MATERIAL SAFETY DATA SHEET Coopex EC Residual Insecticide

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1 1. IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND SUPPLIER Product name: Other names: None Product code: AE F EC12 A4 Recommended use: A general purpose residual insecticide for general pest control around buildings. Supplier: Bayer CropScience Pty Ltd ABN Address: Tooronga Road, East Hawthorn Victoria 3123, Australia Telephone: (03) Facsimile: (03) Website: Contact: Technical Manager (03) Emergency Telephone Number: Orica SH&E Shared Services 2. HAZARDS IDENTIFICATION HAZARDOUS SUBSTANCE - NON-DANGEROUS GOOD Harmful if swallowed. May cause lung damage if swallowed. Not flammable. Hazard designation: Risk phrases: Safety phrases: ADG classification: SUSDP classification: Hazardous according to criteria of Worksafe Australia. R22 Harmful if swallowed R65 Harmful: may cause lung damage if swallowed Not dangerous goods for transport by road or rail according to the Australian Code for the Transport of Dangerous Goods by Road and Rail. For shipment by sea this product is a MARINE POLLUTANT. Schedule 5 (Standard for the Uniform Scheduling of Drugs and Poisons) 3. COMPOSITION / INFORMATION ON INGREDIENTS Ingredients: CAS Number: Concentration (g/l): Permethrin 25:75 [ ] 100 Hydrocarbon solvent [ ] 672 Other ingredients (non hazardous) 71 Page 1 of 6

2 4. FIRST AID MEASURES If poisoning occurs, immediately contact a doctor or Poisons Information Centre (telephone ), and follow the advice given. Show this Material Safety Data Sheet to a doctor. Inhalation: Remove person to fresh air. Keep at rest. Seek medical advice if exposure has been more than trivial. Administer artificial respiration if breathing has stopped. Skin contact: Remove all contaminated clothing and shoes. Wash off skin immediately with soap and plenty of water. Seek medical advice if irritation persists. Launder contaminated clothing before reuse. Eye contact: Immediately rinse eyes thoroughly, including under eyelids, with running water for at least 15 minutes. Seek immediate medical advice. Ingestion: If swallowed do not induce vomiting. Give a glass of water. Seek medical advice. First Aid Facilities: Provide washing facilities in the workplace. Symptoms: Medical attention: Inhalation of spray may produce respiratory irritation and can result in headaches, dizziness, drowsiness, and possibly nausea. There is no specific antidote. Treat symptoms. This product contains a synthetic pyrethroid insecticide and a hydrocarbon solvent. Small amounts of liquid solvent aspirated into the respiratory system during ingestion or from vomiting may cause bronchopneumonia or pulmonary oedema. 5. FIRE FIGHTING MEASURES Extinguishing media: Hazards from combustion products: Precautions for fire fighters: Foam, dry chemical or water spray. Do not use a water jet from a fire hose.. This product is a combustible liquid. Fire fighters should wear full protective clothing and selfcontained breathing apparatus. Do not release contaminated water into the environment. Keep intact containers cool by spraying with water. 6. ACCIDENTAL RELEASE MEASURES Wear suitable protective clothing and boots. Prevent spill from entering drains, sewers or any body of water. Contain and absorb with sand, earth or inert absorbent. Scoop or shovel absorbent material into sealable containers for disposal in accordance with applicable local, state and federal regulations. 7. HANDLING AND STORAGE Handling: Storage: Keep out of reach of children. Avoid contact with skin and eyes and do not inhale spray mist. Use only in a well-ventilated area. Avoid ingestion and inhalation. Do not apply in the presence of naked flames, hot surfaces or unprotected electrical equipment. Use proper grounding procedures. Store product in the closed, original container in a cool, well-ventilated area away from direct sunlight. Page 2 of 6

3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure standards: Engineering controls: No exposure standard has been assigned by the National Occupational Health and Safety Commission (Worksafe Australia). The manufacturer of the hydrocarbon solvent recommends an occupational exposure limit of 300 ppm total hydrocarbons. Control process conditions to avoid contact. Use local exhaust ventilation. Keep product away from sources of ignition. Personal Protective Equipment: Eyes: Clothing: Gloves: Respiratory: Other: Avoid contact with the eyes. Wear safety goggles. Wear a face shield if splashing is possible. Wear suitable protective clothing. Protective clothing must be stored separately from private clothing. Avoid contact with the skin. Wear elbow-length PVC or nitrile gloves. Wear an approved respirator to prevent inhalation, if other control measures are inadequate. Do not eat, drink or smoke until after washing. Wash thoroughly after handling. After each day s use wash gloves, goggles and contaminated clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear yellow to brown liquid Odour: Mild hydrocarbon odour Vapour pressure: No data Vapour density: Boiling point: ~200 o C Freezing/melting point: Solubility: Emulsifies Density: at 20 C ph: Flash Point: 79 C (Abel closed cup) Flammability % approximately (solvent) (explosive) limits: Auto-ignition 216 C temperature: Octanol/water partition coefficient: Formulation: Emulsifiable concentrate Page 3 of 6

