HAZARDOUS WASTE INCINERATION PLANTS

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HAZARDOUS WASTE INCINERATION PLANTS Effective removal of harmful substances and energy recovery A Bayer and LANXESS company

Clean the extreme CURRENTA Environment is an expert service provider that ensures seamless production processes in Germany s largest chemical park at its three sites in Leverkusen, Dormagen and Krefeld-Uerdingen. CURRENTA offers its customers, both within and outside CHEMPARK, a customized portfolio of services in core fields such as training and further education, infrastructure, safety and security, utilities, waste management, technical services and analytics. We have our own state-of-the-art waste management facilities, an excellent disposal network and skilled personnel from the chemical and pharmaceutical industry, all of which enable us to meet the disposal requirements of our customers efficiently and cost-effectively. We treat biodegradable wastewater, deal with the incineration and landfill disposal of hazardous waste, and clean tanks. We provide advice and support in the construction and operation of waste management facilities and in the collection and recycling of valuable materials. Our portfolio covers individual services and complete solutions that meet the statutory requirements pertaining to the safe disposal of waste and wastewater that is particularly difficult to treat.

HAZARDOUS WASTE INCINERATION PLANTS Hazardous waste incinerator 1 Leverkusen-Bürrig HAZARDOUS WASTE INCINERATOR 1 LEVERKUSEN-BÜRRIG Rotary kiln incinerator with afterburner chambers Start-up 1967 Upgraded 1989 1995 Authorization status Recycling/disposal no.: E31632082 Permit notification dated June 29, 2000 File reference: 56.8851/8.1-16-6/99 authorities of Cologne Throughput capacity: 50,000 t/a of mixed waste Thermal output: 32.8 MW Availability: 7,500 h/a Solid waste for bunkers, loose and packed Packaged waste, e.g. drums, Big Bags, cardboard boxes Liquid waste: tank farm, direct transfer Containers: Schütz containers, drums, IBCs etc. Disposal of particularly hazardous waste Non-miscible, reactive or hot liquids Highly halogenated waste Waste containing silicon/ phosphorus Metal alkyls Insecticides, pesticides PCBs Concentrates High-temperature components - Rotary kiln incinerator with feed of waste from bunkers or drums and burners for liquid residue, afterburner chamber - Waste heat boiler with 2 radiation ducts, 2 superheaters and evaporators - 36 t of steam per hour is fed into the site grid as process steam at 39 bar and 320 C - Quenching, rotary scrubber (acidic), rotary scrubber (alkaline), wet-wall electrostatic precipitation, selective catalytic reaction - Bunkers, drum feed system, container stations, tank farm The focus is on safe and environmentally sound waste management. All inorganic incineration residue stays within CURRENTA Environment s Waste Management Center. 03

HAZARDOUS WASTE INCINERATION PLANTS Hazardous waste incinerator 2 Leverkusen-Bürrig HAZARDOUS WASTE INCINERATOR 2 LEVERKUSEN-BÜRRIG Rotary kiln incinerator with afterburner chambers Throughput capacity: 30,000 t/a of mixed waste Thermal output: 22 MW Availability: 7,500 h/a Solid waste for bunkers, loose and packed Packaged waste, e.g. drums, Big Bags, cardboard boxes Liquid waste: tank farm, direct transfer Containers: Schütz containers, drums, IBCs etc. Start-up 1976 Upgraded 1992 1995 Authorization status Recycling/disposal no.: E31632082 Permit notification dated June 29, 2000 File reference: 56.8851/8.1-16-6/99 authorities of Cologne Disposal of particularly hazardous waste Non-miscible, reactive or hot liquids Highly halogenated waste Waste containing silicon/phosphorus Metal alkyls Insecticides, pesticides PCBs Concentrates - Rotary kiln incinerator with feed of waste from bunkers or drums and burners for liquid residue, afterburner chamber - Waste heat boiler with 2 radiation ducts, superheaters and evaporators - 21 t of steam per hour is fed into the site grid as process steam at 39 bar and 320 C - Quenching, rotary scrubber (acidic), rotary scrubber (alkaline), wet-wall electrostatic precipitation, selective catalytic reaction - Bunkers, drum feed system, container stations, tank farm All inorganic incineration residue stays within CURRENTA Environment s Waste Management Center. 04 05

