acute and delayed: Treat symptomatically. Move to fresh air. Get medical attention if symptoms persist. Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Get medical attention. In case of irritation from airborne exposure, move to fresh air. Get medical attention if symptoms persist. Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash contaminated clothing before reuse. Destroy or thoroughly clean contaminated shoes. Seek medical advice. May irritate and cause redness and pain. Indication of any immediate medical attention and special treatment needed Hazards: Treatment: Treat symptomatically. SECTION 5: Firefighting measures General Fire Hazards: Extinguishing media Suitable extinguishing media: Unsuitable extinguishing media: Special hazards arising from the substance or mixture: Advice for firefighters Special fire fighting procedures: Special protective equipment for fire-fighters: Water spray. Dry chemical. Carbon Dioxide. Alcohol foam. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures: Environmental Precautions: Wear appropriate personal protective equipment. Avoid release to the environment. COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 3/11

4 Methods and material for containment and cleaning up: Notification Procedures: Absorb spill with vermiculite or other inert material, then place in a container for chemical waste. Large Spillages: Flush spill area with water spray. Prevent runoff from entering drains, sewers, or streams. Dike for later disposal. In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. SECTION 7: Handling and storage: Precautions for safe handling: Conditions for safe storage, including any incompatibilities: Specific end use(s): Avoid contact with eyes, skin, and clothing. Do not taste or swallow. Use only with adequate ventilation. Wash thoroughly after handling. Keep container closed. Keep away from food, drink and animal feeding stuffs. Industrial chemical. Fuel Blending Mining SECTION 8: Exposure controls/personal protection Control Parameters Occupational Exposure Limits Country specific exposure limits have not been established or are not applicable unless listed below. Chemical name type Exposure Limit Values Source methanol Exposure controls Appropriate engineering controls: TWA 200 ppm US. ACGIH Threshold Limit Values ( ) STEL 250 ppm US. ACGIH Threshold Limit Values ( ) PEL 200 ppm 260 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) ( ) Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment General information: Eye/face protection: Eye bath. Safety shower. Washing facilities. Wear safety glasses with side shields (or goggles). Wear a full-face respirator, if needed. COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 4/11

5 Skin protection Hand Protection: Other: Respiratory Protection: Hygiene measures: Environmental Controls: Wear chemical-resistant gloves, footwear, and protective clothing appropriate for the risk of exposure. Contact health and safety professional or manufacturer for specific information. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR 1152, January 8, Respirator type: Airpurifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister. Contact health and safety professional or manufacturer for specific information. Observe good industrial hygiene practices. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties Appearance Physical state: Form: Color: Odor: Odor Threshold: ph: liquid liquid Freezing Point: 0 C Colorless Alcohol, licorice 0.15 ppb Boiling Point: 180 C Flash Point: Evaporation Rate: Flammability (solid, gas): Flammability Limit - Upper (%) : Flammability Limit - Lower (%) : Vapor pressure: Vapor density (air=1): Specific Gravity: Solubility(ies) Solubility in Water: Solubility (other): Partition coefficient (n-octanol/water): Autoignition Temperature: Decomposition Temperature: Dynamic viscosity: C (Setaflash Closed Cup) Not determined. 24 mbar (20 C) < 1 (estimated) Appreciable Thermal stability not tested. Low stability hazard expected at normal operating temperatures. Kinematic viscosity: Not determined. COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 5/11

6 Explosive properties: Oxidizing properties: SECTION 10: Stability and reactivity Reactivity: Chemical Stability: Possibility of Hazardous Reactions: Conditions to Avoid: Incompatible Materials: Hazardous Decomposition Products: Materials containing similar structural groups are normally stable. Not fully evaluated. None at ambient temperatures. Strong oxidizing agents. Carbon Dioxide. Carbon Monoxide. SECTION 11: Toxicological information Information on likely routes of exposure Inhalation: Ingestion: Skin contact: Eye contact: Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Information on toxicological effects Oral Dermal Oral LD-50: (Rat): 825 mg/kg Dermal LD-50: (Rat): > 2,000 mg/kg Inhalation methanol Repeated dose toxicity LC50 (Rat, 6 h): > 2.91 mg/l LC50 (Rat, 4 h): ppm LC50 (Rat, 6 h): > 1.25 mg/l NOAEL (Rat, Dermal Study): 2,000 mg/kg COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 6/11