4 10. STABILITY AND REACTIVITY Chemical stability: Hazardous polymerisation: Conditions to avoid: Incompatible materials: Hazardous decomposition products: Stable under normal conditions of use. Do not apply in the presence of naked flames, hot surfaces or unprotected electrical equipment. Use proper grounding procedures. Incompatible with strong oxidising agents. No information available. 11. TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS Inhalation: Skin contact: Eye contact: Ingestion: Other: Acute: Oral toxicity: Dermal toxicity: Inhalation toxicity: Skin irritation: Eye irritation: Sensitisation: Avoid breathing vapour / spray / fumes. Inhalation of spray may produce respiratory irritation and can result in headaches, dizziness, drowsiness, and possibly nausea. Mildly irritating and drying to the skin. The material should not be allowed to come into contact with the skin. Extremely irritating. The material should not be allowed to contact the eyes. Harmful if swallowed. None ANIMAL TOXICITY DATA ACTIVE INGREDIENT: LD 50 rat: 1479 mg/kg (Permethrin 25:75 in corn oil) LD 50 rabbit: > 2000 mg/kg (Permethrin) LC 50 (3 hr) for mice and rats >685 mg/m 3 air (permethrin) Mild irritant rabbit (Permethrin) Mild irritant rabbit (Permethrin) Studies carried out by Bayer on Permethrin technical material indicate that it is not a skin sensitiser. Chronic: Permethrin is not mutagenic, teratogenic or carcinogenic. At high doses, the solvent caused reversible damage to the liver and kidney of male rats. These effects are not relevant to humans at occupational levels of exposure. Page 4 of 6

5 12. ECOLOGICAL INFORMATION DO NOT contaminate streams, rivers, or waterways with the chemical or used containers. Fish toxicity: Daphnia toxicity: Toxicity to algae: Bird toxicity: Bee toxicity: Other: Environmental fate, persistence and degradation: Permethrin is toxic to fish. LC 50 (48h) 0.6 µg/l Typical oral LD 50 values for cis/trans ratio of c40:60 for chickens >3000 mg/kg. Mallard ducks >9800. Permethrin is toxic to bees. LD50 (24h) (oral) µg/ bee; (topical) µg/bee. None Permethrin degrades rapidly in soil and water. 13. DISPOSAL CONSIDERATIONS Follow Avcare guidelines. Do not discharge into drains. Triple or preferably pressure rinse containers before disposal. Add rinsings to dye bath or spray mix or dispose of rinsate in disposal pit. Do not dispose of undiluted chemicals on site. Break, crush, or puncture and bury empty containers in a local authority landfill. If no landfill is available, bury the containers below 500 mm in a disposal pit specifically marked and set up for the purpose, clear of waterways, desirable vegetation and tree roots. Empty containers and product should not be burnt. 14. TRANSPORT INFORMATION UN number: Proper shipping name: Class and Subsidiary Risk: Packing Group: EPG: Hazchem code: Not dangerous goods for transport by road or rail according to the Australian Code for the Transport of Dangerous Goods by Road and Rail. 15. REGULATORY INFORMATION Registered according to the Agricultural and Veterinary Chemicals Act 1988 APVMA Approval Number: Page 5 of 6

6 16. OTHER INFORMATION Trademark information: Preparation information: Data sources: Coopex is a Registered Trademark of Bayer. First edition. Derived from Perigen Industrial Mothproofer MSDS. Bayer CropScience Pty Ltd product safety data and published data This MSDS summarises our best knowledge of the health and safety hazard information of the product and how to safely handle and use the product in the workplace. Each user should read this MSDS and consider the information in the context of how the product will be handled and used in the workplace including in conjunction with other products. If clarification or further information is needed to ensure that an appropriate risk assessment can be made, the user should contact this company. Our responsibility for products sold is subject to our standard terms and conditions, a copy of which is sent to our customers and is also available on request. END OF MSDS Page 6 of 6

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