Safety in the EKL cleanrooms Cassan Visser March 2015 13
Introduction What is Safety? - Safety Principles - Risk Assessment - Toxicology - Psychology 14
Introduction: Safety principles Precautionary principle Assume the worst, if you do not know or in doubt: STOP (e.g. asbestos) Proportionality principle Make a risk assessment (e.g. drive a car) www.nu.nl De voorstellingen van de musical The Bodyguard in het Beatrix Theater in Utrecht zijn tot en met dinsdag afgelast wegens de aanwezigheid van asbest in het achtergebouw van het theater. Volgens de organisatie was er geen direct gevaar voor de gezondheid, maar uit voorzorg en voor verder onderzoek kon de voorstelling van The Bodyguard niet doorgaan. 15
Introduction: Risk Assessment Safety is about Risk Assessment - What are the risks of the project? - Worst case scenario - Avoid/Prevent/Minimize the risks - What to do if it is going wrong - Are there alternatives? - Is the project worth the risks? - Make an informed decision (risk is probability) - Need Knowledge - Risk Assessment always neccessary by every user 16
Introduction: Risk Assessment Safety is about Risk Assessment - What are the risks of the project? - Worst case scenario - Avoid/Prevent/Minimize the risks - What to do if it is going wrong - Are there alternatives? - Is the project worth the risks? street? - Make an informed decision (risk is probability) - Need Knowledge - Risk Assessment always neccessary by every user Project: crossing the street -hit by car -Injury/Death -Look, determine speed -Run, turn back -Go to official street crossing -Do I really have to cross the 17
Introduction: Risk Assessment Safety is about Risk Assessment - What are the risks of the project? - Worst case scenario - Avoid/Prevent/Minimize the risks - What to do if it is going wrong - Are there alternatives? - Is the project worth the risks? - Make an informed decision (risk is probability) - Need Knowledge - Risk Assessment always neccessary by every user Project: etching in HF -HF on skin, inhale vapors -Injury -Check MSDS, Use PPE, work in fume hood -Alarm, Hexafluorine, Hospital -Plasma etching? -Do I really have to etch the layer? 18
Introduction: Lab Safety Lab Management provides a save environment 1. Create an Institutional Safety and Security Oversight Committee and Appoint a CSSO 2. Develop a Chemical Safety and Security Policy 3. Create Administrative Controls and Processes for Performance Measurement * 4. Identify and Address Particularly Hazardous Situations 5. Evaluate Facilities and Address Weaknesses 6. Set Procedures for Chemical Handling and Management 7. Use Engineering Controls and Personal Protective Equipment 8. Plan for Emergencies 9. Identify and Address Barriers to Following Safety and Security Best Practices 10.Train, Communicate, and Mentor Source: USA-National Research Counsil 19
Introduction: Lab Safety Safety Organisation 1. Safety Management (CSSO): Casper 2. Head EKL Emergency Response Team: Jan Warmerdam 3. Occupational Health Regulations: Tom de Weger 4. Chemical/Gas Inventory and Waste: Robert Verhoeven, Ron van Viersen 5. Emergency Plans and Systems -Detectors, Buttons, Emergency kits: Jan Warmerdam 6. Training: Cassan, Johannes, Mapper 7. Training material, Information, Safety Notes, Procedures: Cassan, Silva 8. Introduction New chemicals: Cassan, Alex 9. General Safety Awareness: Cassan 20
Introduction Paracelsus (1493-1541) "All substances are poisons; there is none, which is not a poison. The right dose differentiates a poison from a remedy." 21
Introduction Paracelsus (1493-1541) "All substances are poisons; there is none, which is not a poison. The right dose differentiates a poison from a remedy." Botulinum toxin LD50=100ng/kg 22
Introduction Paracelsus (1493-1541) "All substances are poisons; there is none, which is not a poison. The right dose differentiates a poison from a remedy." Botulinum toxin LD50=100ng/kg Botox dose 5 pg 23
Introduction Paracelsus (1493-1541) "All substances are poisons; there is none, which is not a poison. The right dose differentiates a poison from a remedy." Botulinum toxin LD50=100ng/kg Botox dose 5 pg USA sold last year: 20mg Turnover: 2 billion dollar! 24
Introduction Paracelsus (1493-1541) "All substances are poisons; there is none, which is not a poison. The right dose differentiates a poison from a remedy." Acute Chronic 25
Introduction: Toxicology Risk = hazard x exposure x individual sensitivity - Amount - Duration of work (in MSDS often 8hr) - Frequency (in MSDS every day of the week) - Subject (Male/Female, Age, ) - Route of exposure 26
Introduction: Psychology Safety is about people - Common sense - Common sense is subjective, based on a person s everyday selective experiences and biased interpretation of those experiences Scientific proof is what counts. (eg water instead of diphoterine) - Accepting rules - Depends on personal factors, culture, respect for authority,... - Mutual responsibility - Who is responsible for safety? - Giving positive feedback - Everyone is accountable for his actions 27
Introduction: Training Goal Awareness of safety Explanation of the Safety, Security and Behavior Rules in EKL Training Intranet course (since 2014) Classroom training 1-1 module training: working with chemicals (since 2016) Lab users must refresh their safety knowlegdge yearly (since 2016) Feedback of users is essential Resources Intranet Safety page with safety information (since 2014) Communication about new or changed rules Safety standard part of lab user meeting and EKL staff meeting (since 2014) 28
Introduction: Training Resources Safety info on internet of most university labs in the world Scientific literature on Safety / Toxicology / Psychology Documents OSHA USA, European Commission Chemical learning centers You tube Input of safety experts inside/outside TU Delft Input of chemists 29
Introduction: Incidents Chemical incidents in EKL in the last 5 years: 12 10 ERT Actions (excl false alarms) 8 6 4 2 Total Fire Chemical Gas Other 0 2010 2011 2012 2013 2014 2015 2016 30
Introduction: Incidents Chemical incidents in EKL in the last 5 years: Drops on skin or suspected contamination (i.e : one feels itching after a couple of hours): HF related: 8x HNO3 related: 6x Fallen/Broken beakers: 5x Inhalation of KOH: 1x 12 10 8 6 ERT Actions (excl false alarms) Total Fire Chemical 4 Gas Other 2 0 2010 2011 2012 2013 2014 2015 2016 31