Material Safety Data Sheet

Transcription

1 Section 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Product information Trade name Use Company Telephone : Telefax : Emergency telephone : number Section 2 HAZARDS IDENTIFICATION : TGIC : Cross-linking agent for powder coating systems : Niutang Town Wujin, Changzhou Jiangsu, China Toxic by inhalation and if swallowed. Risk of serious damage to eyes. May cause sensitization by skin contact. May cause heritable genetic damage. Harmful: danger of serious damage to health by prolonged exposure if swallowed. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Section 3 COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature Trifunctional epoxy resin substance CAS-No. : EINECS-NR. : Hazardous components Chemical Name CAS-No. Symbol(s): R-phrase(s) Concentration [%] 1,3,5-tris(oxyranylmethyl)- 1,3,5-triazine- 2,4,6(1H,3H,5H)-trione (TGIC) EC-No.: T R23/25 R41 R43 R46 R48/22 R52/53 <= Document: MSDS Issue Date: July 23,

2 Section 4 FIRST AID MEASURES Inhalation Eye contact Skin contact Ingestion : Move to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion. If symptoms persist, call a physician. : Rinse immediately with plenty of water for at least 15 minutes. If eye irritation persists, consult a specialist. : Wash off with soap and plenty of water. : Immediately give plenty of water (if possible charcoal slurry). If a person vomits when lying on his back, place him in the recovery position. Do not induce vomiting without medical advice. Oxygen or artificial respiration if needed. Section 5 FIRE-FIGHTING MEASURES Suitable extinguishing media Extinguishing media which must not be used for safety reasons Specific hazards during fire fighting Special protective equipment for fire-fighters : Carbon dioxide (CO2). Foam. Water spray. Dry powder. : High volume water jet. : Carbon oxides. Nitrogen oxides. Burning produces obnoxious and toxic fumes. : Standard procedure for chemical fires. Wear self-contained breathing apparatus and protective suit. Section 6 ACCIDENTAL RELEASE MEASURES Personal precautions : Avoid dust formation. Do not breathe vapours/dust. Keep away from sources of ignition - No smoking. Avoid contact with skin, eyes and clothing. Document: MSDS Issue Date: July 23,

3 Environmental precautions Methods for cleaning up Additional advice : Do not allow material to contaminate ground water system. Prevent product from entering drains. Avoid subsoil penetration. : Take up mechanically and collect in suitable container for disposal. : Ensure adequate ventilation. Section 7 HANDLING AND STORAGE Handling Advice on safe handling Advice on protection against fire and explosion Storage Further information on storage conditions Storage hazard class Huntsman Advanced Materials : Provide for appropriate exhaust ventilation and dust collection at machinery. Keep out of reach of children. : Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). : Keep away from food, drink and animal feeding stuffs. Keep container tightly closed. Store in original container. Keep at temperatures between 2 and 40 C. : Storage class 13, Solid materials, not dangerous Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Control parameters Update Basis 1,3,5-tris(oxyranylmethyl)- 1,3,5-triazine- 2,4,6(1H,3H,5H)-trione (TGIC) mg/m3 GB-MEL I Engineering measures Avoid dust formation. Provide appropriate exhaust ventilation at machinery and at places where dust can be generated. Document: MSDS Issue Date: July 23,

4 Personal protective equipment Respiratory protection : In case of insufficient ventilation wear suitable respiratory equipment. Filter type AX-P3 (organic vapours, particles) Eye protection Hand protection : Tightly fitting safety goggles. Face-shield. : Material of gloves for long term application (BTT>480 min): Butyl rubber Ethyl Vinyl Alcohol Laminate (EVAL) Material of gloves for short term/splash application (10 min<btt<480 min): Nitrile rubber Use gloves approved to relevant standards e.g. EN 374 (Europe), F739 (US). Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material and dexterity. Always seek advice from glove suppliers. Skin and body protection : Protective suit. Safety shoes. Protective measures : Do not breathe dust. Keep away from sources of ignition - No smoking. Avoid contact with skin, eyes and clothing. Section 9 PHYSICAL AND CHEMICAL PROPERTIES Form Colour Odour ph : solid Pellets : off-white : none : approx.6 at (20 C) 1:1 in water Melting point : C Document: MSDS Issue Date: July 23,

