MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1. CHEMICAL PRODUCT AD COMPAY IDETIFICATIO Product ame: TPE 5187 Product Description: atural Thermoplastic Vulcanizate Date Prepared: 5/15/2009 Date Revised: 6/30/2015 MSDS # TPE 5187 MAUFACTURER: 24 HR. EMERGECY TELEPHOE UMBERS:. Day: PO Box 120 Evening: Allamuchy, J COMPOSITIO / IFORMATIO O IGREDIETS COMPOET APPX. WT.% OSHA PEL CAS Registry # EPDM A Bromine Flame Retardant mg/m 3 Proprietary Antimony Trioxide mg/m Polypropylene mg/m Proprietary Stabilizers mg/m 3 Proprietary 3. HAZARDS IDETIFICATIO EMERGECY OVERVIEW Physical Appearance: natural (beige) pellets / Slight odor POTETIAL HEALTH EFFECTS Eyes: Mechanical irritation is possible Skin: Molten polymer may cause thermal burns Ingestion: Ingestion is not a likely route of exposure Inhalation: Inhalation of process fumes and vapors may cause irritation in the respiratory system Chronic: o known chronic health effects MEDICAL CODITIOS AGGRAVATED: ot Known ROUTES OF ETRY: Eyes, Ingestion, Inhalation, Skin COMMETS: Hazard identification shown in section 3 is based upon general information as to normal uses and conditions. Where special or unusual use or conditions exists, it is suggested that the expert assistance of an industrial hygienist or other qualified profession be sought. Page 1 of 12

2 4. FIRST AID MEASURES EYES: Immediately flush eyes with plenty of water for two to three minutes. Remove any contact lenses and continue flushing for 15 minutes. SKI: If molten material contacts the skin, immediately flush with large amounts of water to cool the affected tissue and polymer. Do not attempt to peel polymer from skin. IGESTIO: Adverse health effects due to ingestion are not anticipated. Seek medical attention if discomfort occurs. IHALATIO: If symptoms are experienced, move victims to fresh air. Seek medical attention if discomfort occurs. 5. FIRE FIGHTIG MEASURES FLAMMABLE LIMITS: /A FLASHPOIT AD METHOD: /A HAZARDOUS COMBUSTIO PRODUCTS: Smoke,Fume,Sulfur Oxides,Incomplete combustion products,oxides of carbon,itrogen Oxides,formaldehyde,Flammable hydrocarbons,hydrogen Halide,Antimony halides FLAMMABLE CLASS: ot classified. Polymer will burn but does not easily ignite. EXTIGUISHIG MEDIA: Carbon Dioxide, foam, fog, sprays and dry chemical water. OTHER COSIDERATIOS: Avoid excessive heat & strong oxidizers. FIRE FIGHTIG PROCEDURES: Wear self-contained breathing apparatus. Assure an extended cooling period to prevent reignition. Evacuate area. Prevent runoff from fire control from entering streams sewers, or drinking water supply. 6. ACCIDETAL RELEASE MEASURES: OTIFICATIO PROCEDURE: In the event of an accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity. RELEASE OTES: Land spill: Sweep or Vacuum up spill and place in drums for recovery or disposal. Water spill: Stop leak if you can without due risk. Confine the spill immediately with booms. Skim from surface. EVIROMETAL PRECAUTIOS: Prevent entry into waterways, sewers, basements, or confined areas. 7. HADLIG AD STORAGE HADLIG: Keep material off walking surfaces, it may create a slipping hazard. Polymer dust may form explosive mixture with air. Avoid accumulation of dust in enclosed space. Use in well-ventilated area. Ground and bond equipment to prevent electrostatic charge when transferring product. Control spilled material to prevent runoff to the sewers and the environment. Avoid elevated temperatures for long periods of time. Avoid vapors from heated materials to prevent exposure to potentially toxic fumes. DO OT store or use near open flame or other sources of heat and ignition. Page 2 of 12

