Accelerated aging of roofing surfaces

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BTO Program Peer Review New York Times, 30 July 2009 Challenge: speed the development of high performance building envelope materials that resist soiling, maintain high solar reflectance, and save energy 2010 2012 Accelerated aging of roofing surfaces Development of Advanced Building Envelope Surface Materials & Integration of Artificial Soiling and Weathering in a Commercial Weatherometer Hugo Destaillats, Ph.D. Lawrence Berkeley National Laboratory HDestaillats@LBL.gov (510) 486-5897 http://heatisland.lbl.gov April 4, 2013 1 Program Name or Ancillary Text eere.energy.gov

Aging markedly decreases solar reflectance of conventional roofs 1.0 0.9 0.8 no change fieldapplied coating factoryapplied coating Aged solar reflectance 0.7 0.6 0.5 0.4 0.3 FLORIDA (n = 573) clay tile metal roofing concrete tile asphalt shingle 0.2 0.1 CA Title 24 running mean single-ply membrane modified bitumen 0.0 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 Initial solar reflectance Sleiman et al. (2011) Solar Energy Materials and Solar Cells, 95, 3385. When a white roof s albedo falls to 0.6 (aged) from 0.8 (initial), annual energy savings decrease by ⅓ 2 Building Technologies Office eere.energy.gov

Purpose & Objectives Problem Statement: CRRC and Energy Star rating programs require three years of natural exposure, delaying introduction of novel cool roofing materials. R&D challenge: Develop technology to quickly rate roofing products, removing barrier to innovation of energy saving roofing materials. Impact of Project: Benefits ~200 roofing manufacturers and suppliers by speeding prototyping and introduction to market of high performance products. The project will yield (1) industry-vetted ASTM/ISO standards for accelerating aging; (2) an accelerated aging device based on IP developed by LBNL with BTO support; (3) peer-reviewed journal articles; and (4) a network of international collaborations. Project Focus: Develop and transfer technology that promotes advanced cool roofs. Wide adoption of cool roofs is projected to yield annual net primary energy savings of nearly 300 TBTU, worth about $2B/year, reduce CO 2 emissions, and partially mitigate global warming. 3 Building Technologies Office eere.energy.gov

Approach Approach: 1) Establish a network of industrial, academic and government partners that provide regular feedback; discuss preliminary results in an international workshop 2) Expose 27 roofing products at three CRRC sites, retrieving and analyzing coupons quarterly 3) Develop laboratory accelerated aging protocol calibrated to CRRC exposure 4) Determine reproducibility of accelerated aging method through inter-laboratory study 5) Develop ASTM and ISO standards for accelerated aging 6) Integrate soiling protocol in a commercial weatherometer to facilitate adoption of the technology Key Issues: No single method can simulate the performance of every product in all possible US climates. We are distilling the essence of complex atmospheric deposition and soiling processes into practical tools (standards and devices) that industry can use to develop energy saving products. Distinctive Characteristics: LBNL's Heat Island Group combines unique expertise in cool roofing materials, rating methods, urban atmospheric chemistry, and engineering. 4 Building Technologies Office eere.energy.gov

Approach: evaluate natural exposure hot & dry (Phoenix, AZ) temperate (Cleveland, OH) 2011 2012 2013 JANUARY APRIL JULY OCTOBER hot & humid (Miami, FL) Solar Reflectance, B891 Method 1.00 0.95 0.90 0.85 0.80 0.75 0.70 0.65 0.60 0.55 0.50 Sample 1: White Single-Ply Membrane, 5 Degree Tilt White single-ply membrane, 5 degree tilt LBNL, Arizona LBNL, Florida LBNL, Ohio CRRC, Arizona CRRC, Florida CRRC, Ohio 0 3 6 9 12 15 18 21 24 27 30 33 36 Number of Months Exposed Since October 2010 Solar Reflectance, B891 Method 1.00 0.95 0.90 0.85 0.80 0.75 0.70 0.65 0.60 0.55 0.50 Sample 2: White Single-Ply Membrane, 5 Degree Tilt LBNL, Arizona LBNL, Florida LBNL, Ohio CRRC, Arizona CRRC, Florida CRRC, Ohio 0 3 6 9 12 15 18 21 24 27 30 33 36 Number of Months Exposed Since October 2010 5 Building Technologies Office eere.energy.gov

