This SDS adheres to the standards and regulatory requirements of Great Britain and may not meet the regulatory requirements in other countries.

Transcription

1 This SDS adheres to the standards and regulatory requirements of Great Britain and may not meet the regulatory requirements in other countries. 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product information Product name Use of the Substance/Preparation : : Cleaning agent Company : Du Pont de Nemours (Nederland) B.V. Baanhoekweg 22 NL-3313 LA Dordrecht The Netherlands Telephone : Emergency telephone : +44-(0) address : sds-support@che.dupont.com 2. HAZARDS IDENTIFICATION Harmful by inhalation. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Can become highly flammable in use. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. EC-No. Classification Concentration [%] (E)-1,2-Dichloroethylene F; R11 Xn; R20 R52/53 >= 65 - <= 90 1,1,1,2,2,3,4,5,5,5-Decafluoropentane R52/53 >= 5 - <= 25 1,1,2,2,3,3,4-Heptafluorocyclopentane R52/53 >= 5 - <= 15 For the full text of the R phrases mentioned in this Section, see Section FIRST AID MEASURES General advice Inhalation : Never give anything by mouth to an unconscious person. Victim to lie down in the recovery position, cover and keep him warm. If breathing is irregular or stopped, administer artificial respiration. : Move to fresh air. Keep patient warm and at rest. Artificial respiration and/or oxygen may be necessary. 1/6

2 Skin contact Eye contact Ingestion Notes to physician Treatment : Wash off with warm water. Take off all contaminated clothing immediately. : Rinse thoroughly with plenty of water, also under the eyelids. Consult a physician. : Do not induce vomiting without medical advice. Drink 1 or 2 glasses of water. Consult a physician. : Do not give adrenaline or similar drugs. 5. FIRE-FIGHTING MEASURES Specific hazards during fire fighting Special protective equipment for fire-fighters Further information : Fire or intense heat may cause violent rupture of packages. : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Cool containers / tanks with water spray. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for cleaning up : Evacuate personnel to safe areas. Ventilate the area. Refer to protective measures listed in sections 7 and 8. : Prevent further leakage or spillage. Prevent spreading over a wide area (e.g. by containment or oil barriers). Should not be released into the environment. : Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). 7. HANDLING AND STORAGE Handling Advice on safe handling Advice on protection against fire and explosion : Provide sufficient air exchange and/or exhaust in work rooms. For personal protection see section 8. Avoid contact with skin, eyes and clothing. : Avoid any dust buildup with fluorocarbons and metal mixtures. Storage Requirements for storage areas and containers Advice on common storage : Keep container tightly closed in a dry and well-ventilated place. Store in original container. : No materials to be especially mentioned. 2/6

3 German storage class : 12 : Non Combustible Liquids 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Type Form of exposure Control parameters (E)-1, TWA 806 mg/m3 Dichloroethylene 200 ppm Update Basis 2002 EH40 OES STEL mg/m3 250 ppm 2002 EH40 OES TWA 806 mg/m3 200 ppm 2005 EH40 WEL STEL mg/m3 250 ppm 2005 EH40 WEL Engineering measures Ensure adequate ventilation, especially in confined areas. Personal protective equipment Respiratory protection : For rescue and maintenance work in storage tanks use self-contained breathing apparatus. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Hand protection : Material: Hydrofluoric acid-resistant and solvent-resistant gloves (gloves made of VITON ). Glove thickness: 0,7 mm Wearing time: 2 h Eye protection Skin and body protection Hygiene measures : Safety glasses : Protective suit : Handle in accordance with good industrial hygiene and safety practice. When using do not eat, drink or smoke. Do not breathe vapours or spray mist. Avoid contact with skin, eyes and clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : liquid, 3/6

4 Colour : clear, colourless, Odour : slight, pleasant, Flash point Flash point Lower explosion limit Upper explosion limit :, Method: Pensky-Martens closed cup - PMCC does not flash, No flash point was obtained, but the product may release flammable vapour. :, Method: Tag open cup - TOC does not flash : 7 %(V) : 14 %(V) 10. STABILITY AND REACTIVITY Conditions to avoid Materials to avoid Hazardous decomposition products Hazardous reactions : The product is not flammable in air under ambient conditions of temperature and pressure. When pressurised with air or oxygen the mixture may become flammable. Certain mixtures of HCFCs or HFCs with chlorine may become flammable or reactive under certain conditions. : Alkali metals, Alkaline earth metals, Powdered metals, Powdered metal salts : Fluorinated hydrocarbons, Hydrogen fluoride, Carbon dioxide (CO2), Carbon monoxide : No decomposition if stored and applied as directed. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity Acute inhalation toxicity : LD50/ rat : 770 mg/kg : LD50/ rat : > mg/kg : LC50/ 8 h/ rat : 104,3 mg/l Acute dermal toxicity : LC50/ 4 h/ rat : 114 mg/l : LD50/ rabbit : > mg/kg Skin irritation : No skin irritation Repeated or prolonged contact with the product may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and skin absorption. Eye irritation : No eye irritation Sensitisation : Did not cause sensitization on laboratory animals. 4/6

5 Mutagenicity assessment : Not mutagenic in Ames Test. 12. ECOLOGICAL INFORMATION Toxicity to fish : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. : LC50 / 96 h/ Zebra fish : 13 mg/l Toxicity to algae : / EC50/ 72 h/ Algae: > 120 mg/l Aquatic toxicity : / EC50/ 24 h/ Daphnia: 62,0 mg/l 13. DISPOSAL CONSIDERATIONS Product Contaminated packaging : Can be used after re-conditioning. If recycling is not practicable, dispose of in compliance with local regulations. The product should not be allowed to enter drains, water courses or the soil. : If recycling is not practicable, dispose of in compliance with local regulations. 14. TRANSPORT INFORMATION Further information : Not classified as dangerous in the meaning of transport regulations. 15. REGULATORY INFORMATION Labelling according to EC Directives Symbol(s) : Xn Harmful Hazardous components: (E)-1,2-Dichloroethylene R-phrase(s) : R20 Harmful by inhalation. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 5/6

6 S-phrase(s) : S 9 Keep container in a well-ventilated place. S16 Keep away from sources of ignition - No smoking. S33 Take precautionary measures against static discharges. S60 This material and its container must be disposed of as hazardous waste. Special labelling of certain preparations : Contains fluorinated greenhouse gas covered by the Kyoto Protocol. Can become highly flammable in use. 16. OTHER INFORMATION Text of R phrases mentioned in Section 3 R11 Highly flammable. R20 Harmful by inhalation. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Further information Before use read DuPont's safety information., For further information contact the local DuPont office or DuPont's nominated distributors., DuPont's registered trademark Significant change from previous version is denoted with a double bar. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The above information relates only to the specific material(s) designated herein and may not be valid for such material(s) used in combination with any other materials or in any process or if the material is altered or processed, unless specified in the text. 6/6