SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable Recommended use : Hand Soap Restrictions on use : Reserved for industrial and professional use. Product dilution information : 7.5 % - 12.5 % Company : Ecolab Inc. 37 N. Wabasha Street St. Paul, Minnesota USA 5512 1-8-352-5326 Emergency health information : 1-8-328-26 (US/Canada), 1-651-222-5352 (outside US) Issuing date : 3/3/216 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Serious eye damage : Category 1 Not a hazardous substance or mixture. GHS label elements Hazard pictograms : Signal Word Hazard Statements Precautionary Statements Precautionary Statements : Danger : Causes serious eye damage. : Prevention: Wear eye protection/ face protection. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. : Response: Get medical advice/ attention if you feel unwell. Storage: Store in accordance with local regulations. 916731-1 1 / 1
Other hazards : None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical name CAS-No. Concentration (%) Sodium poly(oxyethylene) dodecyl ether sulfate 68585-34-2 1-3 glycerin 56-81-5 1-3 2-methylpentane-2,4-diol 17-41-5 5-1 Alkylamidopropylbetaines 61789-4- 1-5 d-glucopyranose, oligomeric, decyl octyl glycosides 68515-73-1 1-5 d-glucopyranose, oligomeric, c1-16-alkyl 11615-47-9 1-5 glycosides Fragrance Proprietary Ingredient.1-1 Chemical name CAS-No. Concentration (%) Sodium poly(oxyethylene) dodecyl ether sulfate 68585-34-2 1-5 glycerin 56-81-5 1-5 2-methylpentane-2,4-diol 17-41-5 1-5 SECTION 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed If inhaled Protection of first-aiders Notes to physician Most important symptoms and effects, both acute and delayed In case of eye contact In case of skin contact If swallowed If inhaled : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur. : If potential for exposure exists refer to Section 8 for specific personal protective equipment. : Treat symptomatically. : See Section 11 for more detailed information on health effects and symptoms. : Rinse with water. : Rinse with water. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. SECTION 5. FIRE-FIGHTING MEASURES 916731-1 2 / 1
Suitable extinguishing media Unsuitable extinguishing media Specific hazards during fire fighting Hazardous combustion products Special protective equipment for fire-fighters Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : None known. : Not flammable or combustible. : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus : Use personal protective equipment. : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. : Refer to protective measures listed in sections 7 and 8. : No special environmental precautions required. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. SECTION 7. HANDLING AND STORAGE 916731-1 3 / 1
Advice on safe handling Conditions for safe storage : Do not get in eyes, on skin, or on clothing. Wash hands thoroughly after handling. : Keep out of reach of children. Store in suitable labeled containers. Storage temperature : 5 C to 5 C Advice on safe handling Conditions for safe storage : No special handling advice required. : Keep out of reach of children. Store in suitable labeled containers. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Form of exposure Permissible concentration Basis glycerin 56-81-5 TWA 1 mg/m3 ACGIH TWA 5 mg/m3 OSHA Z1 (respirable fraction) 2-methylpentane-2,4-diol 17-41-5 Ceiling 25 ppm ACGIH Ceiling 25 ppm 125 mg/m3 NIOSH REL Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures Engineering measures : Wear eye protection/ face protection. : No special protective equipment required. : No special protective equipment required. : No personal respiratory protective equipment normally required. : Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard. : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection Hand protection Skin protection : No special protective equipment required. : No special protective equipment required. : No special protective equipment required. 916731-1 4 / 1
Respiratory protection : No personal respiratory protective equipment normally required. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid liquid Color : clear, yellow light yellow Odor : sweet sweet ph : 5. - 7., 1 % 5. - 7. Flash point Odor Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapor pressure Relative vapor density : Not applicable Relative density : 1.2-1.12 Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Autoignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC : soluble SECTION 1. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition : Stable under normal conditions. : No dangerous reaction known under conditions of normal use. : None known. : None known. : Decomposition products may include the following materials: 916731-1 5 / 1
products Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes Skin Ingestion Inhalation Chronic Exposure Eyes Skin Ingestion Inhalation Chronic Exposure : Causes serious eye damage. Experience with human exposure Eye contact Skin contact Ingestion Inhalation Eye contact Skin contact Ingestion Inhalation : Redness, Pain, Corrosion Toxicity Product Acute oral toxicity : Acute toxicity estimate : > 5, mg/kg 916731-1 6 / 1
Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT-single exposure STOT-repeated exposure Aspiration toxicity Ingredients Acute inhalation toxicity : Acute toxicity estimate : > 5, mg/kg : 2-methylpentane-2,4-diol 4 h LC5 Rat: > 1.1 mg/l Fragrance 4 h Acute toxicity estimate : 4.29 mg/l SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Ingredients Toxicity to fish : Harmful to aquatic life. : Sodium poly(oxyethylene) dodecyl ether sulfate 96 h LC5 Fish: 28 mg/l glycerin 96 h LC5 Fish: 855 mg/l Alkylamidopropylbetaines 96 h LC5 Fish: 2 mg/l d-glucopyranose, oligomeric, c1-16-alkyl glycosides 96 h LC5 Fish: 5 mg/l Ingredients Toxicity to daphnia and other aquatic invertebrates : 2-methylpentane-2,4-diol 48 h EC5 Daphnia: 2,8 mg/l 916731-1 7 / 1
Ingredients Toxicity to algae : d-glucopyranose, oligomeric, decyl octyl glycosides 72 h EC5: 18 mg/l Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations Disposal methods Disposal considerations : Do not contaminate ponds, waterways or ditches with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. Dispose of in accordance with local, state, and federal regulations. : Diluted product can be flushed to sanitary sewer. : Dispose of in accordance with local, state, and federal regulations. SECTION 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) Not dangerous goods Sea transport (IMDG/IMO) Not dangerous goods SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity 916731-1 8 / 1
This material does not contain any components with a CERCLA RQ. SARA 34 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 34 EHS RQ. SARA 311/312 Hazards SARA 32 SARA 313 : Acute Health Hazard : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 32. : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: Switzerland. New notified substances and declared preparations : not determined United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL Australia Inventory of Chemical Substances (AICS) : On the inventory, or in compliance with the inventory New Zealand. Inventory of Chemical Substances : On the inventory, or in compliance with the inventory Japan. ENCS - Existing and New Chemical Substances Inventory : not determined Japan. ISHL - Inventory of Chemical Substances (METI) : not determined Korea. Korean Existing Chemicals Inventory (KECI) : On the inventory, or in compliance with the inventory Philippines Inventory of Chemicals and Chemical Substances (PICCS) : not determined China. Inventory of Existing Chemical Substances in China (IECSC) : On the inventory, or in compliance with the inventory SECTION 16. OTHER INFORMATION 916731-1 9 / 1
Health Health Instability Instability SAFETY DATA SHEET NFPA: Flammability HMIS III: HEALTH 3 3 FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic NFPA: Flammability HMIS III: HEALTH FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Issuing date : 3/3/216 Version : 1.7 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 916731-1 1 / 1