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DRAFT ÖNORM EN 19694-4 Edition: 2016-03-15 Stationary source emissions Determination of greenhouse gas (GHG) emissions in energy-intensive industries Part 4: Aluminium industry Emissionen aus stationären Quellen Bestimmung von Treibhausgasen (THG) aus energieintensiven Industrien Teil 4: Aluminiumindustrie Émissions de sources fixes Détermination des émissions de gaz à effet de serre (GES) dans les industries énergo-intensives Partie 4: Industrie de l'aluminium Publisher and printing Austrian Standards Institute/ Österreichisches Normungsinstitut Heinestraße 38, 1020 Wien Copyright Austrian Standards Institute 2016 All rights reserved. No part of this publication may be reproduced or utilized in any form or by any means electronic, mechanical and photocopying or any other data carrier without prior permission! E-Mail: publishing@austrian-standards.at Internet: www.austrian-standards.at/terms-of-use Sale and distribution of national and foreign standards and technical regulations via Austrian Standards plus GmbH Heinestraße 38, 1020 Wien E-Mail: sales@austrian-standards.at Internet: www.austrian-standards.at Webshop: www.austrian-standards.at/webshop Tel.: +43 1 213 00-300 Fax: +43 1 213 00-818 Note: Because of possible comments, the final version of this ÖNORM can differ from the present Draft. Please send your comments (in writing) by 2016-04-15 to Austrian Standards Institute. ICS 13.040.40 Identical (IDT) with FprEN 19694-4:2016-02 responsible Committee 139 Air quality

DRAFT ÖNORM EN 19694-4:2016-03 Explanations concerning Draft The present Draft European Standard EN 19694-4 has been submitted to CEN members for voting. In case of a positive result of the voting as required by CEN/CENELEC regulations, this Draft will be published as EN. Like all member organizations of CEN, Austrian Standards Institute is basically obliged to implement European Standards in Austria and to withdraw conflicting standards. Austrian Standards Institute herewith submits this Draft of a European Standard as Draft ÖNORM to public enquiry and information. Comments on this Draft Please find below some practical instructions intended to offer you and the responsible committee assistance for the processing of comments and proposals for modification: Form Structure Language Script/Format Dispatch Aspects concerning patent law For your comments/proposals for change, please use the relevant form available from Internet. Download under http://www.austrian-standards.at/comments/ or use the Draft Standard Portal http://www.austrian-standards.at/standards-draft-portal/ Please use a new line for each comment. This facilitates the attribution of the comments received to the different clauses and chapters of the respective Draft. Please formulate technical comments on European Standards if possible in English, since English is the common working language of the most European standardizing bodies. Editorial and/or linguistic proposals for change/improvement of German versions of European Standards shall (certainly) be submitted in German. Please use the script Arial with 9 pt font size. Please do not change the formats. Please send your comments by E-Mail to the responsible Committee Manager (j.nachbaur@austrian-standards.at) The recipients of this Draft ÖNORM are requested to add information on any patent rights known to their comments and to provide supporting documentation, if available. 2

EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM FINAL DRAFT FprEN 19694-4 February 2016 ICS 13.040.40 English Version Stationary source emissions - Determination of greenhouse gas (GHG) emissions in energy-intensive industries - Part 4: Aluminium industry Émissions de sources fixes - Détermination des émissions de gaz à effet de serre (GES) dans les industries énergo-intensives - Partie 4 : Industrie de l'aluminium Emissionen aus stationären Quellen - Bestimmung von Treibhausgasen (THG) aus energieintensiven Industrien - Teil 4: Aluminiumindustrie This draft European Standard is submitted to CEN members for formal vote. It has been drawn up by the Technical Committee CEN/TC 264. If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are aware and to provide supporting documentation. Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without notice and shall not be referred to as a European Standard. EUROPEAN COMMITTEE FOR STANDARDIZATION COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2016 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. FprEN 19694-4:2016 E

