SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Apicide Product code : AP1012 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Insecticide 1.3. Details of the supplier of the safety data sheet Mystic Chemical Products 4520 West 160 th St. Cleveland, OH 44135 (216) 251-4416 1.4. Emergency telephone number Emergency Number: Infotrac 1-800-535-5053 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Carc. 2 H351 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS08 : Warning : H351 - Suspected of causing cancer. : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P280 - Wear protective gloves/eye protection/protective clothing P308+P313 - IF exposed or concerned: Get medical advice/attention P405 - Store locked up P501 - Dispose of contents/container to in accordance with loacl/national regulations 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients Mixture Name Product identifier % Classification (GHS-US) carbaryl (CAS No) 63-25-2 5 Acute Tox. 3 (Oral), H301 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation:dust,mist), H332 Carc. 2, H351 Aquatic Acute 1, H400 06/19/2015 EN (English US) Page 1
SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Suspected of causing cancer (.). : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Protect from moisture. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. : Store in original container. Keep container closed when not in use. Protect from moisture. : Strong bases. strong acids. : Sources of ignition. 06/19/2015 EN (English US) 2/6
SECTION 8: Exposure controls/personal protection 8.1. Control parameters USA ACGIH ACGIH TWA (mg/m³) 0.5 mg/m³ 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Respiratory protection : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. : Wear approved mask. : When using, do not eat, drink or smoke. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : White to tan solid. Color : white to tan. Odor : Minimal, if any. Odor threshold ph Relative evaporation rate (butyl acetate=1) Melting point : > 1300 C Freezing point Boiling point Flash point : 380 F Self ignition temperature Decomposition temperature Flammability (solid, gas) : Not flammable Vapor pressure Relative vapor density at 20 C Relative density : 1.23 Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidizing properties Explosive limits 9.2. SECTION 10: Stability and reactivity 10.1. Reactivity 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Extremely high or low temperatures. 06/19/2015 EN (English US) 3/6
10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rat LD50 dermal rabbit ATE (oral) ATE (gases) ATE (vapors) ATE (dust, mist) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC group Reproductive toxicity Specific target organ toxicity (single exposure) 230 mg/kg (Rat) 4000 mg/kg (Rat) 2000 mg/kg (Rabbit) 500.000 mg/kg body weight 4500.000 ppmv/4h 11.000 mg/l/4h 1.500 mg/l/4h : Suspected of causing cancer. 3 - Not Classifiable Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1. Toxicity LC50 fish 1 EC50 Daphnia 1 EC50 other aquatic organisms 1 LC50 fish 2 EC50 Daphnia 2 TLM fish 1 TLM fish 2 Threshold limit algae 1 Threshold limit algae 2 2-10.36 mg/l (96 h; Cyprinus carpio) 0.0064 mg/l (48 h; Daphnia pulex; Larvae) 0.0076 mg/l (48 h; Simocephalus serrulatis) 0.86-4.3 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) 2.3 ppm (96 h; Mytilus edulis) 2.5 ppm (96 h; Oncorhynchus kisutch; Young) 5.5 ppm (96 h; Lepomis macrochirus) 0.03 mg/l (Microcystis aeruginosa) 1.4 mg/l (Scenedesmus quadricauda) 12.2. Persistence and degradability Apicide Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) Not established. Readily biodegradable in water. 0 g O²/g substance 06/19/2015 EN (English US) 4/6
12.3. Bioaccumulative potential Apicide Bioaccumulative potential Not established. BCF fish 1 BCF other aquatic organisms 1 BCF other aquatic organisms 2 140 (Ictalurus punctatus) 4000 (Algae) 260 (Crustacea) Log Pow 2.32-2.36 Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). 12.4. Mobility in soil Ecology - soil 12.5. Other adverse effects Not toxic to plants. Toxic to bees. : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with DOT No dangerous good in sense of transport regulations Additional information ADR Transport document description : Transport by sea Air transport SECTION 15: Regulatory information : Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment. : No supplementary information available. This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION: Harmful if swallowed. Harmful is absorbed through the skin. Avoid contact with eyes, skin, or clothing. 15.1. US Federal regulations 15.2. International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC or 1999/45/EC Not classified 15.2.2. National regulations 06/19/2015 EN (English US) 5/6
15.3. US State regulations SECTION 16: : None. Full text of H-phrases: see section 16: ------ Acute Tox. 3 (Oral) Acute toxicity (oral) Category 3 ------ Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category 4 ------ Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 ------ Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1 ------ Carc. 2 Carcinogenicity Category 2 ------ H301 Toxic if swallowed ------ H312 Harmful in contact with skin ------ H332 Harmful if inhaled ------ H351 Suspected of causing cancer ------ H400 Very toxic to aquatic life SDS US (GHS HazCom 2012) - Pesticides This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. 06/19/2015 EN (English US) 6/6