3 STORAGE: Keep container dry. Store away from excessive heat and away from strong oxidizing agents. Keep container closed to prevent contamination. Conditions such as humidity, sunlight, and temperature have an influence on the way this product behaves during storage. Special attention should be paid to avoid inappropriate stacking of palletized bags or other packaging units. Polymer products may be dimensionally unstable under certain conditions. 8. EXPOSURE COTROLS / PERSOAL PROTECTIO EGIEERIG COTROLS: If dust is generated, provide local exhaust ventilation to control airborne levels below the ACGIH TLV-TWA exposure limit for Particulates ot Otherwise Classified of 10 mg/m3 for inhalable particles and 3 mg/m3 of respirable. Adequate ventilation should be provided so that exposure limits are not exceeded. PERSOAL PROTECTIVE EQUIPMET: EYES AD FACE: Wear safety glasses with side shields or goggles when handling this material. SKI: To prevent any contact, wear impervious protective clothing such as neoprene or butyl rubber gloves, apron, boots or whole bodysuit as appropriate, when handling dry material. Use thermal resistant gloves when handling molten material. Refer to glove manufacturer s data for proper glove selection. 9. PHYSICAL AD CHEMICAL PROPERTIES PHYSICAL STATE: Solid APPERACE: Plastics pellets VAPOR PRESSURE: ot Applicable BOILIG POIT: ot Applicable SOLUBILITY I WATE: egligible ODOR: Slight Odor. ph: ot Applicable VAPOR DESITY: ot Available MELTIG POIT: 347 F to 446 F EVAPORATIO RATE: ot Applicable 10. PHYSICAL AD CHEMICAL PROPERTIES STABLE: Yes HAZARDOUS POLYMERIZATIO: o CODITIOS TO AVOID: Excessive heat and strong oxidizers. HAZARDOUS DECOMPOSTIO PRODUCTS: Hydrogen Bromide, Bromine, Carbon dioxide, Carbon Monoxide 11. TOXICOLOGICAL IFORMATIO ACUTE: ot fully investigated but not expected EYES: Low Hazard for usual industrial handling SKI ABSORPTIO: Molten material will produce thermal burns. CARCIOGEITY: From data comparisons to similar flame retardants, the Environmental Protection Agency has concluded that the bromine flame retardant used in this compound may cause cancer as a result of significant chronic dermal and inhalation exposures to workers. However, the flame retardant contained in this product is completely encapsulated in thermoplastics and as such, should not present a health hazard. Page 3 of 12

4 12. ECOLOGICAL IFORMATIO EXCOTOXICOLOGICAL IFORMATIO: Based on comparisons to other flame retardants, the Environmental Protection Agency has concluded that the flame retardant in this product may be toxic to aquatic organisms. However, the flame retardant contained in this product is completely encapsulated in thermoplastics and as such, has limited bio-availability. Do not release into U.S. waters. 13. DISPOSAL COSIDERATIO DISPOSAL METHOD: Dispose of waste at an appropriate waste disposal facility according to applicable laws and regulations. 14. TRASPORT IFORMATIO DOT (DEPARTMET OF TRASPORTATIO) PRIMARY HAZARD CLASS/DIVISIO: ot Regulated U/A UMBER: /A PACKIG GROUP: /A 15. REGULATORY IFORMATIO SARA TITLE III SECTIO 313: This product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right to Know Act of 1986 and of 40 CFR 372: Ingredient ame CAS umber Percent Antimony Trioxide to 40% -PROP 65 (TERATOGE) WARIG: This product contains a chemical known to the state of California to cause birth defects or other reproductive harm. Ingredient ame CAS umber Percent Antimony Trioxide to 40% TSCA REGULATORY: All ingredients are on the TSCA inventory or are not required to be listed on TSCA inventory. 16. OTHER IFORMATIO FPA CODES: FIRE: 1 HEALTH: 1 REACTIVITY: 0 SPECIAL: - Page 4 of 12