HAZARDOUS WASTE INCINERATION PLANTS Sewage sludge incinerator Leverkusen-Bürrig SEWAGE SLUDGE INCINERATOR LEVERKUSEN-BÜRRIG Multiple-hearth furnace with afterburner chamber Throughput capacity: 90,000 t/a of sewage sludge (25,000 t/a dry substance), up to 70 t/d of heating oil substitute Thermal output: 24 MW Availability: 7,500 h/a Waste similar to sewage sludge Sewage sludge: via a site-specific trolley system Liquid residue: tank farm Highly chlorinated solvents (compact) Highly contaminated industrial sludge - Multiple-hearth furnace with feed of sewage sludge and afterburner chamber - Waste heat boiler with 1 radiation duct, superheater and evaporator Year of construction 1988 Increase in boiler output 1996 1996 Authorization status Recycling/disposal no.: E31632082 Permit notification dated June 29, 2000 File reference: 56.8851/8.1-16-6/99 authorities of Cologne bundle - 23 t of steam per hour is fed into the site grid at 39 bar and 320 C - Quenching, rotary scrubber (acidic), jet scrubber (alkaline), entrained-flow adsorber - Sludge bunker (treatment plant), sludge transport system, tank farm High qualified employees ensur for the smooth flow of waste. All inorganic incineration residue stays within CURRENTA Environment s Waste Management Center. 06 07

HAZARDOUS WASTE INCINERATION PLANTS Wastewater incinerator Leverkusen-Bürrig WASTEWATER INCINERATOR LEVERKUSEN-BÜRRIG Gas phase oxidation Year of construction 1988 1996 Authorization status Disposal no.: E31632082 Permit notification dated June 29, 2000 File reference: 55.8851/8.1-16-6/99-Kin-1 authorities of Cologne Throughput capacity: 20,000 t/a of wastewater, 9,000 t/a of organic sludge Thermal output: 4 MW Availability: 7,500 h/a Liquid waste, wastewater: in mobile containers Disposal of particularly hazardous waste Liquid waste containing salt Wastewater toxic to bacteria Insecticides, pesticides - Incineration chamber with burners for wastewater, gas burner as a supplementary burner - Special vessel as incineration chamber with downstream heatdissipating surfaces - 7 t of steam per hour is fed into the site grid at 39 bar and 320 C - Quenching, jet scrubber (alkaline), wet-wall electrostatic precipitation (two-duct) - Wastewater concentrate tank All inorganic incineration residue stays within CURRENTA Environment s Waste Management Center. 09

HAZARDOUS WASTE INCINERATION PLANTS Residue incinerator Dormagen RVAD RESIDUE INCINERATOR DORMAGEN (RVAD) Rotary kiln incinerator with afterburner chambers Year of construction 1994 1994 Authorization status Disposal no.: E16212061 Permit notification dated June 14, 2005 File reference: 56.8851.8.1-4662 authorities of Düsseldorf Throughput capacity: 75,000 t/a of mixed waste Thermal output: 42 MW Availability: 7,900 h/a Solid waste for bunkers, loose and packed Packaged waste, e.g. drums, Big Bags, cardboard boxes Liquid waste: tank farm, direct transfer Containers: Schütz containers, drums, IBCs etc. Gases, grid degassing from liquid gas container Disposal of particularly hazardous waste Non-miscible, reactive or hot liquids Highly halogenated waste Waste containing silicon/phosphorus Metal alkyls Insecticides, pesticides PCBs Concentrates Wastewater - Rotary kiln incinerator with feed of waste from bunkers or drums and burners for liquid residue, afterburner chamber for liquid residue and wastewater - Waste heat boiler with ten partitioned ducts with economizer, evaporator and superheater - Up to 44.2 t of steam per hour is fed into the site grid at 30 bar and 300 C - Quenching, rotary scrubber (acidic), rotary scrubber (alkaline), condenser, wet-wall electrostatic precipitation, selective catalytic reaction DeNOx (two-duct) - Bunkers, automatic drum preparation/feed system, drum storage, tank farm and container stations, wastewater treatment All residue stays within CURRENTA Environment s hazardous waste landfill site in Dormagen 10 11

HAZARDOUS WASTE INCINERATION PLANTS Thermal waste air incinerator Dormagen TVA THERMAL WASTE AIR INCINERATOR DORMAGEN (TVA) Waste air/gas incineration plant with 30 connected plants/plant sections Year of construction 1 9 7 0 (with subsequent expansion phases) Authorization status Certification in accordance with DIN EN ISO 14001/DIN EN ISO 9001 Permit notification dated September 20, 2006 File reference:: 63/B26/2896/2006 authorities of Cologne Max. throughput capacity: 75,000 m³/h of waste air Thermal output: 18 MW Availability: 99.9 % - 2 muffle furnaces, 1 thermal reactor, 2 combustors as back-up furnaces - 12 t of steam per hour is fed into the site grid at 30 bar - Quenching, jet scrubber, induced-draft fan Measurement of emissions in Dormagen The rinsing water generated by the waste air cleaning process is treated at CURRENTA Environment s wastewater treatment plant in Dormagen. 13

