Material Safety Data Sheet

Transcription

1 1. Product name Supplier/Manufacturer Material Safety Data Sheet Product and company identification MOLYVAN 856B Vanderbilt Chemicals, LLC 30 Winfield Street Norwalk, CT Canada English In case of emergency Chemtrec: Outside US: Chemical name Synonym Material uses Code 2. Physical state Color Emergency overview Organomolybdenum complex of organic amide. organomolybdenum complex Friction reducer Hazards identification Routes of entry 3. Liquid. Amber. CAUTION! MAY CAUSE EYE AND SKIN IRRITATION. Avoid contact with skin and eyes. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Dermal contact. Eye contact. Inhalation. Ingestion. See toxicological information (Section 11) Composition/information on ingredients Name CAS number % by weight monoglycerides and molybdenum oxide. petroleum process oil, <3.0% DMSO extractable material Eye contact Skin contact Inhalation Ingestion First aid measures Protection of first-aiders Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention if symptoms occur. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention if symptoms occur. Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms occur. Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur. No action shall be taken involving any personal risk or without suitable training. 1/8

2 4. First aid measures Notes to physician 5. Fire-fighting measures Flammability of the product Extinguishing media Suitable Not suitable Special exposure hazards Hazardous thermal decomposition products Special protective equipment for fire-fighters 6. Environmental precautions No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. In a fire or if heated, a pressure increase will occur and the container may burst. Use an extinguishing agent suitable for the surrounding fire. None known. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Accidental release measures Personal precautions Methods for cleaning up Small spill Large spill 7. Handling and storage No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment (see Section 8). Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Handling Storage Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. This product has a tendency upon standing to exhibit some crystallization or gelling. If this happens, the product may be re-liquified by agitation and heating at 40 to 50 C. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. 2/8

3 8. Exposure controls/personal protection Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations monoglycerides and molybdenum oxide., as Mo monoglycerides and molybdenum oxide. monoglycerides and molybdenum oxide., as Mo petroleum process oil, <3.0% DMSO extractable material US ACGIH 6/ [a] [b] AB 4/ [c] BC 7/ [d] BC 7/ [c] ON 1/ [a] ON 1/ [b] QC 12/ US ACGIH 6/ [a] US ACGIH AB 4/ [e] ON 1/ [f] QC 12/ [f] Form: [a]inhalable fraction [b]respirable fraction [c]respirable [d]inhalable [e]mist [f]mist Recommended monitoring procedures Engineering measures Hygiene measures Personal protection Respiratory Hands Eyes Skin If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended: Vapor and dust respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Recommended: Protective gloves should be worn under normal conditions of use. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields. Recommended: splash goggles Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: lab coat 3/8

4 8. Exposure controls/personal protection Environmental exposure controls Personal protective equipment (Pictograms) Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 9. Physical state Color Flash point Physical and chemical properties Flammability (solid, gas) Vapor pressure Density Relative density Solubility Viscosity Physical/chemical properties comments Liquid. Amber. Open cup: C (380.3 F) [Cleveland.] Slightly flammable in the presence of the following materials or conditions: open flames, sparks and static discharge. <0.093 kpa (<0.7 mm Hg) [room temperature] 0.98 g/cm³ [15.6 C (60.1 F)] 0.98 Insoluble in the following materials: cold water. Kinematic (room temperature): 7.96 cm 2 /s (796 cst) [at 25 C] Soluble in petroleum and synthetic lubricant bases. 10. Stability and reactivity Chemical stability Possibility of hazardous reactions Hazardous polymerization Conditions to avoid Materials to avoid Hazardous decomposition products Conditions of reactivity 11. The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous polymerization will not occur. No specific data. No specific data. Toxicological information Under normal conditions of storage and use, hazardous decomposition products should not be produced. Slightly flammable in the presence of the following materials or conditions: open flames, sparks and static discharge. Acute toxicity Product/ingredient name Result Species Dose Exposure LD50 Dermal Rabbit >2000 mg/kg - LD50 Oral Rat >5000 mg/kg - Chronic toxicity Product/ingredient name Result Species Dose Exposure 4/8