FprEN 19694-4:2016 (E) ÖNORM DRAFT Contents Page European foreword... 3 Introduction... 4 1 Scope... 5 2 Normative references... 5 3 Terms and definitions... 5 4 List of abbreviated terms... 5 5 Symbols, units and chemical formulae... 6 5.1 Symbols and units... 6 5.2 Chemical formulae... 7 6 Calculation methods General remarks... 8 6.1 Introduction... 8 6.2 Calculation methods for process GHG emissions from primary aluminium production... 8 6.3 Sources of carbon dioxide... 9 6.4 Sources of PFC... 9 7 Methods for calculation of process carbon dioxide emissions... 10 7.1 General... 10 7.2 Tier 1 Method using process specific equations with technology typical parameters for carbon dioxide emissions... 10 7.3 Tier 2 Method using process specific equations with facility specific parameters for carbon dioxide emissions... 10 7.4 Calculation of carbon dioxide emissions from prebake processes... 10 7.5 Baking furnace carbon dioxide emissions... 12 7.6 Calculation of carbon dioxide emissions from the Søderberg process... 16 8 Methods for calculation of PFC emissions... 17 8.1 Introduction... 17 8.2 Tier 1 method for calculating PFC emissions... 18 8.3 Tier 2 method for calculating PFC emissions... 19 8.4 Calculation of PFC emissions from aluminium reduction processes... 19 8.5 Verification of GHG calculation... 21 9 Key performance indicators... 22 Bibliography... 23 2

ÖNORM DRAFT FprEN 19694-4:2016 (E) European foreword This document (FprEN 19694-4:2016) has been prepared by Technical Committee CEN/TC 264 Air quality, the secretariat of which is held by DIN. This document is currently submitted to the Formal Vote. This document has been prepared under a mandate M/478 given to CEN by the European Commission and the European Free Trade Association. FprEN 19694, Stationary source emissions Determination of greenhouse gas (GHG) emissions in energy-intensive industries is a series of standards that consists of the following parts: Part 1: General aspects Part 2: Iron and steel industry Part 3: Cement industry Part 4: Aluminium industry Part 5: Lime industry Part 6: Ferroalloy industry 3

FprEN 19694-4:2016 (E) ÖNORM DRAFT Introduction This European Standard serves the following purposes: measuring, testing and quantifying GHG emissions from the aluminium industry; assessing the level of GHG emissions performance of production processes over time, at production sites; establishing and providing reliable, accurate and quality information for reporting and verification purposes. This European Standard can be used to measure, report and compare the GHG emissions of an aluminium production facility. Data for individual facilities, sites or works may be combined to measure, report and compare GHG emissions for a company, corporation or group. Direct fuel based emissions are not included; for calculation of this part of the GHG emissions, see FprEN 19694 1. The European Standard deals with sector-specific aspects for the determination of greenhouse gas (GHG) emissions from aluminium production and is based on documents mentioned under tier 3 of Section 4.4.2.4 of the 2006 IPCC guidelines [6]. 4

ÖNORM DRAFT FprEN 19694-4:2016 (E) 1 Scope This European Standard specifies a harmonized method for calculating the emissions of greenhouse gases from the electrolysis section of primary aluminium smelters and aluminium anode baking plants. It also specifies key performance indicators for the purpose of benchmarking of aluminium. This also defines the boundaries. NOTE Other requirements and other EU Directives may be applicable to the product(s) falling within the scope of this standard. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. FprEN 19694-1, Stationary source emissions - Determination of greenhouse gas (GHG) emissions in energy-intensive industries - Part 1: General aspects 3 Terms and definitions For the purposes of this document, the terms and definitions given in FprEN 19694-1 and the following apply. 3.1 aluminium electrolysis section of an aluminium primary smelter where aluminium is converted from aluminium oxide to aluminium metal in electrolysis cells 3.2 anode baking plant production of carbon anodes for use in aluminium prebake electrolysis cells 3.3 PFC gases gas emitted from aluminium electrolysis consisting of CF 4 and C 2F 6 3.4 grid specific CO 2 factor CO 2 factor (t CO 2/MWh) associated with the electricity delivered to a specific aluminium smelter from their supplier 4 List of abbreviated terms AE CWPB DAE DEE GHG HSS Anode effect Centre-Worked prebake Direct anode emissions Direct electrolysis emissions Green House Gas Horizontal Stud Søderberg 5