7 Skin Corrosion/Irritation (Rabbit, 4 h): moderate Serious Eye Damage/Eye Irritation 4- methylcyclohexanemetha nol methanol 1,4- cyclohexanedimethanol (Rabbit): moderate (Rabbit): moderate Read-across from a similar material (Rabbit): slight to moderate (Rabbit, 24 h): Severe Respiratory or Skin Sensitization Skin Sensitization (Guinea Pig): non-sensitizing Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Toxicity to reproduction OECD Test No. 421: Reproduction/Developmental Toxicity Screening Test (Rat, Female.); NOAEL: 1,124 mg/kg; Ingestion OECD Test No. 421: Reproduction/Developmental Toxicity Screening Test (Rat, Male and Female); NOAEL: 479 mg/kg; Ingestion Developmental toxicity Rat; NOAEL: 1,000 mg/kg; Ingestion; OECD Test No. 414: Prenatal Developmental Toxicity Study; Remarks: value listed is NOEL COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 7/11

8 Germ Cell Mutagenicity In vitro In vivo Salmonella typhimurium assay (Ames test): negative Chromosomal aberration (Mammalian Bone Marrow Chromosome Aberration Test) oral: gavage (Rat): negative Specific Target Organ Toxicity - Single Exposure Not classified. Specific Target Organ Toxicity - Repeated Exposure Not classified. Aspiration Hazard Other effects: SECTION 12: Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Aquatic Invertebrates LC-50 (Fathead Minnow, 96 h): 57.4 mg/l EC-50 (daphnid, 48 h): 98.1 mg/l Chronic hazards to the aquatic environment: Fish Aquatic Invertebrates NOEC (Fish): >= mg/l Toxicity to Aquatic Plants methanol EC-50 (Alga, 72 h): > mg/l NOEC: (Alga, 72 h): > mg/l EC-50 (Algae (Pseudokirchneriella subcapitata), 96 h): 22,000 mg/l COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 8/11

9 EC-50 (Alga, 72 h): > mg/l NOEC: (Alga, 72 h): >= mg/l Persistence and Degradability Biodegradation Inherently biodegradable BOD/COD Ratio 2.8 % Bioaccumulative Potential Bioconcentration Factor (BCF) Potential to bioaccumulate is low. Bioconcentration Factor (BCF): 4.45 (estimated) Partition Coefficient n-octanol / water (log Kow) Log Kow: 2.29 methanol Log Kow: Log Kow: C Mobility in Soil: Known or predicted distribution to environmental compartments Log Koc: (QSAR model) Other Adverse Effects: SECTION 13: Disposal considerations Waste treatment methods General information: Disposal methods: Dispose of waste and residues in accordance with local authority requirements. Incinerate. SECTION 14: Transport information Important Note: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Consult your company's Hazardous Materials/Dangerous Goods expert for information specific to your situation. COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 9/11

10 DOT Class not regulated IMDG - International Maritime Dangerous Goods Code Class not regulated IATA Class not regulated SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture.: This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. WHMIS (Canada) Status: controlled WHMIS (Canada) Hazard Classification: D/2/B SARA Hazard Classification(s): immediate (acute) health hazard US EPCRA (SARA Title III) Section Toxic Chemical List METHANOL OSHA: hazardous TSCA (US Toxic Substances Control Act): All components of this product are listed on the TSCA inventory. Any impurities present in this product are exempt from listing. DSL (Canadian Domestic Substances List) and CEPA (Canadian Environmental Protection Act): One or more components of this product are not listed on the DSL. In Canada, its use is restricted to research and development purposes only. MITI (Japanese Handbook of Existing and New Chemical Substances): One or more components or reactants of this product are not listed in the Handbook. In Japan, its use is restricted to research and development purposes only. ECL (Korean Toxic Substances Control Act): One or more components of this product are not listed on the Korean inventory. In Korea, its use is restricted to research and development purposes only. SECTION 16: Other information HMIS Hazard Ratings: Health - 2, Flammability - 1, Chemical Reactivity - 0 COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 10/11

11 HMIS rating involves data interpretations that may vary from company to company. They are intended only for rapid, general identification of the magnitude of the specific hazard. To deal adequately with the safe handling of this material, all the i nformation contained in this MSDS must be considered. Revision Information: Key literature references and sources for data: Training information: Not relevant. Issue Date: 06/05/2015 SDS No.: Disclaimer: This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment. COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 11/11