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Transcription:

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable Recommended use : All Purpose Cleaner Restrictions on use : Reserved for industrial and professional use. Product dilution information : Product is sold ready to use. Company : Ecolab Inc. 370 N. Wabasha Street St. Paul, Minnesota USA 55102 1-800-352-5326 Emergency health information : 1-800-328-0026 (US/Canada), 1-651-222-5352 (outside US) Issuing date : 02/16/2016 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Not a hazardous substance or mixture. GHS label elements Precautionary Statements Other hazards : Prevention: Wash hands thoroughly after handling. Intentional misuse by deliberate inhalation may be harmful or fatal. Response: Get medical advice/ attention if you feel unwell. Storage: Store in accordance with local regulations. : None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical name CAS-No. Concentration (%) GLYCOLS -Glycolethers 1569-01-3 1-5 Aliphatic hydrocarbons 106-97-8 1-5 propane 74-98-6 1-5 SECTION 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed If inhaled : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. 942664 1 / 8

Protection of first-aiders Notes to physician Most important symptoms and effects, both acute and delayed : No special precautions are necessary for first aid responders. : No specific measures identified. : See Section 11 for more detailed information on health effects and symptoms. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during fire fighting Hazardous combustion products Special protective equipment for fire-fighters Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : None known. : Fire Hazard Keep away from heat and sources of ignition. Flash back possible over considerable distance. Pressurised container: May burst if heated. : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus : Use personal protective equipment. : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Remove all sources of ignition. Refer to protective measures listed in sections 7 and 8. : No special environmental precautions required. : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. SECTION 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage : Keep away from fire, sparks and heated surfaces. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Contents under pressure. Do not puncture. : Keep away from heat and sources of ignition. Keep away from oxidizing agents. Keep out of reach of children. Store in suitable labeled containers. Storage temperature : 5 C to 45 C 942664 2 / 8

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Form of exposure Permissible concentration Basis Aliphatic hydrocarbons 106-97-8 TWA 800 ppm NIOSH REL 1,900 mg/m3 STEL 1,000 ppm ACGIH propane 74-98-6 TWA 1,000 ppm NIOSH REL 1,800 mg/m3 TWA 1,000 ppm 1,800 mg/m3 OSHA Z1 Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures : No special protective equipment required. : No special protective equipment required. : No special protective equipment required. : No personal respiratory protective equipment normally required. : Wash hands before breaks and immediately after handling the product. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Color Odor : aerosol : clear, colorless : ammoniacal ph : 10.0-11.4, 100 % Flash point Odor Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapor pressure Relative vapor density : -104 C, Sustains combustion Relative density : 0.977-0.98 Water solubility Solubility in other solvents 942664 3 / 8

Partition coefficient: n- octanol/water Autoignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC Heat of combustion : 1.74 kj/g SECTION 10. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : No dangerous reaction known under conditions of normal use. : Heat, flames and sparks. : None known. : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Eye contact, Skin contact Potential Health Effects Eyes Skin Ingestion Inhalation Chronic Exposure Intentional misuse by deliberate inhalation may be harmful or fatal. Experience with human exposure Eye contact Skin contact Ingestion : No symptoms known or expected. : No symptoms known or expected. : No symptoms known or expected. 942664 4 / 8

Inhalation : No symptoms known or expected. Toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT-single exposure STOT-repeated exposure Aspiration toxicity Ingredients Acute inhalation toxicity : Acute toxicity estimate : > 5,000 mg/kg : Acute toxicity estimate : > 5,000 mg/kg : GLYCOLS -Glycolethers 4 h LC50 Rat: > 10.21 mg/l Aliphatic hydrocarbons 4 h LC50 Rat: 280000 ppm SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Ingredients Toxicity to fish : Harmful to aquatic life. : GLYCOLS -Glycolethers 96 h LC50 Fish: > 100 mg/l Aliphatic hydrocarbons 96 h LC50 Fish: 22.03 mg/l Persistence and degradability No data available Bioaccumulative potential 942664 5 / 8

No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations : The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. Dispose of in accordance with local, state, and federal regulations. SECTION 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) UN number : 1950 Description of the goods : Aerosols Class : 2.1 Environmentally hazardous : no Sea transport (IMDG/IMO) UN number : 1950 Description of the goods : AEROSOLS Class : 2.1 Marine pollutant : no SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity Ingredients CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Ammonia 7664-41-7 100 20833 SARA 304 Extremely Hazardous Substances Reportable Quantity Ingredients CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Ammonia 7664-41-7 100 20833 SARA 311/312 Hazards : No SARA Hazards 942664 6 / 8

SARA 302 : The following components are subject to reporting levels established by SARA Title III, Section 302: Ammonia 7664-41-7 0.48 % SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL Australia Inventory of Chemical Substances (AICS) : New Zealand. Inventory of Chemical Substances : Japan. ENCS - Existing and New Chemical Substances Inventory : Japan. ISHL - Inventory of Chemical Substances (METI) : Korea. Korean Existing Chemicals Inventory (KECI) : Philippines Inventory of Chemicals and Chemical Substances (PICCS) : China. Inventory of Existing Chemical Substances in China (IECSC) : SECTION 16. OTHER INFORMATION 942664 7 / 8

Health Instability SAFETY DATA SHEET NFPA: Flammability HMIS III: 1 0 HEALTH 0 FLAMMABILITY PHYSICAL HAZARD 1 0 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Issuing date : 02/16/2016 Version : 1.1 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 942664 8 / 8