Approach: develop accelerated aging method Accelerated soiling (atmospheric deposition) Accelerated weathering (UV, heat, moisture) Dust Salts Organics Soot Spraying nozzle Pressure Air Soiling mix Spraying vessel Coupons of roofing products 6 Building Technologies Office eere.energy.gov

Approach: validate accelerated aging method 0.9 Accelerated aging (LBNL) 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 Solar Reflectance Field-Applied Coating Factory-Applied Coating Single-Ply Membrane Modified Bitumen Shingle Tile Metal y = (1.02 ± 0.03) x - (0.01 ± 0.02) R 2 =0.96 Field applied coating (n=7) Single-ply membrane (n=11) Asphalt shingle (n=4) Metal or factoryapplied coating (n=8) Clay tile (n=2) Modified bitumen (n=3) 0.0 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 Three years of natural exposure (CRRC) 7 Building Technologies Office eere.energy.gov

Approach: develop standards to formalize accelerated aging method International Workshop on Advances in Cool Roof Research Berkeley, July 28-29, 2011 June 2012 & Dec 2012 Draft standard presented at ASTM Created Task Group D08.20.45 Test Method for Accelerated Aging of Solar Reflectance of Roofing Materials 75 participants from 7 countries Industry, academia and government http://coolroofs2011.lbl.gov September 2012 Draft standard presented at ISO TC-163: Thermal performance and energy use in the built environment 8 Building Technologies Office eere.energy.gov

Accomplishments and Progress Accomplishments: 1) Hosted workshop at Berkeley in 2011 to receive feedback from industry on draft method for accelerated aging. 2) Tunable accelerated aging method completed in 2012 and validated against 35 rated products. 3) Three years of natural exposure (CRRC) will be completed in Oct 2013. 4) ASTM and ISO standard development started in 2012. 5) Inter-laboratory study started in 2013. 6) Integration of soiling with commercial weatherometer started in 2013. Progress on Goals: These accomplishments were met within the original project schedule and goals. Awards/Recognition: LBNL applied for a US patent for this technology; industrial partners recognized potential of accelerated aging method and work with us to develop and implement it. 9 Building Technologies Office eere.energy.gov

Project Plan & Schedule Project original initiation date: FY10 Project planned completion date: FY14 WBS Number or Agreement Number Project Number Agreement Number Summary BT-480010-13 ET-ENV-LBNL-FY13-01 and -03 22292 Legend Work completed Active Task Milestones & Deliverables (Original Plan) Milestones & Deliverables (Actual) FY2012 FY2013 FY2014 Task / Event Q1 (Oct-Dec) Q2 (Jan-Mar) Q3 (Apr-Jun) Q4 (Jul-Sep) Q1 (Oct-Dec) Q2 (Jan-Mar) Q3 (Apr-Jun) Q4 (Jul-Sep) Q1 (Oct-Dec) Q2 (Jan-Mar) Q3 (Apr-Jun) Q4 (Jul-Sep) Project Name: Development of Advanced Building Envelope Surface Materials FY11 Q4 Milestone: Complete consultation with industrial partners (workshop) FY12 Q4 Milestone: Complete 2 years of natural exposure (interim) FY12 Q4 Milestone: Complete laboratory accelerated aging method FY13 Q4 Milestone: Develop ASTM and ISO standards FY13 Q4 Milestone: Inter-laboratory validation FY13 Q4 Milestone: Complete 3 years of natural exposure (final) Project Name: Integration of Artificial Soiling and Weathering in a Commercial Weatherometer FY13 Q4 Milestone: Add soiling to commercial weatherometer FY13 Q4 Milestone: Validate the integrated system Current work and future research Complete analysis of the 3 years of natural exposure Complete inter-laboratory validation Develop ASTM and ISO standards Complete integration of soiling and weathering 10 Building Technologies Office eere.energy.gov

Project Budget Project Budget: $600K in FY10, $600K in FY11, $400K in FY12 and $250K in FY13. Planned for FY14: $300K. Variances: No major variances. Cost to Date: ~$1.7M since FY10 (including expenditures through 4/13). ~80% of the FY10-FY14 budget has been expended to date. Additional Funding: Roofing material samples for field and laboratory exposure were received as in-kind contributions during FY10 from several manufacturers. The value of preparing 200 coupons of each of 27 different roofing products was approximately $200K. In FY13, in-kind contribution received from weathering equipment manufacturer to implement soiling integration tests. Budget History FY2010 FY2011 FY2012 DOE Cost-share DOE Cost-share DOE Cost-share $600K In-kind (~$200K) $600K -- $400K -- 11 Building Technologies Office eere.energy.gov