5 Restriction of Hazardous Substances Directive, Citation EC (RoHS) TPE 5187 complies with Restriction of Hazardous Substances Directive, Citation EC, commonly known as RoHS without exemption. It does not contain any of the following substances: 1. Lead 2. Mercury 3. Cadmium 4. Chromium 5. Polybrominated biphenyls (PBB) 6. Polybrominated diphenyl ethers (PBDE) including decabromodiphenyl ether Registration, Evaluation and Authorization of Chemicals (REACH) Substance ame CAS umber Substance Present (Y/) Ammonium dichromate Anthracene Anthracene Oil Anthracene Related Compounds , , Boric Acid , ,2,3-Trichloropropane Dibutyl phthalate ,2 Benzenedicarboxylic acid,di-c branched alkyl esters,c7-rich 1-Methyl-2pyrrolidone Hydrazine / ,2 Benzenedicarboxylic acid,di-c branched and linear alkyl esters Strontium chromate Ethoxyethyl acetate Cyclododecane Cobalt dichloride Cobalt (II) sulfate Cobalt (II) dinitrate Cobalt (II) carbonate Cobalt (II) diacetate Chromium trioxide Chromic Acid Oligomers of chromic acid and dichromic acid, Dichromic Acid ,4'- Diaminodiphenylmethane Diarsenic pentaoxide Diarsenic trioxide Page 5 of 12

6 Disodium tetraborate, anhydrous , , Sodium dichromate, dihydrate tert-butyl-2,4,6-trinitro-m-xylene (musk xylene) Bis (2-ethyl(hexyl)phthalate) (DEHP) Hexabromocyclododecane (HBCDD) , Alpha-hexabromocyclododecane Beta-hexabromocyclododecane Gamma-hexabromocyclododecane Alkanes, C10-13, chloro (Short Chain Chlorinated Paraffins) Bis(tributyltin)oxide Lead hydrogen arsenate Potassium chromate Potassium dichromate Sodium chromate Tetraboron disodium heptaoxide, hydrate Triethyl arsenate Trichloroethylene ,4 Dinitrotoluene Methoxy ethanol Ethoxy ethanol Acrylamide Aluminosilicate Refractory Ceramic Fibers Lead Chromate Tris(2-chloroethyl)phosphate Lead sulfochromate yellow Pitch, coal tar, high temp Zirconia Aluminosilicate Refractory Ceramic Fibers Diisobutyl phthalate Lead chromate molybdate sulphate red Benzyl butyl phthalate Potassium hydroxyoctaoxodizincatedichromate Calcium arsenate Bis(2-methoxyethyl) ether Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number Page 6 of 12

7 00-8 in Annex VI, part 3, table 3.1 of Regulation (EC) o 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfil the three following conditions: a) oxides of aluminium and silicon are the main components present (in the fibres) within variable concentration ranges b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (µm) c) alkaline oxide and alkali earth oxide (a2o+k2o+cao+mgo+bao) content less or equal to 18% by weight Potassium hydroxyoctaoxodizincatedichromate Lead dipicrate ,-dimethylacetamide Arsenic acid Methoxyaniline; o-anisidine Trilead diarsenate ,2-dichloroethane Pentazinc chromate octahydroxide (1,1,3,3-tetramethylbutyl)phenol Formaldehyde, oligomeric reaction products with aniline Bis(2-methoxyethyl) phthalate Lead diazide, Lead azide Lead styphnate ,2'-dichloro-4,4'-methylenedianiline Phenolphthalein Dichromium tris(chromate) [4-[4,4'-bis(dimethylamino) benzhydrylidene]cyclohexa-2,5-dien-1- ylidene]dimethylammonium chloride (C.I. Basic Violet 3) [with 0.1% of Michler's ketone (EC o ) or Michler's base (EC o )] α,α-bis[4-(dimethylamino)phenyl] Page 7 of 12