5 Thermal decomposition : > 280 C Flash point : > 200 C Method: DIN (Pensky-Martens Closed Cup) Ignition temperature : 460 C Vapour pressure Bulk density Water solubility Miscibility with water : 0.88 Pa at 140 C : approx.0.8 g/cm3 : approx.9 g/l at 25 C Note: partly soluble : immiscible at 20 C Partition coefficient : log Pow = 0.8 (noctanol/water) at: 20 C Section 10 STABILITY AND REACTIVITY Conditions to avoid Materials to avoid Hazardous decomposition products : Note: Take necessary action to avoid static electricity discharge. : Strong acids and strong bases. Strong oxidizing agents. : Carbon oxides. Nitrogen oxides. Burning produces obnoxious and toxic fumes. Section 11 TOXICOLOGICAL INFORMATION Acute oral toxicity Acute inhalation toxicity : LD50 rat Dose: approx. 390 mg/kg Method: OECD 401 : LC50 mouse Document: MSDS Issue Date: July 23,

6 Dose: 2,000 mg/m3 Eye irritation Skin irritation Sensitization : irritating rabbit Method: Draize-Test : No skin irritation rabbit Method: Draize-Test dermal : Causes sensitization. guinea pig Method: Modified maximation test of Magnusson and Kligman dermal Section 12 ECOLOGICAL INFORMATION Elimination information (persistence and degradability) Biodegradability : Result: Not readily biodegradable % Method: OECD 301 B (Mod. Sturm) Ecotoxicity effects Toxicity to fish Toxicity to daphnia Toxicity to algae Toxicity to bacteria : LC50 Species: Zebrabaerbling Dose: > 77 mg/l Exposure time: 96 h : EC50 Species: Daphnia magna Straus 1820 Dose: > 100 mg/l Exposure time: 24 h : EC50 Species: Scenedesmus subspicat Dose: 29 mg/l Exposure time: 72 h : IC50 Species: aerobic bacteria Dose: > 100 mg/l Document: MSDS Issue Date: July 23,

7 Exposure time: 3 h Further information on ecology Additional ecological : Avoid subsoil penetration. Information Prevent product from entering drains. Do not contaminate surface water. Section 13 DISPOSAL CONSIDERATIONS Product : Waste Key Number: Must be incinerated, when in compliance with local regulations. Container : Empty containers can be landfilled after cleaning, when in compliance with the Environmental Protection (Duty of Care) Regulations Section 14 TRANSPORT INFORMATION Land transport ADR: Regulation RID: Regulation : Not dangerous goods : Not dangerous goods Sea transport IMDG: Regulation : Not dangerous goods Air transport IATA-DGR: Regulation : Not dangerous goods Section 15 REGULATORY INFORMATION Labelling according to EEC Directive Labelling required Symbol(s) : T Toxic R-phrase(s) : R23/25 Toxic by inhalation and if swallowed. R41 Risk of serious damage to eyes. Document: MSDS Issue Date: July 23,

8 R43 May cause sensitization by skin contact. R46 May cause heritable genetic damage. R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) : S53 Avoid exposure - obtain special instructions before use. S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Exceptional labelling of special preparations : Contains epoxy constituents. See information supplied by the manufacturer. Restricted to professional users. Hazardous components : 1,3,5-tris(oxyranylmethyl)-1,3,5-triazine which must be listed on -2,4,6(1H,3H,5H)-trione (TGIC) the label EC-No.: National legislation Notification status : EINECS yes Notification number: : TSCA yes : AICS yes : DSL yes : INV (CN) yes Document: MSDS Issue Date: July 23,

9 Section 16 - OTHER INFORMATION : PICCS (PH) yes : JEX (JP) yes Japan: Examinated new chemical substances Notification number: : KECI (KR) yes Notification number: KE The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. Niutang Chemical Inc. extends no warranties and makes no representation as to the accuracy or completeness of the information contained herein. Users should make a determination of the suitability of the information for their particular purpose. Document: MSDS Issue Date: July 23,