Issuing Date January 5, 2015 Revision Date New Revision Number 0 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
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1 SAFETY DATA SHEET Issuing Date January 5, 2015 Revision Number 0 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Liquid-Plumr Disposal + Drain Foaming Cleaner Other means of identification Synonyms ne Recommended use of the chemical and restrictions on use Recommended Use Uses advised against Drain cleaner and deodorizer information available Details of the supplier of the safety data sheet Supplier Address The Clorox Company 1221 Broadway Oakland, CA Phone: Emergency telephone number Emergency Phone Numbers For Medical Emergencies, call: For Transportation Emergencies, call Chemtrec: Page 1 / 9
2 2. HAZARDS IDENTIFICATION Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ). Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A GHS Label elements, including precautionary statements Emergency Overview Signal word Warning Hazard statements Causes skin irritation Causes serious eye irritation Appearance White granulate in a square pack Physical State Granulate Odor Grapefruit, citrus Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response Specific treatment (see supplemental first aid instructions on this label) If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention If on skin: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse Precautionary Statements - Storage ne Precautionary Statements - Disposal ne Hazards not otherwise classified (HNOC) t Applicable Unknown Toxicity 22% of the mixture consists of ingredient(s) of unknown toxicity Other information May be harmful if swallowed Toxic to aquatic life with long lasting effects Page 2 / 9
3 Interactions with Other Chemicals May react with other drain cleaners, including other Liquid-Plumr products, to produce hazardous gases. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS- Weight % Trade Secret Citric acid * Sodium lauryl sulfate * * The exact percentage (concentration) of composition has been withheld as a trade secret First aid measures 4. FIRST AID MEASURES General Advice Eye Contact Skin Contact Inhalation Ingestion Protection of First-aiders Show this safety data sheet to the doctor in attendance. If symptoms persist, call a physician. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Remove contact lenses, if applicable, and continue flushing. Do not rub affected area. Wash skin with soap and water. In the case of skin irritation or allergic reactions see a physician. Wash off immediately with soap and plenty of water for at least 15 minutes. Move to fresh air. If symptoms persist, call a physician. Get medical attention immediately if symptoms occur. Do NOT induce vomiting. Clean mouth with water and afterwards drink plenty of water. Never give anything by mouth to an unconscious person. Consult a physician. Avoid contact with skin, eyes and clothing. Use personal protective equipment. For personal protection see Section 8. Most important symptoms and effects, both acute and delayed Most Important Symptoms/Effects Burning sensation. Indication of any immediate medical attention and special treatment needed tes to Physician Treat symptomatically. Page 3 / 9
4 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical information available Hazardous Combustion Products Carbon oxides. Explosion Data Sensitivity to Mechanical Impact Sensitivity to Static Discharge Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Use personal protective equipment. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental Precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage if safe to do so. Methods and material for containment and cleaning up Methods for Containment Methods for Cleaning Up Prevent further leakage or spillage if safe to do so. Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing before re-use. Conditions for safe storage, including any incompatibilities Storage Incompatible Products Keep containers tightly closed in a dry, cool and well-ventilated place. Other drain cleaners, including other Liquid-Plumr products. Page 4 / 9
5 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Appropriate engineering controls Engineering Measures This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Hygiene Measures If splashes are likely to occur, wear: Safety glasses with side-shields. ne required for consumer use. Wear protective gloves/clothing. Long sleeved clothing. Impervious gloves. protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this product. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Granulate Appearance Granulate in a square pack Odor Grapefruit, citrus Color White Odor Threshold information available Property Values Remarks/ Method ph data available ne known Melting/freezing point data available ne known Boiling Point/Range data available ne known Flash Point data available ne known Evaporation rate data available ne known Flammability (solid, gas) data available ne known Flammability Limits in Air Upper flammability limit data available Lower flammability limit data available Vapor pressure data available ne known Vapor density data available ne known Specific Gravity data available ne known Water Solubility Soluble in water. ne known Solubility in other solvents data available ne known Partition coefficient: n-octanol/water data available ne known Autoignition temperature data available ne known Decomposition temperature data available ne known Kinematic viscosity data available ne known Dynamic viscosity data available ne known Explosive Properties data available Oxidizing Properties data available Page 5 / 9
6 9. PHYSICAL AND CHEMICAL PROPERTIES Other Information Softening Point VOC Content (%) data available data available 10. STABILITY AND REACTIVITY Reactivity May react with other drain cleaners, including other Liquid-Plumr products, to produce hazardous gases. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions ne under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to avoid ne known based on information supplied. Incompatible materials Other drain cleaners, including other Liquid-Plumr products. Hazardous Decomposition Products Carbon oxides. Information on likely routes of exposure Product Information 11. TOXICOLOGICAL INFORMATION Inhalation Eye Contact Skin Contact Ingestion May cause irritation of respiratory tract. Causes eye irritation. May cause redness and irritation. Ingestion may cause irritation to mucous membranes, gastrointestinal irritation, nausea, vomiting and diarrhea. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Sodium lauryl sulfate = 1288 mg/kg ( Rat ) = 580 mg/kg ( Rabbit ) > 3900 mg/m 3 ( Rat ) 1 h Information on toxicological effects Symptoms May cause redness and tearing of the eyes and skin redness. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization Mutagenic Effects There is no data available for this product Page 6 / 9
7 Carcinogenicity Reproductive Toxicity STOT - single exposure STOT - repeated exposure Chronic Toxicity Target Organ Effects Aspiration Hazard Contains no ingredient listed as a carcinogen. information available known effect based on information supplied. Carcinogenic potential is unknown. Respiratory system. Eyes. Skin. Kidney. Numerical measures of toxicity Product Information The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 4.6 g/kg ATEmix (dermal) 8.8 g/kg (ATE) Ecotoxicity Toxic to aquatic life with long lasting effects 12. ECOLOGICAL INFORMATION Persistence and Degradability Bioaccumulation Other Adverse Effects 13. DISPOSAL CONSIDERATIONS Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations. Contaminated Packaging Dispose of in accordance with all applicable federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT TDG ICAO IATA IMDG/IMO t regulated t regulated t regulated t regulated t regulated 15. REGULATORY INFORMATION International Inventories Page 7 / 9
8 TSCA DSL Complies All components are listed either on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/n-Domestic Substances List U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ). CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. Chemical Name Citric acid Hazardous Substances RQs Extremely Hazardous Substances RQs RQ RQ Section number U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations ne known. International Regulations Canada WHMIS Hazard Class D2B Toxic materials 16. OTHER INFORMATION Page 8 / 9
9 16. OTHER INFORMATION NFPA Health Hazard 2 Flammability 0 Instability 0 Physical and Chemical Hazards - HMIS Health Hazard 2 Flammability 0 Physical Hazard 0 Personal Protection B Prepared By Revision Date Revision te Reference Product Stewardship 23 British American Blvd. Latham, NY New New / General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of Safety Data Sheet Page 9 / 9
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