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Transcription:

This SDS adheres to the standards and regulatory requirements of the United States and may not meet the regulatory requirements in other countries. SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Tradename/Synonym : B12954857 INDOXACARB: (S)-Methyl 7-chloro-2,5-dihydro 2[[(methoxycarbonyl)[4- (trifluoromethoxy)phenyl]amino]-carbonyl]indeno[1,2e][1,3,4]oxadiazine- 4a(3H)-carboxylate) MSDS Number : 130000104284 Manufacturer : DuPont 1007 Market Street Wilmington, DE 19898 Product Information : 1-800-441-7515 (outside the U.S. 1-302-774-1000) Medical Emergency : 1-800-441-3637 (outside the U.S. 1-302-774-1139) Transport Emergency : CHEMTREC: 1-800-424-9300 (outside the U.S. 1-703-527-3887) SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Caution Avoid contact with skin, eyes and clothing. Wash thoroughly with soap and water after handling. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Avoid treating areas that are easily accessible to children and pets. Potential Health Effects This product has no known adverse effect on human health. Carcinogenicity None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, or OSHA, as a carcinogen. 1 / 7

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS-No. Concentration Indoxacarb 173584-44-6 0.6 % Other Ingredients 99.4 % SECTION 4. FIRST AID MEASURES Skin contact : The material is not likely to be hazardous by skin contact, but cleansing the skin after use is advisable. Consult a physician if necessary. Eye contact Inhalation Ingestion General advice : No specific intervention is indicated as the compound is not likely to be hazardous. Consult a physician if necessary. : No specific intervention is indicated as the compound is not likely to be hazardous. Consult a physician if necessary. : No specific intervention is indicated as the compound is not likely to be hazardous. Consult a physician if necessary. : Have the product container or label with you when calling a poison control center or doctor, or going for treatment. For medical emergencies involving this product, call toll free 1-800-441-3637. See Label for Additional Precautions and Directions for Use. SECTION 5. FIRE-FIGHTING MEASURES Fire and Explosion Hazard : Not a fire or explosion hazard. Suitable extinguishing media : Water spray, Foam, Dry chemical, Carbon dioxide (CO2) 2 / 7

Unsuitable extinguishing media Firefighting Instructions : High volume water jet, (contamination risk) : In the event of fire, wear self-contained breathing apparatus. Wear full protective equipment. Evacuate personnel and keep upwind of fire. SECTION 6. ACCIDENTAL RELEASE MEASURES NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with cleanup. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Safeguards (Personnel) Spill Cleanup Accidental Release Measures : Evacuate personnel, thoroughly ventilate area, use self-contained breathing apparatus. : Clean-up methods - small spillage For small spills, use cloth or paper towels and place collected material and towels in appropriate container for disposal. Clean-up methods - large spillage Soak up with sawdust, sand, oil dry or other absorbent material. Sweep up and shovel into suitable containers for disposal. Flush away traces with water and detergent. : Prevent material from entering sewers, waterways, or low areas. Dispose of in accordance with local regulations. SECTION 7. HANDLING AND STORAGE Handling (Personnel) : Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Avoid contamination of food. Handling (Physical Aspects) Storage : Do not apply this product around electrical equipment due to the possibility of shock hazard. : Do not contaminate water, other pesticides, fertilizer, food or feed in storage. Store in a cool, dry place. Store product in original container only in a location inaccessible to children and pets. 3 / 7

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment Skin and body protection Protective measures : No PPE is specified however, avoid contact with skin, eyes, and clothing. : Use this product in accordance with its label. Exposure Guidelines Exposure Limit Values None established. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Form : gel Color : yellow Odor : none ph : 6.08 Oxidizing : The product is not oxidizing. Density : 1.0755 g/ml at 20 C (68 F) SECTION 10. STABILITY AND REACTIVITY Stability : Stable at normal temperatures and storage conditions. Incompatibility : None reasonably foreseeable. SECTION 11. TOXICOLOGICAL INFORMATION Dermal LD50 : > 5,000 mg/kg, rat Oral LD50 : > 5,000 mg/kg, rat Skin irritation : No skin irritation, rabbit 4 / 7

Eye irritation : No eye irritation, rabbit Sensitisation : Causes skin sensitization., guinea pig Indoxacarb Inhalation 4 h LC50 : 4.2 mg/l, female, rat Repeated dose toxicity : The following effects occurred at levels of exposure that significantly exceed those expected under labeled usage conditions. Inhalation rat Incoordination, Increased mortality or reduced survival, Respiratory irritation Oral rat Red blood cell destruction causing abnormal decrease in number of red blood cells (anaemia) Carcinogenicity : Did not show carcinogenic effects in animal experiments. Mutagenicity : Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Did not cause genetic damage in animals. Reproductive toxicity : Animal testing did not show any effects on fertility. Teratogenicity : Animal testing showed effects on embryo-fetal development at levels equal to or above those causing maternal toxicity. SECTION 12. ECOLOGICAL INFORMATION Aquatic Toxicity Indoxacarb 96 h LC50 : Oncorhynchus mykiss (rainbow trout) 0.65 mg/l 48 h EC50 : Daphnia magna (Water flea) 0.60 mg/l 5 / 7

Additional ecological information : Environmental Hazards: Do not apply directly to water, or to areas where surface water is present, or to intertidal areas below the mean high water mark. SECTION 13. DISPOSAL CONSIDERATIONS Waste Disposal : Do not contaminate water, food or feed by disposal. Wastes resulting from the use of this product must be disposed of on site or at an approved waste disposal facility. Container Disposal : Do not reuse/refill the gel bait dispenser. Place empty bait dispensers in trash, offer for recycling, or call your local solid waste authority for disposal instructions. SECTION 14. TRANSPORT INFORMATION Not Regulated as a hazardous material by DOT, IMO, or IATA. SECTION 15. REGULATORY INFORMATION SARA 313 Regulated Chemical(s) : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. EPA Reg. No. : 352-652 In the United States this product is regulated by the US Environmental Protection Agency (EPA) under the Federal Insecticide, Fungicide and Rodenticide Act (FIFRA). It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Read and follow all label directions. This product is excluded from listing requirements under EPA/TSCA. 6 / 7

SECTION 16. OTHER INFORMATION Trademark of E.I. du Pont de Nemours and Company. Registered trademark of E.I. du Pont de Nemours and Company Contact person : DuPont Crop Protection, Wilmington, DE, 19898, Phone: 1-888-638-7668 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Significant change from previous version is denoted with a double bar. 7 / 7