1. Product name Material Safety Data Sheet Product and company identification Supplier/Manufacturer VANLUBE SL Vanderbilt Chemicals, LLC 30 Winfield Street Norwalk, CT 06855 Canada English In case of emergency +12038531400 Chemtrec: 18004249300 Outside US: +17035273887 Chemical name Synonym Material uses Code 2. Physical state Color Odor Emergency overview Mixture of alkylated diphenylamines Lubricant additives 51008 Hazards identification Routes of entry 3. Liquid. Amber. Aminelike. [Slight] WARNING! MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION. Contains material which may cause damage to the following organs: blood, kidneys, the reproductive system, liver, bladder, cardiovascular system, upper respiratory tract, skin, eye, lens or cornea. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Dermal contact. Eye contact. Inhalation. Ingestion. See toxicological information (Section 11) Composition/information on ingredients Name CAS number % by weight benzenamine, Nphenyl, reaction products with styrene and 2,4,4trimethylpentene 68921459 >98 diphenylamine 122394 <2 4. Eye contact Skin contact Inhalation First aid measures Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. 1/7
4. Ingestion First aid measures Protection of firstaiders Notes to physician Medical conditions aggravated by overexposure 5. Firefighting measures Flammability of the product Extinguishing media Suitable Not suitable Special exposure hazards Hazardous thermal decomposition products Special protective equipment for firefighters 6. Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouthtomouth resuscitation. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Preexisting disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by overexposure to this product. In a fire or if heated, a pressure increase will occur and the container may burst. In case of fire, use water spray (fog), foam, dry chemical or CO₂. Do not use water jet. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides Firefighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full facepiece operated in positive pressure mode. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up Small spill Large spill No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if watersoluble. Alternatively, or if waterinsoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 2/7
7. Handling Storage 8. Handling and storage Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Do not store below the following temperature: 22 C (71.6 F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Exposure controls/personal protection Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations diphenylamine US ACGIH 6/2013 10 AB 4/2009 10 BC 7/2013 10 ON 1/2013 10 QC 12/2012 10 Recommended monitoring procedures Engineering measures Hygiene measures Personal protection Respiratory Hands If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Use a properly fitted, airpurifying or airfed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended: Vapor and dust respirator. Chemicalresistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Recommended: Protective gloves should be worn under normal conditions of use. 3/7
8. Eyes Skin Exposure controls/personal protection Environmental exposure controls Personal protective equipment (Pictograms) Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Recommended: splash goggles Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: lab coat Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 9. Physical and chemical properties Physical state Color Odor Melting point Boiling point Flash point Density Relative density Solubility Viscosity Physical/chemical properties comments Liquid. Amber. Aminelike. [Slight] 7 C (44.6 F) >198 C (>388.4 F) Closed cup: 176 C (348.8 F) [PenskyMartens.] Open cup: 210 C (410 F) [Cleveland.] 1.01 g/cm³ [15.6 C (60.1 F)] 0.99 Insoluble in the following materials: cold water. Kinematic (room temperature): 0.1144 cm 2 /s (11.44 cst) [at 25 C] Very soluble in alcohol and toluene. 10. Stability and reactivity Chemical stability Possibility of hazardous reactions Hazardous polymerization Conditions to avoid Materials to avoid Hazardous decomposition products Incompatibility with various substances The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous polymerization will not occur. No specific data. No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Reactive or incompatible with the following materials: oxidizing materials. 4/7
11. Toxicological information Acute toxicity Product/ingredient name Result Species Dose Exposure diphenylamine LD50 Dermal Rabbit >5000 mg/kg LD50 Oral Rat 1165 mg/kg Product contains diphenylamine which may contribute to irritation. Diphenylamine may be absorbed through the skin in toxic amounts. Diphenylamine may cause methemoglobinemia and red blood cell damage. Chronic toxicity Irritation/Corrosion Skin Sensitizer Skin Carcinogenicity Mutagenicity Teratogenicity Reproductive toxicity Benzenamine, Nphenyl, reaction products with styrene and 2,4,4trimethylpentene: Nonirritating to the skin. Benzenamine, Nphenyl, reaction products with styrene and 2,4,4trimethylpentene: Not a sensitizer. Product contains diphenylamine which may contribute to irritation. Diphenylamine may be absorbed through the skin in toxic amounts. Diphenylamine may cause methemoglobinemia and red blood cell damage. Classification Product/ingredient name ACGIH IARC EPA NIOSH NTP OSHA diphenylamine A4 Other information 12. Ecological information Environmental effects No known significant effects or critical hazards. Aquatic ecotoxicity Product/ingredient name Test Result Species Exposure diphenylamine Acute EC50 2.17 Algae 72 hours mg/l ISO Acute EC50 1.2 Daphnia 6 to 24 48 hours mg/l hours Chronic NOEC 0. Algae 72 hours 37 mg/l Benzenamine, Nphenyl, reaction products with styrene and 2,4,4trimethylpentene: Not readily biodegradable and due to low water solubility and low vapor pressure is not expected to partition to water or air if released into the environment. Biodegradability Other adverse effects No known significant effects or critical hazards. 5/7
13. Disposal considerations Waste disposal The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and nonrecyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations. 14. Regulatory information Transport information DOT Classification UN number Not Proper shipping name TDG Classification Not ADR/RID Class Not IMDG Class Not IATADGR Class Not PG* : Packing group 15. Regulatory information WHMIS (Canada) WHMIS (Canada) (Pictograms) Classes PG* Label Additional information Class D2A: Material causing other toxic effects (Very toxic). Canadian lists International regulations (for residual diphenylamine) CEPA Toxic substances: The following components are listed: Benzenamine, Nphenyl Canadian ARET: None of the components are listed. Canadian NPRI: The following components are listed: Diphenylamine Alberta Designated Substances: None of the components are listed. Ontario Designated Substances: None of the components are listed. Quebec Designated Substances: None of the components are listed. Canada inventory Benzenamine, Nphenyl, reaction products with styrene and 2,4,4trimethylpentene: Listed on Canadian Environmental Protection Act Schedule 1 List of Toxic Substances. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 6/7
15. Regulatory information International lists Europe inventory Australia inventory (AICS) China inventory (IECSC) Japan inventory Korea inventory New Zealand Inventory of Chemicals (NZIoC) Philippines inventory (PICCS) United States inventory (TSCA 8b) 16. Other information Hazardous Material Identification System (U.S.A.) Health Flammability Physical hazards Personal protection * Chronic Potential The customer is responsible for determining the PPE code for this material. * 1 1 0 National Fire Protection Association (U.S.A.) Health 1 1 0 Flammability Instability Special Validation date 9/11/2014. Print date 9/11/2014. Date of previous issue 5/14/2013. Information contact Vanderbilt Global Services, LLC Corporate Risk Management 12032952143 Indicates information that has changed from previously issued version. Visit www.vanderbiltchemicals.com for more information. Notice to reader Information presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of our knowledge and belief but is not guaranteed to be so. Nothing herein is to be construed as recommending any practice or any product in violation of any patent or in violation of any law or regulation. It is the user's responsibility to determine for himself the suitability of any material for a specific purpose and to adopt such safety precautions as may be necessary. We make no warranty as to the results to be obtained in using any material and, since conditions of use are not under our control, we must necessarily disclaim all liability with respect to the use of any material supplied by us. 7/7