SAFETY DATA SHEET Date of issue: 05.01.2009 O Done in accordance with Regulation (EC) No 1907/2006 European Parliament and of the Council of 18 December 2007 concerning Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing European Chemicals Agency, amending directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directives 76/769/EEC and Commission Regulation 91/155/EEC, 93/67/EEC, 93/105/EC and 200/21/, ECRegulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1. Identification of product Decrust B- NanoClean Krustenfix 1.2. Use of product Surfactant: Degreasing and Submigrating Agent 1.3. Company FLUOROCHEMIKA Poland Sp. z o.o. ul. Kwiatkowskiego 8, 33-101 Tarnów tel: +48 14 637 25 25 Plant Kędzierzyn-Koźle ul. Energetyków 9, 47 225 Kędzierzyn-Koźle Katarzyna Janiec Tel/fax: + 48 77 487 37 51/+ 48 668 397 230 e-mail: katarzyna.janiec@fluorochemika.pl 1.4. Emergency phone + 48 668 397 230 2. HAZARD IDENTIFICATION 2.1. Classification Irritating ; X i 2.2. Risk phrases R36/38 Irritating to eyes and skin. 3. COMPOSITION AND INFORMATION ON INGREDIENTS Substance No EC No CAS Classification % by weight 2,2',2''- nitrilotriethanol 203-049-8 102-71-6 X i ; R36/37/38 5-25 2-(2- butoxyethoxy)ethanol 203-961-6 112-34-5 Xi; R36 5-25 Fluorokanol FLC 327 ; Ethanol, 2-(2- ethoxyethoxy)-, 2''- [(C12-15-branched and linear alkyl)oxy] derivs., hydrogen sulfates, sodium salts 293-918-8 91648-56-5 X i ; R 36/38 5-25 Page 1 / 5
4. FIRST AID MEASURES 4.1. Skin contact Flush skin with plenty of water. Remove contaminated clothes. 4.2. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. 4.3. Inhalation Immediately remove affected person to fresh air. 4.4. Ingestion Call a physician. 5. FIRE FIGHTING MEASURES 5.1. Products of combustion The product is non-combustible. Vapours are heavier than air. 5.2. Extinguishing media Use water spray, carbon dioxide, foam, dry chemicals for extinguishing. 5.3. Special protective equipment for fire-fighters Wear self-contained breathing apparatus. Wear full protective equipment. 6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions Use proper protective equipment as indicated in Section 8. 6.2. Environmental precautions Material is biodegradable. 6.3. Methods for cleaning up Soak up non solidified material with absorbent materials: sand, sawdust, dry oil. Sweep or scoop up and place in container for disposal. After solidification: scoop up and place in container for disposal. Flush spill area with water. Material is biodegradable. 7. HANDLING AND STORAGE 7.1. Handling Avoid contact with eyes, skin and clothing. Rinse thoroughly after handling. Do not inhale vapours. Do not spray directly on the food. 7.2. Storage Store in the drums tightly closed. Store at room temperature in well ventilated, dry storage room. Page 2 / 5
8. EXSPOSURE CONTROLS / PERSONAL PROTECTION 8.1. Engineering controls Workplace should be equipped with safety shower and eye bath. 8.2. Hand protection Chemical - resistant gloves (CE). 8.3. Eye protection Chemical safety goggles or glasses. 8.4. Skin protection Apron, pants and jacket. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. Physical state Viscous liquid 9.2. Colour Colourless to yellowish 9.3. Odour Slightly orange 9.4. ph 12 9.5. Flash point Does not ignite 9.6. Specific gravity 1.00 g/cm 3 9.7. Solubility in water Soluble 9.8. % volatiles None 10. TOXICOLOGICAL INFORMATION 10.1. Toxicological information LD 50 > 2000 mg/kg. 10.2. Contact with skin Severe skin irritant. 10.3. Contact with eyes Severe eyes irritant. 10.4. Certificate Certificate of Health Quality No HŻ/0018/01/2007 released by National Institute of Hygiene in Warsaw. 11. ECOLOGICAL INFORMATION 11.1. Biodegradation Biodegradable in accordance with Council Directive 67/548/EEC. GLP: yes Page 3 / 5
12. DISPOSAL CONSIDERATIONS 12.1. Waste disposal Decrust B is biodegradable. Product and waste water should be charged after cleaning operation into biological waste water treatment unit. Observing of all federal, state and local environmental regulations required. 12.2. Polluted packaging After cleaning, empty drums may be used for other materials. 13. TRANSPORT INFORMATION 13.1. Road: ADR/RID Non-hazardous for road transport. 13.2. Sea: IMDG Non-hazardous for sea transport. 13.3. Air: ICAO/IATA Non-hazardous for air transport. 14. REGULATORY INFORMATION 14.1. Label Decrust B /NanoClean Krustenfix 14.2. Hazard symbols Irritant; X i 14.3. R-phrases R36/38 Irritating to eyes and skin 14.4. S-phrases S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S28 After contact with skin, wash immediately with plenty of water S37/39 Wear suitable gloves and eye protection 14.5. Regulations Regulation (EC) No 1907/2006 European Parliament and of the Council of 18 December 2007 concerning Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing European Chemicals Agency, amending directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directives 76/769/EEC and Commission Regulation 91/155/EEC, 93/67/EEC, 93/105/EC and 200/21/EC Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substance Directive 1999/45/EC of the European Parliament and of the Council of 31 May 1999 concerning the approximation of the laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 Page 4 / 5
December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Transport Regulations: ADR/RID; IMDG; ICAO/IATA. 15. OTHER INFORMATION 15.1. R-phrases from section 2. R36/37/38 Irritating to eyes, respiratory system and skin R36 Irritating to eyes R36/38 Irritating to eyes and skin The statements are based on the current status of our information; they are meant to describe the products with regard to safety requirements and consequently do not have the significance of guaranteeing certain characteristics. Page 5 / 5