SAFETY DATA SHEET For Coatings, Resins, and Related Materials Complies with U.S. Department of Labor Occupational Safety and Health Administration For OSHA Hazard Communication Standard Specific Requirements Consult: 29 CFR 1910.1200 Address: The TryLine Group Date of Creation: June 23, 1998 365 118 th Avenue SE, Suite 100 Date of Revision: January 7th 2014 Bellevue, WA 98005 SECTION I - PRODUCT IDENTIFICATION Product Identification: Emergency Information: Product Name Titanium Dioxide (R255Z,R245PC,R245CC/HG/HD Information Phone: 425-450-8822 Chemical Family: Non-Ferrous Inorganic Pigment Chemtrec Phone: 800-424-9300 CAS Number: 13463-67-7 Formula: TiO2 TSCA Status: In Compliance Potential Health Effects SECTION II - HAZARDOUS IDENTIFICATION Skin Eyes Inhalation : Repeated exposure may cause skin dryness or cracking : May cause: mechanical irritation with tearing, pain or visual impairment : May cause nose, throat, and lung irritation. Carcinogenicity Material IARC NTP OSHA Titanium Dioxide 2B 1
SECTION III COMPOSITION/INFORMATION ON INGREDIENTS Boiling Point: N/A Specific Gravity: 4.10 Vapor Pressure: N/A Melting Point: N/A Vapor Density: N/A Evaporatio n Rate: N/A Appearance & Odor: Very Fine Brilliant White and Odorless Powder Component CAS-No. Concentration Titanium Dioxide 13463-67-7 80 98 % Aluminum hydroxide 21645-51-2 0 9 % Silicon dioxide, amorphous 7631-86-9 0 11 % SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flammability Classification OSHA: N/A Flash Point: Non-Flammable DOT: N/A LEL: N/A UEL: N/A Extinguishing Media: [ ] Foam [ ] Alcohol Foam [ ] CO 2 [ ] Dry Chemical [ ] Water Fog [ ] Other [X] Any Unusual Fire and Explosion Hazards: N/A Special Fire Fighting Procedures: N/A SECTION V -HEALTH HAZARD DATA Health Hazards (Acute and Chronic): Acute: No applicable information found concerning any adverse acute health effects from overexposure to product. Chronic: Inhalation of airborne particles may cause transient irritation in mouth, nose and throat. Signs and Symptoms of Exposure: N/A Medical Conditions Generally Aggravated by Exposure: N/A Emergency and First Aid Procedures: Eye Contact -Flush thoroughly with water. Inhalation -Remove to fresh air. Skin Contact -Wash thoroughly with soap or mild detergent, and water. Ingestion -If conscious, give large quantities of water to induce vomiting, and call a physician. 2
SECTION VI REACTIVITY DATA Stability: [ ] Unstable [X] Stable Conditions to Avoid: None in normal use. Incompatibility: None Reported. Hazardous Decomposition Products: N/A Hazardous Polymerization: [ ] May occur [X] Will not occur SECTION VII - SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Material will be blown away as dust. Prevent spread of material and keep dust level down. Scoop up material or use vacuum technique. Those involved in the clean-up should use respiratory protection. Waste Disposal Methods: As with other pigment powders, disposal must be made in accordance with Federal, State and local regulations. SECTION VIII - PRECAUTIONS FOR SAFE HANDLING AND USE Respiratory Protection: Wear NIOSH approved dust respirator. Ventilation: Provide local exhaust ventilation system to meet TLV requirements. Protective Gloves: Wear Gloves to minimize contact. Eye Protection: Goggles advisable against dust. Hygienic Practices: Wash thoroughly with soap and water before eating, drinking or using SECTION IX - SPECIAL PRECAUTIONS -Avoid contact with water or strong acids; -Keep storage area dry; -Use ventilation to keep dust level down -Use a personal respirator if dust cannot be controlled; Store away from heat - Use good hygienic practice SECTION X STABILITY AND REACTIVITY Stability Incompatibility : Stable : None 3
SECTION XI- TOXICOLOGICAL INFORMATION Inhalation 4 h ALC : > 6.82 mg/l, rat Dermal ALD Oral ALD Skin irritation Eye irritation Sensitization : > 10,000 mg/kg, rabbit : > 24,000 mg/kg, rat : slight irritation : slight irritation : Did not cause sensitization on laboratory animals. SECTION XII ECOLOGICAL INFORMATION Aquatic Toxicity Titanium Dixode Pigment Pain Coatings Dry Grades 96 h LC50 : Fathead minnow > 1,000 mg/l SECTION XIII Waste Disposal : Dispose of in accordance with local regulations. SECTION XIII DISPOSAL CONSIDERATION Waste Disposal : Dispose of in accordance with local regulations. SECTION XIV TRANSPORT INFORMATION Not regulated in transportation by DOT/IMO/IATA 4
SECTION XV-REGULATORY INFORMATION EINECS Status TSCA Status AICS Status DSL Status ENCS ( JP) Status KECI ( KR) Status PICCS (PH ) Status INV ( CN) Status NZ HSNO Status : Exempt SARA 313 : This material does not contain any chemical components with Regulated known CAS numbers that exceed the threshold ( De Minimis) Chemical (s) reporting levels established by SARA Title III, Section 313. California Prop. 65 : Chemicals known to the State of California to cause cancer, birth defects or any other harm; none known PA Right to Know : Substances on the Pennsylvania Hazardous Substances List Regulated present at a concentration of 1 % or more ( 0.01 % for Special Chemical (s) Hazardous Substances ) : Titanium Dioxide, Silicon dioxide, amorphous NJ Right to Know Substance Regulated substances Chemical (s) : Substances on the New Jersey Workplace Hazardous List present at concentration of 1% or more ( 0.1% for identified as carcinogens, mutagens or teratogens); Titanium Dioxide, Silicon dioxide, amorphous 5
SECTION XVI-OTHER INFORMATION HMIS Health : 1 Flammability : 0 Reactivity/Physical hazard : 0 PPE : Personal Protection rating to be supplied by user depending on use conditions Restriction for use : TiO2 products may not be directly added to food or pharmaceuticals and are not recommended for use in medical devices or cosmetics. Keep out of Reach of Children The information contained herein is based on the data available to us and is believed to be accurate. However, The TryLine Group makes no warranty, express or implied, regarding the accuracy of this data or the results to be obtained from the use thereof. TheTryLine Group assumes no responsibility for the injury from the use of the product described herein. 6