8 (phenylamino)naphthalene-1-methanol (C.I. Solvent Blue 4) [with 0.1% of Michler's ketone (EC o ) or Michler's base (EC o )],,','-tetramethyl-4,4'-methylenedianiline (Michler s base) 1,3,5-tris[(2S and 2R)-2,3-epoxypropyl] ,3,5-triazine-2,4,6-(1H,3H,5H)-trione (β- TGIC) Diboron trioxide ,2-bis(2-methoxyethoxy)ethane (TEGDME; triglyme) 4,4'-bis(dimethylamino)-4'' (methylamino)trityl alcohol [with 0.1% of Michler's ketone (EC o ) or Michler's base (EC o )] Lead(II) bis(methanesulfonate) Formamide [4-[[4-anilino-1-naphthyl][4- (dimethylamino)phenyl]methylene]cyclohexa- 2,5-dien-1-ylidene] dimethylammonium chloride (C.I. Basic Blue 26) [with 0.1% of Michler's ketone (EC o ) or Michler's base (EC o )] 1,2-dimethoxyethane; ethylene glycol dimethyl ether (EGDME) 1,3,5-Tris(oxiran-2-ylmethyl)-1,3,5- triazinane-2,4,6-trione (TGIC) 4,4'-bis(dimethylamino)benzophenone (Michler s ketone) Bis(pentabromophenyl) ether (decabromodiphenyl ether; DecaBDE) Pentacosafluorotridecanoic acid Tricosafluorododecanoic acid Henicosafluoroundecanoic acid Heptacosafluorotetradecanoic acid Diazene-1,2-dicarboxamide (C,C'- azodi(formamide)) Cyclohexane-1,2-dicarboxylic anhydride [1] cis-cyclohexane-1,2-dicarboxylic anhydride [2] trans-cyclohexane-1,2-dicarboxylic anhydride [3] [The individual cis- [2] and trans- [3] isomer substances and all possible combinations of the cis- and trans-isomers [1] are covered , , Page 8 of 12

9 by this entry]. Hexahydromethylphthalic anhydride [1], Hexahydro-4-methylphthalic anhydride [2], Hexahydro-1-methylphthalic anhydride [3], Hexahydro-3-methylphthalic anhydride [4] [The individual isomers [2], [3] and [4] (including their cis- and trans- stereo isomeric forms) and all possible combinations of the isomers [1] are covered by this entry] 4-onylphenol, branched and linear , , , [substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 to phenol, covering also UVCB- and well-defined substances which include any of the individual isomers or a combination thereof] 4-(1,1,3,3-tetramethylbutyl)phenol, ethoxylated [covering well-defined substances and UVCB substances, polymers and homologues] - - Methoxyacetic acid ,-dimethylformamide Dibutyltin dichloride (DBTC) Lead monoxide (Lead oxide) Orange lead (Lead tetroxide) Lead bis(tetrafluoroborate) Trilead bis(carbonate)dihydroxide Lead titanium trioxide Lead titanium zirconium oxide Silicic acid, lead salt Silicic acid (H 2Si 2O 5), barium salt (1:1), leaddoped [with lead (Pb) content above the applicable generic concentration limit for 'toxicity for reproduction' Repr. 1A (CLP) or category 1 (DSD); the substance is a member of the group entry of lead compounds, with index number in Regulation (EC) o Page 9 of 12

10 1272/2008] 1-bromopropane (n-propyl bromide) Methyloxirane (Propylene oxide) ,2-Benzenedicarboxylic acid, dipentylester, branched and linear Diisopentylphthalate (DIPP) pentyl-isopentylphthalate ,2-diethoxyethane Acetic acid, lead salt, basic Lead oxide sulfate [Phthalato(2-)]dioxotrilead Dioxobis(stearato)trilead Fatty acids, C16-18, lead salts Lead cynamidate Lead dinitrate Pentalead tetraoxide sulphate Pyrochlore, antimony lead yellow Sulfurous acid, lead salt, dibasic Tetraethyllead Tetralead trioxide sulphate Trilead dioxide phosphonate Furan Diethyl sulphate Dimethyl sulphate ethyl-2-methyl-2-(3-methylbutyl)-1,3- oxazolidine Dinoseb (6-sec-butyl-2,4-dinitrophenol) ,4'-methylenedi-o-toluidine ,4'-oxydianiline and its salts aminoazobenzene methyl-m-phenylenediamine (toluene-2, Page 10 of 12

