SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable Recommended use : Degreaser Restrictions on use : Reserved for industrial and professional use. Product dilution information : 1.54 % - 33.3 % Company : Ecolab Inc. 45 Corporate Dr., #1 Grapevine, Texas USA 7651-2326 1-866-999-7484 Emergency telephone : 1-866-897-861 (US/Canada), 952-852-4656 (oustide US) Issuing date : 4/16/215 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Eye irritation Eye irritation GHS Label element Signal Word Hazard Statements Precautionary Statements Signal Word Hazard Statements Precautionary Statements : Category 2B : Category 2B : Warning : Causes eye irritation. : Prevention: Wash skin thoroughly after handling. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. : Warning : Causes eye irritation. : Prevention: Wash skin thoroughly after handling. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. Other hazards : None known. 91532 1 / 1
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration (%) Sodium Carbonate(soda) 497-19-8 5-1 Sodium Xylenesulfonate 13-72-7 5-1 ethylenediamine tetraacetate 64-2-8 1-5 alcohols, c1-14, ethoxylated 66455-15- 1-5 Chemical Name CAS-No. Concentration (%) Sodium Carbonate(soda) 497-19-8 1-5 Sodium Xylenesulfonate 13-72-7 1-5 ethylenediamine tetraacetate 64-2-8 1-5 SECTION 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed If inhaled Protection of first-aiders Notes to physician Most important symptoms and effects, both acute and delayed In case of eye contact In case of skin contact If swallowed If inhaled : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. : No special precautions are necessary for first aid responders. : Treat symptomatically. : See Section 11 for more detailed information on health effects and symptoms. : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during fire fighting : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : None known. : Not flammable or combustible. 91532 2 / 1
Hazardous combustion products Special protective equipment for fire-fighters Specific extinguishing methods : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus : Use personal protective equipment. : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. : Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. SECTION 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage : Wash hands thoroughly after handling. : Do not store near acids. Keep out of reach of children. Store in suitable labeled containers. Storage temperature : -5 C to 5 C Advice on safe handling Conditions for safe storage : Wash hands thoroughly after handling. : Do not store near acids. Keep out of reach of children. Store in suitable labeled containers. 91532 3 / 1
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection No special protective equipment required. Hand protection Skin protection Respiratory protection Hygiene measures Engineering measures : No personal respiratory protective equipment normally required. : Handle in accordance with good industrial hygiene and safety practice. : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection : No personal respiratory protective equipment normally required. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid liquid Color : clear, purple purple Odor : citrus citrus ph : 12.4-13.2, 1 % 12.2-13. Flash point Odor Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) : Not applicable, Does not sustain combustion. : 1 C 91532 4 / 1
Upper explosion limit Lower explosion limit Vapor pressure Relative vapor density Relative density : 1.12-1.14 Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Autoignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC : The substance or mixture is not classified as oxidizing. SECTION 1. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : No dangerous reaction known under conditions of normal use. : None known. : Acids : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes Skin Ingestion Inhalation Chronic Exposure : Causes eye irritation. 91532 5 / 1
Eyes Skin Ingestion Inhalation Chronic Exposure : Causes eye irritation. Experience with human exposure Eye contact Skin contact Ingestion Inhalation Eye contact Skin contact Ingestion Inhalation : Redness, Irritation : Redness, Irritation Toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT-single exposure STOT-repeated exposure Aspiration toxicity Ingredients Acute dermal toxicity : Acute toxicity estimate : > 5, mg/kg : Mild skin irritation : Mild eye irritation : alcohols, c1-14, ethoxylated LD5 Rat: > 2, mg/kg 91532 6 / 1
SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Ingredients Toxicity to fish : This product has no known ecotoxicological effects. : ethylenediamine tetraacetate 96 h LC5 Fish: 121 mg/l alcohols, c1-14, ethoxylated 96 h LC5 Fish: 1.125 mg/l Ingredients Toxicity to daphnia and other aquatic invertebrates Ingredients Toxicity to algae : Sodium Carbonate(soda) 48 h EC5 Daphnia: 2 mg/l : Sodium Xylenesulfonate 96 h EC5: 23 mg/l Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations RCRA - Resource Conservation and Recovery Authorization Act Hazardous waste : Diluted product can be flushed to sanitary sewer. : Dispose of in accordance with local, state, and federal regulations. : D2 (Corrosive) 91532 7 / 1
Disposal methods Disposal considerations : Diluted product can be flushed to sanitary sewer. : Dispose of in accordance with local, state, and federal regulations. SECTION 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) Not dangerous goods Sea transport (IMDG/IMO) Not dangerous goods Not intended for transport. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 34 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 34 EHS RQ. SARA 311/312 Hazards SARA 32 SARA 313 : Acute Health Hazard : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 32. : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: Switzerland. New notified substances and declared preparations : United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : This product contains one or several components listed in the Canadian NDSL. 91532 8 / 1
Health Health Instability Instability SAFETY DATA SHEET Australia Inventory of Chemical Substances (AICS) : On the inventory, or in compliance with the inventory New Zealand. Inventory of Chemical Substances : On the inventory, or in compliance with the inventory Japan. ENCS - Existing and New Chemical Substances Inventory : Japan. ISHL - Inventory of Chemical Substances (METI) : Korea. Korean Existing Chemicals Inventory (KECI) : Philippines Inventory of Chemicals and Chemical Substances (PICCS) : China. Inventory of Existing Chemical Substances in China (IECSC) : SECTION 16. OTHER INFORMATION NFPA: Flammability HMIS III: HEALTH 1 1 FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic NFPA: Flammability HMIS III: HEALTH 1 1 FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Issuing date : 4/16/215 Version : 1. Prepared by : Regulatory Affairs 91532 9 / 1
REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 91532 1 / 1