1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : OFF! SKINTASTIC LOTION INSECT REPELLENT - UNSCENTED Use of the Substance/Preparation : Insect Repellent Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1 Emergency telephone : 24 Hour Transport & Medical Emergency Phone (866) 231-5406 24 Hour International Emergency Phone (952) 852-4647 24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666 2. HAZARDS IDENTIFICATION Emergency Overview Appearance / Odor Immediate Concerns : white / cream / pleasant : Caution CAUSES EYE IRRITATION. Avoid contact with eyes and lips. Potential Health Effects Routes of exposure : Eye, Skin, Inhalation, Ingestion. Eyes : May cause: Moderate eye irritation Skin : May cause skin reactions in rare cases. Inhalation : None known. Ingestion : May cause: Abdominal discomfort. May cause irritation to mouth, throat and stomach. Aggravated Medical Condition : None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight % Deionized Water 7732-18-5 60.00-100.00 N,N-Diethyl-m-toluamide 134-62-3 7.50 1/8
Distearyldimethylammoniu 107-64-2 m chloride 3.00-7.00 Petrolatum 8009-03-8 1.00-5.00 Glycerol 56-81-5 1.00-5.00 Cetyl Alcohol 36653-82-4 1.00-5.00 4. FIRST AID MEASURES Eye contact : Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists. Skin contact : Wash off with soap and water. Get medical attention if irritation develops and persists. Inhalation : No special requirements. Ingestion : Do NOT induce vomiting. Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician or Poison Control Centre immediately. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Specific hazards during fire fighting : Alcohol foam, carbon dioxide, dry chemical, water fog : Container may melt and leak in heat of fire. Further information : Wear full protective clothing and positive pressure selfcontained breathing apparatus. Standard procedure for chemical fires. Flash point : Note: does not flash Lower explosion limit : Note Upper explosion limit : Note 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up : Dike large spills. Soak up with inert absorbent material. 2/8
Sweep up and shovel into suitable containers for disposal. 7. HANDLING AND STORAGE Handling Advice on safe handling : Use only as directed. Avoid contact with eyes and lips. KEEP OUT OF REACH OF CHILDREN AND PETS. Storage Requirements for storage areas and containers : Keep in a dry, cool and well-ventilated place. 3/8
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Basis Glycerol 56-81-5 10 mg/m3 ACGIH_TWAS 10 mg/m3 CA-AB_TWAS 10 mg/m3 CA-BC_TWAS 3 mg/m3 CA-BC_TWAS 10 mg/m3 CA-MB_TWAS 10 mg/m3 CA-NB_TWAS 10 mg/m3 CA-NS_TWAS 20 mg/m3 CA-NT_STEL 10 mg/m3 CA-NT_TWAS 20 mg/m3 CA-NU_STEL 10 mg/m3 CA-NU_TWAS 10 mg/m3 CA-ON_TWAE 10 mg/m3 CA-QC_TWAE 10 mg/m3 CA-YK_TWAS 20 mg/m3 CA-SK_STEL 10 mg/m3 CA-SK_TWAS 10 mg/m3 GCC_OELTWA Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Hand protection : not required under normal use 4/8
Eye protection : No special requirements. If prolonged or repeated contact is possible: Safety glasses with side-shields Hygiene measures : Use only with adequate ventilation. Wash thoroughly after handling. Wear suitable protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Color Odor : cream : white : pleasant ph : 5.0-5.5 Boiling point Flash point Evaporation rate Autoignition temperature Lower explosion limit Upper explosion limit Vapour pressure Water solubility Specific Gravity : does not flash : dispersible : similar to water 10. STABILITY AND REACTIVITY Conditions to avoid : None known. Materials to avoid Hazardous decomposition products : Oxidizing agents Natural Rubber Plastic : When exposed to fire, produces normal products of combustion. 5/8
Hazardous reactions : Stable 11. TOXICOLOGICAL INFORMATION Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Sensitisation 12. ECOLOGICAL INFORMATION Ecotoxicity effects Not Available 13. DISPOSAL CONSIDERATIONS Product : Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. 14. TRANSPORT INFORMATION Land transport U.S. DOT and Canadian TDG Surface Transportation UN-Number: Proper shipping name not regulated Class: 6/8
Packaging group Sea transport IMDG: UN-Number: Packaging group: Proper shipping name Class: Air transport ICAO/IATA: Class: Packaging group: Proper shipping name UN/ID No.: not regulated not regulated 15. REGULATORY INFORMATION Global Chemical Inventories Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65. : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. OTHER INFORMATION HMIS Ratings 7/8
Health 2 Flammability 0 Reactivity 0 NFPA Ratings Health 2 Fire 0 Reactivity 0 Special Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) 8/8