SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable Recommended use : Disinfectant Restrictions on use : Reserved for industrial and professional use. Product dilution information :.625 % -.9375 % Company : Ecolab Inc. 37 N. Wabasha Street St. Paul, Minnesota USA 5512 1-8-352-5326 Emergency telephone : 1-8-328-26 (US/Canada), 1-651-222-5352 (outside US) Issuing date : 2/16/215 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Serious eye damage : Category 1 Eye irritation : Category 2B GHS Label element Hazard pictograms : Signal Word Hazard Statements Precautionary Statements Signal Word Hazard Statements Precautionary Statements : Danger : Causes serious eye damage. : Prevention: Wear eye protection/ face protection. Do not mix with bleach or other chlorinated products will cause chlorine gas. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. : Caution : Causes eye irritation. : Prevention: Wash skin thoroughly after handling. 915516 1 / 1
Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. Other hazards : None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration (%) citric acid 77-92-9 1-3 amines, c8-18 and c18-unsatd. alkyl, ethoxylated 68439-72-5 1-3 Decanoic Acid 334-48-5 1.65 Nonanoic acid 112-5- 1-5 Chemical Name CAS-No. Concentration (%) Decanoic Acid 334-48-5.1 -.15 SECTION 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed If inhaled Protection of first-aiders Notes to physician Most important symptoms and effects, both acute and delayed In case of eye contact In case of skin contact If swallowed If inhaled : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur. : If potential for exposure exists refer to Section 8 for specific personal protective equipment. : Treat symptomatically. : See Section 11 for more detailed information on health effects and symptoms. : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. SECTION 5. FIRE-FIGHTING MEASURES 915516 2 / 1
Suitable extinguishing media Unsuitable extinguishing media Specific hazards during fire fighting Hazardous combustion products Special protective equipment for fire-fighters Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : None known. : Not flammable or combustible. : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus : Use personal protective equipment. : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. : Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Do not get in eyes, on skin, or on clothing. Wash hands thoroughly 915516 3 / 1
after handling. Do not mix with bleach or other chlorinated products will cause chlorine gas. Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. Storage temperature : 5 C to 4 C Advice on safe handling Conditions for safe storage : Wash hands thoroughly after handling. : Keep out of reach of children. Store in suitable labeled containers. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures Engineering measures : Wear eye protection/ face protection. : No special protective equipment required. : No special protective equipment required. : No personal respiratory protective equipment normally required. : Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard. : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection : No special protective equipment required. : No special protective equipment required. : No special protective equipment required. : No personal respiratory protective equipment normally required. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid liquid Color : clear, pink pink Odor : soapy soapy 915516 4 / 1
ph : 2.8, 1 % 2.8 Flash point Odor Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapor pressure Relative vapor density : Not applicable, Does not sustain combustion. : 1 C Relative density : 1.75-1.95 Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Autoignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC : soluble SECTION 1. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : Do not mix with bleach or other chlorinated products will cause chlorine gas. : None known. : Chlorine-based bleaching agents Strong bases Water-reactive substances : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of : Inhalation, Eye contact, Skin contact 915516 5 / 1
exposure Potential Health Effects Eyes Skin Ingestion Inhalation Chronic Exposure Eyes Skin Ingestion Inhalation Chronic Exposure : Causes serious eye damage. : Causes eye irritation. Experience with human exposure Eye contact Skin contact Ingestion Inhalation Eye contact Skin contact Ingestion Inhalation : Redness, Pain, Corrosion : Redness, Irritation Toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Respiratory or skin sensitization Carcinogenicity : Acute toxicity estimate : > 5, mg/kg : 4 h Acute toxicity estimate : > 4 mg/l 915516 6 / 1
Reproductive effects Germ cell mutagenicity Teratogenicity STOT-single exposure STOT-repeated exposure Aspiration toxicity Ingredients Acute dermal toxicity : Decanoic Acid LD5 Rabbit: > 5, mg/kg Nonanoic acid LD5 Rat: > 2, mg/kg SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Ingredients Toxicity to fish : This product has no known ecotoxicological effects. : citric acid 96 h LC5 Fish: > 1 mg/l Decanoic Acid 96 h LC5 Fish: 2 mg/l Ingredients Toxicity to daphnia and other aquatic invertebrates : Nonanoic acid 48 h EC5 Daphnia: 96 mg/l Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS 915516 7 / 1
Disposal methods Disposal considerations Disposal methods Disposal considerations : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. Dispose of in accordance with local, state, and federal regulations. : Diluted product can be flushed to sanitary sewer. : Dispose of in accordance with local, state, and federal regulations. SECTION 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) Not dangerous goods Sea transport (IMDG/IMO) Not dangerous goods Not intended for transport. SECTION 15. REGULATORY INFORMATION EPA Registration number : 1677-246 EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 34 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 34 EHS RQ. SARA 311/312 Hazards SARA 32 SARA 313 : Acute Health Hazard : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 32. : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. 915516 8 / 1
Health Instability SAFETY DATA SHEET The ingredients of this product are reported in the following inventories: United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : This product contains one or several components that are not on the Canadian DSL nor NDSL. Australia Inventory of Chemical Substances (AICS) : New Zealand. Inventory of Chemical Substances : Japan. ENCS - Existing and New Chemical Substances Inventory : Japan. ISHL - Inventory of Chemical Substances (METI) : Korea. Korean Existing Chemicals Inventory (KECI) : Philippines Inventory of Chemicals and Chemical Substances (PICCS) : China. Inventory of Existing Chemical Substances in China (IECSC) : SECTION 16. OTHER INFORMATION NFPA: Flammability HMIS III: HEALTH 3 3 FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic 915516 9 / 1
NFPA: Flammability HMIS III: HEALTH Health Instability FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Issuing date : 2/16/215 Version : 1. Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 915516 1 / 1