5 11. Toxicological information Sub-chronic NOAEL Oral Rat 150 mg/kg 28 days Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation Skin - Mild irritant Rabbit Eyes - Moderate Rabbit irritant Sensitizer Product/ingredient name Route of Species Result exposure skin Guinea pig Not sensitizing Carcinogenicity Mutagenicity Product/ingredient name Test Experiment Result OECD 471 Experiment: In vitro Negative Subject: Bacteria OECD 476 Experiment: In vitro Negative Subject: Mammalian- Animal OECD 473 Experiment: In vitro Subject: Mammalian- Human Negative Conclusion/Summary Teratogenicity Conclusion/Summary Reproductive toxicity Conclusion/Summary Other information 12. Not available. Not available. Reproductive toxicity (90 days Two generation): NOEL: 3000 ppm (F0). No NOEL could be established in F1. Reproductive toxicity/developmental toxicity (90 days Two generation): NOEL(F0 & F1): 6000 ppm Not available. Ecological information Environmental effects No known significant effects or critical hazards. Aquatic ecotoxicity Product/ingredient name Test Result Species Exposure 5/8

6 12. Ecological information OECD 203 Acute LC50 >10 mg/l Fish 96 hours OECD 202 Acute LC Daphnia 48 hours mg/l - NOEC 100 mg/l Micro-organism 28 days OECD 201 Acute LC Algae 72 hours mg/l OECD 202 Acute NOEC 1 Daphnia 48 hours mg/l OECD 201 Acute NOEC mg/l Algae 72 hours Biodegradability Product/ingredient name Test Result Dose Inoculum - 61 % - Readily - 28 days - - Conclusion/Summary Other adverse effects 13. Waste disposal Not available. Disposal considerations No known significant effects or critical hazards. The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations. 14. Regulatory information Transport information DOT Classification TDG Classification Not regulated. ADR/RID Class UN number Not regulated. Proper shipping name Classes PG* Label Additional information 3082 Environmentally hazardous substance, liquid, n.o.s. (Organomolybdenum complex) 9 III Remarks Marine pollutant - 6/8

7 14. IMDG Class Transport information 3082 Environmentally hazardous substance, liquid, n.o.s. (Organomolybdenum complex) 9 III Remarks Marine pollutant IATA-DGR Class 3082 Environmentally hazardous substance, liquid, n.o.s. (Organomolybdenum complex) 9 III Remarks Marine pollutant PG* : Packing group 15. Regulatory information WHMIS (Canada) WHMIS (Canada) (Pictograms) Not controlled under WHMIS (Canada). Canadian lists Canada inventory CEPA Toxic substances: None of the components are listed. Canadian ARET: None of the components are listed. Canadian NPRI: None of the components are listed. Alberta Designated Substances: None of the components are listed. Ontario Designated Substances: None of the components are listed. Quebec Designated Substances: None of the components are listed. All components are listed or exempted. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. International regulations International lists United States inventory (TSCA : All components are listed or exempted. 8b) Europe inventory: At least one component is not listed in EINECS but all such components are listed in ELINCS. Please contact your supplier for information on the inventory status of this material. Australia inventory (AICS): All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. Japan inventory: All components are listed or exempted. Korea inventory: All components are listed or exempted. Malaysia Inventory (EHS Register): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): Not determined. 7/8

8 15. Regulatory information EINECS: European Inventory. This product contains the following chemical(s) for which one or more Pre-Market Notifications have been filed. Should you wish to export products containing this product into an EC country, contact Product Risk Manager at Vanderbilt Global Services, LLC at for more information. Chemical name: CAS No.: Other information Hazardous Material Identification System (U.S.A.) Health Flammability Physical hazards Personal protection * Chronic Potential The customer is responsible for determining the PPE code for this material. National Fire Protection Association (U.S.A.) Health Flammability Instability Special Validation date 2/25/2014. Print date 2/25/2014. Date of previous issue 5/14/2013. Information contact Vanderbilt Global Services, LLC Corporate Risk Management Indicates information that has changed from previously issued version. Visit for more information. Notice to reader Information presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of our knowledge and belief but is not guaranteed to be so. Nothing herein is to be construed as recommending any practice or any product in violation of any patent or in violation of any law or regulation. It is the user's responsibility to determine for himself the suitability of any material for a specific purpose and to adopt such safety precautions as may be necessary. We make no warranty as to the results to be obtained in using any material and, since conditions of use are not under our control, we must necessarily disclaim all liability with respect to the use of any material supplied by us. 8/8