HAZARDOUS WASTE INCINERATION PLANTS Residue incinerator Krefeld-Uerdingen RVA2 RESIDUE INCINERATOR KREFELD-UERDINGEN (RVA2) Rotary kiln incinerator with afterburner chambers Thermal output: 13.8 MW Availability: 7,500 h/a Solid waste for bunkers, loose and packed Packaged waste, e.g. drums, Big Bags, cardboard boxes Liquid waste: tank farm, direct transfer Containers: Schütz containers, drums, IBCs etc. Gases Disposal of particularly hazardous Year of construction 1985 Upgraded 1996 1996 Authorization status Disposal no.: E11412043 Permit notification dated March 22, 1996 File reference: 56.8851.8.1/3991 authorities of Düsseldorf Throughput capacity: 25,000 t/a of mixed waste waste Non-miscible, reactive or hot liquids Highly halogenated waste Waste containing silicon/phosphorus Metal alkyls Insecticides, pesticides PCBs Concentrates - Rotary kiln incinerator with feed of waste from bunkers or drums and lances for liquid residue, afterburner chamber with lances for liquid residue and wastewater - Waste heat boiler with eight partitioned ducts - 13.5 t of steam per hour is fed into the site grid at 16 bar and 250 C - Quenching, rotary scrubber (acidic), rotary scrubber (alkaline), wet-wall electrostatic precipitation, DAGAVO (steam pre-heater), induced draft and selective catalytic reaction - Bunkers, drum feed system, container stations, tank farm, slag bunker, boiler ash removal, wastewater treatment, shredder, rail tank car unloading stations All inorganic incineration residue stays within CURRENTA Environment s Waste Management Center. 14 15

HAZARDOUS WASTE INCINERATION PLANTS Gas phase oxidation plant Brunsbüttel GPO GAS PHASE OXIDATION PLANT BRUNSBÜTTEL (GPO) Gas phase oxidation plant with upstream wastewater evaporation Year of construction 1980 1992 Authorization status Disposal no.: A51D10521 Permit notification dated April 30, 1993 File reference: 308/406/Kn BA BY, permit no. 26/02 Responsible authority: StUA (State Environmental Office) Itzehoe Throughput capacity: 27,000 t/a of wastewater Thermal output: 11.5 MW Availability: 7,200 h/a Liquid waste, wastewater: in mobile containers Disposal of particularly hazardous waste Liquid waste, in particular oils containing PCBs and flammable liquids with an Fp < 21 C Wastewater toxic to bacteria Insecticides, pesticides Solvents as a substitute fuel - Incineration chamber with burners for wastewater and liquid waste - Special vessel as incineration chamber with downstream heatdissipating surfaces - 14 t of steam per hour is fed into the site grid at 34 bar and 300 C - Quenching and wet-wall electrostatic precipitation - Transfer station and tank farm, wastewater treatment and evaporation All inorganic incineration residue in the form of salts is consigned to one of the controlled hazardous waste landfill sites operated by CURRENTA Environment. 17

HAZARDOUS WASTE INCINERATION PLANTS Types of incineration plants TYPES OF INCINERATION PLANTS Boiler Step by step: An overview of plant components and processes Incineration chamber INCINERATION HEAT RECOVERY FLUE GAS CLEANING Wastewater tanks Molten salt Salt discharge Quencher Jet scrubber Wet-wall electrostatic precipitator Induced draft fan Stack Selective catalytic reaction Afterburner chamber Catalytic unit Wastewater incinerator Ash remover Heat exchanger Rotary kiln Bunker Container feed Slag remover Boiler Quencher Rotary scrubber Wet-wall electrostatic precipitator Induced draft fans Stack Hazardous waste incinerator Boiler Rotary scrubber Entrained-flow adsorber Afterburner chamber Adsorbent Waste transport worm Sludge transport Multiple-hearth furnace Additional feed point for waste similar to sewage sludge Liquid residue Ash discharge Dust discharge Quencher Jet scrubber Induced draft fan Kamin Stack Sewage sludge incinerator 18 19

Published by Currenta GmbH & Co. OHG 51368 Leverkusen Germany www.currenta.com As at: March 2010