SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable Recommended use : All Purpose Cleaner Restrictions on use : Reserved for industrial and professional use. Product dilution information : 1.5625 % - 6.25 % Company : Ecolab Inc. 37 N. Wabasha Street St. Paul, Minnesota USA 5512 1-8-352-5326 Emergency telephone : 1-8-328-26 (US/Canada), 1-651-222-5352 (outside US) Issuing date : 1/2/214 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Eye irritation : Category 2A Skin sensitization : Category 1 Not a hazardous substance or mixture. GHS Label element Hazard pictograms : Signal Word Hazard Statements Precautionary Statements : Warning : May cause an allergic skin reaction. Causes serious eye irritation. : Prevention: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Wash skin thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear eye protection/ face protection. Wear protective gloves. Do not mix with bleach or other chlorinated products will cause chlorine gas. Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Wash contaminated clothing before reuse. Disposal: 914412 1 / 1
Dispose of contents/ container to an approved waste disposal plant. Precautionary Statements : Prevention: Wash hands thoroughly after handling. Response: Get medical advice/ attention if you feel unwell. Storage: Store in accordance with local regulations. Other hazards : None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration (%) sodium dodecylbenzene sulfonate 25155-3- 5-1 Linear Alkylbenzenesulphonates 27323-41-7 5-1 Poly(oxy-1,2-ethanediyl),.alpha.-(phenylmethyl)- 2643-74-7 5-1.omega.-hydroxy- Ethoxylated alkyl sulfate 68585-34-2 1-5 d-limonene 5989-27-5 1-5 ethanol 64-17-5 1-5 No hazardous ingredients SECTION 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed If inhaled Protection of first-aiders Notes to physician In case of eye contact In case of skin contact If swallowed If inhaled : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention. : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. : If potential for exposure exists refer to Section 8 for specific personal protective equipment. : Treat symptomatically. : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. 914412 2 / 1
See toxicological information (Section 11) SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during fire fighting Hazardous combustion products Special protective equipment for fire-fighters Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : None known. : Not flammable or combustible. : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus : Use personal protective equipment. : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. : Refer to protective measures listed in sections 7 and 8. : No special environmental precautions required. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. SECTION 7. HANDLING AND STORAGE 914412 3 / 1
Advice on safe handling Conditions for safe storage : Do not get in eyes, on skin, or on clothing. Wash hands thoroughly after handling. Do not mix with bleach or other chlorinated products will cause chlorine gas. : Keep out of reach of children. Store in suitable labeled containers. Storage temperature : C to 5 C Advice on safe handling : Wash hands after handling. For personal protection see section 8. Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Form of exposure Permissible concentration Basis d-limonene 5989-27-5 TWA 2 ppm ACGIH ethanol 64-17-5 TWA 1, ppm NIOSH REL 1,9 mg/m3 TWA 1, ppm OSHA Z1 1,9 mg/m3 STEL 1, ppm ACGIH sulphuric acid 7664-93-9 TWA (Thoracic.2 mg/m3 ACGIH fraction) TWA 1 mg/m3 NIOSH REL TWA 1 mg/m3 OSHA Z1 Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures Engineering measures : Safety glasses with side-shields : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. : No special protective equipment required. : No personal respiratory protective equipment normally required. : Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. 914412 4 / 1
Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection : No special protective equipment required. : No special protective equipment required. : No special protective equipment required. : No personal respiratory protective equipment normally required. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid liquid Color : dark orange light orange Odor : citrus citrus ph : 8.25, 1 % 7. - 8. Flash point Odor Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapor pressure Relative vapor density : Not applicable Relative density : 1. - 1.12 Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Autoignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC SECTION 1. STABILITY AND REACTIVITY Chemical stability : Stable under normal conditions. 914412 5 / 1
Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Do not mix with bleach or other chlorinated products will cause chlorine gas. : None known. : None known. : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes Skin Ingestion Inhalation Chronic Exposure Eyes Skin Ingestion Inhalation Chronic Exposure : Causes serious eye irritation. : May cause allergic skin reaction. Experience with human exposure Eye contact Skin contact Ingestion Inhalation Eye contact Skin contact Ingestion : Redness, Pain, Irritation : Redness, Irritation, Allergic reactions 914412 6 / 1
Inhalation Toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT-single exposure STOT-repeated exposure Aspiration toxicity Ingredients Acute inhalation toxicity Ingredients Acute dermal toxicity : Acute toxicity estimate : > 5, mg/kg : ethanol 4 h LC5 Rat: 117 mg/l : Ethoxylated alkyl sulfate LD5 Rat: > 2, mg/kg d-limonene LD5 Rabbit: > 5, mg/kg ethanol LD5 Rabbit: 15,8 mg/kg SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Ingredients Toxicity to fish : Harmful to aquatic life with long lasting effects. : sodium dodecylbenzene sulfonate 914412 7 / 1
Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available 96 h LC5: 3.2 mg/l Poly(oxy-1,2-ethanediyl),.alpha.-(phenylmethyl)-.omega.-hydroxy- 96 h LC5: > 1 mg/l Ethoxylated alkyl sulfate 96 h LC5 Fish: 28 mg/l SECTION 13. DISPOSAL CONSIDERATIONS ethanol 96 h LC5 Fish: 11, mg/l Disposal methods Disposal considerations Disposal methods Disposal considerations : The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. SECTION 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) Not dangerous goods Sea transport (IMDG/IMO) 914412 8 / 1
Not dangerous goods Not intended for transport. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity Ingredients CAS-No. Component RQ (lbs) Calculated product RQ (lbs) sodium dodecylbenzene sulfonate 25155-3- 1 1375 SARA 34 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 34 EHS RQ. SARA 311/312 Hazards SARA 32 SARA 313 : Acute Health Hazard : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 32. : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: Switzerland. New notified substances and declared preparations : The mixture contains substances listed on the Swiss Inventory United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : This product contains one or several components listed in the Canadian NDSL. Australia Inventory of Chemical Substances (AICS) : New Zealand. Inventory of Chemical Substances : Japan. ENCS - Existing and New Chemical Substances Inventory : Japan. ISHL - Inventory of Chemical Substances (METI) : Korea. Korean Existing Chemicals Inventory (KECI) : Philippines Inventory of Chemicals and Chemical Substances (PICCS) : 914412 9 / 1
Health Health Instability Instability SAFETY DATA SHEET China. Inventory of Existing Chemical Substances in China (IECSC) : SECTION 16. OTHER INFORMATION NFPA: Flammability HMIS III: HEALTH 2* 2 FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic NFPA: Flammability HMIS III: HEALTH FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Issuing date : 1/2/214 Version : 1. Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 914412 1 / 1