11 diamine) 6-methoxy-m-toluidine (p-cresidine) Biphenyl-4-ylamine o-aminoazotoluene [(4-o-tolylazo-otoluidine]) o-toluidine methylacetamide Cadmium Ammonium pentadecafluorooctanoate (APFO) Pentadecafluorooctanoic acid (PFOA) Dipentyl phthalate (DPP) onylphenol, branched and linear, ethoxylated [substances with a linear and/or branched alkyl chain with a carbon # of 9 covalently bound in position 4 to phenol, ethoxylated covering UVCB- and well defined substances, polymers and homologues, which include any of the isomers and/or combinations thereof] Cadmium Oxide Lead di(acetate) Disodium 3,3'-[[1,1'-biphenyl]-4,4'- diylbis(azo)]bis(4-aminonaphthalene sulphonate) (C.I. Direct Red 28) Trixylyl phosphate Imidazolidine-2-thione; (2-imidazoline-2- thiol) Dihexyl phthalate Disodium 4-amino-3-[[4'-[(2,4- diaminophenyl)azo][1,1'-biphenyl]-4- yl]azo] -5-hydroxy-6- (phenylazo)naphthalene-2,7-disulphonate (C.I. Direct Black 38) Cadmium sulphide ,2-Benzenedicarboxylic acid, dihexyl ester, branched and linear Sodium perborate; perboric acid, sodium salt /A Sodium peroxometaborate Cadmium chloride benzotriazol-2-yl-4,6-di-tert-butylphenol (UV-320) ethylhexyl 10-ethyl-4,4-dioctyl-7-oxo-8- oxa-3,5-dithia-4-stannatetradecanoate (DOTE) 2-(2H-benzotriazol-2-yl)-4,6- ditertpentylphenol (UV-328) Cadmium fluoride Page 11 of 12

12 Cadmium sulphate , ,2-benzenedicarboxylic acid, di-c6-10-alkyl esters; 1,2-benzenedicarboxylic acid, mixed decyl and hexyl and octyl diesters with 0.3% of dihexyl phthalate (EC o ) 5-sec-butyl-2-(2,4-dimethylcyclohex-3-en-1- yl)-5-methyl-1,3-dioxane [1], 5-sec-butyl-2- (4,6-dimethylcyclohex-3-en-1-yl)-5-methyl- 1,3-dioxane [2] [covering any of the individual stereoisomers of [1] and [2] or any combination thereof] THIS MATERIAL SAFETY DATA SHEET IS PROVIDED BY T & T MARKETIG, IC. PURSUAT TO OSHA REGULATIOS, 29 CFR THE IFORMATIO PROVIDED I THE SHEET IS TRUE AD ACCURATE AS THE DATE IDICATED, TO THE BEST OF T & T MARKETIG S KOWLEDGE. THE IFORMATIO IS OT ITEDED TO COVER EVERY COCEIVABLE USE OR HADLIG OF THE MATERIAL, AD ACTUAL CODITIOS OF USE AD HADLIG MAY REQUIRE COSIDERATIOS OR IFORMATIO OTHER THA, OR I ADDITIO TO, THAT WHICH IS COTAIED I THIS SHEET. T & T MARKETIG DISTRIBUTIO OF THE MATERIAL THAT IS THE SUBJECT OF THIS SHEET IS MADE WITHOUT RELIACE OF AY KID O THIS SHEET, AD THE SHEET IS OT, AD SHALL OT BE COSTRUED AS, A REPRESETATIO OR WARRATY OF AY KID WHATSOEVER OF THE IFORMATIO COTAIED I THE SHEET OR I COECTIO WITH THE DISTRIBUTIO OF THE MATERIAL OR THE MATERIAL ITSELF. Page 12 of 12