Project Integration, Collaboration & Market Impact Partners, Subcontractors, and Collaborators: ORNL (A. Desjarlais), Concordia University (H. Akbari), Cool Roofing Rating Council. Coupons were received from 20 industrial partners (roofing manufacturers and distributors). Other partners include two commercial weathering firms. The inter-laboratory tests involve eight partners (industry and academia). Technology Transfer, Deployment, Market Impact: Developing ASTM and ISO standards will facilitate deployment and market impact of the accelerated aging methodology developed in this project. A provisional US patent was filed in 2012, and a patent application in March 2013. Communications: Results have been presented at US and international conferences. In FY11, we held a workshop in Berkeley to share our draft method with participants from industry and academia. One journal article was published in 2011 and another is in preparation. (References are presented on the next slide.) 12 Building Technologies Office eere.energy.gov

Communications (cont d) US Patent application: Sleiman M, Kirchstetter TW, Destaillats H, Levinson R, Berdahl PH, Akbari H. Laboratory method mimicking natural soiling and weathering of outdoor surfaces. Ser. No. 61/638,949, 2012. Draft ASTM standard: Standard practice for simulated field aging of roofing materials for determination of solar reflectance and thermal emittance. Presented to ASTM Committee D08. Draft ISO standard: Accelerated aging method to mimic changes in solar reflectance of roofing materials. Presented to ISO Technical Committee TC-163. Peer-reviewed publications: 1) Sleiman M, Ban-Weiss G, Gilbert HE, François D, Kirchstetter TW, Berdahl PH, Destaillats H, Levinson R. 2011. Soiling of building envelope surfaces and its effect on solar reflectance Part I: Analysis of roofing product databases. Solar Energy Materials & Solar Cells 95, 3385-3399. 2) Sleiman M, Kirchstetter TW, Berdahl PH, Gilbert HE, Akbari H, Levinson R, Destaillats H. Soiling of building envelope surfaces and its effect on solar reflectance Part II: Development of an accelerated aging method for roofing materials. In preparation. Workshop in Berkeley, CA: International Workshop on Advances in Cool Roof Research: Protocols, Standards & Policies for Accelerated Aging, July 28-29, 2011 http://coolroofs2011.lbl.gov International conferences: 1) Sleiman M, Kirchstetter TW, Berdahl PH, Gilbert HE, François D, Spears S, Levinson R, Akbari H, Destaillats H. 2010. Development of an accelerated soiling method that mimics natural exposure of roofing materials (keynote presentation). 3 rd Conference on Passive and Low Energy Cooling for the Built Environment (PALENC), 5 th European Conference on Energy Performance & Indoor Climate in Buildings (EPIC), 1 st Cool Roofs Conference, Rhodes, Greece. 2) Sleiman M, Kirchstetter TW, Gilbert HE, Preble C, Berdahl PH, Destaillats H, Levinson R. 2012. Accelerated aging method to mimic changes in solar reflectance of roofing materials. International Roof Coatings Conference, Baltimore MD. 13 Building Technologies Office eere.energy.gov

Next Steps and Future Plans Short term (FY14): 1) Complete natural aging and analyze seasonal and long term changes to solar reflectance and thermal emittance 2) Complete inter-laboratory evaluation of accelerated aging methodology 3) Advance ASTM and ISO standards of accelerated aging 4) Complete integration of soiling in a weatherometer to facilitate commercialization 5) Host a second workshop to expand collaborative network, including our current international partners. Long term: 1) Completion and adoption of ASTM and ISO standards 2) Extend method to serve other climates/regions 3) Develop tools to evaluate anti-soiling properties of novel advanced materials 4) Extend to other envelope surfaces (façades, BIPV) 14 Building Technologies Office eere.energy.gov

Next Steps and Future Plans Related ongoing work: 3 CRADAs Future work: emerging technologies Stay-clean white elastomeric coatings Retro-reflective surfaces Fluorescent cool pigments white fluorescent red Photoactive self-cleaning surfaces cool red red Improved cool asphalt shingles black 0 0.2 0.4 0.6 0.8 1 Solar absorptance Future work: beyond cool roofs Cool façades Cool pavements Stay-clean PV and CSP Waterborne superhydrophobic coatings CERC-BEE 15 Building Technologies Office eere.energy.gov