SAFETY DATA SHEET. Creation Date 23-Sep-2009 Revision Date 19-Nov-2014 Revision Number Identification

Transcription

1 SAFETY DATA SHEET Creation Date 23-Sep-2009 Revision Number 1 Product Name Cat. : Synonyms Recommended Use 1. Identification a,a,a-trifluorotoluene AC ; AC ; AC ; AC ; AC Benzotrifluoride Laboratory chemicals. Uses advised against Information available Details of the supplier of the safety data sheet Company Fisher Scientific One Reagent Lane Fair Lawn, NJ Tel: (201) Entity / Business Name Acros Organics One Reagent Lane Fair Lawn, NJ Emergency Telephone Number For information US call: ACROS-01 / Europe call: Emergency Number US: / Europe: CHEMTREC Tel..US: / Europe: Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Flammable liquids Category 2 Label Elements Signal Word Danger Hazard Statements Highly flammable liquid and vapor Precautionary Statements Page 1 / 7

2 Prevention Keep away from heat/sparks/open flames/hot surfaces. - smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/equipment Use only non-sparking tools Take precautionary measures against static discharge Wear protective gloves/protective clothing/eye protection/face protection Skin IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower Fire In case of fire: Use CO2, dry chemical, or foam for extinction Storage Store in a well-ventilated place. Keep cool Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Toxic to aquatic life with long lasting effects 3. Composition / information on ingredients Component CAS- Weight % Benzotrifluoride First-aid measures Eye Contact Skin Contact Inhalation Ingestion Most important symptoms/effects tes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention. Wash off immediately with plenty of water for at least 15 minutes. Get medical attention immediately if symptoms occur. Move to fresh air. If breathing is difficult, give oxygen. Obtain medical attention. Get medical attention. Breathing difficulties. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting Treat symptomatically 5. Fire-fighting measures Water spray. Carbon dioxide (CO 2). Dry chemical. chemical foam. Flash Point 12 C / 53.6 F Method - Autoignition Temperature 620 C / 1148 F Explosion Limits Upper Lower Sensitivity to Mechanical Impact Sensitivity to Static Discharge Page 2 / 7

3 Specific Hazards Arising from the Chemical Flammable. Thermal decomposition can lead to release of irritating gases and vapors. Flash back possible over considerable distance. May form explosive mixtures with air. Hazardous Combustion Products Carbon monoxide (CO) Carbon dioxide (CO2) Gaseous hydrogen fluoride (HF) Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 3 Flammability 3 Instability 1 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Ensure adequate ventilation. Use personal protective equipment. See Section 12 for additional ecological information. Collect spillage. Should not be released into the environment. Methods for Containment and Clean Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, Up sawdust). Keep in suitable, closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Do not let this chemical enter the environment. Handling Storage Exposure Guidelines 7. Handling and storage Avoid contact with skin and eyes. Avoid contact with clothing. Avoid breathing vapors or mists. Do not ingest. Use explosion-proof equipment. Use only non-sparking tools. Ensure adequate ventilation. Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Keep away from heat and sources of ignition. Flammables area. 8. Exposure controls / personal protection Component ACGIH TLV OSHA PEL NIOSH IDLH Benzotrifluoride TWA: 2.5 mg/m 3 (Vacated) TWA: 2.5 mg/m 3 Legend Component Quebec Mexico OEL (TWA) Ontario TWAEV Benzotrifluoride TWA: 2.5 mg/m 3 TWA: 2.5 mg/m 3 TWA: 2.5 mg/m 3 ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration Engineering Measures Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Hygiene Measures Ensure adequate ventilation, especially in confined areas. Use explosion-proof electrical/ventilating/lighting/equipment. Ensure that eyewash stations and safety showers are close to the workstation location. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Wear appropriate protective gloves and clothing to prevent skin exposure. Follow the OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Handle in accordance with good industrial hygiene and safety practice. Page 3 / 7

4 9. Physical and chemical properties Physical State Liquid Appearance Colorless Odor Odorless Odor Threshold ph Melting Point/Range -29 C / F Boiling Point/Range 102 C / mmhg Flash Point 12 C / 53.6 F Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure Vapor Density Relative Density Solubility Partition coefficient; n-octanol/water Autoignition Temperature 620 C / 1148 F Decomposition Temperature Viscosity Molecular Formula C7 H5 F3 Molecular Weight Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials ne known, based on information available Stable under normal conditions. Keep away from open flames, hot surfaces and sources of ignition. Incompatible products. Strong oxidizing agents, Strong bases, Strong reducing agents Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2), Gaseous hydrogen fluoride (HF) Hazardous Polymerization Hazardous Reactions Acute Toxicity Hazardous polymerization does not occur. ne under normal processing. 11. Toxicological information Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation Benzotrifluoride 15 g/kg ( Rat ) 2000 mg/kg ( Rat ) mg/m 3 ( Rat ) 4 h Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS- IARC NTP ACGIH OSHA Mexico Benzotrifluoride t listed t listed t listed t listed t listed Page 4 / 7

5 Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard... ne known ne known Symptoms / effects,both acute and delayed Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting Endocrine Disruptor Information Other Adverse Effects Ecotoxicity Do not empty into drains. The toxicological properties have not been fully investigated. See actual entry in RTECS for complete information. 12. Ecological information Component Freshwater Algae Freshwater Fish Microtox Water Flea Benzotrifluoride t listed 212 mg/l LC50 96 h t listed t listed Persistence and Degradability Bioaccumulation/ Accumulation Mobility Waste Disposal Methods Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information DOT UN- UN2338 Hazard Class 3 TDG UN- UN2338 Hazard Class 3 IATA UN Hazard Class 3 IMDG/IMO UN Hazard Class 3 Page 5 / 7

6 International Inventories 15. Regulatory information Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Benzotrifluoride X - X X X - X - Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) SARA 313 SARA 311/312 Hazardous Categorization Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes Clean Water Act Clean Air Act OSHA Occupational Safety and Health Administration CERCLA California Proposition 65 This product does not contain any Proposition 65 chemicals State Right-to-Know Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island Benzotrifluoride X X X - X U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant N N N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Page 6 / 7

7 Mexico - Grade Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR WHMIS Hazard Class B2 Flammable liquid Prepared By Creation Date Revision Date Print Date Revision Summary 16. Other information Regulatory Affairs Thermo Fisher Scientific EMSDS.RA@thermofisher.com 23-Sep v v-2014 This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of SDS Page 7 / 7